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WO2012010820A3 - Fischer-tropsch catalyst treatment - Google Patents

Fischer-tropsch catalyst treatment Download PDF

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Publication number
WO2012010820A3
WO2012010820A3 PCT/GB2011/001067 GB2011001067W WO2012010820A3 WO 2012010820 A3 WO2012010820 A3 WO 2012010820A3 GB 2011001067 W GB2011001067 W GB 2011001067W WO 2012010820 A3 WO2012010820 A3 WO 2012010820A3
Authority
WO
WIPO (PCT)
Prior art keywords
fischer
tropsch catalyst
catalyst treatment
catalyst
support material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2011/001067
Other languages
French (fr)
Other versions
WO2012010820A2 (en
Inventor
Sigrid Eri
Erling Rytter
Rune Myrstad
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GTL F1 AG
Original Assignee
GTL F1 AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GTL F1 AG filed Critical GTL F1 AG
Priority to EP11738259.8A priority Critical patent/EP2595748B1/en
Priority to US13/811,588 priority patent/US9249359B2/en
Priority to CN201180035916.5A priority patent/CN103153459B/en
Publication of WO2012010820A2 publication Critical patent/WO2012010820A2/en
Publication of WO2012010820A3 publication Critical patent/WO2012010820A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/705—Passivation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

A method of preparing a Fischer-Tropsch catalyst for handling, storage, transport and deployment, including the steps of: impregnating a porous support material with a source of cobalt; calcining the impregnated support material; activating the catalyst; and passivating the activated catalyst.
PCT/GB2011/001067 2010-07-22 2011-07-15 Catalyst treatment Ceased WO2012010820A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP11738259.8A EP2595748B1 (en) 2010-07-22 2011-07-15 Fischer-tropsch catalyst treatment
US13/811,588 US9249359B2 (en) 2010-07-22 2011-07-15 Catalyst treatment
CN201180035916.5A CN103153459B (en) 2010-07-22 2011-07-15 Catalyst treatment

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1012326.3 2010-07-22
GB1012326.3A GB2482171B (en) 2010-07-22 2010-07-22 Catalyst treatment

Publications (2)

Publication Number Publication Date
WO2012010820A2 WO2012010820A2 (en) 2012-01-26
WO2012010820A3 true WO2012010820A3 (en) 2012-05-03

Family

ID=42752644

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2011/001067 Ceased WO2012010820A2 (en) 2010-07-22 2011-07-15 Catalyst treatment

Country Status (5)

Country Link
US (1) US9249359B2 (en)
EP (1) EP2595748B1 (en)
CN (1) CN103153459B (en)
GB (1) GB2482171B (en)
WO (1) WO2012010820A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2794009C (en) 2010-03-22 2020-01-07 Brigham Young University Method for making highly porous, stable metal oxide with a controlled pore structure
GB2482171B (en) 2010-07-22 2018-04-11 Gtl F1 Ag Catalyst treatment
US9114378B2 (en) 2012-03-26 2015-08-25 Brigham Young University Iron and cobalt based fischer-tropsch pre-catalysts and catalysts
US9289750B2 (en) 2013-03-09 2016-03-22 Brigham Young University Method of making highly porous, stable aluminum oxides doped with silicon
CN106268815B (en) * 2015-05-29 2019-02-01 中国石油化工股份有限公司 A kind of loaded nano Co catalysts and its application
TWI677374B (en) * 2018-11-06 2019-11-21 國立清華大學 Method for fabricating heterogeneous nickel-based catalysts on aluminum oxide support, heterogeneous nickel-based catalysts on aluminum oxide support and method for synthesizing polyetheramine
WO2021139898A1 (en) * 2020-01-10 2021-07-15 Bp P.L.C. Process for producing a fischer-tropsch synthesis catalyst and fischer-tropsch start-up process
GB202103659D0 (en) 2021-03-17 2021-04-28 Johnson Matthey Plc Getter activation and use
GB202103658D0 (en) 2021-03-17 2021-04-28 Johnson Matthey Plc Catalyst activation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999042214A1 (en) * 1998-02-20 1999-08-26 Sasol Technology (Proprietary) Limited Process for producing hydrocarbons from a synthesis gas, and catalysts therefor
WO2005072866A1 (en) * 2004-01-28 2005-08-11 Statoil Asa Fischer-tropsch catalysts
WO2008139407A2 (en) * 2007-05-11 2008-11-20 Sasol Technology (Proprietary) Limited Catalysts
US20100022670A1 (en) * 2008-07-25 2010-01-28 Soled Stuart L Preparation of high activity cobalt catalysts, the catalysts and their use
WO2010078360A2 (en) * 2008-12-29 2010-07-08 Chevron U.S.A. Inc. Preparation of cobalt-containing fischer-tropsch catalysts

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729981A (en) * 1981-10-13 1988-03-08 Shell Internationale Research Maatschappij B.V. ROR-activated catalyst for synthesis gas conversion
US4585798A (en) * 1981-10-13 1986-04-29 Gulf Research & Development Company Synthesis gas conversion using ruthenium-promoted cobalt catalyst
US4605679A (en) * 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
US4605676A (en) * 1981-10-13 1986-08-12 Chevron Research Company Synthesis gas conversion using ROR-activated catalyst
IT1292423B1 (en) * 1997-06-26 1999-02-08 Agip Petroli PROCEDURE FOR THE PREPARATION OF A COBALT AND SCANDIUM BASED CATALYST
US6753351B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Supported catalyst activation
GB0226514D0 (en) * 2002-11-13 2002-12-18 Statoil Asa Fischer-tropsch catalysts
FR2879477A1 (en) * 2004-12-17 2006-06-23 Inst Francais Du Petrole Catalyst to make hydrocarbon synthesis from mixture comprising carbon monoxide and hydrogen, comprises support constituted by mixed spinel structure/simple type and an active phase deposited on support, which contains metals of group VIII
WO2008129024A1 (en) * 2007-04-24 2008-10-30 Basf Se Porous organometallic framework materials loaded with catalyst metal components
CA2685135C (en) * 2007-05-04 2015-02-10 Sasol Technology (Proprietary) Limited Catalysts
GB2482171B (en) 2010-07-22 2018-04-11 Gtl F1 Ag Catalyst treatment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999042214A1 (en) * 1998-02-20 1999-08-26 Sasol Technology (Proprietary) Limited Process for producing hydrocarbons from a synthesis gas, and catalysts therefor
WO2005072866A1 (en) * 2004-01-28 2005-08-11 Statoil Asa Fischer-tropsch catalysts
WO2008139407A2 (en) * 2007-05-11 2008-11-20 Sasol Technology (Proprietary) Limited Catalysts
US20100022670A1 (en) * 2008-07-25 2010-01-28 Soled Stuart L Preparation of high activity cobalt catalysts, the catalysts and their use
WO2010078360A2 (en) * 2008-12-29 2010-07-08 Chevron U.S.A. Inc. Preparation of cobalt-containing fischer-tropsch catalysts

Also Published As

Publication number Publication date
CN103153459B (en) 2015-08-05
US20130184360A1 (en) 2013-07-18
EP2595748B1 (en) 2019-10-30
WO2012010820A2 (en) 2012-01-26
US9249359B2 (en) 2016-02-02
GB2482171B (en) 2018-04-11
GB201012326D0 (en) 2010-09-08
EP2595748A2 (en) 2013-05-29
GB2482171A (en) 2012-01-25
CN103153459A (en) 2013-06-12

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