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WO2012145750A3 - Electroplated lubricant-hard-ductile nanocomposite coatings and their applications - Google Patents

Electroplated lubricant-hard-ductile nanocomposite coatings and their applications Download PDF

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Publication number
WO2012145750A3
WO2012145750A3 PCT/US2012/034678 US2012034678W WO2012145750A3 WO 2012145750 A3 WO2012145750 A3 WO 2012145750A3 US 2012034678 W US2012034678 W US 2012034678W WO 2012145750 A3 WO2012145750 A3 WO 2012145750A3
Authority
WO
WIPO (PCT)
Prior art keywords
lubricant
applications
ductile
hard
nanocomposite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2012/034678
Other languages
French (fr)
Other versions
WO2012145750A2 (en
Inventor
Danny Xiao
Heng Zhang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANO GROUP Inc
Original Assignee
NANO GROUP Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANO GROUP Inc filed Critical NANO GROUP Inc
Publication of WO2012145750A2 publication Critical patent/WO2012145750A2/en
Publication of WO2012145750A3 publication Critical patent/WO2012145750A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00—Electrophoretic coating characterised by the process
    • C25D13/22—Servicing or operating apparatus or multistep processes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1651—Two or more layers only obtained by electroless plating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1655—Process features
    • C23C18/1662—Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10—Electroplating with more than one layer of the same or of different metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60—Electroplating characterised by the structure or texture of the layers
    • C25D5/605—Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611—Smooth layers
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60—Electroplating characterised by the structure or texture of the layers
    • C25D5/615—Microstructure of the layers, e.g. mixed structure
    • C25D5/617—Crystalline layers
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Lubricants (AREA)
  • Chemically Coating (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

Disclosed herein is a non-line-of-sight ("NLOS") process for electroplating nanocomposite coatings onto a substrate. This coating reveals a combination of lubricant-hard-ductile nanocomposite coating compositions. Applications of the coatings are disclosed herein. In one embodiment, the plating process uses a nickel electrode, or an electroless plating process. In another embodiment, the obtained coating is a nanocomposite coating composition that comprises a lubricant/soft phase for providing lubrication to a surface; a hard ceramic phase for providing structural integrity and wear resistance to the surface; and a ductile metal phase for providing ductility to the surface. In a third embodiment, this coating composition has applications in mating parts where a combination of high lubricity, wear resistance and ductility is important, including hydraulic cylinders and sleeves, copper mold in steel making industry, rollers in printing, and gear geometries.
PCT/US2012/034678 2011-04-22 2012-04-23 Electroplated lubricant-hard-ductile nanocomposite coatings and their applications Ceased WO2012145750A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161478097P 2011-04-22 2011-04-22
US61/478,097 2011-04-22

Publications (2)

Publication Number Publication Date
WO2012145750A2 WO2012145750A2 (en) 2012-10-26
WO2012145750A3 true WO2012145750A3 (en) 2013-01-17

Family

ID=47042200

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/034678 Ceased WO2012145750A2 (en) 2011-04-22 2012-04-23 Electroplated lubricant-hard-ductile nanocomposite coatings and their applications

Country Status (1)

Country Link
WO (1) WO2012145750A2 (en)

Families Citing this family (25)

