WO2012008014A1 - Associated-water concentration system and associated-water concentration method - Google Patents
Associated-water concentration system and associated-water concentration method Download PDFInfo
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- WO2012008014A1 WO2012008014A1 PCT/JP2010/061804 JP2010061804W WO2012008014A1 WO 2012008014 A1 WO2012008014 A1 WO 2012008014A1 JP 2010061804 W JP2010061804 W JP 2010061804W WO 2012008014 A1 WO2012008014 A1 WO 2012008014A1
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- evaporation method
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/048—Purification of waste water by evaporation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/007—Energy recuperation; Heat pumps
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/008—Control or steering systems not provided for elsewhere in subclass C02F
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/16—Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/10—Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/40—Liquid flow rate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Definitions
- the present invention relates to an accompanying water concentrating system and an accompanying water concentrating method, and more particularly to an accompanying water concentrating system and an accompanying water concentrating system characterized by a circulating system of cooling water required when processing accompanying water generated during coal mining by an evaporation method. Regarding the method.
- coal seam methane gas existing in the coal seam has attracted attention as a new natural gas. Since coal seam methane gas is dissolved in the accompanying water contained in the coal seam, it is obtained by separating the methane gas from the accompanying water after pumping up the accompanying water with a screw pump installed in the well (see Non-Patent Document 1).
- the method of temporarily storing the accompanying water in the reservoir causes a problem that a large reservoir is required as mining of the coal bed methane gas continues, making it difficult to continuously implement the coal bed methane gas mining project.
- concentration is reduced by using a reverse osmosis membrane device
- the required power of the reverse osmosis membrane device increases as the salt concentration increases, so a high concentration rate can be obtained in terms of processing costs. It becomes difficult and a similar problem occurs.
- the present invention has been made based on the above-mentioned matters, and its purpose is to reduce the accompanying water generated when obtaining coal-bed methane gas, and to use the accompanying method using an evaporation method concentrating device capable of reducing the amount of concentrated water stored in the reservoir.
- an accompanying water concentration system and an accompanying water concentration method that do not require special equipment for treating cooling water after being used in an evaporation method concentration apparatus are provided.
- the first invention is an accompanying water concentration system including an evaporation method concentrating device for concentrating accompanying water discharged together with coal bed gas from a coal bed, wherein the evaporation method concentrating device is provided.
- the cooling system for cooling includes an indirect heat exchanger for cooling the evaporation method concentrator, a cooling water supply means for taking the cooling water used for cooling from a well or a reservoir, and supplying the cooling water to the indirect heat exchanger, and the indirect heat.
- the second invention is an accompanying water concentration system comprising an evaporation method concentrating device for concentrating accompanying water discharged together with coal bed gas from a coal bed, wherein the evaporation method concentrating device is provided.
- the cooling system for cooling includes an indirect heat exchanger for cooling the evaporation method concentrator, a cooling water supply means for taking cooling water used for cooling from a well or a reservoir, and supplying the cooling water to the indirect heat exchanger, It shall be comprised with the closed circuit which consists of a waste warm water return means which returns waste warm water to the said well or the said pond.
- the third invention is characterized in that, in the first or second invention, a power generation facility capable of utilizing waste heat as a heat source of the evaporation method concentrator and a waste heat recovery boiler are provided.
- a fourth invention is the method according to any one of the first to third inventions, further comprising a reverse osmosis membrane type concentrating device in front of the evaporation method concentrating device, and the concentrated water from the reverse osmosis membrane type concentrating device It is characterized in that it is supplied as raw water for the evaporation method concentrator.
- 5th invention is the water temperature measurement means which measures the water temperature of the said waste warm water discharged
- a control device for controlling the flow rate of the cooling water supply means and / or the flow rate of the waste warm water return means so that the temperature of the waste hot water becomes equal to or lower than a predetermined value set in advance.
- a sixth invention is the fifth invention, wherein, in order to control the flow rate of the cooling water supply means and / or the flow rate of the waste warm water return means, the cooling water supply means according to the output of the control device. And / or using the inverter which outputs motive power to the said waste warm water return means.
- the seventh invention is characterized in that, in any one of the first to sixth inventions, a cooling means for cooling the cooling water is provided in a previous stage to be supplied to the evaporation method concentrating device.
- an eighth invention is characterized in that, in any one of the first to seventh inventions, a predetermined water depth range is provided in the pond and the cooling water intake is provided below the water depth range.
- the ninth invention is characterized in that, in any one of the first to eighth inventions, an electric immersion pump is used as a device for taking the cooling water from the well.
- a tenth aspect of the invention is based on the ninth aspect of the invention based on the fine particle detector that detects the amount of solid fine particles in the accompanying water solution and the solid fine particle signal that is the output of the fine particle detector.
- an electric immersion pump control device for stopping the electric immersion pump or reducing the suction flow rate.
- the eleventh invention is based on the ninth invention, based on an in-liquid bubble detector that detects an amount of bubbles in the liquid of the accompanying water, and a bubble signal that is an output of the in-liquid bubble detector.
- An electric immersion pump control device that stops the electric immersion pump or reduces the suction flow rate is provided.
- the twelfth invention is an accompanying water concentration method by an evaporation method concentrating device for concentrating the accompanying water discharged from the coal seam together with the coal bed gas, wherein the cooling step for cooling the evaporation method concentrating device is used for cooling.
- a cooling water supply process for taking cooling water from a well or a reservoir and supplying it to an indirect heat exchanger that cools the evaporative concentration apparatus, and a waste hot water returning process for returning the waste warm water after cooling to the well or the reservoir. Shall have.
- the volume of the accompanying water can be reduced by the evaporation method, so that the accompanying water can be easily discarded.
- the evaporation method concentrator taken from a well or pond is returned to the source, no cooling or chemical treatment is required. Running costs can be reduced.
- FIG. 1 is a system configuration diagram showing a first embodiment of an accompanying water concentration system of the present invention
- FIG. 2 is a schematic cross-sectional view showing a water intake portion of a pond in the first embodiment of the accompanying water concentration system of the present invention. It is.
- the accompanying water which becomes unnecessary after taking the coal bed gas and separating the coal bed gas becomes the raw water 10 for the accompanying water concentration system.
- the raw water 10 flows into the reverse osmosis membrane type concentrator 12 and is separated into fresh water 14 and concentrated water 16.
- the use of the fresh water 14 is not specified, it can be used as river discharge or irrigation water because the salt concentration is low.
- the concentrated water 16 of the reverse osmosis membrane type concentrator 12 is supplied to an evaporation method concentrator 18.
- the evaporation method concentrator 18 is supplied with steam 24 from an exhaust heat recovery boiler 26 that converts exhaust heat of the exhaust gas 22 of the power generation facility 20 into steam 24. Indirect heat that is provided in the evaporation method concentrator 18 using the heat energy of the steam 24 and cools the evaporation method concentrator 18 without changing the water quality of the cooling water 36 so as not to affect the groundwater layer.
