WO2012036408A2 - Submerged-membrane bioreactor that easily responds to load regulation, and method of treating wastewater using the same - Google Patents
Submerged-membrane bioreactor that easily responds to load regulation, and method of treating wastewater using the same Download PDFInfo
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- WO2012036408A2 WO2012036408A2 PCT/KR2011/006608 KR2011006608W WO2012036408A2 WO 2012036408 A2 WO2012036408 A2 WO 2012036408A2 KR 2011006608 W KR2011006608 W KR 2011006608W WO 2012036408 A2 WO2012036408 A2 WO 2012036408A2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/18—Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/08—Prevention of membrane fouling or of concentration polarisation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1236—Particular type of activated sludge installations
- C02F3/1268—Membrane bioreactor systems
- C02F3/1273—Submerged membrane bioreactors
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
- C02F3/2813—Anaerobic digestion processes using anaerobic contact processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2315/00—Details relating to the membrane module operation
- B01D2315/06—Submerged-type; Immersion type
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/18—Use of gases
- B01D2321/185—Aeration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/005—Valves
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/04—Oxidation reduction potential [ORP]
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/22—O2
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/006—Regulation methods for biological treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/308—Biological phosphorus removal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Definitions
- the present invention relates to a membrane bioreactor used for sewage or wastewater treatment, and more particularly, to a submerged membrane bioreactor and a sewage treatment method using the same. will be.
- protozoa-induced lesions in the intestinal tract are not included in the water quality criteria, but are also removed by chlorine disinfection. The difficulty is increasing the need to remove these.
- Membrane bioreactors replace the precipitation function with membranes in conventional bioreactors, and microfiltration membranes (MF) and ultrafiltration membranes are widely used in general applications. It is widely used because it is very effective for removing suspended solids, bacteria and protozoa.
- the amount of air required for membrane cleaning is 00 to 150 m 3 / itf.hr for the bottom area of the membrane, and the inflow load must be continuously supplied and cleaned at the time the membrane is operating regardless of the load of sewage. If less, the amount of air required for membrane cleaning may be much greater than the amount of air needed for biological treatment in the aerobic tank. Since the dissolved oxygen concentration of excessively increases, there is a big problem that the dissolved oxygen concentration in the aerobic tank cannot be adjusted to an appropriate value.
- the amount of cleaning air required for membrane cleaning is large and cannot be changed (reduced). Therefore, when the load of sewage flowing into the immersion membrane bioreactor is small, excess oxygen is supplied to the aerobic tank to increase the dissolved oxygen concentration. Total nitrogen and total nitrogen by increasing the dissolved oxygen concentrations in the anaerobic and anaerobic tanks, which are returned from the aerobic tank, and the anaerobic and anaerobic tanks to be aerobic, resulting in no phosphorus release or denitrification of microorganisms that occur only in anaerobic conditions. Phosphorus removal is extremely low or causes problems that cannot be removed.
- the amount of cleaning air of the filtration membrane described above corresponds to the amount of air required for the sewage treatment of the inflow sewage B0D concentration of 100 mg / L, the above problems occur in the advanced treatment of sewage having a lower B0D concentration.
- the above example illustrates the case of a microfiltration membrane (MF), but in the case of a high-treatment process in which an ultrafiltration (UF) membrane is applied to a bioreactor with a similar amount of membrane cleaning air but a much smaller membrane permeation rate than a microfiltration membrane.
- MF microfiltration membrane
- UF ultrafiltration
- the amount of air required for cleaning becomes more excessive, and the influence on the advanced treatment process is absolute, and thus the application is further limited.
- the needle In sewage or wastewater treatment, even when the inflow load is low, the needle can maintain the membrane cleaning ability, and easily adjust the dissolved oxygen concentration in the aerobic tank to facilitate the change of load, and always maintain the normal treatment capacity.
- the present invention provides a membrane bioreactor and a sewage treatment method using the same.
- ⁇ 21> Inject air from the membrane cleaner blower to the diffuser installed in the lower part of the immersion membrane filter in the membrane filtration tank, and wash the surface of the membrane of the immersion membrane filter by using the air cleaning function. After washing, some or all of the rising air (gas) is circulated to the inlet of the membrane cleaning blower to clean the membrane filter, and the dissolved oxygen concentration of the membrane filter tank is adjusted by adjusting the ratio of the circulating gas amount and the air amount.
- a sewage treatment method using an immersion membrane bioreactor that can easily cope with load fluctuation, wherein the sewage from the degassing treatment step is returned to the anaerobic treatment step and the anaerobic treatment step.
- the immersed membrane bioreactor of the present invention maintains the cleaning function by cleaning the air necessary for cleaning the membrane using a separate blower and recirculating some or all of the air rising above the water surface.
- the dissolved oxygen concentration in the membrane filtration tank can be maintained appropriately by adjusting the ratio of the gas volume and the air volume to be recycled, and the appropriate dissolved oxygen concentration can be maintained by controlling the air volume separately by installing an acid base and an aerobic blower in the aerobic tank. Even under heavy load fluctuations, it is easy to respond, so that the sewage can always be treated in the best condition.
- Figure 2 is an exemplary view of the second A / 0 processes using a membrane filtration aerobic tank of the present invention.
- FIG 3 is an exemplary diagram of an aerobic denitrification process using the membrane filtration tank of the present invention.
- FIG. 4 is a diagram illustrating the configuration of the anaerobic tank of the present invention.
- 5 is an exemplary view of the configuration of an aerobic denitrification tank of the present invention.
- FIG. 6 is an exemplary view of the configuration of the membrane filtration tank of the present invention.
- FIG. 7 is a diagram illustrating the configuration of an aerobic tank according to the present invention.
- FIG. 9 is an embodiment of an aerobic tank used in the small sewage treatment facility of the present invention.
- Membrane filters form a unit by fixing a membrane to a frame and combining these units together to form a membrane filter.
- Membranes include microfiltration membranes (MF) and ultrafiltration membranes, depending on the eye size.
- UF ultrafiltration membrane
- NF nano membrane
- R0 reverse osmosis membrane
- microfiltration membrane and ultrafiltration membrane are mainly used for advanced treatment of sewage and wastewater.
- the microfiltration membrane has a pore size in the range of 0.1 to 0.4, and can generally remove bacteria, Escherichia coli, protozoa, and fine suspended solids (SS).
- the ultrafiltration membrane has a pore size in the range of 0.001 to 0.05 mi, and can usually remove bacteria, E. coli, protozoa and viruses, and fine suspended solids (SS).
- Membrane filters have a very good performance in water treatment as described above, while the eye size is so small that they tend to be clogged.
- the membrane filter is immersed in the aerobic tank in which a large microbial floc is present, and the membrane filter is installed at the lower part of the membrane filter to prevent the membrane filter. Air is blown through the device to prevent clogging of the outer surface of the membrane filter using the cleaning power of air bubbles blown out from the diffuser.
- the amount of air used to clean the membrane filter generally corresponds to the bottom area of the membrane filter.
- hypochlorite solution is periodically refluxed inside the hollow fiber membrane to clean the contaminants attached to the membrane.
- the amount of air cleaning the membrane filter is a fixed value and must be kept constant at all times, regardless of the inflow load of sewage.
- the air volume required in the aerobic tank decreases.
- the inflow load of sewage during the commissioning stage or the initial stage of operation is typically 30 ⁇ 50 ⁇ 3 ⁇ 4 Since there are many places, the air volume required for the aerobic tank should also be supplied only 30-50% of the air volume calculated during design.
- the amount of air required for the membrane filter is usually 70 «3 ⁇ 4 of the total required air volume, so that the aerobic tank becomes an excessively high dissolved oxygen concentration, and therefore, the anaerobic tank and the anoxic tank also become aerobic, which leads to extremely low nitrogen removal efficiency. And a treatment method using a membrane filter causes a problem in operation at the initial low load for the same reason.
- nitrogen is 78% and oxygen is 21%.
- concentration of nitrogen and oxygen in water is determined by each Henry's constant.
- Henry's constant E of nitrogen is 9.24 (EX10 -4 ) for water at 30 ° C
- Henry's constant of oxygen is 4/75 (EX10 ⁇ 4 )
- the larger the Henry's constant the less dissolved in water.
- nitrogen is dissolved in water about 1/2 times less than oxygen, and in nitrogen at low pressure, inorganic nitrogen is dissolved at a low solubility that is equilibrium with the partial pressure of nitrogen gas in the air. Since it is not consumed by the air, nitrogen is not further dissolved even if it is continuously given up by supplying air or nitrogen gas into sewage.
- the oxygen gas ratio decreases as much as dissolved, but the nitrogen gas remains as it was originally supplied, collects the air used for cleaning, and enters the membrane cleaning blower 620.
- the oxygen gas rate is lowered and reduced to the partial pressure equilibrated with the dissolved oxygen concentration in the water. If no external air is supplied, all the oxygen in the circulating gas is consumed, and the oxygen partial pressure becomes zero, and the dissolved oxygen concentration in the membrane filtration tank becomes zero, resulting in anaerobic condition. will be.
- the circulating gas is supplied to the inlet of the membrane cleaning blower, and only a part of the external air is supplied to adjust the ratio of the circulating gas amount and the external air amount, for example, when the inflow load of the sewage is small, the external air supply amount is reduced.
- the inflow load of sewage increases, it increases the external air supply, circulates the circulating gas, maintains the amount of gas necessary for membrane cleaning, and effectively washes the membrane filter, while easily maintaining the dissolved oxygen concentration in the membrane filtration tank to the desired level. I can regulate it.
- the membrane filtration treatment step is configured using the same principle as above, and the configuration of the membrane filtration tank of the membrane filtration step is shown in FIG. 6.
- the membrane filter 630 is installed in the water of the membrane filtration tank 610, and the membrane cleaning air diffuser 640 is installed below the membrane filter, and the membrane cleaning air diffuser is discharged from the outlet of the membrane cleaning blower 620.
- An air line was connected to the inlet of the device 640.
- a ventilation pipe 670 was provided in the shutoff cover to prevent negative pressure or static pressure from acting on the space sealed by the shutoff cover through the exhaust of remaining gas.
- the circulating gas collected in the upper space of the membrane filtration tank is supplied to the membrane cleaning blower 620 through the gas circulation pipe 660 connected to the inlet pipe of the membrane cleaning blower 620 at the upper portion of the blocking cover 660.
- the gas circulation pipe 660 connected to the inlet pipe of the membrane cleaning blower 620 at the upper portion of the blocking cover 660.
- An inlet pipe is installed at the inlet side of the membrane cleaning blower 620 to suck external air, and an air volume control valve 690 is installed at the inlet pipe to adjust the intake air amount.
- the membrane filtration tank is maintained while controlling the ratio of supplying circulating gas and external air to the membrane cleaning blower according to the load amount of the inflow sewage, while maintaining the air amount (gas amount) required for membrane cleaning.
- the dissolved oxygen concentration in 610) can be easily adjusted to the desired concentration.
- Figure 1 is an exemplary view configure the membrane using a filtration tank, A 2/0 process described above.
