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WO2012156369A1 - Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide - Google Patents

Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide Download PDF

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Publication number
WO2012156369A1
WO2012156369A1 PCT/EP2012/058933 EP2012058933W WO2012156369A1 WO 2012156369 A1 WO2012156369 A1 WO 2012156369A1 EP 2012058933 W EP2012058933 W EP 2012058933W WO 2012156369 A1 WO2012156369 A1 WO 2012156369A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaning
preferred
temperature
solution
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/058933
Other languages
English (en)
Inventor
Christoph MAUL
Dirk Kullwitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab Inc
Original Assignee
Ecolab Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Inc filed Critical Ecolab Inc
Publication of WO2012156369A1 publication Critical patent/WO2012156369A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00—Washing or rinsing machines for crockery or tableware
    • A47L15/0002—Washing processes, i.e. machine working principles characterised by phases or operational steps
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/06—Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/08—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/16—Phosphates including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/34—Organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00—Washing or rinsing machines for crockery or tableware
    • A47L15/42—Details
    • A47L15/4236—Arrangements to sterilize or disinfect dishes or washing liquids
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L2601/00—Washing methods characterised by the use of a particular treatment
    • A47L2601/20—Other treatments, e.g. dry cleaning
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40—Specific cleaning or washing processes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40—Specific cleaning or washing processes
    • C11D2111/44—Multi-step processes