- the concentrated water 16 of the reverse osmosis membrane type concentrator 12 is separated into fresh water 30 and highly concentrated water 32 by the exchanger 28.
- the highly concentrated water 32 having a high salt concentration cannot be used as river discharge or irrigation water, it is discarded in the pond 34 or supplied to a crystallization apparatus (not shown) for recovering valuable materials.
- the capacity of the basin 34 can be reduced or the crystallization apparatus (not shown) can be downsized.
- the cooling water 36 required by the indirect heat exchanger 28 is taken from the reservoir 34 by the cooling water supply means 38.
- the cooling water supply unit 38 may be specifically configured by an electric pump or the like, for example.
- the cooling means 42 for lowering the water temperature of the cooling water 36 is provided on the downstream side of the cooling water supply means 38, and the cooling water 36 whose water temperature has been lowered is supplied to the indirect heat exchanger 28.
- the cooling means 42 a method using a heat pump, a method of electronically cooling by a Peltier element, or a part of the cooling water 36 is vaporized by a spraying device or the like, and the remaining cooling water 36 is further cooled by the overheating.
- the cooling means 42 may not be provided.
- the cooling water 36 receives heat energy and becomes waste hot water 44.
- the waste hot water 44 is circulated to the reservoir 34 by the waste hot water return means 40 to form a closed circuit.
- the pond 34 has no restriction on the difference between the intake temperature and the disposal temperature, and therefore it is not necessary to provide a special cooling facility.
- the cooling water 36 When the cooling water 36 is taken from a pond, the water temperature fluctuates over time due to the effects of solar radiation and temperature. Even when the cooling water 36 is taken from the well, the time constant is larger than in the case of the pond, but the water temperature fluctuates with time.
- the concentration capacity of the indirect heat exchanger 28 is affected by the water temperature of the cooling water 36, this capacity can be evaluated by the water temperature of the waste hot water 44.
- the temperature of the waste hot water 44 is measured by the water temperature sensor 46 and given to the control device 50 as a water temperature signal 48.
- the control device 50 controls the flow rate of the cooling water supply means 38 or the flow rate of the waste hot water return means 40 based on the preset waste hot water temperature target value 52 and the water temperature signal 48, and the cooling capacity of the cooling means 42.
- control device 50 calculates the operating condition that minimizes the sum of the operating cost of the cooling water supply means 38 or the waste hot water return means 40 and the operating cost of the cooling means 42, and realizes the condition. Control of the cooling water supply means 38, the waste warm water return means 40, and the cooling means 42 is performed.
- These flow rates are controlled by outputting operation signals 60 and 64 from the control device 50 to the cooling water supply means inverter 54 or the waste hot water return means inverter 56, respectively, thereby pumping the cooling water supply means 38 and the waste hot water return means 40.
- the cooling water supply means power 62 and the waste hot water return means power 66 which are power to the electric motor or the like, are controlled. As compared with the case where a valve is used for the flow rate control, the pressure loss that is wasted can be reduced, and the running cost can be further reduced.
- the cooling means 42 When the cooling means 42 is not provided, only the cooling water supply means 38 or the waste hot water return means 40 is controlled by the control device 50. Even in this case, the flow rate of each means is controlled via the cooling water supply means inverter 54 or the waste hot water return means inverter 56 based on the waste warm water temperature signal 48 and the waste warm water temperature target value 52. The running cost can be reduced.
- FIG. 2 is a schematic view showing the intake portion of the pond in the first embodiment of the accompanying water concentration system of the present invention.
- FIG. 2 the same reference numerals as those shown in FIG.
- the cooling water 36 When the cooling water 36 is taken from the pond 34, the water near the water surface of the pond 34 is affected by solar radiation and temperature, so the water temperature is high. On the other hand, when water evaporates from the water surface of the pond 34, heat is removed as heat of vaporization, so that a physical phenomenon that lowers the water temperature also occurs simultaneously. In addition, when the air temperature around the pond is lower than the water temperature, heat escapes from the water surface to the air, so the water temperature decreases. The density of water varies with the water temperature and is maximum at about 4 ° C. Since there is no stirrer in the pond 34, water having a low water temperature generally moves toward the bottom of the pond 34.
- a water intake 70 for the cooling water 36 is provided at a location deeper than a predetermined water depth, and the cooling water 36 is taken. Thereby, the cooling water 36 whose water temperature is lower can be obtained.
- the volume of the accompanying water can be reduced by the evaporation method, so that the accompanying water can be easily discarded.
- cooling and chemical treatments are not required when returning the cooling water from the evaporative concentration device taken from the pond to the water source, so equipment costs and running costs are reduced compared to returning cooling water to rivers and seawater. Can be reduced.
- the cooling water is supplied from the reservoir 34.
- the reservoir 34 By taking water 36, it is possible to reduce the cost of pipe laying and the operating cost.
- FIG. 3 is a system configuration diagram showing a second embodiment of the accompanying water concentration system of the present invention.
- the same reference numerals as those shown in FIGS. 1 and 2 are the same parts, and detailed description thereof is omitted.
- the cooling water supply means 38 in the first embodiment is omitted.
- water can be taken in by the waste hot water returning means 40, and the cooling water supply means 38 can be omitted.
- the cooling water 36 is taken from the reservoir 34 by the waste warm water returning means 40, the water temperature in the waste hot water returning means 40 is increased, so that the viscosity resistance of the water is lowered and the running cost can be reduced.
- the waste warm water returning means 40 may be constituted by, for example, an electric pump or the like.
- FIG. 4 is a system configuration diagram showing a third embodiment of the accompanying water concentration system of the present invention. 4, the same reference numerals as those shown in FIG. 1 to FIG.
- the waste warm water returning means 40 in the first embodiment is omitted.
- the waste warm water returning means 40 in the first embodiment is omitted.
- FIG. 5 is a system configuration diagram showing a fourth embodiment of the accompanying water concentration system of the present invention. 5, the same reference numerals as those shown in FIG. 1 to FIG.
- the accompanying water which became unnecessary after taking water from the coal bed and separating the coal bed gas becomes the raw water 10 for the accompanying water concentration system.
- This raw water 10 flows into the reverse osmosis membrane type concentrator 12 and is separated into fresh water 14 and concentrated water 16.
- fresh water 14 is not specified, but it can be used as river discharge or irrigation water because of its low salt concentration.
- the concentrated water 16 of the reverse osmosis membrane type concentrator 12 is supplied to an evaporation method concentrator 18.
- the evaporation method concentrator 18 is supplied with steam 24 from an exhaust heat recovery boiler 26 that converts exhaust heat of the exhaust gas 22 of the power generation facility 20 into steam 24.
- the concentrated water 16 of the reverse osmosis membrane type concentrator 12 is separated into fresh water 30 and highly concentrated water 32 by an indirect heat exchanger 28 provided in the evaporation method concentrator 18.
- the highly concentrated water 32 having a high salt concentration cannot be used for discharge or irrigation, it is discarded in the pond 34 or supplied to a crystallization apparatus (not shown) for recovering valuable materials.
