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WO2012022729A2 - Procédé d'amélioration de la santé d'une plante - Google Patents

Procédé d'amélioration de la santé d'une plante Download PDF

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Publication number
WO2012022729A2
WO2012022729A2 PCT/EP2011/064060 EP2011064060W WO2012022729A2 WO 2012022729 A2 WO2012022729 A2 WO 2012022729A2 EP 2011064060 W EP2011064060 W EP 2011064060W WO 2012022729 A2 WO2012022729 A2 WO 2012022729A2
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Prior art keywords
compound
plant
mixtures
iii
mixture
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WO2012022729A3 (fr
Inventor
Siegfried Strathmann
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BASF SE
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BASF SE
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Publication of WO2012022729A3 publication Critical patent/WO2012022729A3/fr
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • each of said compounds may be fully or partially present in its tautomeric form.
  • the present invention further relates to the use of a mixture comprising an active ingredient, selected from the group of compound I, compound II, compound III and compound IV as component 1 and a specific herbicidal compound as component 2 for improving the health of a plant, preferably for synergistically increasing the health of a plant.
  • the present invention also relates to a method for synergistically increasing the health of a plant, in particular the yield of a plant, wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material from which the plant grows is treated with a synergistically effective amount of said mixture.
  • the present invention further relates to a mixture comprising an active ingredient, selected from the group of compound I, compound II, compound III and compound IV as component 1 and a specific herbicidal compound as component 2 as defined below.
  • each of said compounds may be fully or partially present in its tautomeric form; and/or agriculturally acceptable salts thereof.
  • Compound IV in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and IVh, can also be depicted by the following formula Y 1 :
  • the compounds I, II, III and IV in particular la, lb, Ma, Mb, Ilia, 1Mb, IVa, IVb, IVc, IVd, IVe, IVf, IVg and compound IVh, may each be fully or partially present in their tautomeric form (as regards the thio-substituted triazole group), i.e. they may be present in the "thiol” or in the "thiono” form. This is exemplarily shown for compounds la/lb:
  • the compounds I, II, III and IV comprise chiral centers and are generally obtained in the form of racemates or as diastereomer mixtures of erythro and threo forms.
  • the erythro and threo diastereomers of the compounds can be separated and isolated in pure form, for example, on the basis of their different solubilities or by column chromatography. Using known methods, such uniform pairs of diastereomers can be used to obtain uniform enantiomers.
  • Suitable for use as antimicrobial agents are both the uniform diastereomers or enantiomers and mixtures thereof obtained in the synthesis. This applies correspondingly to the compositions.
  • the active ingredient used in the inventive methods and of the inventive mixtures is a compound I, in particular la and/or lb.
  • the enantiomer mixture of the "trans” isomers i.e. compound la, wherein the phenyl rings are "trans” to each other, is particularly preferred.
  • compound la (2-[rel (2R, 3S)-3-(2-chlorophenyl)- 2-(2,4-difluorophenyl)oxiranylmethyl]-2,4-dihydro-[1 ,2,4]triazole-3-thione), which can also be present in its tautomeric form or as tautomeric mixture, is preferred.
  • a racemic mixture is present.
  • any other proportions of the trans-enantiomers may be present and also any one of the trans-enantiomers may also be present in pure form.
  • the "cis" isomers may be present, i.e. compound lb (2-[rel (2R, 3R)-3-(2-chlorophenyl)-2-(2,4- difluorophenyl)oxiranylmethyl]-2,4-dihydro-[1 ,2,4]triazole-3-thione) and/or its tautomeric thiol-form. This applies to every method or use according to the present invention and to every binary or ternary mixture detained herein.
  • the active ingredient used in the inventive methods and of the inventive mixtures is a compound II, in particular lla and/or lib.
  • the enantiomer mixture of the "trans” isomers i.e. compound lla, wherein the phenyl rings are "trans" to each other, is particularly preferred.
  • compound lla (1 -[rel (2R,3S)- 3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxiranylmethyl]-5-thiocyanato-1 H- [1 ,2,4]triazole), which can also be present in its tautomeric form or as tautomeric mixture, is preferred.
  • a racemic mixture is present.
  • any other proportions of the trans-enantiomers may be present and also any one of the trans-enantiomers may also be present in pure form.
  • the "cis" isomers may be present, i.e.
  • the active ingredient used in the inventive methods and of the inventive mixtures is a compound III, in particular Ilia and/or 1Mb.
  • the enantiomer mixture of the "trans” isomers i.e. compound Ilia, wherein the phenyl rings are "trans" to each other, is particularly preferred.
  • any other proportions of the trans-enantiomers may be present and also any one of the trans-enantiomers may also be present in pure form.
  • the "cis" isomers may be present, i.e. compound 1Mb (5-Allylsulfanyl- 1 -[[rel (2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxiran-2-yl]methyl]- [1 ,2,4]triazole) and/or its tautomeric thiol-form. This applies to every method or use according to the present invention and to every binary or ternary mixture detained herein.
  • the active ingredient used in the inventive methods and of the inventive mixtures is a compound IV, in particluar IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh.
  • the isomers IVa, IVb, IVc and IVd are in each case present alone or in a combination with one or more others of said isomers, in particular as combination of said two diasteromers (that are each enantiomeric pairs) in ratios of 5 : 1 to 1 : 5 or 4 : 1 to 1 : 4, in particular 2 : 1 to 1 : 2, specifically 1 : 1.
  • a racemic mixture is present.
  • any other proportions of the enantiomers may be present and also any one of the enantiomers may also be present in pure form. Any isomer may fully or partially be present in its respective tautomeric form. This applies to every method or use according to the present invention and to every binary or ternary mixture detained herein.
  • the compounds I, II, III and IV are capable of forming salts or adducts with inorganic or organic acids or with metal ions, in particular salts with inorganic acids.
  • inorganic acids examples include hydrohalic acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, carbonic acid, sulfuric acid, phosphoric acid and nitric acid.