- a 2/0 process is one of the advanced treatment process of wastewater treatment, the method for removing the organic matter as well as nitrogen and phosphorus at the same time, how the biological process contained in the sewage, the most widely used worldwide, showing a good treatment outcome .
- Figure 1 shows a modification of the example 2 a standard A / 0 processes of the invention, numerous modifications, such as changing the process sequence or to a part omitted should be considered to be within the scope of the invention.
- the sewage from which the contaminants and sand are removed is introduced into the flow adjustment tank in the flow adjustment step and the flow rate is reduced while staying for a predetermined time, and the sewage is transferred to the anaerobic treatment step 300, which is the next process, by the inflow pump.
- the return water 1 (860) returned from the degassing treatment step (700) and the sewage are equally mixed in the anaerobic tank, and the microorganisms in the sewage discharge the phosphorus in the living body while remaining in the anaerobic state for a certain time. .
- the 0RP (redox potential) value should be maintained at -300 ⁇ 400mV and the dissolved oxygen concentration should be kept below O.lmg / L.
- the sewage that has passed through the anaerobic stage is sent to an anaerobic treatment stage 400.
- the sewage and return water 2 flows into the anaerobic tank 410 and is mixed evenly by the action of the anaerobic tank stirrer 320.
- the nitrate nitrogen is converted to inorganic nitrogen by the denitrification of the denitrifying bacteria in the anaerobic state, and released into the atmosphere, thereby removing nitrogen from the sewage.
- the anaerobic and anaerobic tanks need to be sealed or covered with a top to prevent contact with oxygen or air.
- the sewage that has passed the anaerobic treatment step is sent to the aerobic treatment step 500.
- the aerobic treatment step the organic matter in the sewage is decomposed, nitrification is carried out to convert ammonia nitrogen to nitrate nitrogen, and the phosphorus-treated microorganism that has released phosphorus in the anaerobic treatment step 300 is about 2 to 6 times more than the normal phosphorus absorption amount.
- Phosphorus over-absorption acts to absorb a larger amount of phosphorus in the vessel, and the phosphorus in the sewage is removed by releasing the excess phosphorus microorganisms into the excess sludge in the subsequent degassing step.
- the aerobic treatment step maintains the dissolved oxygen concentration at 2.0 to 4.0 mg / L in the advanced treatment process for nitrogen and phosphorus removal.
- the aerobic treatment step should be kept low unless the concentration of organic matter in the sewage is low, as long as it does not interfere with nitrification. It is desirable to maintain 1.5 ⁇ 2.0mg / L.
- the air diffuser for supplying air as shown in FIG.
- an aeration tank stirrer 520 for agitation may be optionally installed.
- the sewage passing through the aerobic treatment step is transferred to the membrane filtration treatment step 600, as shown in FIG. 6, the supernatant is separated from the membrane filter 630, and the remaining sewage is transferred to the degassing treatment step 700.
- the present invention can effectively clean the membrane filter by adjusting the ratio of supplying circulating gas and external air to the membrane cleaning blower 620, and also maintain the dissolved oxygen concentration in the membrane filter tank 610 in an appropriate range. It was. (See Figure 6)
- the sewage remaining after separating the supernatant from the membrane filtration treatment step (600), is maintained in the degassing step (700) with the air supply interrupted for a certain time, so that the dissolved oxygen concentration in the sewage to less than 0.5mg / L Lowering, a part is returned to the anaerobic treatment step 300 (860), and a part is returned to the anaerobic treatment step 400 (850).
- Returning refers to the transfer of a mixture containing sewage and activated sludge to an anaerobic or anaerobic treatment step, and the returned sewage is called "return water"
- the remaining sludge is more than the amount of sludge needed in the treatment process, and the excess sludge is disposed of by discharging it out of the process to remove phosphorus in the sewage due to the disposal of the excess sludge.
- a stirrer it is preferable to install a stirrer to prevent sludge settling in the degassing step.
- the sewage is treated while repeating the above process.
- FIG. 2 is by way of illustration of A 2/0 process using a membrane filtration aerobic tank of the present invention, wherein Fig.
- the sewage that has passed through the anaerobic treatment stage is an anaerobic treatment stage in the anaerobic treatment stage 400 and the sewage and return water 1 (850) evenly mixed in the anaerobic tank, the action of the stirrer, while staying in an anaerobic state for a certain time With the action of denitrifying bacteria, nitric acid nitrogen in sewage is converted to inorganic nitrogen gas and released into the atmosphere to remove nitrogen.
- the sewage that has passed through the anaerobic treatment step is sent to the membrane filtration aerobic treatment step 500B.
- a membrane filter 630 is installed in the internal water of the aerobic tank 510, and a membrane cleaning diffuser 640 is installed at the lower portion of the membrane filter to remove the membrane cleaner.
- the outlets were connected by air piping.
- an air diffuser 530 for supplying air to the exhalation tank was installed, and also connected to the discharge port of the membrane filtration exhalation tank blower 550 by an air pipe.
- the upper portion of the exhalation tank 510 was installed by blocking the cover 650, the upper space of the exhalation tank was sealed by air, and the ventilation cover 670 was installed in the blocking cover to communicate with the atmosphere.
- the aeration pipe is to prevent the occurrence of negative pressure (-pressure) or positive pressure (+ pressure) in the space above the aeration tank and to exhaust the air (circulating gas) remaining after the aeration.
- a gas circulating pipe 660 was connected from the upper portion of the blocking cover 650 to the inlet of the membrane filtration aeration tank blower 550, and a circulating gas flow control valve 560 was installed in the gas circulation pipe. It was done.
- an air inlet pipe for inhaling air in the atmosphere is installed, and an air volume control valve for adjusting the intake air amount is installed.
- the opening degree of the air flow control valve 570 and the circulating gas flow control valve 560 provided at the inlet of the membrane filtration aerobic blower 550 is controlled. Adjust the ratio between the amount of intake air and the amount of circulating gas to achieve the desired dissolved oxygen concentration.
- the amount of air sucked in and the amount of circulating gas change depending on the opening degree of the valve, the amount of air discharged from the membrane filtration aeration tank blower 550 (combined air of the air and the circulating gas) is constant. Due to the low load, the amount of air required to maintain the dissolved oxygen concentration appropriately decreases, so that even if the amount of air supplied from the outside is reduced, the cleaning action for cleaning the membrane filter is kept constant.
- FIG. 8 shows the oxygen concentration meter 10, the automatic controller 30, the circulating gas volume automatic control valve 560a and the air volume automatically in the water of the aerobic tank 510 in the membrane filtration aerobic treatment step of the present invention.
- the example which installed the valve 570a and controls it automatically so that the dissolved oxygen concentration in an aerobic tank may be kept at the set value is shown.
- the automatic controller 30 increases the opening degree of the air volume control valve 570a and increases the amount of air sucked from the outside. If the dissolved oxygen concentration in the exhalation tank is larger than the set value, the automatic controller sets the dissolved oxygen concentration in the exhalation tank by increasing the opening degree of the circulating gas amount automatic control valve 560a and decreasing the opening degree of the air volume automatic control valve 570a. Keep it constant at one value.
- FIG 9 shows an embodiment of an aerobic tank in which the present invention is applied to a small sewage treatment facility. All.
- the upper portion of the aerobic tank may be closed with a shield cover, and the upper portion of each membrane filter 630 may be closed. It is often more economical to install the blocking covers 650 individually.
- the membrane filter 630 is installed in the water of the aerobic tank 510, the membrane cleaning diffuser 640 is installed below the membrane filter, and the membrane cleaning diffuser and the membrane cleaning blower 620 are provided. ) Between the discharge port is connected to the air piping.
- the inlet side of the membrane cleaning blower 620 was connected to the gas circulation pipe 660, and the gas circulation pipe was provided with a circulating gas flow control valve 680.
- a suction pipe for inhaling air in the atmosphere was installed, and an air volume control valve 690 for adjusting the intake air amount was installed.
- an air diffuser 530 for abandoning the aerobic tank was installed near the inner bottom of the aerobic tank 510, and the air outlet was connected between the air diffuser and the discharge port of the membrane filtration aerobic blower 550.
- the amount of air supplied to the air diffuser is controlled by releasing some discharged air into the atmosphere from the noise blower 590 and controlling the number of revolutions of the blower. Can be.
- the method of adjusting the ratio of the amount of circulating gas and the amount of hop-in air is the same as described above.
- FIG 3 is an exemplary view of a sewage treatment process using the membrane filtration tank of the present invention.
- Flow rate adjustment step 200 to maintain the sewage for a certain time
- An aerobic denitrification treatment step 500A that maintains a low dissolved oxygen concentration and a specific redox potential value, decomposes organic matter in the sewage, denitrates nitrogen, and allows the microorganism to absorb excessively phosphorus;
- Membrane that keeps dissolved oxygen concentration of sewage at l ⁇ 2.0mg / L, activates microorganism, converts some untreated ammonia nitrogen to nitrate nitrogen, and separates supernatant Filtration treatment step 600;
- Degassing treatment step 700 to lower the dissolved oxygen concentration in the sewage
- a sewage treatment method using a submerged membrane bioreaction device that is easy to vary in load, characterized by consisting of a conveying pump 800 and a conveying water 900.
- the pretreatment step 100 and the flow rate adjusting step 200 are as described above, and in the anaerobic treatment step 300, the return water 900 and the sewage are mixed in the anaerobic tank 310 as shown in FIG. During a certain period of time, the phosphorus contained in the microorganisms is released, and the nitric acid nitrogen contained in traces in the return water is converted to nitrogen gas by the action of denitrifying bacteria.
- an air diffuser 530 is installed near the inner bottom of the aerobic denitrification tank 510a, and an aerobic denitrification stirrer 520a is installed.
- the discharge port of the air diffuser and the blower blower 540 was connected by air piping.
- the dissolved oxygen concentration of the aerobic denitrification tank (510a) is kept relatively low at 0.3 ⁇ 0.5mg / L by controlling the air supply of the aerobic blower, and the redox potential (0RP) is maintained at + 330mV based on the hydrogen electrode.
- the redox potential (0RP) is maintained at + 330mV based on the hydrogen electrode.
- ammonia nitrogen in sewage is oxidized to nitrate nitrogen by the action of aerobic denitrification bacteria, and at the same time, denitrification occurs by conversion to nitrogen gas.
- microorganisms that released phosphorus in the anaerobic treatment step absorb excess phosphorus in aerobic state, and organic matter is decomposed and treated in aerobic state.
- the membrane filtration tank of the membrane filtration treatment step 600 was configured as shown in FIG. 6, and the configuration and operation were as described above, but the dissolved oxygen concentration in the membrane filtration tank 610 was maintained at 1.0 to 2.0 mg / L for a predetermined time.
- the activity of the microorganism is increased, and ammonia nitrogen, which may not be partially nitrified in the aerobic denitrification tank 510a due to the action of nitrifying bacteria, is oxidized to nitrate nitrogen.
- sewage and supernatant are separated in membrane filter 630.
- the advantage of aerobic denitrification is that the amount of air required is low, and in theory, 100% of denitrification is possible if the operating conditions such as pH, ORP and HRT are ideally maintained.