- the capacity of the basin 34 can be reduced or the crystallization apparatus (not shown) can be downsized.
- the cooling water 36 required by the indirect heat exchanger 28 is taken from the well 68 by the cooling water supply means 38 or the waste hot water return means 40. Since the well from which the coal seam gas is collected is generally located at a location far from the river or the ocean, the cooling water 36 can be taken from the well 68 to reduce the cost of piping installation and the operation cost.
- Well water taken from the well 68 is generally suitable as the cooling water 36 because the water temperature is generally stable and is not affected by temperature or solar radiation.
- the cooling means 42 is provided on the downstream side of the cooling water supply means 38, and the cooling water 36 with the water temperature lowered is supplied to the indirect heat exchanger 28.
- the cooling means 42 a method using a heat pump, a method of electronically cooling with a Peltier element, or a part of the cooling water 36 is vaporized by a spraying device or the like, and the remaining cooling water 36 is further cooled by the heat of vaporization.
- There are a method, a method using an absorption refrigerator, a method using cold heat previously stored in ice or the like with surplus power, and any of them may be used. If the water temperature of the cooling water 36 can be cooled by the well 68, the cooling means 42 need not be provided.
- the cooling water 36 receives heat energy and becomes waste hot water 44.
- the waste hot water 44 is circulated to the well 68 by the waste hot water returning means 40 to form a closed circuit.
- the well 68 has no restriction on the difference between the water intake temperature and the disposal temperature, and therefore there is no need to provide a special cooling facility. Further, since the cooling water 36 only changes in temperature in the indirect heat exchanger 28 and does not change in chemical properties, there is no problem even if it is circulated to the well 68 as the waste hot water 44.
- FIG. 5 shows a flow of returning the waste warm water 44 after taking water from the well 68 and using it for cooling to the well 68
- the waste warm water 44 may be returned to the reservoir 34.
- the concentration capacity of the indirect heat exchanger 28 is affected by the water temperature of the cooling water 36, and this capacity can be evaluated by the water temperature of the waste hot water 44.
- the temperature of the waste hot water 44 is measured by the water temperature sensor 46 and given to the control device 50 as a water temperature signal 48.
- the control device 50 controls the flow rate of the cooling water supply means 38 or the flow rate of the waste hot water return means 40 based on the preset waste hot water temperature target value 52 and the water temperature signal 48, and the cooling capacity of the cooling means 42. Control.
- the control device 50 calculates the operating condition that minimizes the sum of the operating cost of the cooling water supply means 38 or the waste hot water return means 40 and the operating cost of the cooling means 42, and realizes the condition. Control of the cooling water supply means 38, the waste warm water return means 40, and the cooling means 42 is performed.
- These flow rates are controlled by outputting operation signals 60 and 64 from the control device 50 to the cooling water supply means inverter 54 or the waste hot water return means inverter 56, respectively, thereby pumping the cooling water supply means 38 and the waste hot water return means 40.
- the cooling water supply means power 62 and the waste hot water return means power 66 which are power to the electric motor or the like, are controlled.
- the cooling means 42 When the cooling means 42 is not provided, only the cooling water supply means 38 or the waste hot water return means 40 is controlled by the control device 50. Even in this case, the flow rate of each means is controlled via the cooling water supply means inverter 54 or the waste hot water return means inverter 56 based on the waste warm water temperature signal 48 and the waste warm water temperature target value 52. The running cost can be reduced.
- the accompanying water volume can be reduced by the evaporation method, so that the accompanying water can be easily discarded.
- cooling and chemical treatment are not required when returning the cooling water from the evaporative concentration device taken from the well to the water source, so equipment costs and running costs are reduced compared to returning cooling water to rivers and seawater. Can be reduced.
- the cooling water is supplied from the well 68.
- the cooling water By taking water 36, it is possible to reduce the cost of pipe laying and the operating cost.
- FIG. 6 is a system configuration diagram showing a fifth embodiment of the accompanying water concentration system of the present invention.
- the same reference numerals as those shown in FIGS. 1 to 5 are the same parts, and detailed description thereof is omitted.
- an electric dipping pump 72 is used as the cooling water supply means 38 for taking the cooling water 36 from the well 68 of the coal seam in the fourth embodiment described above.
- the electric immersion pump 72 is used when pumping the accompanying water contained in the coal seam, the ratio of mechanical loss is reduced as compared with a screw pump conventionally used, and maintenance is facilitated. As a result, the running cost can be reduced.
- Examples of the solid matter that can be included in the accompanying water include coal powder, rock particles, sand particles, and the like, and when these particles become fine particles, they are likely to be mixed between the pump components and induce a failure.
- the submerged particle detector 74 that detects the amount of solid particulates in the accompanying water liquid, and the electric immersion pump 72 is stopped based on the detection signal of the submerged particle detector 74.
- an electric dipping pump control device 82 for reducing the suction flow rate.
- the suction flow rate of the electric dipping pump 72 is reduced or stopped to wait for these solid particulates to sink downward, and then pumped up. By starting the operation, it is possible to suppress the performance degradation of the electric immersion pump 72 and the like.
- the electric immersion pump 72 runs idle, resulting in a case where the performance deteriorates or the failure occurs in the worst case.
- the electric immersion pump 72 is provided below the well 68, so that time and cost are spent for lifting and maintenance.
- the submerged bubble detector 78 that detects the amount of bubbles in the liquid of the accompanying water, and the electric immersion pump 72 is stopped based on the detection signal of the submerged bubble detector 78, And an electric immersion pump controller 82 for reducing the suction flow rate.
- the same effect as that of the fourth embodiment described above can be obtained, and the electric immersion pump 72 is used instead of the screw pump. Therefore, the rate of mechanical loss is reduced, and maintenance is facilitated. As a result, the running cost can be reduced.
- the accompanying water since the in-liquid particle detector 74, the in-liquid bubble detector 78, and the electric immersion pump control device are provided, the accompanying water It is possible to suppress deterioration in performance or failure of the electric immersion pump 72 caused by solid fine particles or bubbles therein at an early stage. As a result, it is possible to reduce the time and cost spent for the lifting operation and maintenance of the electric immersion pump 72.
- the evaporation method concentrating device 18 to which the concentrated water 16 concentrated by the reverse osmosis membrane type concentrating device 12 is supplied has been described.
- the present invention is not limited to this.
- the evaporation method concentration apparatus 18 to which the accompanying water is directly supplied as the raw water 10 may be used.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
本発明は随伴水濃縮システムおよび随伴水濃縮方法に係り、特に石炭採掘時に生じる随伴水を蒸発法で処理する際に必要となる冷却水の循環システムに特徴を有する随伴水濃縮システムおよび随伴水濃縮方法に関する。 The present invention relates to an accompanying water concentrating system and an accompanying water concentrating method, and more particularly to an accompanying water concentrating system and an accompanying water concentrating system characterized by a circulating system of cooling water required when processing accompanying water generated during coal mining by an evaporation method. Regarding the method.