  • Suitable organic acids are, for example, formic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid and other arylcarboxylic acids, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids having straight-chain or branched alkyl radicals of 1 to 20 carbon atoms), arylsulfonic acids or aryldisulfonic acids (aromatic radicals, such as phenyl and naphthyl, which carry one or two sulfonic acid groups), alkylphosphonic acids (phosphonic acids having straight-chain or branched alkyl radicals with 1 to 20 carbon atoms), arylphosphonic acids or aryldiphosphonic acids (aromatic radicals, such as phenyl and naph
  • Suitable metal ions are in particular the ions of the elements of the second main group, in particular calcium and magnesium, of the third and fourth main group, in particular aluminum, tin and lead, and also of the elements of transition groups one to eight, in particular chromium, manganese, iron, cobalt, nickel, copper, zinc, and others. Particular preference is given to the metal ions of the elements of transition groups of the fourth period.
  • the metals can be present in the various valencies that they can assume.
  • imidazolinone herbicides or specific imidazolinone herbicide species in this application shall mean the compounds as mentioned above, as well as their a) salts, e.g. salts of alkaline or earth alkaline metals or ammonium or
  • organoammonium salts for instance, sodium, potasium, ammonium, preferably isopropyl ammonium etc.
  • respective isomers e.g. stereo isomers such as the respective enantiomers, in particular the respective R-or S-enantiomers (including salts, ester, amides)
  • respective esters e.g. carboxylic acid Ci-Ce-(branched or non-branched) alkyl esters, such as methyl esters, ethyl esters, iso propyl esters, d) respective amides, e.g.
  • locus is to be understood as any type of environment, soil, area or material where the plant is growing or intended to grow as well as the environmental conditions (such as temperature, water availability, radiation) that have an influence on the growth and development of the plant and/or its propagules.
  • health of a plant or "plant health” is defined as a condition of the plant and/or its products which is determined by several aspects alone or in combination with each other such as increased yield, plant vigor, quality and tolerance to abiotic and/or biotic stress.
  • plant health indicator listed herein, and which is selected from the groups consisting of yield, plant vigor, quality and tolerance to abiotic and/or biotic stress, is to be understood as a preferred embodiment of the present invention either each on its own or preferably in combination with each other.
  • the methods according to the invention lead to an enhanced plant health even in the absence of any biotic stress.
  • the yield is increased by at least 4 %, preferably at least 8 %, more preferably at least 15 %, even more preferably at least 25 %, even more preferably at least 35 %.
  • the yield is increased preferably by 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 %. In general, the yield increase may even be higher.
  • Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes.
  • a compound III in particular Ilia and/or 1Mb, preferably Ilia
  • a method for increasing the health of plants wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material from which the plant grows is treated with an effective amount of a compound III, in particular Ilia and/or 1Mb, preferably Ilia.
  • the compound II in particular lla and/or lib, preferably lla
  • compound II is used for increasing the yield of a plant or its product.
  • compound II, in particular lla and/or lib, preferably lla is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the compound III, in particular Ilia and/or 1Mb, preferably la is used for increasing the yield of a plant or its product.
  • the compound IV in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, preferably IVa, IVb, IVc and/or IVd, is used for increasing the yield of a plant or its product.
  • compound IV in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, preferably IVa, IVb, IVc and/or IVd, is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the compound I in particular la and/or lb, preferably la, is used for increasing the vigor of a plant or its product or improvement of the plant vigor.
  • the compound II in particular lla and/or lib, preferably lla, is used for increasing the tolerance and/or resistance of a plant or its product against biotic stress.
  • the compound III in particular Ilia and/or 1Mb, preferably Ilia, is used for increasing the tolerance and/or resistance of a plant or its product against biotic stress.
  • the compound I in particular la and/or lb, preferably la, is used for increasing the tolerance and/or resistance of a plant or its product against abiotic stress.
  • Any one of compounds I, II, III and IV, in particular la, lb, lla, lib, Ilia, 1Mb, IVa, IVb, IVc, IVd, IVe, IVf, IVg and IVh, given in the resepctive method or use of the invention is employed by treating the plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow with an effective amount of the active compounds.
  • the application can be carried out in the absense of pest pressure and/or both before and after an infection of the materials, plants or plant propagation materials (preferably seeds) by pests.
  • the active ingredient selected from I, II, III and IV in particular la, lb, lla, lib, Ilia, lllb, IVa, IVb, IVc, IVd, IVe, IVf, IVg and IVh, is used for increasing the health, specifically for improving one or more of the above mentioned particular characteristics, wherein the active ingredient selected from I, II, III and IV, in particular la, lb, lla, lib, Ilia, lllb, IVa, IVb, IVc, IVd, IVe, IVf, IVg and IVh, is applied at a growth stage (GS) between GS 00 and GS 21 BBCH of the treated plant.
  • GS growth stage
  • mixture IV+2-2 compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and imazethapyr
  • mixture IV+2-3) compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and imazapic
  • mixture IV+2-4 compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and imazapyr
  • mixture IV+2-5) compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and imazamethabenz-methyl
  • mixture IV+2-6) compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and imazaquin
  • mixture IV+2-8) compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and saflufenacil
  • mixture IV+2-9) compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and glyphosate
  • mixture IV+2-10) compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and glufosinate
  • mixture IVabcd+2-1 compound IVa, IVb, IVc and/or IVd and imazamox mixture IVabcd+2-2) compound IVa, IVb, IVc and/or IVd and imazethapyr mixture (IVabcd+2 ⁇ 3) compound IVa, IVb, IVc and/or IVd and imazapic mixture (IVabcd+2 ⁇ 4) compound IVa, IVb, IVc and/or IVd and imazapyr mixture (IVabcd+2 ⁇ 5) compound IVa, IVb, IVc and/or IVd and
  • IVabcd+2 6 compound IVa, IVb, IVc and/or IVd and imazaquin mixture
  • IVabcd+2 compound IVa, IVb, IVc and/or IVd and dicamba mixture
  • IVabcd+2 8 compound IVa, IVb, IVc and/or IVd and saflufenacil mixture
  • IVabcd+2 9 compound IVa, IVb, IVc and/or IVd and glyphosate mixture (IVabcd+2 10) compound IVa, IVb, IVc and/or IVd and glufosinate
  • weight ratios are calculated as the free acid, in case one or more compounds are used as agriculturally acceptable salt.