Definitions

  • Dishwashing process comprising a basic and acidic cleaning step
  • This invention relates generally to the field of machine dishwashing processes, e.g. for cleaning tableware or other surfaces soiled with food remains. More particular this invention relates to field of continuous or discontinuous machine dishwashing processes in single or multi-tank dish machines.
  • Dish washing machines especially industrial dish washing machines are known in the field.
  • dish washing methods are known in which basic cleaning steps are altered with acidic cleaning steps, e.g. from the EP 1 477 552 Al which is hereby incorporated by reference. These washing methods have been described to be effective against starch deposits.
  • a process for continuous or discontinuous machine dishwashing comprising the steps of a) Applying a first basic cleaning step whereby the cleaning solution has a pH of ⁇ 10,6 and ⁇ 10,9 b) Applying an acidic cleaning step whereby the cleaning solution has a pH of ⁇ 1 and ⁇ 2 c) Applying a second basic cleaning step whereby the cleaning solution has a pH of ⁇ 10,5 and ⁇ 13
  • a process for continuous or discontinuous machine dishwashing comprising the steps of a) Applying a first basic cleaning step whereby the cleaning solution has a pH of ⁇ 10,6 and ⁇ 10,9 b) Applying an acidic cleaning step whereby the cleaning solution has a pH of ⁇ 1 and ⁇ 2 c) Applying a second basic cleaning step whereby the cleaning solution has a pH of ⁇ 10,5 and ⁇ 13
  • the cleaning solution has a pH of ⁇ 10,6 and 10,9.
  • step c) the cleaning solution has a pH of >11 and 12,5.
  • step a) is performed at a temperature of ⁇ 30°C and ⁇ 70°C
  • step b) is performed at a temperature of ⁇ 55°C and ⁇ 85°C
  • step c) is performed at a temperature of ⁇ 30°C and ⁇ 70°C
  • step a) is performed for ⁇ 8s and ⁇ 60s.
  • step b) is performed for ⁇ 10s and ⁇ 20s.
  • step c) is performed for ⁇ 20s and ⁇ 60s.
  • Step a) First alkaline cleaning step
  • Step a) is the first alkaline cleaning step in the context of the invention and is performed using a cleaning solution having a pH of ⁇ 10,6 and ⁇ 10,9.
  • This pH can be achieved e.g. by using hydroxide solution and/or hydroxide/buffer solution, especially hydroxide/ phosphate buffer solution
  • the cleaning solution used in step a) may include one or more of the following ingredients:
  • the cleaning solution is sprayed onto the tableware trough a rotating washing arm as a heavy water curtain.
  • Step a) is performed at a temperature of ⁇ 30 and ⁇ 70°C, which means that the cleaning solution which is applied to the tableware has this temperature. More preferred, step a) is performed at a temperature of ⁇ 40 and ⁇ 65°C, yet more preferred ⁇ 50 and ⁇ 60°C Step a) preferably is performed for ⁇ 8s and ⁇ 60s, more preferred for ⁇ 20s and ⁇ 30s. However, it should be noted that the duration of step a) is not limiting for the invention, only for some preferred applications within the same.
  • Step b) Acidic cleaning step
  • Step b) is the acidic cleaning step in the context of the invention and is performed using a cleaning solution having a pH of ⁇ 1 and ⁇ 2. This pH can be achieved e.g. by using an inorganic or organic acid.
  • Suitable acidic compounds in the context of this invention which are insofar preferred are sulfuric acid, nitric acid, phosphoric acid, formic acid, acetic acid, propanoic acid, glycolic acid, citric acid, maleic acid, lactic acid, gluconic acid, alkanesulfonic acid, amidosulfonic acid, succinic acid, glutaric acid, adipic acid, phosphonic acids, polyacrylic acids or mixtures thereof and, in a most particularly embodiment, from formic acid, glycolic acid, gluconic acid, amidosulfonic acid or the alkanesulfonic acids, more particularly methanesulfonic acid or mixtures thereof. Especially preferred is methanesulfonic acid.
  • the cleaning solution used in step b) may include one or more of the following ingredients:
  • the cleaning solution is allowed to act on the tableware and the soil for a certain contact time (during which spraying stops) .
  • the tableware is not intentionally sprayed during the contact time.
  • the cleaning solution is sprayed onto the tableware as a fine, gentle mist-like liquid spray.
  • the cleaning solution is applied to the tableware as foam.
  • the cleaning solution is applied to the tableware in droplet form or by the Ecolab process known commercially as thin film cleaning (TFC) .
  • Step b) is performed at a temperature of ⁇ 55 and ⁇ 85°C, which means that the cleaning solution which is applied to the tableware has this temperature. More preferred, step b) is performed at a temperature of ⁇ 60 and ⁇ 80°C and
  • Step b) preferably is performed for ⁇ 10s and ⁇ 20s.
  • the duration of step b) is not limiting for the invention, only for some preferred applications within the same.
  • Step c) is the second alkaline cleaning step in the context of the invention and is performed using a cleaning solution having a pH of ⁇ 10,5 and ⁇ 13, preferably ⁇ 10,6 and ⁇ 10,9. This pH can be achieved e.g. by using hydroxide solution and/or hydroxide/buffer solution, especially hydroxide/ phosphate buffer solution
  • the cleaning solution used in step a) may include one or more of the following ingredients:
  • the cleaning solution is sprayed onto the tableware trough a rotating washing arm as a heavy water curtain.
  • Step c) is performed at a temperature of ⁇ 30 and ⁇ 70°C, which means that the cleaning solution which is applied to the tableware has this temperature. More preferred, step c) is performed at a temperature of ⁇ 40 and ⁇ 65°C, yet more preferred ⁇ 50 and ⁇ 60°C
  • Step c) preferably is performed for ⁇ 20s and ⁇ 60s, more preferred ⁇ 45s and ⁇ 55s.
  • the duration of step c) is not limiting for the invention, only for some preferred applications within the same.
  • the process furthermore comprises a step d) being a neutral rinsing step. This embodiment will be described in more detail later on.
  • Step d) is the neutral rinsing step in the context of the invention and is performed using a rinse aid solution having a pH of ⁇ 5 and ⁇ 7.
  • the rinse aid solution used in step d) may include one or more of the following ingredients:
  • the cleaning solution is allowed to act on the tableware and the soil for a certain contact time (during which spraying stops) , as it step d) usually is the last step in the dishwashing cycle.
  • the tableware is not intentionally sprayed during the contact time.
  • Step d) is performed at a temperature of ⁇ 55 and ⁇ 85°C, which means that the cleaning solution which is applied to the tableware has this temperature. More preferred, step b) is performed at a temperature of ⁇ 60 and ⁇ 80°C.
  • Step d) preferably is performed for ⁇ 5s and ⁇ 15s, preferably ⁇ 9s and ⁇ 12s.
  • the duration of step d) is not limiting for the invention, only for some preferred applications within the same.
  • the afore mentioned components, as well as the claimed components and the components to be used in accordance with the invention in the described embodiments, are not subject to any special exceptions with respect to their size, shape, material selection and technical concept such that the selection criteria known in the pursuant field can be applied without a limitation.
  • Example I Cleaning of table cups and table plates in a MEIKO DV80.2 dishwashing machine sold by Meiko company, Offenburg, Germany .
  • 3 dry, clean table cups were soiled by being dipped in a coffee and milk brew at 70°C for 25 times (1 min in the solution followed by 1 min drying each dipping cycle) and afterwards dried for 2 hours at 90°C according to a standardized test protocol.
  • the cleaning tests were carried out in a Meiko DV80.2 hood-type dishwashing machine according to the following scheme: a) Cleaning for 25 seconds at a temperature of around 60 °C with a 0.2% by weight aqueous solution of an alkaline detergent, the solution having a pH of about 10,9.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Washing And Drying Of Tableware (AREA)

