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WO2012010750A3 - Procédé de production de sucres a partir de biomasse lignocellulosique prétraitée avec un mélange de sels inorganiques hydratés et de sels métalliques - Google Patents

Procédé de production de sucres a partir de biomasse lignocellulosique prétraitée avec un mélange de sels inorganiques hydratés et de sels métalliques Download PDF

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Publication number
WO2012010750A3
WO2012010750A3 PCT/FR2011/000426 FR2011000426W WO2012010750A3 WO 2012010750 A3 WO2012010750 A3 WO 2012010750A3 FR 2011000426 W FR2011000426 W FR 2011000426W WO 2012010750 A3 WO2012010750 A3 WO 2012010750A3
Authority
WO
WIPO (PCT)
Prior art keywords
lignocellulosic biomass
mixture
hydrated inorganic
salts
metal salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2011/000426
Other languages
English (en)
Other versions
WO2012010750A2 (fr
Inventor
Christophe Vallee
Didier Morvan
Emmanuel Pellier
Hélène Olivier-Bourbigou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to EP11749870.9A priority Critical patent/EP2596110A2/fr
Priority to BR112013001757A priority patent/BR112013001757A2/pt
Priority to CA2801831A priority patent/CA2801831A1/fr
Priority to US13/811,676 priority patent/US20130210089A1/en
Publication of WO2012010750A2 publication Critical patent/WO2012010750A2/fr
Publication of WO2012010750A3 publication Critical patent/WO2012010750A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00—Preparation of compounds containing saccharide radicals
    • C12P19/02—Monosaccharides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H1/00—Processes for the preparation of sugar derivatives
    • C07H1/06—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/02—Monosaccharides
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00—Preparation of compounds containing saccharide radicals
    • C12P19/14—Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C12P7/08—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
    • C12P7/10—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00—Glucose; Glucose-containing syrups
    • C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/18—Pulping cellulose-containing materials with halogens or halogen-generating compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/20—Pulping cellulose-containing materials with organic solvents or in solvent environment
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P2201/00—Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

La présente invention porte sur un procédé de conversion de la biomasse lignocellulosique en sucres, comprenant au moins trois étapes. La première étape est une étape de cuisson de la biomasse lignocellulosique en présence d'au moins un sel inorganique hydraté en mélange avec au moins un autre sel métallique. La seconde étape est une étape de séparation d'au moins une fraction solide ayant subi l'étape de cuisson et la troisième étape est une étape d'hydrolyse enzymatique de ladite fraction solide pour convertir les polysaccharides en monosaccharides. Les sucres ainsi obtenus sont ensuite fermentescibles en alcools.
PCT/FR2011/000426 2010-07-23 2011-07-19 Procédé de production de sucres a partir de biomasse lignocellulosique prétraitée avec un mélange de sels inorganiques hydratés et de sels métalliques Ceased WO2012010750A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP11749870.9A EP2596110A2 (fr) 2010-07-23 2011-07-19 Procédé de production de sucres a partir de biomasse lignocellulosique prétraitée avec un mélange de sels inorganiques hydratés et de sels métalliques
BR112013001757A BR112013001757A2 (pt) 2010-07-23 2011-07-19 processo de produção de açúcares, a partir de biomassa lignocelulósica pré-tratada com uma mistura de sais inorgânicos hidratados e de sais metálicos
CA2801831A CA2801831A1 (fr) 2010-07-23 2011-07-19 Procede de production de sucres a partir de biomasse lignocellulosique pretraitee avec un melange de sels inorganiques hydrates et de sels metalliques
US13/811,676 US20130210089A1 (en) 2010-07-23 2011-07-19 Process for the production of sugars from lignocellulosic biomass pre-treated with a mixture of hydrated inorganic salts and metallic salts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR10/03092 2010-07-23
FR1003092A FR2963008B1 (fr) 2010-07-23 2010-07-23 Procede de production de sucres a partir de biomasse lignocellulosique pretraitee avec un melange de sels inorganiques hydrates et de sels metalliques

Publications (2)

Publication Number Publication Date
WO2012010750A2 WO2012010750A2 (fr) 2012-01-26
WO2012010750A3 true WO2012010750A3 (fr) 2012-04-12

Family

ID=43706425

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2011/000426 Ceased WO2012010750A2 (fr) 2010-07-23 2011-07-19 Procédé de production de sucres a partir de biomasse lignocellulosique prétraitée avec un mélange de sels inorganiques hydratés et de sels métalliques

Country Status (6)