  • the weight ratio of the particular first active ingredient selected from I, II, III and IV, in particular la, lb, lla, lib, Ilia, lllb, IVa, IVb, IVc, IVd, IVe, IVf, IVg and IVh (component 1 ) to component 2 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 .
  • any one of the mixtures (1+2-1 ) to (1+2-10), preferably (la+2-1 ) to (la+2-10), is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the application can be carried out in the absense of pest pressure and/or both before and after an infection of the materials, plants or plant propagation materials (preferably seeds) by pests.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • GS growth stage
  • a preferred mixtures 11+2-1 ), (II+2-2), (II+2-3), (II+2-4), (II+2-5), (II+2-6), (II+2-7), (II+2-8), (II+2-9) and (11+2-10), preferably (lla+2-1 ), (lla+2- 2), (lla+2-3), (lla
  • any one of the mixtures (11+2-1 ) to (11+2-10), preferably (lla+2-1 ) to (lla+2-10), is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • plant propagation material preferably seed
  • soil, area, material or environment in which a plant is growing or may grow with an effective amount of the active compounds.
  • the application can be carried out in the absense of pest pressure and/or both before and after an infection of the materials, plants or plant propagation materials (preferably seeds) by pests.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as de
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as de
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained
  • any one of the mixtures (111+2-1 ) to (111+2-10), preferably (llla+2-1 ) to (llla+2-10), is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the application can be carried out in the absense of pest pressure and/or both before and after an infection of the materials, plants or plant propagation materials (preferably seeds) by pests.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • any one of the mixtures (111+2-1 ), (III+2-2), (III+2- 3), (III+2-4), (III+2-5), (III+2-6), (III+2-7), (III+2-8), (III+2-9) and (111+2-10), preferably (llla+2-1 ), (llla+2-2), (llla+2-3), (llla+2-4), (llla+2-5), (llla+2-6), (llla+2-7), (llla+2-8), (llla+2-9) and (llla+2-10) is used for increasing the health, specifically for improving one or more of the above mentioned particular characteristics, wherein any one of the mixtures (llla+2-1 ) to (llla+2-10), preferably (llla+2-1 ) to (llla+2-10), is applied at a growth stage (GS) between GS 00 and GS 65 BBCH of the treated plant.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • any one of the mixtures (IV+2-1 ) to (IV+2-10), preferably (IVabcd+2-1 ) to (IVabcd+2-10), is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • the components of the binary mixture used are present in a weight ratio or preferred weight ratio as detained above for the binary mixtures.
  • mixtures used according to the invention can further contain at least one additional compound selected from the group consisting of insecticides, fungicides, herbicides and plant growth regulators.
  • mixture (11+2-3+3-1 ): compound II, in particular la and/or lb, and imazapic and glyphosate
  • mixture (11+2-7+3-1 ): compound II, in particular la and/or lb, and dicamba and glyphosate
  • mixture (II+2-8+3-2 compound II, in particular la and/or lb, and saflufenacil and glufosinate mixture ;ila+2- -1 +3- -1 ) : compound la and mazamox and glyphosate mixture ;ila+2- -1 +3- -2) : compound la and mazamox and glufosinate
  • mixture 11+2-1 +3-2 compound III in particular Ilia and/or lllb, and imazamox and glufosinate
  • mixture 11+2-2+3-1 compound III in particular Ilia and/or lllb, and imazethapyr and glyphosate
  • mixture 11+2-3+3-1 compound III in particular Ilia and/or lllb, and imazapic and glyphosate
  • mixture 11 +2-3+3-2 compound III in particular Ilia and/or lllb, and imazapic and glufosinate
  • mixture 11+2-4+3-1 compound III in particular Ilia and/or lllb, and imazapyr and glyphosate
  • mixture 11+2-5+3-1 compound III in particular Ilia and/or lllb, and
  • imazamethabenz-methyl and glufosinate mixture 11+2-6+3-1 compound III in particular Ilia and/or lllb
  • imazaquin and glyphosate mixture (111+2-6+3-2) compound I in particular I la and/or 1Mb
  • mixture (IV+2-2+3-1 ): compound IV, in particular IVa, IVb, IVc, IVd, IVe, IVf, IVg and/or IVh, and imazethapyr and glyphosate
  • imazamethabenz-methyl and glufosinate mixture IVabcd+2-6+3-1 : compound IVa, IVb, IVc and/or IVd and imazaquin and glyphosate
  • mixture (IVabcd+2-7+3-1 ): compound IVa, IVb, IVc and/or IVd and dicamba and glyphosate
  • mixture (IVabcd+2-7+3-2): compound IVa, IVb, IVc and/or IVd and dicamba and glufosinate
  • mixture (IVabcd+2-8+3-2): compound IVa, IVb, IVc and/or IVd and saflufenacil and glufosinate
  • the weight ratio of component 1 to component 2 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 .