- the supply of air to the sewage is stopped for a certain time, and the dissolved oxygen concentration of the sewage is kept lower than 0.5 mg / L to increase the treatment effect of the anaerobic treatment step, which is a connecting process.
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Abstract
Description
【명세세 [Specifications
【발명의 명칭】 [Name of invention]
부하변동에 대응이 용이한 침지식 막 생물 반웅장치 및 이를 이용한 하수처 리 방법 Submerged membrane bioreactor and easy sewage treatment method
【기술분야】 Technical Field
<ι> 본 발명은 하수 또는 폐수처리에 사용하는 막 (membrane)생물 반응장치에 관 한 기술로서 더욱 상세하게는 부하변동에 대응이 용이한 침지식 막 생물반응장치 및 이를 이용한 하수처리 방법에 관한 것이다. The present invention relates to a membrane bioreactor used for sewage or wastewater treatment, and more particularly, to a submerged membrane bioreactor and a sewage treatment method using the same. will be.
【배경기술】 Background Art
<2> 하수 또는 폐수처리에 있어서, 방류수질기준의 강화와수질 환경보호를 위하 여, 더욱 깨끗한 방류수질에 대한 수요는 계속 증가하고 있다. <2> In sewage or wastewater treatment, the demand for cleaner discharged water quality continues to increase in order to strengthen the discharged water quality standards and protect the water quality environment.
<3> 과거 주로 생물학적 방법과 중력식 침전을 위주로 한 하수 또는 폐수 처리방 법에서는 방류수 내의 SS (부유물질), 세균 , 바이러스, 유해한 원생동물 등을 효과 적으로 제거하기가 곤란하였다. In the past, it has been difficult to effectively remove SS (sustained substances), bacteria, viruses, and harmful protozoa from effluents in the sewage or wastewater treatment methods, mainly biological methods and gravity sedimentation.
<4> 특히 일부 유해한 원생동물 예를 들면 지아디아 (giardia cysts)나 크립토스 포리디움 (cyptosporidium)같이 장관내에 병변을 유발하는 원생동물들은 방류수질 기준에는 포함되어 있지 않으나, 염소소독으로도 제거하기 어렵기 때문에 이것들을 제거할 필요성이 증가하고 있다. In particular, some harmful protozoa, such as giardia cysts or cyptosporidium, protozoa-induced lesions in the intestinal tract are not included in the water quality criteria, but are also removed by chlorine disinfection. The difficulty is increasing the need to remove these.
<5> 막 생물반응장치는 기존의 생물반응장치에서 침전기능을 막 (membrane)으로 대치한 것으로서, 일반적 용도로서는 정밀여과 막 (microfiltration membrane; MF), 한외여과 막 (ultrafiltration membrane)이 널리 사용되고 있으며, 부유물질과 세 균, 원생동물의 제거에 매우 효과적이기 때문에 널리 사용되고 있다. <5> Membrane bioreactors replace the precipitation function with membranes in conventional bioreactors, and microfiltration membranes (MF) and ultrafiltration membranes are widely used in general applications. It is widely used because it is very effective for removing suspended solids, bacteria and protozoa.
<6> 막의 설치면적 절약 및 막 세척 기능 향상을 위하여 막 (membrane)을 생물 반 웅조의 호기조 내부에 침지 (물속에 잠기게 설치)한 침지식 막 생물 반응장치가 널 리 사용되고 있다. <6> Submerged membrane bioreactors in which membranes are immersed in submerged aerobic tanks (submerged in water) are widely used to save membrane installation area and improve membrane cleaning function.
<7> 침지식 막 생물반응장치는 상기와 같이 커다란 장점이 있는 반면, 막의 공극 이 작아서 막이 쉽게 막히는 것을 방지하기 위하여 연속적으로 막 (membrane)을 세 정하여야 하고, 세정하는데 다량의 공기를 필요로 한다. Submerged membrane bioreactors have the above advantages, while the membrane pores are so small that the membranes must be continuously cleaned to prevent the membranes from clogging and a large amount of air is required for cleaning. do.
<8> 막 세정에 필요한 공기량은 막의 바닥면적에 대하예 00〜 150m3 / itf.hr로서, 하수의 부하량에 관계없이 막 이 작동하는 시간에는 계속적으로 공급하여 세척을 해야 하기 때문에, 유입부하량이 적을 경우, 막 세정에 필요한 공기량이 호기조에 서 생물학적으로 처리하는데 필요한 공기량보다 훨씬 큰 경우가 발생하고, 호기조 의 용존산소 농도를 과도하게 높이기 때문에, 호기조의 용존산소 농도를 적정한 값 으로 조정하지 못하게 되는 커다란 문제가 있다. <8> The amount of air required for membrane cleaning is 00 to 150 m 3 / itf.hr for the bottom area of the membrane, and the inflow load must be continuously supplied and cleaned at the time the membrane is operating regardless of the load of sewage. If less, the amount of air required for membrane cleaning may be much greater than the amount of air needed for biological treatment in the aerobic tank. Since the dissolved oxygen concentration of excessively increases, there is a big problem that the dissolved oxygen concentration in the aerobic tank cannot be adjusted to an appropriate value.
상기와 같이 막 세정에 필요한 세정 공기량은 그 양이 많고, 변동 (감소)시킬 수 없는 것이기 때문에 침지막 생물반응장치로 유입하는 하수의 부하량이 적을 때 는 호기조에 과도한 산소가 공급되어 용존산소 농도가 높아지고, 호기조에서 반송 수를 받는 처리 공정인 무산소조 및 혐기조의 용존산소 농도가 높아져서, 무산소 조및 혐기조가 호기성으로 변하여, 혐기성 상태에서만 일어나는 미생물의 인 방출 이나 탈질 작용이 일어나지 않음으로써, 총 질소 및 총 인의 제거율이 극히 낮아지 거나 제거가 안 되는 문제가 야기된다. As described above, the amount of cleaning air required for membrane cleaning is large and cannot be changed (reduced). Therefore, when the load of sewage flowing into the immersion membrane bioreactor is small, excess oxygen is supplied to the aerobic tank to increase the dissolved oxygen concentration. Total nitrogen and total nitrogen by increasing the dissolved oxygen concentrations in the anaerobic and anaerobic tanks, which are returned from the aerobic tank, and the anaerobic and anaerobic tanks to be aerobic, resulting in no phosphorus release or denitrification of microorganisms that occur only in anaerobic conditions. Phosphorus removal is extremely low or causes problems that cannot be removed.
상기에서 설명한 여과 막의 세정공기량은, 유입 하수 B0D농도 100mg/L의 하 수처리에 필요한 공기량에 상당하기 때문에, 이보다 낮은 B0D농도를 가진 하수의 고도처리시에 상기와 같은 문제가 발생하게 된다. Since the amount of cleaning air of the filtration membrane described above corresponds to the amount of air required for the sewage treatment of the inflow sewage B0D concentration of 100 mg / L, the above problems occur in the advanced treatment of sewage having a lower B0D concentration.
상기 예는 정밀여과 막 (MF)의 경우를 예시한 것이지만, 막 세정 공기량은 비 슷하면서 막 투과량이 정밀여과 막에 비하여 훨씬 더 작은 한외 여과 (UF) 막을 생 물반응조에 적용한 고도처리 공정의 경우에는 ,상기에서 설명한 것과 같이 세정에 필요한 공기량이 더욱 과도하게 되어, 고도처리 공정에 미치는 영향이 절대적이라 서 적용에 더욱 큰 제한을 받게 된다. The above example illustrates the case of a microfiltration membrane (MF), but in the case of a high-treatment process in which an ultrafiltration (UF) membrane is applied to a bioreactor with a similar amount of membrane cleaning air but a much smaller membrane permeation rate than a microfiltration membrane. As described above, the amount of air required for cleaning becomes more excessive, and the influence on the advanced treatment process is absolute, and thus the application is further limited.
【발명의 상세한 설명】 [Detailed Description of the Invention]
【기술적 과제】 [Technical problem]
하수 또는 폐수 처리에 있어서, 유입부하가 저부하 시에도, 막 세정능력을 유지하고, 호기조의 용존산소 농도를 용이하게 조절하여 부하변동에 대옹이 용이하 도록 하고, 항상 정상적인 처리 능력을 유지하는 침지식 막 생물 반웅장치 및 이를 이용한 하수처리방법을 제공하는 것이다. In sewage or wastewater treatment, even when the inflow load is low, the needle can maintain the membrane cleaning ability, and easily adjust the dissolved oxygen concentration in the aerobic tank to facilitate the change of load, and always maintain the normal treatment capacity. The present invention provides a membrane bioreactor and a sewage treatment method using the same.
【기술적 해결방법】 Technical Solution
본 발명은 상기 해결하려는 과제의 목적을 달성하기 위하여, In order to achieve the object of the present invention to solve the above,
하수 중의 모래 및 협잡물을 제거하는 전처리 단계; Pretreatment to remove sand and contaminants in sewage;
유입 하수를 일정시간 저류하고, 후속 공정으로 하수를 균등하게 이송하는 유량 조정단계 ; A flow rate adjusting step of storing the influent sewage for a predetermined time and transferring the sewage to the subsequent process evenly;
유입 하수와 탈기조에서 반송한 반송수를 흔합하여, 혐기조에서 일정시간 체 류하면서, 슬러지 중의 미생물이 흡수하고 있던 인을 방출하는 혐기 처리 단계; <19> 혐기 처리 단계를 통과한 하수와 탈기조에서 반송한 반송수를 흔합하여, 무 산소조에서 일정시간 체류하면서, 탈질 세균의 탈질 작용으로 질소를 제거하는 무 산소 처리 단계 ; An anaerobic treatment step of mixing the inflow sewage and the return water returned from the degassing tank and releasing phosphorus absorbed by the microorganisms in the sludge while staying in the anaerobic tank for a predetermined time; An oxygen-free treatment step of removing nitrogen by denitrification by denitrifying bacteria by mixing the sewage passed through the anaerobic treatment step and the return water returned from the degassing tank for a predetermined time;
<20> 무산소 처리 단계를 통과한 하수에 공기를 공급하여, 호기조에서 일정시간 체류하면서, 호기성 조건에서 유기물을 산화하고 질산화를 일으키는 호기 처리 단 계; An aerobic treatment step of supplying air to the sewage that has passed through the anoxic treatment step, staying in the aerobic tank for a predetermined time, and oxidizing the organic substance under aerobic conditions and causing nitrification;
<21> 막 여과조 내에 위치한 침지식 막 여과기의 하부에 설치한 산기장치에 막 세 정 송풍기에서 이송한 공기를 분사하고, 부상하는 공기의 세정작용을 이용하여 침 지식 막 여과기의 막 표면을 세정하고, 세정한 후에 상승하는 공기 (가스)의 일부 또는 전부를 막 세정 송풍기의 입구로 순환시키면서 막 여과기를 세정하고, 순환가 스량과 공기량의 비율을 조절하여 막 여과조의 용존산소 농도를 조절하고, 침지식 막 여과기를 이용하여, 하수에서 상등수를 분리하는 막 여과 처리 단계 ; <21> Inject air from the membrane cleaner blower to the diffuser installed in the lower part of the immersion membrane filter in the membrane filtration tank, and wash the surface of the membrane of the immersion membrane filter by using the air cleaning function. After washing, some or all of the rising air (gas) is circulated to the inlet of the membrane cleaning blower to clean the membrane filter, and the dissolved oxygen concentration of the membrane filter tank is adjusted by adjusting the ratio of the circulating gas amount and the air amount. A membrane filtration treatment step of separating supernatant from sewage using a membrane filter;
<22> 막 여과 처리 단계를 통과한 하수에 공기공급을 중단하고 일정시간 체류시켜 서 하수 중의 용존산소 농도를 낮추는 탈기 처리 단계 ; 및 A degassing step of stopping air supply to the sewage passing through the membrane filtration step and holding it for a certain time to lower the dissolved oxygen concentration in the sewage; And
<23> 탈기 처리단계의 하수를 무산소 처리 단계와 혐기 처리 단계로 반송하도록 구성한 것을 특징으로 하는 부하변동에 대응이 용이한 침지막 생물 반응장치를 이 용한 하수처리 방법을 제공한다. Provided is a sewage treatment method using an immersion membrane bioreactor that can easily cope with load fluctuation, wherein the sewage from the degassing treatment step is returned to the anaerobic treatment step and the anaerobic treatment step.