近年、新たな天然ガスとして石炭層に賦存する炭層メタンガスが注目されている。炭層メタンガスは炭層に含まれる随伴水中に溶解しているため、井戸に設置したスクリューポンプで随伴水を汲み上げた後に、随伴水からメタンガスを分離することで得られる(非特許文献1参照)。 Recently, coal seam methane gas existing in the coal seam has attracted attention as a new natural gas. Since coal seam methane gas is dissolved in the accompanying water contained in the coal seam, it is obtained by separating the methane gas from the accompanying water after pumping up the accompanying water with a screw pump installed in the well (see Non-Patent Document 1).
メタンガス分離後の随伴水には塩分が含まれるため、灌漑用水や緑化への使用や未処理状態での河川への排水等はできず、別途設けたため池に一時的に貯留して自然蒸発によって減容することや、逆浸透膜装置によって濃縮してからため池に貯留して自然蒸発によって減容する処理等が実施されてきた。 Because the accompanying water after separation of methane gas contains salt, it cannot be used for irrigation or greening or drained into rivers in an untreated state. A process of reducing the volume, concentrating with a reverse osmosis membrane apparatus, storing in a pond and reducing the volume by natural evaporation has been performed.
しかし、随伴水をため池で一時的に貯留する方法では、炭層メタンガスの採掘が継続するに伴って広大なため池が必要となるという問題が生じ、炭層メタンガス採掘事業の継続的な実施を難しくする。また、逆浸透膜装置を用いて濃縮処理をして減容化する場合でも、逆浸透膜装置の所要動力は塩濃度が高くなるに従って増加するため、処理コストの点から高い濃縮率を得ることが困難となり、同様の問題が生起する。 However, the method of temporarily storing the accompanying water in the reservoir causes a problem that a large reservoir is required as mining of the coal bed methane gas continues, making it difficult to continuously implement the coal bed methane gas mining project. In addition, even when concentration is reduced by using a reverse osmosis membrane device, the required power of the reverse osmosis membrane device increases as the salt concentration increases, so a high concentration rate can be obtained in terms of processing costs. It becomes difficult and a similar problem occurs.
一方、海水を淡水化する場合に逆浸透膜処理の濃縮水を多重効用蒸発法や多段フラッシュ法などの蒸発法濃縮装置に供給し、全体の濃縮水量を低減する脱塩装置がある(例えば、特許文献1参照)。また、蒸発法濃縮装置として水溶液の蒸発濃縮を低コストで効率よく行えるものがある(例えば、特許文献2参照)。蒸発法濃縮装置の所要動力や所要エネルギは塩濃度の影響が小さいため、このような脱塩装置を用いることで、高い濃縮率を得ることが現実的に可能となる。 On the other hand, when desalinating seawater, there is a desalination device that supplies the concentrated water of the reverse osmosis membrane treatment to an evaporation method concentration device such as a multi-effect evaporation method or a multistage flash method to reduce the total amount of concentrated water (for example Patent Document 1). In addition, there is an evaporation method concentration apparatus that can efficiently evaporate and concentrate an aqueous solution at low cost (see, for example, Patent Document 2). Since the required power and required energy of the evaporation method concentrator are less affected by the salt concentration, it is practically possible to obtain a high concentration ratio by using such a desalting apparatus.
上述した特許文献1及び2の技術を用いれば、メタンガス分離後の随伴水を減容化することが可能となる。
しかしながら、蒸発法濃縮装置の凝縮装置を作動させるためには、例えば河川や海等から冷却水を取り込み供給すると共に、熱交換後の温排水を河川や海等に排出して戻すことが必要となる。蒸発法濃縮装置で用いる冷却水を使用後に河川や海へ戻すと、水温が取水時より高いこと、あるいは成分に化学薬品が添加されること等が原因となり、河川や海の生態系や環境に悪影響を及ぼす場合がある。
If the technique of
However, in order to operate the condensing device of the evaporation method concentrating device, for example, it is necessary to take in and supply cooling water from a river or the sea, and to discharge the warm waste water after heat exchange back to the river or the sea. Become. If the cooling water used in the evaporation method concentrator is returned to the river or sea after use, the water temperature is higher than that at the time of water intake or chemicals are added to the components. May have adverse effects.
これらの悪影響を抑制するため、海水や河川水を冷却水に利用して使用後に海や河川へ戻す場合に、水温差や含有物質に対する環境規制をかけることが多くの地域で行われている。この環境規制を遵守するためには、使用後の冷却水を冷却する設備や化学薬品を除去する設備が必要となり、設備コストやランニングコストが増大するという課題があった。 In order to suppress these adverse effects, in many areas, when seawater or river water is used as cooling water and then returned to the sea or river after use, environmental regulations are imposed on water temperature differences and contained substances. In order to comply with this environmental regulation, equipment for cooling the cooling water after use and equipment for removing chemicals are required, and there is a problem that equipment costs and running costs increase.
本発明は上述の事柄に基づいてなされたもので、その目的は、炭層メタンガスを得る際に発生する随伴水を減容し、ため池に貯める濃縮水水量を低減できる蒸発法濃縮装置を用いた随伴水濃縮システムにおいて、蒸発法濃縮装置で使用した後の冷却水を処理するための特別な設備を必要としない随伴水濃縮システム及び随伴水濃縮方法を提供するものである。 The present invention has been made based on the above-mentioned matters, and its purpose is to reduce the accompanying water generated when obtaining coal-bed methane gas, and to use the accompanying method using an evaporation method concentrating device capable of reducing the amount of concentrated water stored in the reservoir. In the water concentration system, an accompanying water concentration system and an accompanying water concentration method that do not require special equipment for treating cooling water after being used in an evaporation method concentration apparatus are provided.
上記の目的を達成するために、第1の発明は、石炭層から炭層ガスと共に排出される随伴水を濃縮する蒸発法濃縮装置を備えた随伴水濃縮システムであって、前記蒸発法濃縮装置を冷却する冷却系統は、前記蒸発法濃縮装置を冷却する間接熱交換器と、冷却に用いる前記冷却水を井戸又はため池から取水し、前記間接熱交換器に供給する冷却水供給手段と前記間接熱交換器とからなる閉回路と、冷却後の廃棄温水を前記井戸又は前記ため池に戻す廃棄温水返送手段と前記間接熱交換器とからなる閉回路とのうちのいずれか一方からなる閉回路で構成するものとする。 In order to achieve the above object, the first invention is an accompanying water concentration system including an evaporation method concentrating device for concentrating accompanying water discharged together with coal bed gas from a coal bed, wherein the evaporation method concentrating device is provided. The cooling system for cooling includes an indirect heat exchanger for cooling the evaporation method concentrator, a cooling water supply means for taking the cooling water used for cooling from a well or a reservoir, and supplying the cooling water to the indirect heat exchanger, and the indirect heat. A closed circuit composed of an exchanger, and a closed circuit composed of any one of a waste warm water return means for returning the waste warm water after cooling back to the well or the pond and the closed circuit composed of the indirect heat exchanger It shall be.