  • a preferable weight ratio of component 1 to component 2 is 95:1 to 1 :95, more preferable 90:1 to 1 :90, even more preferable 85:1 to 1 :85, even more preferable 80:1 to 1 :80, even more preferable 75:1 to 1 :75, even more preferable 70:1 to 1 :70, even more preferable 65:1 to 1 :65, 60:1 to 1 :60, even more preferable 55:1 to 1 :55, even more preferable 50:1 to 1 :50, even more preferable 45:1 to 1 :45, even more preferable 30:1 to 1 :30, even more preferable 25:1 to 1 :25, even more preferable 15:1 to 1 :15, even more preferable 10:1 to 1 :
  • the weight ratio of component 1 to component 3 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 . Furthermore, a preferable weight ratio of component 1 to component 3 is in each case 95:1 to 1 :95, more preferable 90:1 to 1 :90, even more preferable 85:1 to 1 :85, even more preferable 80:1 to 1 :80, even more preferable 75:1 to 1 :75, even more preferable 70:1 to 1 :70, even more preferable 65:1 to 1 :65, 60:1 to 1 :60, even more preferable 55:1 to 1 :55, even more preferable 50:1 to 1 :50, even more preferable 45:1 to 1 :45, even more preferable 30:1 to 1 :30, even more preferable 25:1 to 1 :25, even more preferable 15:1 to 1 :15, even more preferable 10:1 to 1 :10, even
  • the weight ratio of component 2 to component 3 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 . Furthermore, a preferable weight ratio of component 2 to component 3 is in each case 95:1 to 1 :95, more preferable 90:1 to 1 :90, even more preferable 85:1 to 1 :85, even more preferable 80:1 to 1 :80, even more preferable 75:1 to 1 :75, even more preferable 70:1 to 1 :70, even more preferable 65:1 to 1 :65, 60:1 to 1 :60, even more preferable 55:1 to 1 :55, even more preferable 50:1 to 1 :50, even more preferable 45:1 to 1 :45, even more preferable 30:1 to 1 :30, even more preferable 25:1 to 1 :25, even more preferable 15:1 to 1 :15, even more preferable 10:1 to 1 :10, even
  • any one of the mixtures (1+2-1 +3-1 ) to (I+2-8+3-2), preferably said mixtures wherein compound I is la, is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • the application can be carried out in the absense of pest pressure and/or both before and after an infection of the materials, plants or plant propagation materials (preferably seeds) by pests.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • GS growth stage
  • any one of the mixtures (11+2-1 +3-1 ) to (II+2-8+3-2), preferably said mixtures wherein compound II is lla is used for increasing the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • plant propagation material preferably seed
  • soil, area, material or environment in which a plant is growing or may grow with an effective amount of the active compounds.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • the components of the ternary mixture used are present in a weight ratio or preferred weight ratio as detained above for the ternary mixtures.
  • growth stage as used herein extended BBCH-scale which is a system for a uniform coding of phenologically similar growth stages of all mono- and
  • the present invention additionally relates to the use of any one of the ternary mixtures as defined herein for synergistically controlling undesirable vegetation in crops.
  • the present invention relates to the binary mixtures (I+2-2), (I+2-3), (I+2-4), (I+2-5), (I+2-6), (I+2-7), (I+2-8) and (1+2-10), preferably (la+2-1 ), (la+2-2), (la+2-3), (la+2-4), (la+2-5), (la+2-6), (la+2-7), (la+2-8), (la+2-9) and (la+2-10), as defined above.
  • the present invention relates to the binary mixtures (111+2-1 ), (III+2-2), (III+2-3), (III+2-4), (III+2-5), (III+2-6), (III+2-7), (III+2-8), (III+2-9) and (111+2-10), preferably (llla+2-1 ), (I I la+2-2), (I I la+2-3), (llla+2-4), (llla+2-5), (llla+2-6), (llla+2-7), (llla+2-8), (llla+2-9) and (llla+2-10), as defined above.
  • the present invention relates to the ternary mixtures (IV+2-1 +3-1 ), (IV+2-1+3-2), (IV+2-2+3-1), (IV+2-2+3-2), (IV+2-3+3-1), (IV+2-3+3-2), (IV+2-4+3-1), (IV+2-4+3-2), (IV+2-5+3-1), (IV+2-5+3-2), (IV+2-6+3-1), (IV+2-6+3-2), (IV+2-7+3-1), (IV+2-7+3-2), (IV+2-8+3-1) and (IV+2-8+3-2), preferably (IVabcd+2-1+3-1),
  • the weight ratio of component 1 to component 2 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 .
  • a preferable weight ratio of component 1 to component 2 is 95:1 to 1 :95, more preferable 90:1 to 1 :90, even more preferable 85:1 to 1 :85, even more preferable 80:1 to 1 :80, even more preferable 75:1 to 1 :75, even more preferable 70:1 to 1 :70, even more preferable 65:1 to 1 :65, 60:1 to 1 :60, even more preferable 55:1 to 1 :55, even more preferable 50:1 to 1 :50, even more preferable 45:1 to 1 :45, even more preferable 30:1 to 1 :30, even more preferable 25:1 to 1 :25, even more preferable 15:1 to 1 :15, even more preferable 10:1 to 1 :10, even more preferable 5:1 to 1 :5, even more preferable 4:1 to 1 :4, even more preferable 3:1 to 1 :3, even more preferable 2:1 to 1 :2.
  • the weight ratio of component 1 to component 3 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 . Furthermore, a preferable weight ratio of component 1 to component 3 is in each case 95:1 to 1 :95, more preferable 90:1 to 1 :90, even more preferable 85:1 to 1 :85, even more preferable 80:1 to 1 :80, even more preferable 75:1 to 1 :75, even more preferable 70:1 to 1 :70, even more preferable 65:1 to 1 :65, 60:1 to 1 :60, even more preferable 55:1 to 1 :55, even more preferable 50:1 to 1 :50, even more preferable 45:1 to 1 :45, even more preferable 30:1 to 1 :30, even more preferable 25:1 to 1 :25, even more preferable 15:1 to 1 :15, even more preferable 10:1 to 1 :10, even
  • the weight ratio of component 2 to component 3 is in each case 1 :100 to 100:1 , preferably 1 :50 to 50:1 , even more preferably 1 :20 to 20:1 . Furthermore, a preferable weight ratio of component 2 to component 3 is in each case 95:1 to 1 :95, more preferable 90:1 to 1 :90, even more preferable 85:1 to 1 :85, even more preferable 80:1 to 1 :80, even more preferable 75:1 to 1 :75, even more preferable 70:1 to 1 :70, even more preferable 65:1 to 1 :65, 60:1 to 1 :60, even more preferable 55:1 to 1 :55, even more preferable 50:1 to 1 :50, even more preferable 45:1 to 1 :45, even more preferable 30:1 to 1 :30, even more preferable 25:1 to 1 :25, even more preferable 15:1 to 1 :15, even more preferable 10:1 to 1 :10, even
  • mixture is not restricted to a physical mixture comprising component 1 and component 2 and, if present, component 3, but refers to any preparation form of the active sompounds, the use of which is time- and locus- related.
  • applying the component 1 and component 2 and, if present, component 3, is to be understood to denote, that at least the component 1 and component 2 and, if present, component 3, occur simultaneously at the site of action (i.e. plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow) in an effective amount.
