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WO2012013581A3 - Process and agents to remove metals from high -boiling paraffinic hydrocarbon fractions - Google Patents

Process and agents to remove metals from high -boiling paraffinic hydrocarbon fractions Download PDF

Info

Publication number
WO2012013581A3
WO2012013581A3 PCT/EP2011/062587 EP2011062587W WO2012013581A3 WO 2012013581 A3 WO2012013581 A3 WO 2012013581A3 EP 2011062587 W EP2011062587 W EP 2011062587W WO 2012013581 A3 WO2012013581 A3 WO 2012013581A3
Authority
WO
WIPO (PCT)
Prior art keywords
agents
hydrocarbon fractions
paraffinic hydrocarbon
remove metals
boiling paraffinic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2011/062587
Other languages
French (fr)
Other versions
WO2012013581A2 (en
Inventor
Ingo Bauer
Rudolf BÖNSCH
Ute Raab-Brill
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to EP11741548.9A priority Critical patent/EP2598607A2/en
Priority to CN2011800363334A priority patent/CN103025850A/en
Priority to US13/811,510 priority patent/US20130180887A1/en
Publication of WO2012013581A2 publication Critical patent/WO2012013581A2/en
Publication of WO2012013581A3 publication Critical patent/WO2012013581A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/28—Organic compounds not containing metal atoms containing sulfur as the only hetero atom, e.g. mercaptans, or sulfur and oxygen as the only hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The object of the invention is a process and agents to remove metal contaminants from hydrocarbon fractions like those obtained as a product from the Fischer-Tropsch synthesis involving the use of suspended catalyst. As per the present invention, the feed hydrocarbon fraction is treated with a demetallizing agent, comprising at least one sulfur source and at least one basic compound, under anhydrous conditions. The metals to be removed are obtained in the form of precipitate that can be easily separated by means of a mechanical separation process such as filtration, for example.
PCT/EP2011/062587 2010-07-26 2011-07-21 Process and agents to remove metals from high-boiling hydrocarbon fractions Ceased WO2012013581A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP11741548.9A EP2598607A2 (en) 2010-07-26 2011-07-21 Process and agents to remove metals from high-boiling paraffinic hydrocarbon fractions
CN2011800363334A CN103025850A (en) 2010-07-26 2011-07-21 Process and reagents for removing metals from high boiling hydrocarbon fractions
US13/811,510 US20130180887A1 (en) 2010-07-26 2011-07-21 Process and agents to remove metals from high-boiling hydrocarbon fractions

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE102010032263 2010-07-26
DE102010032263 2010-07-26
DE102011013470A DE102011013470A1 (en) 2010-07-26 2011-03-09 Process and means for removing metals from high boiling hydrocarbon fractions
DE102011013470.0 2011-03-09

Publications (2)

Publication Number Publication Date
WO2012013581A2 WO2012013581A2 (en) 2012-02-02
WO2012013581A3 true WO2012013581A3 (en) 2012-05-24

Family

ID=44629994

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/062587 Ceased WO2012013581A2 (en) 2010-07-26 2011-07-21 Process and agents to remove metals from high-boiling hydrocarbon fractions

Country Status (5)

Country Link
US (1) US20130180887A1 (en)
EP (1) EP2598607A2 (en)
CN (1) CN103025850A (en)
DE (1) DE102011013470A1 (en)
WO (1) WO2012013581A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013104696A1 (en) 2013-05-07 2014-11-13 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for removing metals from high boiling hydrocarbon fractions
DE102013106439A1 (en) 2013-06-20 2014-12-24 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for removing metals from high boiling hydrocarbon fractions
DE102013106441A1 (en) 2013-06-20 2014-12-24 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for removing metals from high boiling hydrocarbon fractions
DE102014107375A1 (en) 2014-05-26 2015-11-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for removing metal from high-boiling hydrocarbon fractions
DE102014107374A1 (en) 2014-05-26 2015-11-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for removing metals from high boiling hydrocarbon fractions
EP3103858A1 (en) 2015-06-08 2016-12-14 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method for washing organic liquids with a liquid comprising flurohydrocarbons
JP6817656B2 (en) * 2016-10-04 2021-01-20 エンライテン イノベーションズ インコーポレイテッド A method for separating particles containing alkali metal salts from liquid hydrocarbons
US12392011B2 (en) * 2018-12-11 2025-08-19 Eni S.P.A. Process for the selective recovery of transition metals from organic residues

