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WO2012030818A3 - Chemochromic hydrogen sensors - Google Patents

Chemochromic hydrogen sensors Download PDF

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Publication number
WO2012030818A3
WO2012030818A3 PCT/US2011/049725 US2011049725W WO2012030818A3 WO 2012030818 A3 WO2012030818 A3 WO 2012030818A3 US 2011049725 W US2011049725 W US 2011049725W WO 2012030818 A3 WO2012030818 A3 WO 2012030818A3
Authority
WO
WIPO (PCT)
Prior art keywords
pgm
chemochromic
compound
supports
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/049725
Other languages
French (fr)
Other versions
WO2012030818A2 (en
Inventor
Gary Bokerman
Ali Tabatabaie-Raisse
Nazim Muradov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Central Florida Research Foundation Inc
Original Assignee
University of Central Florida Research Foundation Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Central Florida Research Foundation Inc filed Critical University of Central Florida Research Foundation Inc
Priority to DE112011102881.4T priority Critical patent/DE112011102881B4/en
Priority to KR1020137007746A priority patent/KR101408215B1/en
Priority to JP2013527189A priority patent/JP5774704B2/en
Publication of WO2012030818A2 publication Critical patent/WO2012030818A2/en
Publication of WO2012030818A3 publication Critical patent/WO2012030818A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
    • G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
    • G01N21/783—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour for analysing gases
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/005—H2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plasma & Fusion (AREA)
  • Food Science & Technology (AREA)
  • Biophysics (AREA)
  • Molecular Biology (AREA)
  • Medicinal Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Electrochemistry (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)

Abstract

An irreversible chemochromic H2 sensor includes supports including a plurality of metal oxide particles exclusive of titania, and a platinum group metal (PGM) compound on the supports. The PGM compound is an oxide, hydroxide hydrated oxide, PGM salt or a PGM complex. The chemochromic H2 sensor can be a composite layer, wherein the gas permeable polymer provides a continuous phase that completely encapsulates the supports and the PGM compound.
PCT/US2011/049725 2010-08-31 2011-08-30 Chemochromic hydrogen sensors Ceased WO2012030818A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE112011102881.4T DE112011102881B4 (en) 2010-08-31 2011-08-30 Chemochrome hydrogen sensors
KR1020137007746A KR101408215B1 (en) 2010-08-31 2011-08-30 Chemochromic Hydrogen Sensor
JP2013527189A JP5774704B2 (en) 2010-08-31 2011-08-30 Chemochromic hydrogen sensor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/872,090 US8048384B1 (en) 2010-08-31 2010-08-31 Chemochromic hydrogen sensors
US12/872,090 2010-08-31

Publications (2)

Publication Number Publication Date
WO2012030818A2 WO2012030818A2 (en) 2012-03-08
WO2012030818A3 true WO2012030818A3 (en) 2012-05-31

Family

ID=44839567

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/049725 Ceased WO2012030818A2 (en) 2010-08-31 2011-08-30 Chemochromic hydrogen sensors

Country Status (5)

Country Link
US (1) US8048384B1 (en)
JP (1) JP5774704B2 (en)
KR (1) KR101408215B1 (en)
DE (1) DE112011102881B4 (en)
WO (1) WO2012030818A2 (en)