  • site of action i.e. plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow
  • This can be obtained by applying the component 1 and component 2 and, if present, component 3, simultaneously, either jointly (e.g. as tank-mix) or seperately, or in succession, wherein the time interval between the individual applications is selected to ensure that the active substance applied first still occurs at the site of action in a sufficient amount at the time of application of the further active substance(s).
  • the order of application is not essential for working of the present invention.
  • component 1 and component 2 and, if present, component 3 are formulated separately but applied to the same plant, plant propagule or locus in a temporal relationship, i.e. simultaneously or subsequently, the subsequent application having a time interval which allows a combined action of the compounds.
  • one component 1 and component 2 and optionally component 3 are applied simultaneously, either as a mixture or separately, or subsequently to plant propagules.
  • component 1 and component 2 and optionally component 3 are applied simultaneously, either as a mixture or separately, as foliar spray treatment.
  • the compounds of the inventive mixtures or the mixtures used according to the present invention can be used individually or already partially or completely mixed with one another to prepare the composition according to the invention. It is also possible for them to be packaged and used further as combination composition such as a kit of parts.
  • kits may include one or more, including all, components that may be used to prepare a subject agrochemical composition.
  • kits may include the component 1 and component 2 and optionally component 3 and/or an adjuvant component and/or a further pesticidal compound (e.g. insecticide, fungicide or herbicide) and/or a growth regulator component).
  • a further pesticidal compound e.g. insecticide, fungicide or herbicide
  • the components may already be combined together or pre-formulated.
  • the components may already be combined together or pre-formulated.
  • kits may include one or more separate containers such as vials, cans, bottles, pouches, bags or canisters, each container containing a separate component for an agrochemical composition.
  • a component of the kit may be applied separately from or together with the further components or as a component of a combination composition according to the invention for preparing the composition according to the invention.
  • the user applies the composition according to the invention or the composition used according to the invention usually from a predosage device, a knapsack sprayer, a spray tank or a spray plane.
  • the agrochemical composition is made up with water and/or buffer to the desired application concentration, it being possible, if appropriate, to add further auxiliaries, and the ready-to-use spray liquid or the agrochemical composition according to the invention is thus obtained.
  • 50 to 500 liters of the ready-to-use spray liquid are applied per hectare of agricultural useful area, preferably 50 to 400 liters.
  • individual compounds of the inventive mixtures or the mixtures used according to the invention formulated as composition (or formulation) such as parts of a kit or parts of the inventive mixture or the mixtures used according to the invention may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate (tank mix).
  • either individual compounds of the inventive mixtures or the mixtures used according to the invention formulated as composition or partially premixed components e.g. components comprising component 1 and component 2 and optionally component 3 may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate (tank mix).
  • either individual components of the composition according to the invention or the composition used according to the invention or partially premixed components, e. g. components comprising component 1 and component 2 and optionally component 3, can be applied jointly (e. .g. after tankmix) or consecutively.
  • the aforementioned methods for increasing the health of a plant and/or increasing the control of undesirable vegetation and/or increasing the control of phytopathogenic fungi comprises treating the plant propagules, preferably the seeds of an agricultural, horticultural, ornamental or silivcultural plant selected from the group consisting of transgenic or non-transgenic plants with a mixture according to the present invention or a mixture as used according to the present invention.
  • plants generally comprises all plants of economic importance and/or men- grown plants. They are preferably selected from agricultural, silvicultural and ornamental plants, more preferably agricultural plants and silvicultural plants, utmost preferably agricultural plants.
  • plant (or plants) is a synonym of the term “crop” which is to be understood as a plant of economic importance and/or a men- grown plant.
  • plant as used herein includes all parts of a plant such as germinating seeds, emerging seedlings, herbaceous vegetation as well as established woody plants including all belowground portions (such as the roots) and aboveground portions.
  • the plants to be treated according to the invention are selected from the group consisting of agricultural, silvicultural, ornamental and horticultural plants, each in its natural or genetically modified form, more preferably from agricultural plants.
  • any one of compounds I, II, III and IV as defined herein is used. According to another embodiment, any one of the mixtures as defined herein is used.
  • the plant to be treated according to the method of the invention is a horticultural plant.
  • the term "horticultural plants” are to be understood as plants which are commonly used in horticulture - e.g. the cultivation of ornamentals, vegetables and/or fruits.
  • ornamentals are turf, geranium, pelargonia, petunia, begonia and fuchsia.
  • vegetables are potatoes, tomatoes, peppers, cucurbits, cucumbers, melons, watermelons, garlic, onions, carrots, cabbage, beans, peas and lettuce and more preferably from tomatoes, onions, peas and lettuce.
  • fruits are apples, pears, cherries, strawberry, citrus, peaches, apricots and blueberries.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • the plant to be treated according to the method of the invention is an ornamental plant.
  • Ornamental plants are plants which are commonly used in gardening, e.g. in parks, gardens and on balconies. Examples are turf, geranium, pelargonia, petunia, begonia and fuchsia.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • the plant to be treated according to the method of the invention is a silvicultural plants.
  • the term "silvicultural plant” is to be understood as trees, more specifically trees used in reforestation or industrial plantations.
  • Industrial plantations generally serve for the commercial production of forest products, such as wood, pulp, paper, rubber tree, Christmas trees, or young trees for gardening purposes.
  • Examples for silvicultural plants are conifers, like pines, in particular Pinus spec, fir and spruce, eucalyptus, tropical trees like teak, rubber tree, oil palm, willow (Salix), in particular Salix spec, poplar (cottonwood), in particular Populus spec, beech, in particular Fagus spec, birch, oil palm and oak.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • the plant to be treated according to the method of the invention is an agricultural plant.
  • Agricultural plants are plants of which a part or all is harvested or cultivated on a commercial scale or which serve as an important source of feed, food, fibres (e.g. cotton, linen), combustibles (e.g. wood, bioethanol, biodiesel, biomass) or other chemical compounds.
  • Agricultural plants also include the horticultural plants fruits and vegetables.