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ES2422455T3 (en) 2005-08-12 2013-09-11 Modumetal Llc Compositionally modulated composite materials and methods for manufacturing them
BR122013014461B1 (en) 2009-06-08 2020-10-20 Modumetal, Inc corrosion resistant multilayer coating on a substrate and electroplating method for producing a multilayer coating
US9352829B2 (en) * 2013-03-07 2016-05-31 Bell Helicopter Textron Inc. Aircraft with protective nanocoating
CN105189826B (en) * 2013-03-15 2019-07-16 莫杜美拓有限公司 Electrodeposited compositions and nanolaminated alloys for articles prepared by additive manufacturing processes
EP2971264A4 (en) 2013-03-15 2017-05-31 Modumetal, Inc. Nanolaminate coatings
HK1220743A1 (en) 2013-03-15 2017-05-12 Modumetal, Inc. Nickel chromium nanolaminate coating having high hardness
EP2971266A4 (en) 2013-03-15 2017-03-01 Modumetal, Inc. A method and apparatus for continuously applying nanolaminate metal coatings
CN103981556B (en) * 2014-05-19 2017-02-22 广东美芝制冷设备有限公司 Electrolyte for hard-anodizing of aluminum alloys and preparation method of aluminum alloy hard self-lubricating coatings
EP3194163A4 (en) 2014-09-18 2018-06-27 Modumetal, Inc. Methods of preparing articles by electrodeposition and additive manufacturing processes
CA2961508C (en) 2014-09-18 2024-04-09 Modumetal, Inc. A method and apparatus for continuously applying nanolaminate metal coatings
CN108699697A (en) * 2016-03-10 2018-10-23 博格华纳公司 Chain with the electroless nickel plating coating containing hard particles
CN106119905B (en) * 2016-08-15 2018-03-16 亚太水处理(天长)有限公司 A kind of preparation method for the aeration machine bearing internal axle sleeve Composite Coatings masking liquid that floats
CA3036191A1 (en) 2016-09-08 2018-03-15 Modumetal, Inc. Processes for providing laminated coatings on workpieces, and articles made therefrom
US12227869B2 (en) 2016-09-09 2025-02-18 Modumetal, Inc. Application of laminate and nanolaminate materials to tooling and molding processes
KR102412452B1 (en) 2016-09-14 2022-06-23 모두메탈, 인크. Systems for Reliable High-Throughput Complex Electric Field Generation, and Methods of Making Coatings Therefrom
US12076965B2 (en) 2016-11-02 2024-09-03 Modumetal, Inc. Topology optimized high interface packing structures
CA3057836A1 (en) 2017-03-24 2018-09-27 Modumetal, Inc. Lift plungers with electrodeposited coatings, and systems and methods for producing the same
CN110770372B (en) 2017-04-21 2022-10-11 莫杜美拓有限公司 Tubular article having an electrodeposited coating and system and method for producing same
WO2019210264A1 (en) 2018-04-27 2019-10-31 Modumetal, Inc. Apparatuses, systems, and methods for producing a plurality of articles with nanolaminated coatings using rotation
CN111826691B (en) * 2020-08-21 2021-09-21 东北大学 Method for preparing zinc-tantalum alloy by using solvated ionic liquid
CN112680761B (en) * 2020-12-16 2023-12-26 江西瑞顺超细铜线科技协同创新有限公司 Nickel-cerium alloy plating annealed copper wire production process
CN112941605B (en) * 2021-01-29 2025-03-28 铱莱科特(东莞)科技有限公司 Insoluble anode for electroplating capable of reducing consumption of electroplating solution additives and preparation method thereof
CN113249712B (en) * 2021-04-28 2022-06-24 南京航空航天大学 Titanium alloy wire copper/yttrium oxide composite modification method and application
CN114635127A (en) * 2022-03-17 2022-06-17 台州学院 A kind of low friction coefficient coating for melt blowing die and preparation method thereof
CN118291936B (en) * 2024-04-01 2024-09-06 江苏富乐华半导体科技股份有限公司 Preparation method of diamond laser heat sink substrate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6270831B2 (en) * 1998-04-30 2001-08-07 Medquest Products, Inc. Method and apparatus for providing a conductive, amorphous non-stick coating
US7022419B2 (en) * 2000-12-20 2006-04-04 Honda Giken Kogyo Kabushiki Kaisha Composite plating film and a process for forming the same
US20070099027A1 (en) * 2005-10-28 2007-05-03 Anand Krishnamurthy Wear resistant coatings
US20090155479A1 (en) * 2006-09-21 2009-06-18 Inframat Corporation Lubricant-hard-ductile nanocomposite coatings and methods of making

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6270831B2 (en) * 1998-04-30 2001-08-07 Medquest Products, Inc. Method and apparatus for providing a conductive, amorphous non-stick coating
US7022419B2 (en) * 2000-12-20 2006-04-04 Honda Giken Kogyo Kabushiki Kaisha Composite plating film and a process for forming the same
US20070099027A1 (en) * 2005-10-28 2007-05-03 Anand Krishnamurthy Wear resistant coatings
US20090155479A1 (en) * 2006-09-21 2009-06-18 Inframat Corporation Lubricant-hard-ductile nanocomposite coatings and methods of making

Also Published As

Publication number Publication date
WO2012145750A2 (en) 2012-10-26

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