<24> <24>
【유리한 효과】 Advantageous Effects
<25> 본 발명의 침지식 막 생물 반웅장치는 막 세정에 필요한 공기를 별도의 송풍 기를 사용하여, 세정을 하고 수면 위로 상승하는 공기의 일부 또는 전부를 재순환 하여 세정을 계속함으로써, 세정기능을 유지하고, 재순환하는 가스량과 공기량의 비율을 조정하여 막 여과조의 용존산소 농도를 적정하게 유지할 수 있고, 호기조에 는 산기장와 호기조 송풍기를 설치하여 별도로 공기량을 조절하여 적정한 용존산소 농도를 유지할 수 있기 때문에 저부하 시 또는 부하 변동이 심한 경우에도 용이하 게 대응을 할 수 있어 항상 하수를 최상의 상태로 처리할 수 있는 효과가 있다. The immersed membrane bioreactor of the present invention maintains the cleaning function by cleaning the air necessary for cleaning the membrane using a separate blower and recirculating some or all of the air rising above the water surface. The dissolved oxygen concentration in the membrane filtration tank can be maintained appropriately by adjusting the ratio of the gas volume and the air volume to be recycled, and the appropriate dissolved oxygen concentration can be maintained by controlling the air volume separately by installing an acid base and an aerobic blower in the aerobic tank. Even under heavy load fluctuations, it is easy to respond, so that the sewage can always be treated in the best condition.
<26> <26>
【도면의 간단한 설명】 [Brief Description of Drawings]
<27> 도 1은 본 발명의 막 여과조를 이용한 A2/0공정의 예시도이다. <27> Figure 1 is an illustration of A 2/0 process using a membrane filtration tank according to the present invention.
<28> 도 2는 본 발명의 막 여과 호기조를 이용한 A2/0공정의 예시도이다. <28> Figure 2 is an exemplary view of the second A / 0 processes using a membrane filtration aerobic tank of the present invention.
<29> 도 3은 본 발명의 막 여과조를 이용한 호기 탈질 공정의 예시도이다. 3 is an exemplary diagram of an aerobic denitrification process using the membrane filtration tank of the present invention.
<30> 도 4는 본 발명의 혐기조의 구성 예시도이다. <31> 도 5는 본 발명의 호기 탈질조의 구성 예시도이다. 4 is a diagram illustrating the configuration of the anaerobic tank of the present invention. 5 is an exemplary view of the configuration of an aerobic denitrification tank of the present invention.
<32> 도 6은 본 발명의 막 여과조의 구성 예시도이다. 6 is an exemplary view of the configuration of the membrane filtration tank of the present invention.
<33> 도 7은 본 발명의 호기조의 구성 예시도이다. 7 is a diagram illustrating the configuration of an aerobic tank according to the present invention.
<34> 도 8은 본 발명의 호기조의 자동제어를 도시한 예시도이다. 8 is an exemplary view showing automatic control of an aerobic tank according to the present invention.
<35> 도 9는 본 발명의 소규모 하수처리시설에서 사용되는 호기조의 일 실시예이 다. 9 is an embodiment of an aerobic tank used in the small sewage treatment facility of the present invention.
<36> <36>
【발명의 실시를 위한 형태】 [Form for implementation of invention]
<37> 막 여과기는 막 (membrane)을 지지체 (frame)에 고정하여 하나의 유니트를 구 성하고, 이런 유니트를 여러 개 조합하여 하나의 막 여과기를 구성한다. Membrane filters form a unit by fixing a membrane to a frame and combining these units together to form a membrane filter.
<38> 멤브레인에는 눈 목 크기 (pore size)에 따라 정밀여과 막 (MF), 한외 여과 막 Membranes include microfiltration membranes (MF) and ultrafiltration membranes, depending on the eye size.
(UF), 나노 막 (NF), 역 삼투 막 (R0)의 구분이 있으며, 하수나 폐수 등의 고도처리 에는 정밀여과 막과 한외여과 막이 주로 사용된다. (UF), nano membrane (NF), reverse osmosis membrane (R0), and microfiltration membrane and ultrafiltration membrane are mainly used for advanced treatment of sewage and wastewater.
<39> 또한 막의 구조에 따라 평 막, 나선형 막, 원통형 막, 중공사막 등이 있으 며, 적은 체적에서 많은 통수면적을 확보할 수 있고 기계적으로 안정적 구조를 가 진 중공사막이 많이 사용되고 있다. In addition, there are flat membranes, spiral membranes, cylindrical membranes, hollow fiber membranes, and the like, and hollow fiber membranes having a stable mechanical structure with a large volume of water can be secured in a small volume.
<40> 상기와 같은 막은 정밀 여과 막은 눈 크기 (pore size)가 0.1 〜 0.4 범위 로서, 통상적으로 세균, 대장균, 원생동물과 미세한 부유물질 (SS)을 제거할 수 있 다. As described above, the microfiltration membrane has a pore size in the range of 0.1 to 0.4, and can generally remove bacteria, Escherichia coli, protozoa, and fine suspended solids (SS).
<4i> 한외여과 막은 눈 크기 (pore size)가 0.001 〜 0.05mi 범위로서, 통상적으로 세균, 대장균, 원생동물과 바이러스 및 미세한 부유물질 (SS)을 제거할 수 있다. <4i> The ultrafiltration membrane has a pore size in the range of 0.001 to 0.05 mi, and can usually remove bacteria, E. coli, protozoa and viruses, and fine suspended solids (SS).
<42> 상기와 같은 특성으로 인하여, 막 여과를 한 물은 매우 깨끗하기 때문에 그 이용이 늘어나는 추세에 있다. Due to the above characteristics, the water after membrane filtration is very clean, the use thereof is increasing.
<43> 그러나 막 여과기는 상기와 같이 물 처리에 있어서 매우 홀륭한 성능이 있는 반면에 눈 크기가 매우 작아서 막히기 쉬운 결함이 있다. Membrane filters, however, have a very good performance in water treatment as described above, while the eye size is so small that they tend to be clogged.
<44> 상기와 같은 결점을 해결하는 수단으로서, 막 여과기를 커다란 미생물 플럭 이 존재하는 호기조의 수중에 침지식으로 설치하고, 막 여과기의 하부에 막 세정용 산기장치를 설치하여, 막 세정용 산기장치에 공기를 송풍하여, 산기장치에서 분출 되는 공기방울의 세정력을 이용하여 막 여과기의 외부표면이 막히는 것을 방지하고 있다. As a means to solve the above drawbacks, the membrane filter is immersed in the aerobic tank in which a large microbial floc is present, and the membrane filter is installed at the lower part of the membrane filter to prevent the membrane filter. Air is blown through the device to prevent clogging of the outer surface of the membrane filter using the cleaning power of air bubbles blown out from the diffuser.
<45> 막 여과기 세정용 공기량은 일반적으로 막 여과기의 바닥면적에 대하예 00〜 <45> The amount of air used to clean the membrane filter generally corresponds to the bottom area of the membrane filter.
150mVm2.hr의 공기를 필요로 하고, 공기량이 많을수록 세정효과가 좋아진다. 또한 주기적으로 중공사막의 내부에서 차 아 염소산 용액을 역류시켜서, 막 에 부착한 오염물질을 세정한다. 150mVm 2 .hr of air is required, and the greater the amount of air, the better the cleaning effect. In addition, the hypochlorite solution is periodically refluxed inside the hollow fiber membrane to clean the contaminants attached to the membrane.
그런데 막 여과기를 세정하는 공기량은 고정된 값으로서, 하수의 유입부하와 는 관계없이 항상 일정한 값을 유지해야 한다. The amount of air cleaning the membrane filter, however, is a fixed value and must be kept constant at all times, regardless of the inflow load of sewage.
하수의 유입량이 적거나 오염농도가 낮아서 유입부하량이 작아지면, 호기조 에서 필요한 공기량이 작아지는데, 우리나라 하수처리장의 경우 시운전 단계나 초 기년도 운전단계에서 하수의 유입부하량은 통상적으로 30~50<¾정도인 곳이 많기 때문에, 호기조에 필요한 공기량도 설계시 산정한 공기량의 30~50%정도만 공급되 어야 한다. If the inflow load is small due to the low inflow of sewage or low pollution concentration, the air volume required in the aerobic tank decreases.In the case of a sewage treatment plant in Korea, the inflow load of sewage during the commissioning stage or the initial stage of operation is typically 30 ~ 50 < ¾ Since there are many places, the air volume required for the aerobic tank should also be supplied only 30-50% of the air volume calculated during design.
그러나 막 여과기에 필요한 공기량은 통상적으로 총 필요 공기량의 70«¾대 이기 때문에, 호기조가 과도하게 높은 용존산소 농도가 되고, 이로 인하여 혐기조 , 무산소조도 호기 상태가 되어서 질소 인의 제거효율이 극히 낮아지는 문제가 발 생하고, 막 여과기를 사용하는 처리 공법에서는 상기와 같은 이유로 초기 저부하 시의 운전에 문제가 야기된다. However, the amount of air required for the membrane filter is usually 70 «¾ of the total required air volume, so that the aerobic tank becomes an excessively high dissolved oxygen concentration, and therefore, the anaerobic tank and the anoxic tank also become aerobic, which leads to extremely low nitrogen removal efficiency. And a treatment method using a membrane filter causes a problem in operation at the initial low load for the same reason.
공기 중에는 질소가 78%, 산소가 21%의 비율로 존재하는데, 질소와산소가 물에 용해되는 농도는 각각의 헨리 정수에 의하여 정해진다. In the air, nitrogen is 78% and oxygen is 21%. The concentration of nitrogen and oxygen in water is determined by each Henry's constant.
