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WO2012168126A2 - Procédé de fabrication d'un produit d'hygiène cosmétique transparent - Google Patents

Procédé de fabrication d'un produit d'hygiène cosmétique transparent Download PDF

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Publication number
WO2012168126A2
WO2012168126A2 PCT/EP2012/060202 EP2012060202W WO2012168126A2 WO 2012168126 A2 WO2012168126 A2 WO 2012168126A2 EP 2012060202 W EP2012060202 W EP 2012060202W WO 2012168126 A2 WO2012168126 A2 WO 2012168126A2
Authority
WO
WIPO (PCT)
Prior art keywords
weight
alkyl
water
cosmetic
oligo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/060202
Other languages
German (de)
English (en)
Other versions
WO2012168126A3 (fr
Inventor
Kirsten Sartingen
Barbara Heide
Stefanie Schmitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO2012168126A2 publication Critical patent/WO2012168126A2/fr
Publication of WO2012168126A3 publication Critical patent/WO2012168126A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the invention is in the field of cosmetics and relates to a process for the preparation of a transparent cosmetic cleanser and a special natural cosmetic cleanser.
  • Cosmetic cleansers such as liquid soaps, shampoos, shower baths, bubble baths, shower gels and / or wash gels have long been known and are regularly adapted to the changing needs of consumers.
  • WO 2010/009978 a transparent care cleaning agent is disclosed which, in addition to water-insoluble components, contains a special mixture of ethoxylated emulsifiers.
  • the present invention has for its object to develop a process for the preparation of transparent cleaning agents that satisfy this consumer desire for natural cosmetic Satisfy compositions yet be able to achieve excellent cleaning and care benefits.
  • the present application is in a first embodiment, a method for producing a transparent cosmetic cleaning agent, comprising the following steps:
  • Suitable cosmetic carriers preferably contain at least 80% by weight of water.
  • the cosmetic carrier may contain from 0.001 to 20% by weight, preferably from 0.005 to 15% by weight, more preferably from 0.01 to 10% by weight and in particular from 0.05 to 5% by weight, of an alcohol selected may be ethanol, glycerine, sorbitol or mixtures of these
  • the cleaning agent obtainable by the process according to the invention is preferably a natural cosmetic (according to Ecocert standard).
  • Natural cosmetics are products which, subject to the exceptions mentioned later, are made exclusively of natural substances (ingredients of natural origin).
  • the surfactant mixture used in process step b) contains the following components A to D, based on the total weight of the surfactant mixture:
  • R is a linear or branched, saturated or unsaturated C 8 -C 2 alkyl radical and X is an alkali metal or ammonium cation
  • Preferred alkyl (oligo) glycosides A are derived from aldoses and / or ketoses having 6 carbon atoms, preferably glucose.
  • the index number x in the general formula RO- [G] x stands for the degree of oligomerization (DP), ie for the distribution of the mono- and oligoglycosides.
  • the index number x preferably has a value in the range of 1 to 6, particularly preferably in the range of 1 to 3, which may be an integer but not a whole number, which can be determined analytically.
  • Particularly preferred alkyl (oligo) glycosides A have a degree of oligomerization of between 1.2 and 1.5.
  • alkyl (oligo) glycosides A are known and commercially available from various suppliers under the INCI names Decyl Glucoside, Lauryl Glucoside and Coco Glucoside.
  • Preferred sulfosuccinic acid esters of the formula (I) are those in which the radical R is a linear or branched, saturated or unsaturated C 8 -C 18 -alkyl radical, preferably a C 10 - C 6 alkyl radical and in particular a C 2 -C 4 alkyl.
  • alkali salts of lauryl sulfosuccinate are particularly preferred.
  • Suitable polyols C are understood to mean the same polyols, which may also be constituents of the cosmetic carrier.
  • glycerin is a particularly preferred polyol of the surfactant mixture b).
  • surfactant mixtures b which - based on their total weight -
  • the surfactant mixture b) is prepared before carrying out the process according to the invention from the aforementioned constituents.
  • surfactant b An example of a commercially available surfactant b) which is suitable for use in the present process is obtainable from Cognis surfactant Plantapon ® PSC (INCI name: Coco Glucoside, Disodium Lauryl sulfosuccinates, Glycerin, Aqua).