  • the term agricultural plants include cereals, e.g. wheat, rye, barley, triticale, oats, sorghum or rice; beet, e.g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e.g.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • the plants to be treated in accordance with the method of the present invention are agricultural plants.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • Preferred agricultural plants are field crops, sugar beets, cereals such as wheat, rye, barley, triticale, oats, sorghum, rice, corn, cotton, rape, sunflowers, oilseed rape, juncea and canola, vine, legumes such as soybeans, peas and beans (fieldbeans), lentil, sugar cane, turf; ornamentals; vegetables, such as vegetables, such as cucumbers, leeks, paprika spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits (squashes, cucumber or melons ); alfalfa, clover and fruits, such as pomes, stone fruits or soft fruits, e.g.
  • any one of compounds I, II, III and IV as defined herein is used. According to another embodiment, any one of the mixtures as defined herein is used.
  • More preferred agricultural plants are selected from soybean, wheat, sunflower, canola, oilseed rape, corn, cotton, sugar cane, juncea, peas, lentils, alfalfa, vine, and fruits (as defined above) and vegegables as defined above).
  • Most preferred agricultural plants are selected from wheat, barley, corn, soybean, rice, canola, sunflower and fruits (as defined above) and vegetables as defined above).
  • the utmost preferred plants are soybean, vine, and fruits (as defined above) and vegetables as defined above. According to one embodiment, any one of compounds I, II, III and IV as defined herein is used. According to another embodiment, any one of the mixtures as defined herein is used.
  • Particularly preferred agricultural plants are selected from wheat, barley soybean, corn, sugar beets, peanuts, oil seed rape, canola, rice, speciality crops, in particular specialty crops such as turf, potato, tomato, cucurbits, grapes, apples, bananas and ornamentals.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • Particularly preferred agricultural plants to be treated with a compound seleceted from I, II, III and IV are selected from cereals, in particular wheat and barley, and soybeans, in a specific embodiment as foliar application such as foliar spray.
  • any one of the mixtures as defined herein is used.
  • Particularly preferred agricultural plants to be treated with a compound selected from I, II, III and IV are selected from cereals, in particular wheat and barley, soybeans, corn, sweet corn, sorghum, sugar beet, potato, rice, sunflower, canola, pomefruit, stonefruit, legumes, dry bean and chickpea, tree nuts, peanuts, lentils, cotton, in a specific embodiment as foliar application such as foliar spray, for any one ofthe above explained plant health effects, for example cold tolerance.
  • said crops are treated by seed treatment in order to achieve the desired plant health effects.
  • any one of the mixtures as defined herein is used.
  • plants also includes plants which have been modified by breeding, mutagenesis or genetic engineering (transgenic and non-transgenic plants).
  • Genetically modified plants are plants, which genetic material has been modified by the use of recombinant DNA techniques in a way that it cannot readily be obtained by cross breeding under natural circumstances, mutations or natural recombination.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • Plants as well as the propagation material of said plants, which can be treated with a compound selected from I, II, III and IV, or the inventive mixtures or mixtures used according to the invention include all modified non-transgenic plants or transgenic plants, e.g. crops which tolerate the action of herbicides or fungicides or insecticides owing to breeding, including genetic engineering methods, or plants which have modified characteristics in comparison with existing plants, which can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures.
  • any one of compounds I, II, III and IV as defined herein is used.
  • any one of the mixtures as defined herein is used.
  • a compound selected from I, II, III and IV as defined herein, or mixtures according to the present invention or used according to th epresent invention can be applied (as seed treatment, foliar spray treatment, in-furrow application or by any other means) also to plants which have been modified by breeding, mutagenesis or genetic engineering including but not limiting to agricultural biotech products on the market or in development (cf.
  • Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
  • Such genetic modifications also include but are not limited to targeted post-transtional modification of protein(s), oligo- or polypeptides e.g. by glycosylation or polymer additions such as prenylated, acetylated or farnesylated moieties or PEG moieties.
  • Plants that have been modified by breeding, mutagenesis or genetic engineering, e.g. have been rendered tolerant to applications of specific classes of herbicides can be obtained by creating insensitivity at the site of action of the herbicide by expression of a target enzyme which is resistant to herbicide; rapid metabolism (conjugation or degradation) of the herbicide by expression of enzymes which inactivate herbicide; or poor uptake and translocation of the herbicide.
  • EPSPS 5- enolpyruvylshikimate-3-phosphate synthase
  • Zea mays with chimeric gene sequences cogi ng for H D D P see e. g . W01 996/38567, WO 2004/551 91 ) ; Arabidopsis thaliana which is resistant to protox inhibitors (see e.g. US2002/0073443).
  • Examples of commercial available plants with tolerance to herbicides are the corn varieties “Roundup Ready® Corn”, “Roundup Ready 2®” (Monsanto), “Agrisure GT®”, “Agrisure GT/CB/LL®”, “Agrisure GT/RW®”, regularlyAgrisure 3000GT® “ (Syngenta), “YieldGard VT Rootworm/RR2®” and “YieldGard VT Triple®” (Monsanto) with tolerance to glyphosate; the corn varieties “Liberty Link®” (Bayer), “Herculex I®”, “Herculex RW®”, “Herculex® Xtra”(Dow, Pioneer), “Agrisure GT/CB/LL®” and “Agrisure CB/LL/RW®” (Syngenta) with tolerance to glufosinate; the soybean varieties “Roundup Ready® Soybean” (Monsanto) and Optimum GAT®” (DuPont, Pioneer) with tolerance
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as ⁇ -endotoxins, e.g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl ) or Cry9c; vegetative insecticidal proteins (VIP), e.g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, e.g. Photorhabdus spp.
  • VIP1 , VIP2, VIP3 or VIP3A vegetative insecticidal proteins
  • toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins
  • toxins produced by fungi such Streptomycetes toxins, plant lectins, such as pea or barley lectins
  • agglutinins agglutinins
  • proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors
  • ribosome-inactivating proteins RIP
  • RIP ribosome-inactivating proteins
  • steroid metabolism enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase
  • ion channel blockers such as blockers of sodium or calcium channels
  • juvenile hormone esterase diuretic hormone receptors (helicokinin receptors); stilben synthase, bibenzyl synthase, chitinases or glucanases.