질소의 헨리 정수 E는 30°C의 물에 대하여, 9.24 (EX10-4), 산소의 헨리 정 수는 4/75 (EX10一 4)이며, 헨리 정수가 클수록 물에 잘 용해되지 않는다. Henry's constant E of nitrogen is 9.24 (EX10 -4 ) for water at 30 ° C, Henry's constant of oxygen is 4/75 (EX10 一4 ), and the larger the Henry's constant, the less dissolved in water.
따라서 질소는 산소보다 약 1/2 배정도 물에 덜 용해되며,대기압하의 물속에 는 무기 질소가 공기 중 질소가스의 분압에 평형이 되는 정도로 낮은 용해도로 녹 아 있으며, 하수처리시 무기 질소는 미생물 등에 의하여 소비되지 않으므로, 공기 나 질소 가스를 하수 속에 계속 공급하여 포기하더라도 질소는 추가로 더 용해되지 않는다. Therefore, nitrogen is dissolved in water about 1/2 times less than oxygen, and in nitrogen at low pressure, inorganic nitrogen is dissolved at a low solubility that is equilibrium with the partial pressure of nitrogen gas in the air. Since it is not consumed by the air, nitrogen is not further dissolved even if it is continuously given up by supplying air or nitrogen gas into sewage.
공기를 막 여과조에 공급하여, 막 여과기를 세정하는 경우 공급된 공기 중의 산소는 하수 중에 용해되지만, 질소는 용해되지 않는다. When air is supplied to the membrane filtration tank and the membrane filter is washed, oxygen in the supplied air is dissolved in sewage, but nitrogen is not dissolved.
막 여과기의 세정에 사용되고 난 후의 공기 중에는 산소가스 비율은 용해된 만큼 줄어들어 있지만, 질소 가스는 처음에 공급된 상태대로 그대로 남아 있으며, 세정에 사용된 공기를 수집하여, 막 세정 송풍기 (620)의 입구로 이송하고, 계속 재 순환 시키면, 그 순환공기 (이하 "순환 가스"라 칭한다)중에는 산소가스비율은 점점 더 낮아져서, 물속의 용존산소 농도에 평형 되는 분압까지 감소하며, 만약에 막 세 정 송풍기에 외부공기를 공급하지 않으면, 순환가스 중에 있던 산소는 전부 소비되 어 산소 분압이 0이 되고, 막 여과조의 용존산소 농도는 0이 되어 혐기 상태가 될 것이다. In the air after being used to clean the membrane filter, the oxygen gas ratio decreases as much as dissolved, but the nitrogen gas remains as it was originally supplied, collects the air used for cleaning, and enters the membrane cleaning blower 620. In the circulating air (hereinafter referred to as the "circulating gas"), the oxygen gas rate is lowered and reduced to the partial pressure equilibrated with the dissolved oxygen concentration in the water. If no external air is supplied, all the oxygen in the circulating gas is consumed, and the oxygen partial pressure becomes zero, and the dissolved oxygen concentration in the membrane filtration tank becomes zero, resulting in anaerobic condition. will be.
<55> 공기 중에는 산소가 21%, 질소가 78%존재하므로, 막 세정 송풍기에 재순환 되는 순환가스의 산소가스가 소비되면, 그 부피만큼 순환가스의 부피가 줄어들게 되지만 소량의 공기를 외부에서 계속 공급하면 순환가스의 부피는 처음의 공기부피 만큼 회복이 되고, 순환가스 중에는 질소가 대부분을 차지하고 산소는 극히 적게 존재하게 된다. 21% oxygen and 78% nitrogen are present in the air, so when the oxygen gas of the circulating gas recycled to the membrane cleaning blower is consumed, the volume of the circulating gas is reduced by the volume, but a small amount of air is continuously supplied from the outside. The volume of the circulating gas is then recovered as much as the initial volume of air, and nitrogen is the major part of the circulating gas and there is very little oxygen.
<56> 따라서 막 세정 송풍기의 입구에 순환가스를 공급하고, 일부분만 외부공기를 공급하면서 순환가스량과 외부 공기량의 비율을 조정하면, 예를 들어서 하수의 유 입부하량이 적을 때는 외부 공기 공급량을 적게 하고, 하수의 유입부하량이 증가할 때는 외부 공기 공급량을 늘리면서, 순환가스를 순환시킴으로쎄 막 세정에 필요한 가스량을 유지하여, 막 여과기를 효과적으로 세척하면서도 막 여과조 내의 용존산 소 농도를 원하는 수준으로 용이하게 조절할 수 있다. Therefore, if the circulating gas is supplied to the inlet of the membrane cleaning blower, and only a part of the external air is supplied to adjust the ratio of the circulating gas amount and the external air amount, for example, when the inflow load of the sewage is small, the external air supply amount is reduced. When the inflow load of sewage increases, it increases the external air supply, circulates the circulating gas, maintains the amount of gas necessary for membrane cleaning, and effectively washes the membrane filter, while easily maintaining the dissolved oxygen concentration in the membrane filtration tank to the desired level. I can regulate it.
<57> 본 발명은 상기와 같은 원리를 이용하여 막 여과 처리 단계를 구성하였으며, 막 여과 처리 단계의 막 여과조에 대한 구성을 도 6에 표시하였다. In the present invention, the membrane filtration treatment step is configured using the same principle as above, and the configuration of the membrane filtration tank of the membrane filtration step is shown in FIG. 6.
<58> 막 여과조 (610)의 수중에 막 여과기 (630)을 설치하고, 막 여과기의 하부에 막 세정용 산기장치 (640)를 설치하고, 막 세정 송풍기 (620)의 출구에서 막 세정용 산기장치 (640)의 입구까지 공기배관을 연결하였다. The membrane filter 630 is installed in the water of the membrane filtration tank 610, and the membrane cleaning air diffuser 640 is installed below the membrane filter, and the membrane cleaning air diffuser is discharged from the outlet of the membrane cleaning blower 620. An air line was connected to the inlet of the device 640.
<59> 또한 막 여과조 (610)의 상부를 밀폐할 수 있도록 차단 덮개 (650)를 설치하 여, 막 여과기를 세정한 공기 (=순환가스)가 막 여과조의 상부에 포집할 수 있게 하 였고, 차단 덮개에는 통기 배관 (670)을 설치하여, 남는 가스의 배기를 통하여, 차 단 덮개로 밀폐한 공간에 부압이나 정압이 작용하지 않도록 하였다. In addition, a blocking cover 650 was installed to seal the top of the membrane filtration tank 610 so that the air (= circulating gas) cleaned by the membrane filter could be collected at the top of the membrane filtration tank. A ventilation pipe 670 was provided in the shutoff cover to prevent negative pressure or static pressure from acting on the space sealed by the shutoff cover through the exhaust of remaining gas.
<60> 막 여과조의 상부 공간에 포집된 순환가스는 차단 덮개 (660)의 상부에서 막 세정 송풍기 (620)의 입구 쪽 배관에 연결한 가스 순환관 (660)을 통하여 막 세정 송 풍기 (620)의 입구로 순환하도록 하였고, 순환가스량의 조절을 위하여 순환가스량 조절밸브 (680)를 설치하였다. The circulating gas collected in the upper space of the membrane filtration tank is supplied to the membrane cleaning blower 620 through the gas circulation pipe 660 connected to the inlet pipe of the membrane cleaning blower 620 at the upper portion of the blocking cover 660. In order to circulate to the inlet of, and to control the amount of circulating gas circulating gas amount control valve 680 was installed.
<6i> 막 세정 송풍기 (620)의 입구 쪽에는 외부 공기를 흡입하기 위하여 흡입배관 을 설치하고, 홉입배관에는 흡입공기량을 조절하기 위하여 공기량 조절밸브 (690)를 설치하였다. An inlet pipe is installed at the inlet side of the membrane cleaning blower 620 to suck external air, and an air volume control valve 690 is installed at the inlet pipe to adjust the intake air amount.
<62> 상기와 같이 구성하고, 유입 하수의 부하량에 따라서, 막 세정 송풍기에 순 환가스와 외부 공기를 공급하는 비율을 조절하여, 막 세정에 필요한 공기량 (가스 량)을 유지하면서도, 막 여과조 (610) 내의 용존산소 농도를 원하는 농도로 용이하 게 조절할 수 있게 하였다. 도 1은 상기에서 설명한 막 여과조를 이용하여 , A2/0공정을 구성한 예시 도 이다. According to the above-described configuration, the membrane filtration tank is maintained while controlling the ratio of supplying circulating gas and external air to the membrane cleaning blower according to the load amount of the inflow sewage, while maintaining the air amount (gas amount) required for membrane cleaning. The dissolved oxygen concentration in 610) can be easily adjusted to the desired concentration. Figure 1 is an exemplary view configure the membrane using a filtration tank, A 2/0 process described above.
A2/0공정은 하수처리의 고도처리 공법의 하나로서, 하수 중에 포함된 유기물 은 물론 질소와 인을 동시에 생물학적 처리방법으로 제거하는 공법이며, 전 세계적 으로 가장 널리 사용되고, 좋은 처리결과를 보이고 있다. A 2/0 process is one of the advanced treatment process of wastewater treatment, the method for removing the organic matter as well as nitrogen and phosphorus at the same time, how the biological process contained in the sewage, the most widely used worldwide, showing a good treatment outcome .
도 1은 본 발명의 표준적인 A2/0공정을 예시한 것이며, 공정순서를 바꾸거나 일부 생략한 것 등의 수많은 변형은 본 발명의 범주에 포함되는 것으로 간주하여야 한다. Figure 1 shows a modification of the example 2 a standard A / 0 processes of the invention, numerous modifications, such as changing the process sequence or to a part omitted should be considered to be within the scope of the invention.
도 1의 공정의 구성내용을 설명하면 다음과 같다. Referring to the configuration of the process of Figure 1 as follows.
전처리 단계 (100)에서 유입된 하수 중에 포함된 협잡물과모래를 제거한다. 제거된 협잡물과 모래는 일시 저장하였다가 외부로 반출처분한다. Removes contaminants and sand contained in the sewage introduced in the pre-treatment step (100). Removed debris and sand are temporarily stored and released to the outside.
협잡물과 모래가 제거된 하수는 유량 조정단계에서 유량 조정조에 유입되어 일정시간 체류하면서 유량 변동률이 적어지게 되고, 하수는 유입펌프에 의하여 다 음 공정인 혐기 처리 단계 (300)로 이송된다. The sewage from which the contaminants and sand are removed is introduced into the flow adjustment tank in the flow adjustment step and the flow rate is reduced while staying for a predetermined time, and the sewage is transferred to the anaerobic treatment step 300, which is the next process, by the inflow pump.
혐기 처리 단계에서는 탈기 처리 단계 (700)에서 반송된 반송수 1(860)과 하 수를 혐기조에서 균등하게 흔합하고, 일정시간 동안 혐기 상태로 체류시키면서 하 수 중의 미생물이 생체내의 인을 방출하게 한다. In the anaerobic treatment step, the return water 1 (860) returned from the degassing treatment step (700) and the sewage are equally mixed in the anaerobic tank, and the microorganisms in the sewage discharge the phosphorus in the living body while remaining in the anaerobic state for a certain time. .