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2683683A (en) * 1951-04-06 1954-07-13 Houdry Process Corp Purification of oils
US20020179493A1 (en) * 1999-08-20 2002-12-05 Environmental & Energy Enterprises, Llc Production and use of a premium fuel grade petroleum coke
US20050004415A1 (en) * 2003-07-02 2005-01-06 Chevron U.S.A. Inc. Ion exchange methods of treating a Fischer-Tropsch derived hydrocarbon stream
WO2005089931A2 (en) * 2004-03-17 2005-09-29 Advanced Minerals Corporation A mercury adsorbent composition, process of making same and method of separating mercury from fluids
WO2006048746A2 (en) * 2004-11-02 2006-05-11 Pfizer Inc. Methods for the removal of heavy metals
WO2009116988A1 (en) * 2008-03-17 2009-09-24 Shell Oil Company Process for the preparation of middle distillates from kerogen
US20090261017A1 (en) * 2008-04-22 2009-10-22 Rashid Iqbal Systems and methods for upgrading hydrocarbons

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD26308A (en)
AT205229B (en) 1957-04-18 1959-09-10 Ici Ltd Process for removing metal-containing catalyst residues from solid polymers of unsaturated hydrocarbons
GB1001190A (en) 1961-10-16 1965-08-11 Synthesewerk Schwarzeide Veb Process for the removal of metal contaminents from hydrocarbons
DE1212662B (en) 1962-05-09 1966-03-17 Universal Oil Prod Co Process for removing metallic and nitrogenous impurities from hydrocarbon oils
US3449243A (en) 1966-09-30 1969-06-10 Standard Oil Co Treating of heavy oils to remove metals,salts and coke forming materials employing a combination of an alcohol,organic acid and aromatic hydrocarbon
US3617530A (en) 1969-11-12 1971-11-02 Atlantic Richfield Co Metals removal from heavy hydrocarbon fractions
CA999821A (en) 1972-10-04 1976-11-16 Chevron Research And Technology Company Process for removing metalliferous contaminants from hydrocarbons
AU533444B2 (en) 1978-09-28 1983-11-24 Salusinszky, A.L. Regeneration of used lubricating oils
US4518484A (en) 1984-02-16 1985-05-21 Phillips Petroleum Company Metals removal with a light hydrocarbon and an organophosphorous compound
US4801573A (en) 1987-10-23 1989-01-31 501 Den Norske Stats Oljeslenskap A.S. Catalyst for production of hydrocarbons
AU720266B2 (en) 1996-12-16 2000-05-25 Res Usa, Llc Catalyst/wax separation device for slurry fischer-tropsch reactor
US6013176A (en) * 1998-12-18 2000-01-11 Exxon Research And Engineering Co. Method for decreasing the metals content of petroleum streams
HRP20180270T1 (en) 2008-01-24 2018-03-23 Dorf Ketal Chemicals (I) Private Limited Method of removing metals from hydrocarbon feedstock using esters of carboxylic acids

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2683683A (en) * 1951-04-06 1954-07-13 Houdry Process Corp Purification of oils
US20020179493A1 (en) * 1999-08-20 2002-12-05 Environmental & Energy Enterprises, Llc Production and use of a premium fuel grade petroleum coke
US20050004415A1 (en) * 2003-07-02 2005-01-06 Chevron U.S.A. Inc. Ion exchange methods of treating a Fischer-Tropsch derived hydrocarbon stream
WO2005089931A2 (en) * 2004-03-17 2005-09-29 Advanced Minerals Corporation A mercury adsorbent composition, process of making same and method of separating mercury from fluids
WO2006048746A2 (en) * 2004-11-02 2006-05-11 Pfizer Inc. Methods for the removal of heavy metals
WO2009116988A1 (en) * 2008-03-17 2009-09-24 Shell Oil Company Process for the preparation of middle distillates from kerogen
US20090261017A1 (en) * 2008-04-22 2009-10-22 Rashid Iqbal Systems and methods for upgrading hydrocarbons

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
VICTOR W ROSSO ET AL: "Removal of Palladium from Organic Reaction Mixtures by Trimercaptotriazine", ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1 January 1997 (1997-01-01), pages 311 - 314, XP055011031, Retrieved from the Internet <URL:http://pubs.acs.org/doi/pdf/10.1021/op970107f> [retrieved on 20111102] *

Also Published As

Publication number Publication date
DE102011013470A1 (en) 2012-01-26
US20130180887A1 (en) 2013-07-18
CN103025850A (en) 2013-04-03
EP2598607A2 (en) 2013-06-05
WO2012013581A2 (en) 2012-02-02

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