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DE102008036370A1 (en) * 2008-08-05 2010-02-18 Deutsches Zentrum für Luft- und Raumfahrt e.V. Sensor-integrated device
CN102768227B (en) * 2012-06-11 2015-04-22 江苏大学 Production method of dye-sensitized TiO2 film based gas sensor
JP2018071969A (en) * 2015-03-06 2018-05-10 コニカミノルタ株式会社 Hydrogen gas detection component, its manufacturing method, and hydrogen gas detection system
KR101745128B1 (en) * 2015-09-01 2017-06-08 현대자동차주식회사 Chemochromic nanoparticles, method for manufacturing the same, and hydrogen sensor comprising the same
KR101734733B1 (en) 2015-12-30 2017-05-11 현대자동차주식회사 Color changeable hydrogen sensor based on molybdenum oxide and method of manufacturing the same
DE102016220418A1 (en) 2016-10-18 2018-04-19 Bayerische Motoren Werke Aktiengesellschaft Hydrogen detector assembly and vehicle
CN110312826A (en) * 2017-02-17 2019-10-08 日东电工株式会社 Gas sensing element and manufacturing method thereof
DE102017205885A1 (en) 2017-04-06 2017-06-01 Carl Zeiss Smt Gmbh Reflective optical element for EUV lithography, hydrogen plasma sensor and EUV lithography system with it
WO2019031383A1 (en) 2017-08-08 2019-02-14 日東電工株式会社 Gas detection element
JP7017994B2 (en) * 2017-08-08 2022-02-09 日東電工株式会社 Gas detection element
JP6786471B2 (en) * 2017-12-15 2020-11-18 キヤノン株式会社 Reducing gas sensor
KR102812421B1 (en) * 2022-04-11 2025-05-26 한양대학교 에리카산학협력단 Pigment for detecting hydrogen, manufacturing method thereof, and hydrogen sensor comprising same
US12259332B2 (en) 2022-10-03 2025-03-25 Honeywell International Inc. Systems, methods, and apparatuses for distinguishing an interfering gas in a gas flow

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US5849073A (en) * 1991-10-14 1998-12-15 Ishihara Sangyo Kaisha, Ltd. Pigment for sensing gas leakage and process for producing the same
US20040037740A1 (en) * 2000-05-05 2004-02-26 Ping Liu Pd/v2o5 device for colorimetric h2 detection
US6895805B2 (en) * 2000-12-05 2005-05-24 William Hoagland Hydrogen gas indicator system
US20070224081A1 (en) * 2005-04-29 2007-09-27 Gary Bokerman Gas permeable chemochromic compositions for hydrogen sensing
US20090053822A1 (en) * 2001-05-05 2009-02-26 Ping Liu METHOD AND Pd/V2 O5 DEVICE FOR H2 DETECTION

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US3567383A (en) * 1968-10-01 1971-03-02 Engelhard Min & Chem Hydrogen detectors
JPH0678987B2 (en) * 1986-04-30 1994-10-05 ホーチキ株式会社 Hydrogen sensor
JPH0672876B2 (en) * 1989-08-31 1994-09-14 工業技術院長 Flammable gas detection material and flammable gas detection method
EP0447949A1 (en) * 1990-03-22 1991-09-25 F. Hoffmann-La Roche Ag Optical oxygen sensor
JP3189013B2 (en) * 1991-10-14 2001-07-16 石原産業株式会社 Gas leak detection pigment and method for producing the same
JPH05307005A (en) * 1992-04-30 1993-11-19 Ngk Spark Plug Co Ltd Concentration measuring material and measuring device using it
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US7897057B1 (en) * 2001-09-04 2011-03-01 Optech Ventures, Llc Sensor for detection of gas such as hydrogen and method of fabrication
JP3781354B2 (en) * 2001-12-04 2006-05-31 慎司 岡崎 Membrane for gas sensor and manufacturing method thereof
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Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5849073A (en) * 1991-10-14 1998-12-15 Ishihara Sangyo Kaisha, Ltd. Pigment for sensing gas leakage and process for producing the same
US20040037740A1 (en) * 2000-05-05 2004-02-26 Ping Liu Pd/v2o5 device for colorimetric h2 detection
US6895805B2 (en) * 2000-12-05 2005-05-24 William Hoagland Hydrogen gas indicator system
US20090053822A1 (en) * 2001-05-05 2009-02-26 Ping Liu METHOD AND Pd/V2 O5 DEVICE FOR H2 DETECTION
US20070224081A1 (en) * 2005-04-29 2007-09-27 Gary Bokerman Gas permeable chemochromic compositions for hydrogen sensing

Also Published As

Publication number Publication date
WO2012030818A2 (en) 2012-03-08
JP5774704B2 (en) 2015-09-09
KR20130057475A (en) 2013-05-31
DE112011102881T5 (en) 2013-06-13
US8048384B1 (en) 2011-11-01
KR101408215B1 (en) 2014-06-16
DE112011102881B4 (en) 2020-02-13
JP2013540998A (en) 2013-11-07

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