도 4는 혐기조의 구성을 예시한 것이며, 혐기조 (310)에 하수와 반송수가 유 입되고, 혐기조 교반기 (320)의 작용에 의하여 하수와 반송수가 균등하게 흔합된다. 혐기조는 인 방출을 촉진하기 위하여 0RP (산화 환원 전위)값은 -300~400mV 로 유지되어야 하며 용존산소 농도는 O.lmg/L이하로 유지되어야 한다. 4 illustrates the configuration of the anaerobic tank, and the sewage and the return water are introduced into the anaerobic tank 310, and the sewage and the return water are equally mixed by the action of the anaerobic agitator 320. In order to promote phosphorus release, the 0RP (redox potential) value should be maintained at -300 ~ 400mV and the dissolved oxygen concentration should be kept below O.lmg / L.
혐기 단계를 통과한 하수는 무산소 처리 단계 (400)로 이송된다. The sewage that has passed through the anaerobic stage is sent to an anaerobic treatment stage 400.
*무산소 처리 단계에서는 무산소조 (410)에 하수와 반송수 2(850)가 유입하 여, 무산소조 교반기 (320)의 작용에 의하여 균둥하게 흔합된다. * In the anaerobic treatment step, the sewage and return water 2 (850) flows into the anaerobic tank 410 and is mixed evenly by the action of the anaerobic tank stirrer 320.
무산소 처리 단계에서는 무산소 상태에서 탈질 세균의 탈질 작용으로 질산성 질소가 무기 질소로 전환되어 대기 중에 방출함으로써, 하수 중의 질소를 제거한 다. In the anaerobic treatment step, the nitrate nitrogen is converted to inorganic nitrogen by the denitrification of the denitrifying bacteria in the anaerobic state, and released into the atmosphere, thereby removing nitrogen from the sewage.
상기 혐기조와 무산소조는 상부를 밀폐하거나 덮개를 덮어서, 산소 또는 공 기와의 접촉을 방지하는 것이 필요하다. The anaerobic and anaerobic tanks need to be sealed or covered with a top to prevent contact with oxygen or air.
무산소 처리 단계를 통과한 하수는 호기 처리 단계 (500)로 이송된다. 호기 처리 단계에서는 하수 중의 유기물을 분해하고, 암모니아성 질소를 질 산성 질소로 전환하는 질산화를 일으키고, 상기 혐기 처리 단계 (300)에서 인을 방 출하였던 인 처리 미생물이 정상적인 인 흡수량보다 약 2~6배의 더 많은 양의 인 을 흡수하는 인 과량 흡수작용을 일으키며, 인을 과량으로 흡수한 미생물을 후속 단계인 탈기 처리 단계에서 잉여 슬러지로 배출함으로써, 하수 중의 인을 제거하게 된다. The sewage that has passed the anaerobic treatment step is sent to the aerobic treatment step 500. In the aerobic treatment step, the organic matter in the sewage is decomposed, nitrification is carried out to convert ammonia nitrogen to nitrate nitrogen, and the phosphorus-treated microorganism that has released phosphorus in the anaerobic treatment step 300 is about 2 to 6 times more than the normal phosphorus absorption amount. Phosphorus over-absorption acts to absorb a larger amount of phosphorus in the vessel, and the phosphorus in the sewage is removed by releasing the excess phosphorus microorganisms into the excess sludge in the subsequent degassing step.
호기 처리 단계는 질소와 인의 제거를 위한 고도처리 공정의 경우에 용존산 소 농도를 2.0~4.0mg/L로 유지하지만, 하수 중의 유기물 농도가 낮은 경우에는 질 산화에 지장이 없는 한 낮게 유지해야하며, 1.5~2.0mg/L 유지하는 것이 바람직하 다. The aerobic treatment step maintains the dissolved oxygen concentration at 2.0 to 4.0 mg / L in the advanced treatment process for nitrogen and phosphorus removal. However, the aerobic treatment step should be kept low unless the concentration of organic matter in the sewage is low, as long as it does not interfere with nitrification. It is desirable to maintain 1.5 ~ 2.0mg / L.
호기 처리 단계에서 특히 유입 하수의 부하량이 적어서 산기장치에서 용존산 소 농도를 유지하기 위한 공기량을 공급할 때 슬러지가 첨전되던지 완전 흔합조건 이 되지 않는 경우에는, 제 5도와 같이 공기를 공급하기 위한 산기장치 (530) 이외 에도, 선택적으로 교반을 위한호기조 교반기 (520)를 설치할 수 있다. In the aerobic treatment stage, especially when the sludge is charged or not completely mixed when supplying air to maintain the dissolved oxygen concentration in the diffuser due to the small load of inflow sewage, the air diffuser for supplying air as shown in FIG. In addition to the apparatus 530, an aeration tank stirrer 520 for agitation may be optionally installed.
호기 처리 단계를 통과한 하수는 막 여과 처리 단계 (600)로 이송되어서, 도 6과 같이, 막 여과기 (630)에서 상등수를 분리하고, 남은 하수는 탈기 처리 단계 (700)로 이송한다. The sewage passing through the aerobic treatment step is transferred to the membrane filtration treatment step 600, as shown in FIG. 6, the supernatant is separated from the membrane filter 630, and the remaining sewage is transferred to the degassing treatment step 700.
막 여과 처리 단계에서는 상등수의 분리와 관련하여, 막 여과기의 세정이 중 요한 사항이며, 세정 공기로 인하여 막 여과조 (610) 내의 용존산소 농도가 적정치 (1.5~2.0mg/L)보다 높아지지 않도록 하여야 한다. In the membrane filtration step, the washing of the membrane filter is important in relation to the separation of the supernatant water, so that the dissolved oxygen concentration in the membrane filtration tank 610 is not higher than the optimum value (1.5 to 2.0 mg / L) due to the washing air. shall.
본 발명은 상기에서 전술한 것처럼, 막 세정 송풍기 (620)에 순환가스와 외부 공기를 공급하는 비율을 조절하여 막 여과기를 효과적으로 세정하고, 막 여과조 (610) 내의 용존산소 농도도 적정범위로 유지할 수 있게 하였다. (도 6 참조) As described above, the present invention can effectively clean the membrane filter by adjusting the ratio of supplying circulating gas and external air to the membrane cleaning blower 620, and also maintain the dissolved oxygen concentration in the membrane filter tank 610 in an appropriate range. It was. (See Figure 6)
막 여과 처리 단계 (600)에서 상등수를 분리하고 남은 하수는, 탈기 처리 단 계 (700)에서 일정시간 동안 공기 공급을 중단한 상태로 체류시켜서, 하수 중의 용 존산소 농도를 0.5mg/L 이하로 낮추어서, 혐기 처리 단계 (300)로 일부를 반송하고 (860), 일부는 무산소 처리단계 (400)로 반송한다 (850). (반송은 하수와 활성 슬러지 가 포함된 흔합액을 혐기 처리 단계 또는 무산소 처리 단계로 이송하는 것을 말하 며, 반송된 하수는 "반송수"라 한다) The sewage remaining after separating the supernatant from the membrane filtration treatment step (600), is maintained in the degassing step (700) with the air supply interrupted for a certain time, so that the dissolved oxygen concentration in the sewage to less than 0.5mg / L Lowering, a part is returned to the anaerobic treatment step 300 (860), and a part is returned to the anaerobic treatment step 400 (850). (Returning refers to the transfer of a mixture containing sewage and activated sludge to an anaerobic or anaerobic treatment step, and the returned sewage is called "return water")
탈기 처리 단계에서, 처리 공정에서 필요로 하는 슬러지의 양보다 더 많아서 남는 슬러지는 잉여 슬러지로, 공정 외로 배출하여서 처분하여, 잉여 슬러지의 처 분으로 인하여 하수 중의 인이 제거되는 것이다. 도시하지는 않았지만 탈기 처리 단계에서 슬러지의 침강을 방지하기 위한 교 반기를 설치하는 것이 바람직하다 . In the degassing step, the remaining sludge is more than the amount of sludge needed in the treatment process, and the excess sludge is disposed of by discharging it out of the process to remove phosphorus in the sewage due to the disposal of the excess sludge. Although not shown, it is preferable to install a stirrer to prevent sludge settling in the degassing step.
상기와 같은 과정을 반복하면서 하수를 처리한다 . The sewage is treated while repeating the above process.
도 2는 본 발명의 막 여과 호기조를 이용한 A2/0공정의 예시도로서, 상기 도 2 is by way of illustration of A 2/0 process using a membrane filtration aerobic tank of the present invention, wherein Fig.
1에서 예시한 공정에서 호기 처리 단계와 막 여과 처리 단계를 하나의 단계로 통합 하여 막 여과 호기 처리 단계를 구성한 것이다. In the process exemplified in step 1, the aerobic treatment step and the membrane filtration treatment step are combined into one step to form a membrane filtration aerobic treatment step.
본 공정의 협잡물 처리 단계 (100) 및 유량 조절단계 (200)는 상기에서 이미 설명한 것과 같으므로 설명을 생략한다. The contaminant treatment step 100 and the flow rate adjustment step 200 of the present process are the same as those already described above, and thus description thereof is omitted.
혐기 처리 단계 (300)에서는 탈기 처리 단계 (700)에서 반송된 반송수 2(860) 와 하수가 혐기조에서, 교반기의 작용으로 균등하게 흔합되면서, 일정시간 혐기 상 태로 체류하면, 인 제거 미생물이 생체 내에 축적하였던 인을 방출한다. In the anaerobic treatment step 300, while the return water 2 860 and the sewage returned from the degassing treatment step 700 are equally mixed in the anaerobic tank by the action of the stirrer, the phosphorus-removing microorganism is living in the anaerobic state for a certain time. The phosphorus accumulated in the body is released.
혐기 처리 단계를 통과한 하수는 무산소 처리 단계 (400)에서 혐기 처리 단계 를 통과한 하수와 반송수 1(850)이 무산소조에서, 교반기의 작용으로 균등하게 흔 합되면서, 일정시간 무산소 상태로 체류하면, 탈질 세균의 작용으로 하수 중의 질 산성 질소가무기 질소가스로 전환되어 대기중으로 방출되면서 질소가 제거된다. 무산소 처리 단계를 통과한 하수는 막 여과 호기 처리 단계 (500B)로 이송된 다. The sewage that has passed through the anaerobic treatment stage is an anaerobic treatment stage in the anaerobic treatment stage 400 and the sewage and return water 1 (850) evenly mixed in the anaerobic tank, the action of the stirrer, while staying in an anaerobic state for a certain time With the action of denitrifying bacteria, nitric acid nitrogen in sewage is converted to inorganic nitrogen gas and released into the atmosphere to remove nitrogen. The sewage that has passed through the anaerobic treatment step is sent to the membrane filtration aerobic treatment step 500B.
도 7은 본 발명의 막 여과 호기 처리 단계 (500B)의 호기조의 구성에 대한 예 시도이다. 7 is an example attempt for the construction of an aerobic tank of the membrane filtration aerobic treatment step 500B of the present invention.