上記の目的を達成するために、第2の発明は、石炭層から炭層ガスと共に排出される随伴水を濃縮する蒸発法濃縮装置を備えた随伴水濃縮システムであって、前記蒸発法濃縮装置を冷却する冷却系統は、前記蒸発法濃縮装置を冷却する間接熱交換器と、冷却に用いる冷却水を井戸又はため池から取水し、前記間接熱交換器に供給する冷却水供給手段と、冷却後の廃棄温水を前記井戸又は前記ため池に戻す廃棄温水返送手段とからなる閉回路で構成するものとする。 In order to achieve the above object, the second invention is an accompanying water concentration system comprising an evaporation method concentrating device for concentrating accompanying water discharged together with coal bed gas from a coal bed, wherein the evaporation method concentrating device is provided. The cooling system for cooling includes an indirect heat exchanger for cooling the evaporation method concentrator, a cooling water supply means for taking cooling water used for cooling from a well or a reservoir, and supplying the cooling water to the indirect heat exchanger, It shall be comprised with the closed circuit which consists of a waste warm water return means which returns waste warm water to the said well or the said pond.
また、第3の発明は、第1又は第2の発明において、前記蒸発法濃縮装置の熱源として排熱を利用できる発電設備と、排熱回収ボイラとを備えることを特徴とする。 Further, the third invention is characterized in that, in the first or second invention, a power generation facility capable of utilizing waste heat as a heat source of the evaporation method concentrator and a waste heat recovery boiler are provided.
更に、第4の発明は、第1乃至第3の発明のいずれかにおいて、前記蒸発法濃縮装置の前段に逆浸透膜式濃縮装置を備え、前記逆浸透膜式濃縮装置からの濃縮水を前記蒸発法濃縮装置の原水として供給することを特徴とする。 Furthermore, a fourth invention is the method according to any one of the first to third inventions, further comprising a reverse osmosis membrane type concentrating device in front of the evaporation method concentrating device, and the concentrated water from the reverse osmosis membrane type concentrating device It is characterized in that it is supplied as raw water for the evaporation method concentrator.
また、第5の発明は、第1乃至第4の発明のいずれかにおいて、前記間接熱交換器で冷却後に排出される前記廃棄温水の水温を計測する水温計測手段と、前記水温計測手段で計測した前記廃棄温水の水温があらかじめ設定した所定の値以下となるように前記冷却水供給手段の流量及び/または前記廃棄温水返送手段の流量を制御する制御装置とを備えることを特徴とする。 Moreover, 5th invention is the water temperature measurement means which measures the water temperature of the said waste warm water discharged | emitted after cooling with the said indirect heat exchanger in any one of 1st thru | or 4th invention, and is measured with the said water temperature measurement means. And a control device for controlling the flow rate of the cooling water supply means and / or the flow rate of the waste warm water return means so that the temperature of the waste hot water becomes equal to or lower than a predetermined value set in advance.
更に、第6の発明は、第5の発明において、前記冷却水供給手段の流量及び/または前記廃棄温水返送手段の流量を制御する為に、前記制御装置の出力に応じて前記冷却水供給手段及び/または前記廃棄温水返送手段に動力を出力するインバータを用いることを特徴とする。 Furthermore, a sixth invention is the fifth invention, wherein, in order to control the flow rate of the cooling water supply means and / or the flow rate of the waste warm water return means, the cooling water supply means according to the output of the control device. And / or using the inverter which outputs motive power to the said waste warm water return means.
また、第7の発明は、第1乃至第6の発明のいずれかにおいて、前記蒸発法濃縮装置に供給する前段に前記冷却水を冷却する冷却手段を備えることを特徴とする。 Further, the seventh invention is characterized in that, in any one of the first to sixth inventions, a cooling means for cooling the cooling water is provided in a previous stage to be supplied to the evaporation method concentrating device.
更に、第8の発明は、第1乃至第7の発明のいずれかにおいて、前記ため池で所定の水深範囲を設け、前記水深範囲より下部に前記冷却水の取水口を設けることを特徴とする。 Furthermore, an eighth invention is characterized in that, in any one of the first to seventh inventions, a predetermined water depth range is provided in the pond and the cooling water intake is provided below the water depth range.
また、第9の発明は、第1乃至第8の発明のいずれかにおいて、前記井戸から前記冷却水を取水するための装置として、電動浸漬ポンプを用いることを特徴とする。 The ninth invention is characterized in that, in any one of the first to eighth inventions, an electric immersion pump is used as a device for taking the cooling water from the well.
更に、第10の発明は、第9の発明において、前記随伴水の液中において固形微粒子の量を検出する液中微粒子検出器と、前記液中微粒子検出器の出力である固形微粒子信号に基づいて前記電動浸漬ポンプを停止あるいは吸込み流量を減少させる電動浸漬ポンプ制御装置とを備えることを特徴とする。 Furthermore, a tenth aspect of the invention is based on the ninth aspect of the invention based on the fine particle detector that detects the amount of solid fine particles in the accompanying water solution and the solid fine particle signal that is the output of the fine particle detector. And an electric immersion pump control device for stopping the electric immersion pump or reducing the suction flow rate.
また、第11の発明は、第9の発明において、前記随伴水の液中において気泡の量を検出する液中気泡検出器と、前記液中気泡検出器の出力である気泡信号に基づいて前記電動浸漬ポンプを停止あるいは吸込み流量を減少させる電動浸漬ポンプ制御装置とを備えることを特徴とする。 The eleventh invention is based on the ninth invention, based on an in-liquid bubble detector that detects an amount of bubbles in the liquid of the accompanying water, and a bubble signal that is an output of the in-liquid bubble detector. An electric immersion pump control device that stops the electric immersion pump or reduces the suction flow rate is provided.
更に、第12の発明は、石炭層から炭層ガスと共に排出される随伴水を濃縮する蒸発法濃縮装置による随伴水濃縮方法であって、前記蒸発法濃縮装置を冷却する冷却工程は、冷却に用いる冷却水を井戸又はため池から取水し、前記蒸発法濃縮装置を冷却する間接熱交換器に供給する冷却水供給工程と、冷却後の廃棄温水を前記井戸又は前記ため池に戻す廃棄温水返送工程とを有するものとする。 Further, the twelfth invention is an accompanying water concentration method by an evaporation method concentrating device for concentrating the accompanying water discharged from the coal seam together with the coal bed gas, wherein the cooling step for cooling the evaporation method concentrating device is used for cooling. A cooling water supply process for taking cooling water from a well or a reservoir and supplying it to an indirect heat exchanger that cools the evaporative concentration apparatus, and a waste hot water returning process for returning the waste warm water after cooling to the well or the reservoir. Shall have.