  • Suitable water-insoluble components which can be used in the method according to the invention in premix c) are understood to mean all water-insoluble cosmetic active ingredients and / or active substance mixtures which are of botanical origin.
  • perfume oils and / or water-insoluble plant extracts which are at least 5% organic and can be prepared from the leaves, fruits, seeds and / or cores of the following plants: aloe vera, mango, apricot, peach, olives, ginseng , Ginger and / or argan.
  • water-insoluble components are difficult to stabilize in cleaning compositions without their Clarity (transparency) or other property of the cleaning compositions (eg the viscosity) is negatively changed.
  • the process according to the invention does not require a specific sequence in the mixing of the components a) to c). It is in principle possible to initially introduce a surfactant mixture b) in a suitable carrier a), and then to add the premix (s) c), which is different from b). It is likewise possible first of all to add the premix (s) c) other than b) and then the surfactant mixture b) to the cosmetic carrier a).
  • a previously described cosmetic carrier is initially introduced. Subsequently, all optional components (to be described later) and the surfactant mixture b) are incorporated into the carrier, it being preferred if all steps are carried out at room temperature by mixing (in particular by gentle stirring) of the respective component with the carrier.
  • premix (s) c) which preferably also takes place at room temperature by stirring the premix (s) c) in the carrier described above, if necessary, in a last process step, the pH and the viscosity of the cleaning agent adjusted to the respectively desired values.
  • the zwitterionic or amphoteric surfactants which are suitable for the preparation of the premix (s) c) are preferably selected from compounds of the following formulas (II) to (IV) in which the radical R is in each case straight-chain or branched, saturated or unsaturated polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms
  • Particularly preferred zwitterionic or amphoteric surfactants are the surfactants available commercially from various manufacturers under the INCI names coco-betaine, cocoampho (di) acetate and / or cocamidopropylbetaine.
  • amphoteric surfactant known by the INCI name cocamidopropyl betaine.
  • the premix c) contains, based on the total weight of the cosmetic cleaning agent, from 0.001 to 0.5% by weight of at least one water-insoluble component,
  • premix c) - based on the total weight of the cosmetic cleaning agent -
  • Disodium cocoamphodiacetate and / or cocamidopropyl betaine known amphoteric or zwitterionic surfactants Disodium cocoamphodiacetate and / or cocamidopropyl betaine known amphoteric or zwitterionic surfactants
  • premix c) - based on the total weight of the cosmetic cleaning agent - 0.1 to 0.3 wt .-% of at least one water-insoluble perfume
  • amphoteric surfactant known under the INCI name cocamidopropyl betaine
  • the premix c) contains - based on the total weight of the cosmetic cleaning agent - 0.0001 to 0.5 wt .-% of at least one water-insoluble component,
  • premix c) - based on the total weight of the cosmetic cleaning agent -
  • Disodium cocoamphodiacetate and / or cocamidopropyl betaine known amphoteric or zwitterionic surfactants Disodium cocoamphodiacetate and / or cocamidopropyl betaine known amphoteric or zwitterionic surfactants
  • premix c) - based on the total weight of the cosmetic cleaning agent -
  • amphoteric surfactant known by the INCI name cocamidopropyl betaine
  • two different premixes c) are prepared, which preferably correspond to the premixes of the second and third embodiments of the method according to the invention described above. Subsequently, these two premixes c) are mixed with the components a) and b) in the manner described above.
  • the subject of the present application is a cosmetic cleanser which is in a cosmetic carrier
  • At least one alkyl (oligo) glycoside at least one alkyl (oligo) glycoside
  • At least one further co-surfactant selected from amphoteric and / or zwitterionic surfactants and contains at least one water-insoluble component
  • the cosmetic cleaning agent - based on its total weight - consists of at least 80% by weight of ingredients which fulfill at least one of the following criteria:
  • the cosmetic cleaning agent is transparent.
  • Preferred cosmetic cleaning agents contain - based on the total weight of the cleaning agent -
  • alkyl (oligo) glycoside of the general formula RO- [G ] x , in which R is an alkyl and / or alkenyl radical having 8 to 18 C atoms,
  • G stands for a sugar residue with 5 or 6 C atoms and x stands for numbers from 1 to 10,
  • R is a linear or branched, saturated or unsaturated C 8 -C 2 alkyl radical and X is an alkali metal or ammonium cation
  • radical R is in each case a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms, and
  • At least one water-insoluble component selected from perfume oils and / or plant extracts.
  • the cleaning agent according to the invention preferably contains those substances which have already been defined in detail in earlier sections of this application.
  • a particularly suitable surfactant combination for the cleaning agents according to the invention preferably contains at least one of the alkyl (oligo) glycosides known under the INCI names Coco glucoside, decyl glucoside or lauryl glucoside and at least one of the INCI names coco-betaine, cocoampho (di) acetate or cocamidopropyl betaine known amphoteric surfactants.
  • the cosmetic cleaning agent may contain, in addition to the aforementioned surfactants and water-insoluble components, other optional ingredients, provided that the transparency of the cleaning agent is maintained and provided that at least 80% by weight of its total weight is composed of ingredients which are at least meet one of the aforementioned criteria.
  • Further preferred cosmetic cleansing agents are natural cosmetic cleansing agents.
  • Natural cosmetics are products that are manufactured exclusively from natural products (active ingredients of natural origin), subject to the following exceptions.
  • Natural substances are substances of botanical, inorganic-mineral or animal origin (except dead vertebrates) as well as their mixtures and reaction products among themselves. Only physical processes (including extraction) and pH adjusters are authorized for recovery and further processing. In addition, enzymatic and microbiological processes are permitted when only naturally occurring enzymes or microorganisms are used. The treatment of plant and animal raw materials as well as the end product with ionizing radiation is not permitted. Bleaching of natural products is permitted, but not using chlorine (sodium hypochlorite).
  • those natural fragrances that comply with ISO standard 9235 can be used. These include isolates of essential oils and reconstituted essential oils. Synthetic nature-identical fragrances and chemically modified natural fragrances must not be used in natural cosmetics.
  • the origin of the water used in natural cosmetics is arbitrary. In the calculation of the natural product content of the finished product, this is considered in any case only as a natural product, if it comes directly from a vegetable source (directly derived plant juices).
  • Natural preservatives may be used for the preservation of natural cosmetics [subject to the conditions set out in Annex VI (first part) of Directive 76/768 / EEC]. Moreover, nature-identical inorganic pigments and minerals can be used in natural cosmetics.
  • Natural cosmetics otherwise only natural materials may be used, which by chemical reaction starting from natural products such.
  • natural products such as fats, oils, botanical, inorganic-mineral or animal growth (except dead vertebrates), lecithins, mono-, oligo- and polysaccharides, proteins, lipoproteins can be obtained.
  • the following chemical reactions are permitted: hydrolysis (including saponification), Neutralization, condensation with elimination of water, esterification, transesterification, hydrogenation, hydrogenolysis, dehydrogenation, glycosylation, phosphorylation, sulfation, acylation, amidation, oxidation (with oxygen, ozone and peroxides) and pyrolysis.
  • Near-natural substances also include other substances which, although they occur naturally, can not be obtained from their natural sources in sufficient quantities according to the respective state of the art.
  • cosmetic cleansing compositions which, based on their total weight, comprise at least 85% by weight, preferably at least 90% by weight, and in particular at least 95% by weight, of ingredients which are listed in US Pat the following substances are selected:
  • cosmetic according to the invention contain