  • insecticidal proteins or toxins are to be understood expressly also as pre- toxins, hybrid proteins, truncated or otherwise modified proteins.
  • Hybrid proteins are characterized by a new combination of protein domains, (see, e. g. WO 02/015701 ). Further examples of such toxins or genetically modified plants capable of
  • insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of athropods, especially to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda).
  • WO 03/018810 MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cryl F toxin and PAT enzyme).
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens.
  • proteins are the so-called "pathogenesis-related proteins" (PR proteins, see, e.g. EP- A 392225), plant disease resistance genes (e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum) or T4-lysozym (e.g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora).
  • PR proteins pathogenesis-related proteins
  • plant disease resistance genes e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum
  • T4-lysozym e.g. potato cultivars capable of
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e.g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, e.g. oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e.g. Nexera® rape, DOW Agro Sciences, Canada).
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, e.g. potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
  • a modified amount of substances of content or new substances of content specifically to improve raw material production, e.g. potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
  • modified plants suitable to be used in the methods of the present invention are those, which are resistant to herbicides, in particular resistant to glyphosate, glufosinate, dicamba and imidazolinones, selected from imazamox, imazapic, imazapyr, imazethapyr, imazaquin and imazamethabenz-methyl.
  • the plant to be treated is a herbicide tolerant plant.
  • herbicide tolerant plants imidazolinone tolerant plants are especially preferred.
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e.g. potatoes), which can be used for the multiplication of the plant.
  • vegetative plant material such as cuttings and tubers (e.g. potatoes)
  • propagules or "plant propagules” is to be understood to denote any structure with the capacity to give rise to a new plant, e.g. a seed, a spore, or a part of the vegetative body capable of independent growth if detached from the parent.
  • the term “propagules” or “plant propagules” denotes for seed.
  • the health of a plant is increased.
  • the health of a plant is preferably increased synergistically.
  • the term "synergistically” refers to the fact that the purely additive effect (in mathematical terms) of a simultaneous, that is joint or separate application of one component 1 and component 2 and, if present, component 3, or the successive application of one component 1 and component 2 and, if present, component 3, of the application of the individual compounds is surpassed by the application of the inventive mixture or the mixture used according to the present invention.
  • the synergistic increase of the health of a plant is more than surprising, since it can be assumed that fungicidal compounds and herbicides have completely different mode of actions.
  • the components of the mixtures are used in synergistically effective amounts, particularly in the weight ratios as detained herein.
  • the application rates are in the range of from 0,1 to 6,0 kg of active ingredient (acid equivalent) per hectare, depending on various parameters such as the weather conditions and the plant species.
  • Solid carriers are mineral earths such as silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
  • mineral earths such as silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g. ammonium sulfate, ammonium phosphate, ammoni
  • Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids, such as ligninsoulfonic acid (Borresperse® types, Borregard, Norway) phenolsulfonic acid, naphthalenesulfonic acid (Morwet® types, Akzo Nobel, U.S.A.),
  • dibutylnaphthalene-sulfonic acid (Nekal® types, BASF, Germany), and fatty acids, alkylsulfonates, alkylarylsulfonates, alkyl sulfates, laurylether sulfates, fatty alcohol sulfates, and sulfated hexa-, hepta- and octadecanolates, sulfated fatty alcohol glycol ethers, furthermore condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxy-ethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol
  • polyvinylpyrrolidone and the copolymers therof.
  • thickeners i.e. compounds that impart a modified flowability to formulations, i.e. high viscosity under static conditions and low viscosity during agitation
  • polysaccharides and organic and anorganic clays such as Xanthan gum (Kelzan®, CP Kelco, U.S.A.), Rhodopol® 23 (Rhodia, France), Veegum® (R.T. Vanderbilt, U.S.A.) or Attaclay® (Engelhard Corp., NJ, USA).
  • 25 parts by weight of compounds of the compound selected from I, II, III and IV or the inventive mixtures or mixtures used according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight).
  • This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion.
  • the composition has an active substance content of 25% by weight.
  • Dustable powders (DP, DS)
  • 0.5 parts by weight of compounds of the compound selected from I, II, III and IV or the inventive mixtures or mixtures used according to the invention is ground finely and associated with 99.5 parts by weight of carriers.
  • Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted having an active substance content of 0.5% by weight.
  • the compound selected from I, II, III and IV or the compounds of the inventive mixtures or mixtures used according to the invention can be used as such or in the form of their compositions, e.g. in the form of directly sprayable solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading, brushing, immersing or pouring.
  • the application forms depend entirely on the intended purposes; it is intended to ensure in each case the finest possible distribution of the compounds present in the inventive mixtures or mixtures used according to the invention.
  • Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water.
  • emulsions, pastes or oil dispersions the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetter, tackifier, dispersant or emulsifier.
  • concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil and such concentrates are suitable for dilution with water.
  • the active substance concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.001 to 1 % by weight of the compound selected from I, II, III and IV or the compounds of the inventive mixtures or mixtures used according to the invention.
  • oils, wetters, adjuvants, herbicides, fungicides, other pesticides, or bactericides may be added to the active compounds, if appropriate not until immediately prior to use (tank mix).
  • These agents can be admixed with the compound selected from I, II, III and IV or the compounds of the inventive mixtures in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1 .
  • the compounds contained in the mixtures as defined above can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
  • a variant of the present invention also comprises seed treatment with component 2 followed by foliar spraying with component 1 .
  • Seed treatment can be made into the seedbox before planting into the field.
  • the weight ratio in the binary or ternary mixtures of the present invention or the mixtures used according to the invention generally depends on the properties of the compounds of the inventive mixtures.
  • compositions which are especially useful for seed treatment are e.g.:
  • compositions can be applied to plant propagation materials, particularly seeds, diluted or undiluted.
  • the compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations. Application can be carried out before or during sowing.
  • Methods for applying or treating agrochemical compounds and compositions thereof, respectively, on to plant propagation material, especially seeds are known in the art, and include dressing, coating, pelleting, dusting and soaking application methods of the propagation material (and also in furrow treatment).