本発明によれば、蒸発法によって随伴水の容積を低減できるため、随伴水の廃棄が容易となる。また、井戸やため池などから取水した蒸発法濃縮装置の冷却水を取水元へ戻す場合に冷却や化学薬品の処理を必要としないので、河川や海水に冷却水を戻す場合に比べて設備コスト及びランニングコストを低減できる。 According to the present invention, the volume of the accompanying water can be reduced by the evaporation method, so that the accompanying water can be easily discarded. In addition, when cooling water from an evaporation method concentrator taken from a well or pond is returned to the source, no cooling or chemical treatment is required. Running costs can be reduced.
<第1の実施の形態>
以下、本発明の随伴水濃縮システムの第1の実施の形態を図面を用いて説明する。図1は本発明の随伴水濃縮システムの第1の実施の形態を示すシステム構成図、図2は本発明の随伴水濃縮システムの第1の実施の形態におけるため池の取水部を示す概略断面図である。
<First Embodiment>
Hereinafter, a first embodiment of an accompanying water concentration system of the present invention will be described with reference to the drawings. FIG. 1 is a system configuration diagram showing a first embodiment of an accompanying water concentration system of the present invention, and FIG. 2 is a schematic cross-sectional view showing a water intake portion of a pond in the first embodiment of the accompanying water concentration system of the present invention. It is.
図1において、炭層から取水して炭層ガスを分離した後に不要となった随伴水は、随伴水濃縮システムにとっての原水10となる。この原水10は、逆浸透膜式濃縮装置12に流入して淡水14と濃縮水16とに分離される。淡水14の用途は規定しないが、塩濃度が低いため、河川放流や灌漑用水として用いることができる。
In FIG. 1, the accompanying water which becomes unnecessary after taking the coal bed gas and separating the coal bed gas becomes the
逆浸透膜式濃縮装置12の濃縮水16は蒸発法濃縮装置18に供給される。蒸発法濃縮装置18には、発電設備20の排ガス22の排熱を蒸気24に転換する排熱回収ボイラ26から蒸気24が与えられる。この蒸気24の熱エネルギを利用し、蒸発法濃縮装置18の中に備えられ、地下水層に影響を与えないために冷却水36の水質を変化させずに蒸発法濃縮装置18を冷却する間接熱交換器28で逆浸透膜式濃縮装置12の濃縮水16を淡水30と高濃縮水32とに分離する。
The
塩濃度が高い高濃縮水32は、河川放流や灌漑用水として用いることができないため、ため池34に廃棄されるか、あるいは有価物回収のため図示しない結晶化装置へ供給される。本実施の形態においては、随伴水濃縮システムから排出される高濃縮水32の量が少ないことから、ため池34の小容量化あるいは図示しない結晶化装置の小型化が可能となる。
Since the highly concentrated
間接熱交換器28が必要とする冷却水36は、ため池34から冷却水供給手段38により取水する。なお、冷却水供給手段38は、具体的には、例えば、電動ポンプ等で構成しても良い。
The cooling
ため池34においては、その水面から常に水分が蒸発しているため、その気化熱がため池34の水温を低下させている。しかし、日射や気温の影響により十分な冷却ができない場合がある。このため、冷却水36の水温を低下させる冷却手段42を冷却水供給手段38の下流側に設け、水温を低下させた冷却水36を間接熱交換器28に供給している。この冷却手段42としては、ヒートポンプを用いる方法、ペルチェ素子によって電子的に冷却する方法、あるいは冷却水36の一部を噴霧装置などにより気化させ、その記過熱で残りの冷却水36をさらに冷却する方法、吸収式冷凍機を用いる方法、余剰電力であらかじめ氷などに蓄えていた冷熱を用いる方法などがあり、いずれを用いても良い。なお、ため池34等で冷却水36の水温を冷却できる場合には、冷却手段42を設けなくても良い。
In the
間接熱交換器28で冷却水36は熱エネルギを受け取り、廃棄温水44となる。この廃棄温水44は廃棄温水返送手段40によってため池34へ循環され、閉回路を構成する。ため池34は河川や海洋と異なり、取水温度と廃棄温度の差に関する制約はないため、特別に冷却設備を設ける必要はない。
In the
冷却水36はため池から取水する場合、日射量や気温の影響により時間的な水温変動が生じる。冷却水36を井戸から取水する場合でもため池の場合よりも時定数は大きいが、時間的に水温変動が生じる。間接熱交換器28の濃縮能力は冷却水36の水温の影響を受けるが、この能力は廃棄温水44の水温で評価することができる。廃棄温水44の温度は水温センサ46で計測し、水温信号48として制御装置50へ与えられる。制御装置50は、あらかじめ設定した廃棄温水水温目標値52と水温信号48とに基づいて、冷却水供給手段38の流量あるいは廃棄温水返送手段40の流量を制御するとともに、冷却手段42の冷却能力を制御する。この際、制御装置50は、冷却水供給手段38あるいは廃棄温水返送手段40の運転コストと冷却手段42の運転コストの総和が最小となる操作条件を算出したうえで、その条件を実現するように冷却水供給手段38、廃棄温水返送手段40および冷却手段42の制御を実施する。
When the cooling
これらの流量制御は、制御装置50から冷却水供給手段用インバータ54あるいは廃棄温水返送手段用インバータ56にそれぞれ操作信号60,64を出力することで冷却水供給手段38、廃棄温水返送手段40のポンプ電動機等への動力である冷却水供給手段動力62、廃棄温水返送手段動力66を制御してなされている。流量制御に弁を用いる場合に比して無駄に消費される圧力損失を低減することができ、さらなるランニングコスト低減が可能となる。
These flow rates are controlled by outputting operation signals 60 and 64 from the
冷却手段42を設けていない場合には、制御装置50で制御する対象は冷却水供給手段38あるいは廃棄温水返送手段40のみとなる。この場合であっても、廃棄温水水温信号48と廃棄温水水温目標値52に基づいてそれぞれの手段の流量を冷却水供給手段用インバータ54あるいは廃棄温水返送手段用インバータ56を介して制御することで、ランニングコストの低減が可能となる。
When the cooling means 42 is not provided, only the cooling water supply means 38 or the waste hot water return means 40 is controlled by the
図2は、本発明の随伴水濃縮システムの第1の実施の形態におけるため池の取水部を示す概略図である。図2において、図1に示す符号と同符号のものは同一部分であるので、その詳細な説明は省略する。 FIG. 2 is a schematic view showing the intake portion of the pond in the first embodiment of the accompanying water concentration system of the present invention. In FIG. 2, the same reference numerals as those shown in FIG.