  • Detergent - based on the total weight of the agent -
  • alkyl (oligo) glycosides known under the INCI names coco glucoside, decyl glucoside or lauryl glucoside,
  • At least one skin care component selected from polyols and / or mono-, di- and / or triesters of glycerol with at least one C 8 - C 2 4 fatty acid, and
  • the cosmetic cleaning agent - based on its total weight - consists of at least 85 wt .-% of ingredients of the aforementioned table.
  • more preferred cosmetic detergents according to the invention contain, based on their total weight,
  • alkyl (oligo) glycosides known under the INCI names coco glucoside, decyl glucoside or lauryl glucoside,
  • a succinic acid ester known under the INCI name Sodium Lauryl Sulfosuccinate
  • 2 to 25 wt .-% of at least one of the known under the INCI names coco-betaine, cocoampho (di) acetate or cocamidopropyl betaine amphoteric surfactants 0.0025 to 0.75 wt .-% of at least one water-insoluble perfume oil and / or a water-insoluble Plant extract, which may be selected from the leaves, fruits, seeds and / or kernels of the aloe vera, mango, apricot, peach, olive, ginseng, ginger and / or argan plant,
  • At least one skin-care component selected from mono-, di- and / or triesters of glycerol with at least one C 8 -C 2 4 fatty acid, and
  • the cosmetic cleaning agent - based on its total weight - consists of at least 90 wt .-% of ingredients of the aforementioned table.
  • water-insoluble perfume oil and / or a water-insoluble plant extract which may be selected from the leaves, fruits, seeds and / or kernels of Aloe Vera, mango, apricot, peach, olives , Ginseng, ginger and / or argan plant,
  • the cosmetic detergent - based on its total weight - consists of at least 95 wt .-% of ingredients of the aforementioned table.
  • the cleaning agents according to the invention preferably have a pH in a skin-friendly range of from 4 to 6, preferably from 4 to 5.5 and in particular from 4.5 to 5.0.
  • Cosmetic detergents preferred according to the invention preferably have a viscosity in the range from 1, 000 to 7,000 mPas, more preferably from 1, 500 to 6,000 mPas, especially preferably from 2,000 to 5,000 mPas and especially from 2,500 to 4,000 mPas (measured in each case with a Haake VT550 rotational viscometer, 20 ° C., measuring device MV, spindle MV II, 8 rpm).
  • compositions of this viscosity can be conveniently and easily applied from a container to the hand or application surface without passing between the fingers and dripping. At the same time, the viscosity of the composition is low enough to ensure a satisfactory distribution on the surface of the application with the assistance of the hands.
  • the process according to the invention makes it possible to produce transparent cosmetic cleansing compositions which contain water-insoluble care components.
  • the detergents can be prepared by simply mixing the premixes a), b) and c) - preferably at room temperature - produce.
  • the cleaning agents of the invention have excellent properties in the application to the skin.
  • Detergents preferred according to the invention are transparent and fall under the Ecocert standard of a natural cosmetic.
  • a third aspect of the invention is the use of a cosmetic cleaning agent according to the invention as a shower gel, shower bath, liquid soap, bubble bath and / or bath additive for the gentle and nourishing cleansing of the human body.
  • a cosmetic cleaning agent according to the invention as a shower gel, shower bath, liquid soap, bubble bath and / or bath additive for the gentle and nourishing cleansing of the human body.
  • the following transparent liquid soap was prepared by the process according to the invention (the amounts are based on the total weight of the liquid soap and are given in% by weight):
  • a cosmetic carrier a) was presented, which in addition to about 63 wt .-% water 2 wt .-% of Ecocert-certified skin care Lamesoft ® PO 65, 13.2 wt .-% Ecocert certified Cocamidopropylbetain (40% in water) and 0.5% by weight of an Ecocert-certified preservative (RonaCare Sodium Benzoate),
  • Plantacare ® 818 UP (containing about 2.6 wt .-% Coco Glucoside and 2.4 wt% water) containing
  • Lamesof PO 65 INCI name: Coco Glucoside, Glyceryl Oleate; Cognis; Plantapon ® PSC: INCI name: Coco-Glucoside, Disodium Lauryl
  • Plantacare® ® 818 INCI name: Aqua, Coco-Glucoside, Cognis
  • Argantesyl ® PW Bio LS 9902 INCI name: Argania Spinosa Extract and sodium cocoyl