호기조 (510)의 내부 물 속에 막 여과기 (630)를 설치하고 막 여과기의 하부 에 막을 세정하기 위한 막 세정용 산기장치 (640)를 설치하고 막 세정용 산기장치와 막 여과 호기조 송풍기 (550)의 토출구 사이는 공기배관으로 연결하였다. A membrane filter 630 is installed in the internal water of the aerobic tank 510, and a membrane cleaning diffuser 640 is installed at the lower portion of the membrane filter to remove the membrane cleaner. The outlets were connected by air piping.
또한 호기조 (510) 내의 하부 바닥 부근에는, 호기조에 공기를 공급하기 위한 산기장치 (530)를 설치하고, 역시 막 여과 호기조 송풍기 (550)의 토출구에 공기배관 으로 연결하였다. In addition, near the bottom of the bottom of the exhalation tank 510, an air diffuser 530 for supplying air to the exhalation tank was installed, and also connected to the discharge port of the membrane filtration exhalation tank blower 550 by an air pipe.
호기조 (510)의 상부는 차단 덮개 (650)를 설치하여, 호기조의 상부 공간을 대 기와 차단하여 밀폐하였고, 상기 차단 덮개에는 통기 배관 (670)을 설치하여, 대기 와 통하게 하였다. The upper portion of the exhalation tank 510 was installed by blocking the cover 650, the upper space of the exhalation tank was sealed by air, and the ventilation cover 670 was installed in the blocking cover to communicate with the atmosphere.
통기 배관은 호기조 상부의 공간에 부압 (-압력)이나 정압 (+압력)이 발생하 는 것을 방지하고, 포기 후에 남는 공기 (순환가스)를 배기하기 위한 것이다. The aeration pipe is to prevent the occurrence of negative pressure (-pressure) or positive pressure (+ pressure) in the space above the aeration tank and to exhaust the air (circulating gas) remaining after the aeration.
차단 덮개 (650)의 상부에서 막 여과 호기조 송풍기 (550)의 흡입구까지는 가 스 순환관 (660)으로 연결하였고, 가스 순환관에는 순환 가스량 조절밸브 (560)를 설 치하였다. A gas circulating pipe 660 was connected from the upper portion of the blocking cover 650 to the inlet of the membrane filtration aeration tank blower 550, and a circulating gas flow control valve 560 was installed in the gas circulation pipe. It was done.
<ιοο> 막 여과 호기조 송풍기 (550)를 가동하여 호기조에 공기를 공급하면, 공기는 산기장치 (530)와 막 세정용 산기장치 (640)에 공급되어서, 호기조 내부의 하수에 공 기를 공급하여 용존산소 농도를 유지하고, 공기의 부상시 발생하는 세정작용올 이 용하여 막 여과기의 막을 세정한다. <ιοο> When the membrane filtration exhalation tank blower 550 is operated to supply air to the exhalation tank, the air is supplied to the air purifier 530 and the membrane cleaning air purifier 640, and the air is supplied to the sewage inside the exhalation tank to be dissolved. The oxygen concentration is maintained, and the membrane of the membrane filter is cleaned by using the cleaning action generated when air is floating.
<ιοι> 하수에 공기를 공급하고, 막 세정을 하고 난 후의 공기는 호기조의 상부 공 간에 모이고, 이 공기 중에는 질소가 상대적으로 많고 산소가 상대적으로 적은 가 스가 되는데, 이 가스의 일부를 가스 순환관 (660)올 통하여, 막 여과 호기조 송풍 기 (550)로 순환시킨다. <ιοι> After the air is supplied to the sewage and the membrane is cleaned, the air collects in the upper space of the aerobic tank, and this air is a gas with relatively high nitrogen and relatively low oxygen. 660 is circulated through the membrane filtration aeration tank blower 550.
<102> 막 여과 호기조 송풍기의 흡입구 쪽에는 대기중의 공기를 흡입하기 위한 공 기 홉입배관을 설치하고, 흡입하는 공기량을 조절하기 위한 공기량 조절밸브를 설 치하였다. At the inlet side of the membrane filtration exhalation tank blower, an air inlet pipe for inhaling air in the atmosphere is installed, and an air volume control valve for adjusting the intake air amount is installed.
<103> 호기조 내의 용존산소 농도를 원하는 값으로 유지하기 위해서는 막 여과 호 기조 송풍기 (550)의 입구에 설치한 공기량 조절밸브 (570)와 순환가스량 조절밸브 (560)의 개도를 조절하여, 외부에서 흡입되는 공기량과 순환가스량의 비율을 조절 하여, 원하는 용존산소 농도가 되도록 조절한다. In order to maintain the dissolved oxygen concentration in the aerobic tank at a desired value, the opening degree of the air flow control valve 570 and the circulating gas flow control valve 560 provided at the inlet of the membrane filtration aerobic blower 550 is controlled. Adjust the ratio between the amount of intake air and the amount of circulating gas to achieve the desired dissolved oxygen concentration.
<104> 흡입되는 공기량과 순환가스량은 밸브의 개도를 조절하는데 따라 변화하지 만, 막 여과 호기조 송풍기 (550)에서 토출하는 공기량 (공기와 순환가스의 흔합공 기)은 일정하기 때문에, 하수의 유입부하가 적어서, 용존산소 농도를 적정하게 유 지하는데 필요한 공기량이 감소하여, 외부에서 공급하는 공기량을 줄이더라도, 막 여과기를 세정하는 세정작용은 일정하게 유지된다. Although the amount of air sucked in and the amount of circulating gas change depending on the opening degree of the valve, the amount of air discharged from the membrane filtration aeration tank blower 550 (combined air of the air and the circulating gas) is constant. Due to the low load, the amount of air required to maintain the dissolved oxygen concentration appropriately decreases, so that even if the amount of air supplied from the outside is reduced, the cleaning action for cleaning the membrane filter is kept constant.
<105> 제 8도는 본 발명의 막 여과 호기 처리 단계에서, 호기조 (510)의 물 속에 용 존산소 농도계 (10)와 자동 제어기 (30) 및 순환가스량 자동 조절밸브 (560a)와 공기 량 자동 조절밸브 (570a)를 설치하여, 호기조 내의 용존산소 농도를 설정한 값으로 유지하도록 자동적으로 제어하는 예를 표시한 것이다. 8 shows the oxygen concentration meter 10, the automatic controller 30, the circulating gas volume automatic control valve 560a and the air volume automatically in the water of the aerobic tank 510 in the membrane filtration aerobic treatment step of the present invention. The example which installed the valve 570a and controls it automatically so that the dissolved oxygen concentration in an aerobic tank may be kept at the set value is shown.
<106> 용존산소 농도계 (10)에서 측정한 호기조 내의 용존산소 농도가 설정한 값보 다 작으면, 자동제어기 (30)는 공기량 조절밸브 (570a)의 개도를 증가하여, 외부에서 흡입하는 공기량을 증가시키고, 호기조 내의 용존산소 농도가 설정한 값보다 크면, 자동제어기는 순환가스량 자동 조절밸브 (560a)의 개도를 증가하고 공기량 자동 조 절밸브 (570a)의 개도를 감소시켜서 호기조 내의 용존산소 농도를 설정한 값으로 일 정하게 유지한다. If the dissolved oxygen concentration in the aerobic tank measured by the dissolved oxygen concentration meter 10 is smaller than the set value, the automatic controller 30 increases the opening degree of the air volume control valve 570a and increases the amount of air sucked from the outside. If the dissolved oxygen concentration in the exhalation tank is larger than the set value, the automatic controller sets the dissolved oxygen concentration in the exhalation tank by increasing the opening degree of the circulating gas amount automatic control valve 560a and decreasing the opening degree of the air volume automatic control valve 570a. Keep it constant at one value.
<107> 제 9도는 본 발명을 소규모 하수처리시설에 적용되는 호기조의 일 실시예이 다. 9 shows an embodiment of an aerobic tank in which the present invention is applied to a small sewage treatment facility. All.
소규모 하수처리시설이나 마을 하수도 같이 막 여과기 (630)의 숫자가 1개 내 지 2~3개 정도로 작을 경우에는 호기조의 상부를 차단 덮개로 밀폐하는 것보다, 각각의 막 여과기 (630)의 상부에 개별적으로 차단 덮개 (650)를 설치하는 것이 더 경제적인 경우가 많다. If the number of membrane filters 630 is small, such as a small sewage treatment plant or village sewage system, between one and two or three, the upper portion of the aerobic tank may be closed with a shield cover, and the upper portion of each membrane filter 630 may be closed. It is often more economical to install the blocking covers 650 individually.
상기와 같은 경우에, 호기조 (510)의 물속에 막 여과기 (630)를 설치하고, 막 여과기의 하부에 막 세정용 산기장치 (640)를 설치하고, 막 세정용 산기장치와 막 세정 송풍기 (620)의 토출구 사이는 공기배관으로 연결하였다. In the case described above, the membrane filter 630 is installed in the water of the aerobic tank 510, the membrane cleaning diffuser 640 is installed below the membrane filter, and the membrane cleaning diffuser and the membrane cleaning blower 620 are provided. ) Between the discharge port is connected to the air piping.
막 여과기마다 개별적으로 설치한 차단 덮개 (650)의 상부에서, 막 세정 송풍 기 (620)의 입구 쪽까지는 가스 순환관 (660)으로 연결하였고, 가스 순환관에는 순환 가스량 조절밸브 (680)를 설치하였고, 막 세정 송풍기 (620)의 입구 쪽에는 대기중의 공기를 흡입하기 위한 흡입배관을 설치하고, 흡입공기량을 조절하기 위한 공기량 조절밸브 (690)를 설치하였다. From the upper part of the blocking cover 650 installed separately for each membrane filter, the inlet side of the membrane cleaning blower 620 was connected to the gas circulation pipe 660, and the gas circulation pipe was provided with a circulating gas flow control valve 680. On the inlet side of the membrane cleaning blower 620, a suction pipe for inhaling air in the atmosphere was installed, and an air volume control valve 690 for adjusting the intake air amount was installed.
또한 호기조 (510)의 내부 바닥 부근에는 호기조의 포기를 위한 산기장치 (530)을 설치하고, 산기장치와 막 여과 호기조 송풍기 (550)의 토출구 사이는 공기 배관으로 연결하였다. In addition, an air diffuser 530 for abandoning the aerobic tank was installed near the inner bottom of the aerobic tank 510, and the air outlet was connected between the air diffuser and the discharge port of the membrane filtration aerobic blower 550.
용존산소 농도를 조절하기 위하여, 산기장치에 공급하는 공기량의 조절은 소 음 방풍기 (590)에서 일부 토출공기를 대기 중으로 방출하여서 조절하는 방법과 송 풍기의 회전수를 제어하여 조절하는 방법을 사용할 수 있다. In order to control the dissolved oxygen concentration, the amount of air supplied to the air diffuser is controlled by releasing some discharged air into the atmosphere from the noise blower 590 and controlling the number of revolutions of the blower. Can be.