ため池34から冷却水36を取水する場合、ため池34の水面付近の水は日射や気温の影響を受けるため、水温が高い。一方、ため池34の水面から水が蒸発する際に気化熱として熱が奪われるため、水温を低下させる物理現象も同時に起こっている。また、ため池の周囲の大気温度が水温よりも低い場合には水面から熱が大気中へ逃げるため、水温が低下する。水の密度は水温によって変化し、約4℃で最大となる。ため池34内に攪拌装置はないため、一般に水温の低い水はため池34の底の方に移動していく。
When the cooling
本実施の形態においては、ため池の水深に対する水温の違いに着目し、所定の水深より深い箇所に冷却水36の取水口70を設け、冷却水36を取水している。これにより、より水温の低い冷却水36を得ることができる。
In this embodiment, paying attention to the difference in water temperature with respect to the water depth of the pond, a
上述した本発明の随伴水濃縮システムの第1の実施の形態によれば、蒸発法によって随伴水の容積を低減できるため、随伴水の廃棄が容易となる。また、ため池から取水した蒸発法濃縮装置の冷却水を取水元へ戻す場合に冷却や化学薬品の処理を必要としないので、河川や海水に冷却水を戻す場合に比べて設備コスト及びランニングコストを低減できる。 According to the first embodiment of the accompanying water concentration system of the present invention described above, the volume of the accompanying water can be reduced by the evaporation method, so that the accompanying water can be easily discarded. In addition, cooling and chemical treatments are not required when returning the cooling water from the evaporative concentration device taken from the pond to the water source, so equipment costs and running costs are reduced compared to returning cooling water to rivers and seawater. Can be reduced.
また、上述した本発明の随伴水濃縮システムの第1の実施の形態によれば、一般的に河川や海洋から遠い場所に位置している炭層ガスを採取する井戸68において、ため池34から冷却水36を取水することで配管敷設の費用や運転コストを低減することができる。
In addition, according to the first embodiment of the accompanying water concentration system of the present invention described above, in the well 68 for collecting coal seam gas that is generally located far from rivers and oceans, the cooling water is supplied from the
また、上述した本発明の随伴水濃縮システムの第1の実施の形態によれば、ため池の取水口70を所定の水深Dより深い箇所に設けたので、水温の低い冷却水36を得られることにより、間接熱交換器28で必要な冷熱を得るために必要な冷却水36の水量を減らすことができる。この結果、冷却水供給手段38あるいは廃棄温水返送手段40の容量や動力費を減らすことが可能となる。
Moreover, according to 1st Embodiment of the accompanying water concentration system of this invention mentioned above, since the
<第2の実施の形態>
以下、本発明の随伴水濃縮システムの第2の実施の形態を図面を用いて説明する。図3は本発明の随伴水濃縮システムの第2の実施の形態を示すシステム構成図である。図3において、図1及び図2に示す符号と同符号のものは同一部分であるので、その詳細な説明は省略する。
<Second Embodiment>
Hereinafter, a second embodiment of the accompanying water concentration system of the present invention will be described with reference to the drawings. FIG. 3 is a system configuration diagram showing a second embodiment of the accompanying water concentration system of the present invention. In FIG. 3, the same reference numerals as those shown in FIGS. 1 and 2 are the same parts, and detailed description thereof is omitted.
図3においては、第1の実施の形態における冷却水供給手段38を省略している。冷却水36の配管の途中に自由水面が無い場合には、廃棄温水返送手段40により取水することが可能となり、冷却水供給手段38を省略することができる。廃棄温水返送手段40で冷却水36をため池34から取水する場合には、廃棄温水返送手段40における水温が上昇しているため、水の粘性抵抗が低下してランニングコストの低減が可能となる。廃棄温水返送手段40とは、具体的には、例えば、電動ポンプ等で構成しても良い。
In FIG. 3, the cooling water supply means 38 in the first embodiment is omitted. When there is no free water surface in the middle of the piping of the cooling
<第3の実施の形態>
以下、本発明の随伴水濃縮システムの第3の実施の形態を図面を用いて説明する。図4は本発明の随伴水濃縮システムの第3の実施の形態を示すシステム構成図である。図4において、図1乃至図3に示す符号と同符号のものは同一部分であるので、その詳細な説明は省略する。
<Third Embodiment>
Hereinafter, a third embodiment of the accompanying water concentration system of the present invention will be described with reference to the drawings. FIG. 4 is a system configuration diagram showing a third embodiment of the accompanying water concentration system of the present invention. 4, the same reference numerals as those shown in FIG. 1 to FIG.
図4においては、第1の実施の形態における廃棄温水返送手段40を省略している。冷却水36の配管の途中に自由水面が無い場合には、冷却水供給手段38のみにより取水/返送することが可能となり、廃棄温水返送手段40を省略することができる。
In FIG. 4, the waste warm water returning means 40 in the first embodiment is omitted. When there is no free water surface in the middle of the piping of the cooling
<第4の実施の形態>
以下、本発明の随伴水濃縮システムの第4の実施の形態を図面を用いて説明する。図5は本発明の随伴水濃縮システムの第4の実施の形態を示すシステム構成図である。図5において、図1乃至図4に示す符号と同符号のものは同一部分であるので、その詳細な説明は省略する。
<Fourth embodiment>
Hereinafter, a fourth embodiment of the accompanying water concentration system of the present invention will be described with reference to the drawings. FIG. 5 is a system configuration diagram showing a fourth embodiment of the accompanying water concentration system of the present invention. 5, the same reference numerals as those shown in FIG. 1 to FIG.