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un procédé de fabrication d'un produit d'hygiène cosmétique transparent qui présente les étapes suivantes consistant à : a) préparer un support cosmétique, b) préparer un mélange tensioactif contenant (i) au moins un alkyl(oligo)glycoside ainsi que (ii) au moins un sel d'un ester d'acide sulphosuccinique, c) préparer un prémélange - différent de b) - contenant (i) au moins un composant insoluble dans l'eau, (ii) au moins un tensioactif amphotère ou zwitterionique et/ou (iii) au moins un alkyl(oligo)glycoside et d) mélanger les composants a), b) et c). Les produits nettoient et soignent la peau et lui confèrent une impression de fraîcheur.
PCT/EP2012/060202 2011-06-08 2012-05-31 Procédé de fabrication d'un produit d'hygiène cosmétique transparent Ceased WO2012168126A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011077221.9 2011-06-08
DE201110077221 DE102011077221A1 (de) 2011-06-08 2011-06-08 Verfahren zur Herstellung eines transparenten kosmetischen Reinigungsmittels

Publications (2)

Publication Number Publication Date
WO2012168126A2 true WO2012168126A2 (fr) 2012-12-13
WO2012168126A3 WO2012168126A3 (fr) 2013-11-07

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PCT/EP2012/060202 Ceased WO2012168126A2 (fr) 2011-06-08 2012-05-31 Procédé de fabrication d'un produit d'hygiène cosmétique transparent

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DE (1) DE102011077221A1 (fr)
WO (1) WO2012168126A2 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3006088A1 (fr) * 2014-09-29 2016-04-13 Johnson & Johnson Consumer Inc. Compositions de nettoyage
WO2020035245A1 (fr) 2018-08-17 2020-02-20 Beiersdorf Ag Composition nettoyante
CN111888275A (zh) * 2020-09-15 2020-11-06 上海百雀羚生物科技有限公司 一种组合物及其制备方法和用途
US20210069092A1 (en) * 2018-05-11 2021-03-11 Conopco, Inc., D/B/A Unilever Cleansing composition
US20220226209A1 (en) * 2021-01-20 2022-07-21 Galaxy Surfactants Ltd. Safe and ecofriendly persistent sanitizing gel for topical application
US11969495B2 (en) 2018-05-11 2024-04-30 Conopco, Inc. Sulphate-free and nonionic surfactant-free cleansing composition

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010009978A2 (fr) 2008-07-23 2010-01-28 Henkel Ag & Co. Kgaa Composition à base de tensioactifs contenant un mélange spécial d'émulsifiants

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6723688B1 (en) * 1999-09-27 2004-04-20 Shaklee Corporation Cleanser that is gentle to human skin
US6805874B1 (en) * 2002-12-03 2004-10-19 Permamed Ag Method and skin cleansing compositions for dermatological basic treatment
WO2007127987A2 (fr) * 2006-04-28 2007-11-08 The Dial Corporation Composition pour nettoyage personnel à base de polymère acrylique ayant une transparence élevée et son procédé de fabrication

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010009978A2 (fr) 2008-07-23 2010-01-28 Henkel Ag & Co. Kgaa Composition à base de tensioactifs contenant un mélange spécial d'émulsifiants

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3006088A1 (fr) * 2014-09-29 2016-04-13 Johnson & Johnson Consumer Inc. Compositions de nettoyage
US20210069092A1 (en) * 2018-05-11 2021-03-11 Conopco, Inc., D/B/A Unilever Cleansing composition
US11969495B2 (en) 2018-05-11 2024-04-30 Conopco, Inc. Sulphate-free and nonionic surfactant-free cleansing composition
WO2020035245A1 (fr) 2018-08-17 2020-02-20 Beiersdorf Ag Composition nettoyante
CN111888275A (zh) * 2020-09-15 2020-11-06 上海百雀羚生物科技有限公司 一种组合物及其制备方法和用途
US20220226209A1 (en) * 2021-01-20 2022-07-21 Galaxy Surfactants Ltd. Safe and ecofriendly persistent sanitizing gel for topical application
US12109283B2 (en) * 2021-01-20 2024-10-08 Galaxy Surfactants Ltd. Safe and ecofriendly persistent sanitizing gel for topical application

Also Published As

Publication number Publication date
WO2012168126A3 (fr) 2013-11-07
DE102011077221A1 (de) 2012-12-13

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