Abstract

La présente invention se rapporte à un procédé permettant de nettoyer la vaisselle à l'aide d'une étape de nettoyage basique suivie par une étape de nettoyage acide, les deux étapes présentant un faible intervalle de pH défini.
PCT/EP2012/058933 2011-05-19 2012-05-14 Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide Ceased WO2012156369A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EPPCT/EP2011/058194 2011-05-19
PCT/EP2011/058194 WO2012155986A1 (fr) 2011-05-19 2011-05-19 Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide

Publications (1)

Publication Number Publication Date
WO2012156369A1 true WO2012156369A1 (fr) 2012-11-22

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Application Number Title Priority Date Filing Date
PCT/EP2011/058194 Ceased WO2012155986A1 (fr) 2011-05-19 2011-05-19 Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide
PCT/EP2012/058933 Ceased WO2012156369A1 (fr) 2011-05-19 2012-05-14 Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide

Family Applications Before (1)

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PCT/EP2011/058194 Ceased WO2012155986A1 (fr) 2011-05-19 2011-05-19 Procédé de lavage de vaisselle comprenant une étape de nettoyage basique et une étape de nettoyage acide

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8871699B2 (en) 2012-09-13 2014-10-28 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US9023784B2 (en) 2012-09-13 2015-05-05 Ecolab Usa Inc. Method of reducing soil redeposition on a hard surface using phosphinosuccinic acid adducts
US9752105B2 (en) 2012-09-13 2017-09-05 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US9994799B2 (en) 2012-09-13 2018-06-12 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US11865219B2 (en) 2013-04-15 2024-01-09 Ecolab Usa Inc. Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11421191B1 (en) 2018-11-15 2022-08-23 Ecolab Usa Inc. Acidic cleaner

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992018047A1 (fr) * 1991-04-20 1992-10-29 Henkel Kommanditgesellschaft Auf Aktien Procede pour le lavage en machine de vaisselle ordinaire
EP0761156A1 (fr) * 1995-09-06 1997-03-12 Sharp Kabushiki Kaisha Lave vaiselle
WO2002100993A1 (fr) * 2001-06-08 2002-12-19 Ecolab Inc. Procede d'epuration destine a l'elimination d'amidon
EP1477552A1 (fr) 2003-05-13 2004-11-17 Ecolab Inc. Procédé de nettoyage d'articles au moyen d'un lave-vaisselle
WO2005068598A1 (fr) * 2003-12-18 2005-07-28 Ecolab Inc. Procedes et compositions pour l'elimination d'amidon

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992018047A1 (fr) * 1991-04-20 1992-10-29 Henkel Kommanditgesellschaft Auf Aktien Procede pour le lavage en machine de vaisselle ordinaire
EP0761156A1 (fr) * 1995-09-06 1997-03-12 Sharp Kabushiki Kaisha Lave vaiselle
WO2002100993A1 (fr) * 2001-06-08 2002-12-19 Ecolab Inc. Procede d'epuration destine a l'elimination d'amidon
EP1477552A1 (fr) 2003-05-13 2004-11-17 Ecolab Inc. Procédé de nettoyage d'articles au moyen d'un lave-vaisselle
WO2005068598A1 (fr) * 2003-12-18 2005-07-28 Ecolab Inc. Procedes et compositions pour l'elimination d'amidon

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10377971B2 (en) 2012-09-13 2019-08-13 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US11001784B2 (en) 2012-09-13 2021-05-11 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US9670434B2 (en) 2012-09-13 2017-06-06 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US9752105B2 (en) 2012-09-13 2017-09-05 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US9994799B2 (en) 2012-09-13 2018-06-12 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US10358622B2 (en) 2012-09-13 2019-07-23 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US11053458B2 (en) 2012-09-13 2021-07-06 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US8871699B2 (en) 2012-09-13 2014-10-28 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US9023784B2 (en) 2012-09-13 2015-05-05 Ecolab Usa Inc. Method of reducing soil redeposition on a hard surface using phosphinosuccinic acid adducts
US11859155B2 (en) 2012-09-13 2024-01-02 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US12371639B2 (en) 2012-09-13 2025-07-29 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US11952556B2 (en) 2012-09-13 2024-04-09 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US12337073B2 (en) 2013-04-15 2025-06-24 Ecolab Usa Inc. Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing
US11865219B2 (en) 2013-04-15 2024-01-09 Ecolab Usa Inc. Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing

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