막 여과기 (630)를 세정하고, 용존산소 농도를 조절하기 위하여 순환가스량과 홉입공기량의 비율을 조절하는 방법은 상기에서 여러번 설명한 것과 같다. In order to clean the membrane filter 630 and to adjust the dissolved oxygen concentration, the method of adjusting the ratio of the amount of circulating gas and the amount of hop-in air is the same as described above.
도 3은 본 발명의 막 여과조를 이용한 하수 처리 공정의 예시 도로서 하기와 같이 구성하였다. 3 is an exemplary view of a sewage treatment process using the membrane filtration tank of the present invention.
유입된 하수 중의 협잡물과 모래를 제거하는 전처리 단계 (100); A pretreatment step (100) for removing contaminants and sand in the introduced sewage;
하수를 일정시간 체류시키는 유량 조정단계 (200); Flow rate adjustment step 200 to maintain the sewage for a certain time;
하수와 반송수를 흔합하여, 혐기 상태에서 미생물 내의 인을 방출시키는 혐 기 처리 단계 (300); An anaerobic treatment step 300 of mixing sewage and return water to release phosphorus in the microorganism in the anaerobic state;
낮은 용존산소 농도와 특정한 산화환원 전위 값으로 유지하여,하수 중의 유 기물을 분해하고, 질소를 탈질하고, 미생물이 인을 과량흡수하게 하는 호기 탈질 처리 단계 (500A); An aerobic denitrification treatment step 500A that maintains a low dissolved oxygen concentration and a specific redox potential value, decomposes organic matter in the sewage, denitrates nitrogen, and allows the microorganism to absorb excessively phosphorus;
하수의 용존산소 농도를 l~2.0mg/L로 높게 유지하여, 미생물을 활성화 하고 일부 미처리된 암모니아성 질소를 질산성 질소로 전환하고, 상등수를 분리하는 막 여과 처리 단계 (600); Membrane that keeps dissolved oxygen concentration of sewage at l ~ 2.0mg / L, activates microorganism, converts some untreated ammonia nitrogen to nitrate nitrogen, and separates supernatant Filtration treatment step 600;
하수 중의 용존산소 농도를 낮추기 위한 탈기 처리 단계 (700); Degassing treatment step 700 to lower the dissolved oxygen concentration in the sewage;
반송펌프 (800) 및 반송수 (900)로 구성한 것을 특징으로 하는 부하변동에 대 웅이 용이한 침지식 막 생물 반웅장치를 이용한 하수처리 방법을 제공한다. Provided is a sewage treatment method using a submerged membrane bioreaction device that is easy to vary in load, characterized by consisting of a conveying pump 800 and a conveying water 900.
전처리 단계 (100) 및 유량 조정단계 (200)는 상기에서 전술한 바와 같으며, 혐기 처리 단계 (300)에서는 도 4와 같이 혐기조 (310)에서 반송수 (900)와 하수가 흔 합되고 혐기 상태로 일정시간 체류하면서, 미생물 내부에 포함되었던 인을 방출하 게 되고, 탈질 세균의 작용으로 반송수 중에 미량 포함되어 있는 질산성 질소가 질 소 가스로 전환되어 탈질이 된다. The pretreatment step 100 and the flow rate adjusting step 200 are as described above, and in the anaerobic treatment step 300, the return water 900 and the sewage are mixed in the anaerobic tank 310 as shown in FIG. During a certain period of time, the phosphorus contained in the microorganisms is released, and the nitric acid nitrogen contained in traces in the return water is converted to nitrogen gas by the action of denitrifying bacteria.
호기 탈질 처리 단계 (500A)에서는 도 5와 같이 호기 탈질조 (510a)의 내부 바 닥부근에 산기장치 (530)를 설치하고, 호기 탈질용 교반기 (520a)를 설치하였다. 산기장치와호기용 송풍기 (540)의 토출구는 공기배관으로 연결하였다. In the aerobic denitrification step 500A, an air diffuser 530 is installed near the inner bottom of the aerobic denitrification tank 510a, and an aerobic denitrification stirrer 520a is installed. The discharge port of the air diffuser and the blower blower 540 was connected by air piping.
호기 탈질조 (510a)의 용존산소 농도는 호기용 송풍기의 공기공급량을 조절하 여 0.3~0.5mg/L로 비교적 낮게 유지하고, 산화환원 전위 (0RP) 값은 수소 전극 기 준으로 +330mV로 유지하면, 호기 탈질 세균의 작용으로 하수 중의 암모니아성 질소 가 질산성 질소로 산화되면서, 동시에 질소가스로 전환되어 탈질이 일어난다. The dissolved oxygen concentration of the aerobic denitrification tank (510a) is kept relatively low at 0.3 ~ 0.5mg / L by controlling the air supply of the aerobic blower, and the redox potential (0RP) is maintained at + 330mV based on the hydrogen electrode. In this case, ammonia nitrogen in sewage is oxidized to nitrate nitrogen by the action of aerobic denitrification bacteria, and at the same time, denitrification occurs by conversion to nitrogen gas.
또한 혐기 처리 단계에서 인을 방출하였던 미생물은 호기 상태에서 인을 과 량으로 흡수하고, 호기 상태에서 유기물도 분해되어 처리된다. In addition, the microorganisms that released phosphorus in the anaerobic treatment step absorb excess phosphorus in aerobic state, and organic matter is decomposed and treated in aerobic state.
막 여과 처리 단계 (600)의 막 여과조는 도 6과 같이 구성하였고, 이 구성과 작용은 전술한 바와 같으나, 막 여과조 (610)내의 용존산소 농도를 1.0~2.0mg/L로 높게 유지하면서 일정시간 처리하여, 미생물의 활성도를 높이고, 질산화 세균의 작 용으로 호기 탈질조 (510a)에서 일부 질산화가 되지 않을 수도 있는 암모니아성 질 소를 질산성 질소로 산화한다. The membrane filtration tank of the membrane filtration treatment step 600 was configured as shown in FIG. 6, and the configuration and operation were as described above, but the dissolved oxygen concentration in the membrane filtration tank 610 was maintained at 1.0 to 2.0 mg / L for a predetermined time. By treatment, the activity of the microorganism is increased, and ammonia nitrogen, which may not be partially nitrified in the aerobic denitrification tank 510a due to the action of nitrifying bacteria, is oxidized to nitrate nitrogen.
또한 막 여과 처리 단계에서, 막 여과기 (630)에서 하수와 상등수를 분리한 다. Also in the membrane filtration treatment step, sewage and supernatant are separated in membrane filter 630.
호기 탈질의 장점은 소요 공기량이 적고, 이론적으로는 pH, ORP, HRT등의 운 전조건을 이상적으로 유지하면 100%의 탈질이 가능한 것이다. The advantage of aerobic denitrification is that the amount of air required is low, and in theory, 100% of denitrification is possible if the operating conditions such as pH, ORP and HRT are ideally maintained.
탈기 처리 단계 (700)에서는 하수를 일정시간 동안 공기공급을 중단하여, 하 수의 용존산소 농도를 0.5mg/L이하로 낮게 유지하여 연결 공정인 혐기 처리 단계의 처리 효과를 높인다. In the degassing treatment step 700, the supply of air to the sewage is stopped for a certain time, and the dissolved oxygen concentration of the sewage is kept lower than 0.5 mg / L to increase the treatment effect of the anaerobic treatment step, which is a connecting process.
탈기 처리 단계에서 잉여 슬러지를 제거함으로써, 하수 중의 인을 제거하게 된다. By removing excess sludge in the degassing step, phosphorus in the sewage is removed.
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| KR20100089834A KR101050375B1 (en) | 2010-09-14 | 2010-09-14 | Submerged membrane bioreactor easy to cope with load variation and sewage treatment method using the same |
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| CN106745725A (en) * | 2017-02-28 | 2017-05-31 | 广东维清环境工程有限公司 | An oxygen-limited membrane bioreactor sewage treatment system |
| CN110054295A (en) * | 2019-05-15 | 2019-07-26 | 桂林市全净生物科技有限公司 | Multi-functional sewage processor |
| IT202300002535A1 (en) * | 2023-02-15 | 2024-08-15 | Giovambattista Greco | MICRO-ULTRAFILTRATION SYSTEM WITH TUBULAR MEMBRANES |
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| KR101367711B1 (en) | 2011-12-09 | 2014-02-27 | (주)필로스 | Operating method of submerged membrane bioreactor |
| KR101367229B1 (en) | 2012-01-03 | 2014-02-25 | (주)필로스 | Operating method of advanced treatment process use of submerged membrane and advanced treatment apparatus thereof |
| KR101356546B1 (en) | 2012-06-13 | 2014-01-29 | (주)필로스 | Membrane filtration bioreactor include improved floatting gas collector |
| KR101424045B1 (en) * | 2012-07-10 | 2014-08-13 | (주)필로스 | Sewage disposal plant use of submerged membrane filtration equipment and energy saving method for use with the same |
| ES2795807T3 (en) | 2013-02-22 | 2020-11-24 | Bl Technologies Inc | Open tank reactor with membrane assembly to support a biofilm |
| CA3207201A1 (en) | 2014-03-20 | 2015-09-24 | Bl Technologies, Inc. | Wastewater treatment with primary treatment and mbr or mabr-ifas reactor |
| CN110093892A (en) * | 2019-05-22 | 2019-08-06 | 上海砼仁环保技术发展有限公司 | A kind of portable porous pavement cleaning vehicle |
| US12428328B2 (en) * | 2020-12-21 | 2025-09-30 | Rtx Bbn Technologies, Inc. | System and method of separating oxygen from a body of water |
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| KR100417701B1 (en) * | 1999-12-29 | 2004-02-11 | 주식회사 포스코 | Filter washing device of waste water filter tank |
| JP2003053378A (en) | 2001-08-13 | 2003-02-25 | Ngk Insulators Ltd | Method and device for treating water by using separation membrane |
| KR20030042133A (en) * | 2001-11-21 | 2003-05-28 | 현대엔지니어링 주식회사 | Method and system for cleaning membrane submersed in reactor |
| KR100639824B1 (en) * | 2005-02-05 | 2006-10-30 | (주)도심엔지니어링 종합건축사사무소 | Nitrogen-phosphorus advanced treatment system and method using microorganism and membrane |
| KR100675977B1 (en) * | 2005-06-29 | 2007-01-30 | (주)송림워터테크 | Wastewater Treatment Method and Device |
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| CN106745725A (en) * | 2017-02-28 | 2017-05-31 | 广东维清环境工程有限公司 | An oxygen-limited membrane bioreactor sewage treatment system |
| CN110054295A (en) * | 2019-05-15 | 2019-07-26 | 桂林市全净生物科技有限公司 | Multi-functional sewage processor |
| IT202300002535A1 (en) * | 2023-02-15 | 2024-08-15 | Giovambattista Greco | MICRO-ULTRAFILTRATION SYSTEM WITH TUBULAR MEMBRANES |
| WO2024171001A1 (en) * | 2023-02-15 | 2024-08-22 | Greco Giovambattista | Micro-ultrafiltration system with tubular membranes |
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