Country Link
US (1) US20130210089A1 (fr)
EP (1) EP2596110A2 (fr)
BR (1) BR112013001757A2 (fr)
CA (1) CA2801831A1 (fr)
FR (1) FR2963008B1 (fr)
WO (1) WO2012010750A2 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2985736B1 (fr) * 2012-01-18 2020-01-10 IFP Energies Nouvelles Procede de pretraitement de la biomasse lignocellulosique avec un sel inorganique hydrate permettant d'obtenir une fraction cellulosique et une fraction hemicellulosique
FR2985737B1 (fr) * 2012-01-18 2020-01-10 IFP Energies Nouvelles Procede de pretraitement de la biomasse lignocellulosique avec un sel inorganique hydrate comprenant une etape d'hydrolyse acide preliminaire
CA2870829A1 (fr) * 2012-04-26 2013-10-31 Archer Daniels Midland Company Separation liquide/liquide de biomasse lignocellulosique pour produire des sirops de sucre et des fractions de lignine
FR2999605A1 (fr) 2012-12-14 2014-06-20 IFP Energies Nouvelles Procede de production de solutions de sucres a partir de biomasse lignocellulosique avec traitement complementaire du residu solide par un sel inorganique hydrate
FR2999604B1 (fr) * 2012-12-14 2017-01-13 Ifp Energies Now Procede de production de solutions de sucres et d'alcools a partir de biomasse lignocellulosique avec traitement complementaire du residu solide par un sel inorganique hydrate
US20160046731A1 (en) * 2014-08-14 2016-02-18 Api Intellectual Property Holdings, Llc Production of sugars from biomass using solid catalysts
US12116642B2 (en) 2020-03-02 2024-10-15 ExxonMobil Technology and Engineering Company Lignocellulosic biomass treatment methods and systems for production of biofuels and biochemicals
US12263463B2 (en) 2020-06-01 2025-04-01 ExxonMobil Technology and Engineering Company Biomass pyrolysis systems and methods for metal removal from biofuel
CN113289680B (zh) * 2021-06-02 2022-09-13 河北科技大学 一种双相催化剂及其制备方法和在木质纤维素生物质转化中的应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0091221A2 (fr) * 1982-04-05 1983-10-12 Imperial Chemical Industries Plc Dissolution et hydrolyse des hydrates de carbone
US4452640A (en) * 1982-05-11 1984-06-05 Purdue Research Foundation Quantitative hydrolysis of cellulose to glucose using zinc chloride
EP2100972A1 (fr) * 2008-03-13 2009-09-16 BIOeCON International Holding N.V. Procédé pour convertir les polysaccharides dans un hydrate de sel fondu

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003904323A0 (en) 2003-08-13 2003-08-28 Viridian Chemical Pty Ltd Solvents based on salts of aryl acids
FI116142B (fi) 2003-09-11 2005-09-30 Kemira Oyj Esteröintimenetelmä
US8236535B2 (en) * 2008-04-30 2012-08-07 Xyleco, Inc. Processing biomass
EP2408782A1 (fr) * 2009-03-17 2012-01-25 BIOeCON International Holding N.V. Procede pour la conversion de polysaccharides dans un hydrate de sel fondu inorganique

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0091221A2 (fr) * 1982-04-05 1983-10-12 Imperial Chemical Industries Plc Dissolution et hydrolyse des hydrates de carbone
US4452640A (en) * 1982-05-11 1984-06-05 Purdue Research Foundation Quantitative hydrolysis of cellulose to glucose using zinc chloride
EP2100972A1 (fr) * 2008-03-13 2009-09-16 BIOeCON International Holding N.V. Procédé pour convertir les polysaccharides dans un hydrate de sel fondu

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ALVIRA P ET AL: "Pretreatment technologies for an efficient bioethanol production process based on enzymatic hydrolysis: A review", BIORESOURCE TECHNOLOGY, ELSEVIER BV, GB, vol. 101, no. 13, 1 July 2010 (2010-07-01), pages 4851 - 4861, XP026986219, ISSN: 0960-8524, [retrieved on 20100327] *
FISCHER S ET AL: "Inorganic molten salts as solvents for cellulose", CELLULOSE, vol. 10, 1 January 2003 (2003-01-01), pages 227 - 236, XP002310360 *
LIU L ET AL: "Corn stover pretreatment by inorganic salts and its effects on hemicellulose and cellulose degradation", BIORESOURCE TECHNOLOGY, ELSEVIER BV, GB, vol. 100, no. 23, 1 December 2009 (2009-12-01), pages 5865 - 5871, XP026469495, ISSN: 0960-8524, [retrieved on 20090708], DOI: 10.1016/J.BIORTECH.2009.06.048 *
YOUNGRAN KIM ET AL: "Ethanosolv pretreatment of barley straw with iron(III) chloride for enzymatic saccharification", JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, vol. 85, no. 11, 15 June 2010 (2010-06-15), pages 1494 - 1498, XP055019529, ISSN: 0268-2575, DOI: 10.1002/jctb.2455 *

Also Published As

Publication number Publication date
FR2963008B1 (fr) 2013-01-04
US20130210089A1 (en) 2013-08-15
CA2801831A1 (fr) 2012-01-26
EP2596110A2 (fr) 2013-05-29
BR112013001757A2 (pt) 2016-08-30
FR2963008A1 (fr) 2012-01-27
WO2012010750A2 (fr) 2012-01-26

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