  • the compounds or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • the application rates of the compound selected from I, II, III and IV or the inventive mixture or the mixtures used according to the invention are generally for the formulated product (which usually comprises from10 to 750 g/l of the active(s)). Further suitable application rates see above.
  • the invention also relates to the propagation products of plants, and especially the seed comprising, that is, coated with and/or containing, a mixture as defined above or a composition containing the mixture of two or more active ingredients or a mixture of two or more compositions each providing one of the active ingredients.
  • the plant propagation material (preferably seed) comprises the inventive mixtures or the mixtures used according to the invention in an amount of from 0.01 g to 10 kg per 100 kg of plant propagation material (preferably seed).
  • the separate or joint application of the compounds of the inventive mixtures or the mixtures used according to the invention is carried out by spraying or dusting the seeds, the seedlings, the plants or the soils before or after sowing of the plants or before or after emergence of the plants.
  • compositions according to the invention can be shown by the tests described below.
  • Example 1 Spring wheat was grown in the 2010/201 1 growing season at the BASF Agricultural Research Station in Utrera, Spain. Two trials were setup in a randomized bloc design with 5 replications. The variety 'Yecora' was planted Dec 15, 2010 with a seeding rate of 200 kg seed per ha and a row spacing of 12 cm. Harvested plot size was 10.1 m 2 .
  • Compound I was applied to the wheat plants at flag leaf stage (growth stage 39, BBCH). Compound I was applied using an experimental formulation (200 g ai/l, SC) with 0.75 l/ha.
  • Total spray volume for the foliar applications were 300 l/ha. Spray applications were made using a pressurized backpack sprayer and a flat fan nozzle IDK 120-02 at 300 kPa pressure. Septoria tritici infection was assessed at the late milk stage (BBCH 78). At maturity the crop was harvested and grain yield and yield components were assessed. Haulms with ear per m row were counted. Grain yield was measured as t/ha (table 1 ). Grain weight was measured in g per 1000 grains (TGW), and number of grains per m 2 , and single ear yield in g per ear was calculated (table 1 ).
  • Tab. 1 Mean values for, Septoria tritici infection, grain yield and yield components for the two trials setup at Utrera Agricultural Research Station, Spain
  • Compound I increased grain yield by 0.14 t/ha compared to the control (table 1 ). In this example, there were no difference in number of ears formed between both, control treatment and compound I treatment. There was also no difference in grain weight between both treatments. Compound I increased the number of grains that were formed per ear, as can be seen in the increased number of grains per m 2 and increased grain yield per ear in table 1 .
  • Compound I was applied to the wheat plants at flowering (growth stage 63/65, BBCH).
  • Compound I was applied using an experimental formulation (200 g ai/l, SC) with 0.75 l/ha. Control plots were sprayed once at the same time with epoxiconazole. Epoxiconazole was applied as epoxiconazolee with 1 l/ha (125 g active ingredient/ha).
  • Total spray volume for the foliar applications were 200 l/ha. Spray applications were made using a pressurized sprayer and a 8001 VS flat fan nozzle at 300 kPa pressure.
  • Tab. 2 Mean values for yellow rust infection, grain yield and grain weight for the trial setup at Dinuba Agricultural Research Station, CA Treatments Prod FormuFormuAppliPuccinia Grain TG
  • Compound I increased grain yield in this example by 0.13 t/ha compared to the
  • Compound I was applied to the wheat plants at either flag leaf stage (BBCH 39/49), shooting and flag leaf stage (BBCH 31/32 and 39/49) or at shooting, flag leaf and heading (BBCH 31/32, 39/49 and 55).
  • Compound I was applied using an experimental formulation (200 g ai/l, SC) with 0.75 l/ha.
  • Epoxiconazole was applied as expoxiconazole with 1 l/ha (125 g active ingredient/ha).
  • Treatments 7 and 8 received in addition 0.8 l/ha of pyraclostrobin (EC, 250 g/l pyraclostrobin) at the flag leaf stage.
  • Total spray volume for the foliar applications were 200 l/ha. Spray applications were made using a pressurized sprayer and a 8001 VS flat fan nozzle at 300 kPa pressure.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • General Health & Medical Sciences (AREA)
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Abstract

L'invention porte sur un procédé d'amélioration de la santé d'une plante. La présente invention porte sur un procédé d'augmentation de la santé de plantes, la plante, le lieu où la plante pousse ou est sensée pousser ou le matériau de propagation de plante à partir duquel la plante pousse étant traités avec une quantité efficace d'un principe actif, choisi dans le groupe de composé I, II, III et IV ou un mélange tel que défini dans les revendications et la description. La présente invention porte également sur des mélanges spécifiques.
PCT/EP2011/064060 2010-08-20 2011-08-16 Procédé d'amélioration de la santé d'une plante Ceased WO2012022729A2 (fr)

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WO2013127818A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide et améliorant la santé des plantes avec le soja
WO2013127843A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le tournesol
WO2013127846A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le maïs
WO2013127821A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide et améliorant la santé des plantes avec le colza
WO2013127820A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le colza
WO2013127859A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja
WO2013127857A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide et d'amélioration de la santé végétale dans des céréales
WO2013127848A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide et améliorant la santé des plantes avec le maïs
WO2013127855A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans des céréales
CN105820129A (zh) * 2016-03-24 2016-08-03 华中师范大学 一种三唑炔类化合物及其应用

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WO2013127845A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le tournesol
WO2013127818A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide et améliorant la santé des plantes avec le soja
WO2013127843A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le tournesol
WO2013127846A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le maïs
WO2013127821A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide et améliorant la santé des plantes avec le colza
WO2013127820A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide, herbicide et améliorant la santé des plantes avec le colza
WO2013127859A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans du soja
WO2013127857A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide et d'amélioration de la santé végétale dans des céréales
WO2013127848A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique à action fongicide et améliorant la santé des plantes avec le maïs
WO2013127855A1 (fr) * 2012-03-01 2013-09-06 Basf Se Utilisation d'une composition agrochimique ayant une action fongicide, herbicide et d'amélioration de la santé végétale dans des céréales
CN105820129A (zh) * 2016-03-24 2016-08-03 华中师范大学 一种三唑炔类化合物及其应用

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