図5において、炭層から取水して炭層ガスを分離した後に不要となった随伴水は、随伴水濃縮システムにとっての原水10となる。この原水10は、逆浸透膜式濃縮装置12に流入して淡水14と濃縮水16に分離される。このうち淡水14の用途は規定しないが、塩濃度が低いため、河川放流や灌漑用水として用いることができる。
In FIG. 5, the accompanying water which became unnecessary after taking water from the coal bed and separating the coal bed gas becomes the
逆浸透膜式濃縮装置12の濃縮水16は蒸発法濃縮装置18に供給される。蒸発法濃縮装置18には、発電設備20の排ガス22の排熱を蒸気24に転換する排熱回収ボイラ26から蒸気24が与えられる。この蒸気24の熱エネルギを利用し、蒸発法濃縮装置18の中に備えられた間接熱交換器28で逆浸透膜式濃縮装置12の濃縮水16を淡水30と高濃縮水32に分離する。
The
塩濃度が高い高濃縮水32は、放流や灌漑に利用できないため、ため池34に廃棄されるか、あるいは有価物回収のため図示しない結晶化装置へ供給される。本実施の形態においては、随伴水濃縮システムから排出される高濃縮水32の量が少ないことから、ため池34の小容量化あるいは図示しない結晶化装置の小型化が可能となる。
Since the highly
間接熱交換器28が必要とする冷却水36は、井戸68から冷却水供給手段38あるいは廃棄温水返送手段40で取水する。炭層ガスを採取する井戸は一般的に河川や海洋から遠い場所に位置しているため、井戸68から冷却水36を取水することで配管敷設の費用や運転コストを低減できる。
The cooling
井戸68から取水する井戸水は一般に水温が安定しており、かつ気温の影響や日射の影響を受けないため、冷却水36として適している。しかし、十分な冷却ができない場合には冷却手段42を冷却水供給手段38の下流側に設け、水温を低下させた冷却水36を間接熱交換器28に供給している。この冷却手段42としては、ヒートポンプを用いる方法、ペルチェ素子によって電子的に冷却する方法、あるいは冷却水36の一部を噴霧装置などにより気化させ、その気化熱で残りの冷却水36をさらに冷却する方法、吸収式冷凍機を用いる方法、余剰電力であらかじめ氷などに蓄えていた冷熱を用いる方法などがあり、いずれを用いても良い。なお、井戸68で冷却水36の水温を冷却できる場合には、冷却手段42を設けなくても良い。
Well water taken from the well 68 is generally suitable as the cooling
間接熱交換器28で冷却水36は熱エネルギを受け取り、廃棄温水44となる。この廃棄温水44は廃棄温水返送手段40により井戸68へ循環され、閉回路を構成する。井戸68は河川や海洋と異なり、取水温度と廃棄温度の差に関する制約はないため、特別に冷却設備を設ける必要はない。また、冷却水36は間接熱交換器28で温度が変化するのみで化学的性状は変化しないため、廃棄温水44として井戸68に循環しても問題は生じない。
In the
図5では井戸68から取水して冷却に用いた後の廃棄温水44を井戸68へ戻すフローを図示しているが、この廃棄温水44をため池34へ戻しても良い。
Although FIG. 5 shows a flow of returning the
間接熱交換器28の濃縮能力は冷却水36の水温の影響を受けるが、この能力は廃棄温水44の水温で評価することができる。廃棄温水44の温度は水温センサ46で計測し、水温信号48として制御装置50へ与えられる。制御装置50は、あらかじめ設定した廃棄温水水温目標値52と水温信号48とに基づいて、冷却水供給手段38の流量あるいは廃棄温水返送手段40の流量を制御するとともに、冷却手段42の冷却能力を制御する。この際、制御装置50は、冷却水供給手段38あるいは廃棄温水返送手段40の運転コストと冷却手段42の運転コストの総和が最小となる操作条件を算出したうえで、その条件を実現するように冷却水供給手段38、廃棄温水返送手段40および冷却手段42の制御を実施する。
The concentration capacity of the
これらの流量制御は、制御装置50から冷却水供給手段用インバータ54あるいは廃棄温水返送手段用インバータ56にそれぞれ操作信号60,64を出力することで冷却水供給手段38、廃棄温水返送手段40のポンプ電動機等への動力である冷却水供給手段動力62、廃棄温水返送手段動力66を制御してなされている。
These flow rates are controlled by outputting operation signals 60 and 64 from the
冷却手段42を設けていない場合には、制御装置50で制御する対象は冷却水供給手段38あるいは廃棄温水返送手段40のみとなる。この場合であっても、廃棄温水水温信号48と廃棄温水水温目標値52に基づいてそれぞれの手段の流量を冷却水供給手段用インバータ54あるいは廃棄温水返送手段用インバータ56を介して制御することで、ランニングコストの低減が可能となる。
When the cooling means 42 is not provided, only the cooling water supply means 38 or the waste hot water return means 40 is controlled by the
上述した本発明の随伴水濃縮システムの第4の実施の形態によれば、蒸発法によって随伴水の容積を低減できるため、随伴水の廃棄が容易となる。また、井戸から取水した蒸発法濃縮装置の冷却水を取水元へ戻す場合に冷却や化学薬品の処理を必要としないので、河川や海水に冷却水を戻す場合に比べて設備コスト及びランニングコストを低減できる。 According to the above-described fourth embodiment of the accompanying water concentration system of the present invention, the accompanying water volume can be reduced by the evaporation method, so that the accompanying water can be easily discarded. In addition, cooling and chemical treatment are not required when returning the cooling water from the evaporative concentration device taken from the well to the water source, so equipment costs and running costs are reduced compared to returning cooling water to rivers and seawater. Can be reduced.
また、上述した本発明の随伴水濃縮システムの第4の実施の形態によれば、一般的に河川や海洋から遠い場所に位置している炭層ガスを採取する井戸68において、井戸68から冷却水36を取水することで配管敷設の費用や運転コストを低減することができる。
Further, according to the above-described fourth embodiment of the accompanying water concentration system of the present invention, in the well 68 that collects coal seam gas that is generally located far from rivers and oceans, the cooling water is supplied from the
<第5の実施の形態>
以下、本発明の随伴水濃縮システムの第5の実施の形態を図面を用いて説明する。図6は本発明の随伴水濃縮システムの第5の実施の形態を示すシステム構成図である。図6において、図1乃至図5に示す符号と同符号のものは同一部分であるので、その詳細な説明は省略する。
<Fifth embodiment>
Hereinafter, a fifth embodiment of the accompanying water concentration system of the present invention will be described with reference to the drawings. FIG. 6 is a system configuration diagram showing a fifth embodiment of the accompanying water concentration system of the present invention. In FIG. 6, the same reference numerals as those shown in FIGS. 1 to 5 are the same parts, and detailed description thereof is omitted.
図6においては、上述した第4の実施の形態における炭層の井戸68から冷却水36を取水する冷却水供給手段38として電動浸漬ポンプ72を用いている。炭層に含まれる随伴水を汲み上げる際に電動浸漬ポンプ72を用いると、従来から用いられているスクリューポンプに比べて機械的に損失となる割合が少なくなり、メンテナンスも容易となる。その結果、ランニングコストを低減することが可能となる。
In FIG. 6, an
一方、汲み上げる随伴水の中に電動浸漬ポンプ72を詰まらせる固形物が含まれると、電動浸漬ポンプ72の性能低下あるいは最悪の場合故障するケースが発生する。ポンプが故障した場合、電動浸漬ポンプ72は井戸68の下方に備え付けるため、その引き上げやメンテナンスに時間やコストが費やされることになる。
On the other hand, when the solid water that clogs the
随伴水の中に含まれ得る固形物としては、例えば、石炭粉や岩石粒や砂粒等が考えられ、これらが微粒子状になるとポンプ構成物の間に混入しやすくなり、故障を誘発する。 Examples of the solid matter that can be included in the accompanying water include coal powder, rock particles, sand particles, and the like, and when these particles become fine particles, they are likely to be mixed between the pump components and induce a failure.
そこで、本実施の形態においては、随伴水の液中において固形微粒子の量を検出する液中微粒子検出器74と、液中微粒子検出器74の検出信号に基づいて電動浸漬ポンプ72を停止させたり、吸込み流量を減少させたりする電動浸漬ポンプ制御装置82とを備えている。随伴水の液中の固形微粒子の量が増加した場合には、電動浸漬ポンプ72の吸込み流量を減らしたり、停止したりすることにより、これらの固形微粒子が下方に沈下するのを待ち、その後汲み上げを開始することによって、電動浸漬ポンプ72の性能低下等を抑制できる。
Therefore, in the present embodiment, the submerged
また、汲み上げる随伴水の中に例えばメタンなどの気体が気泡状に多く含まれている場合には、電動浸漬ポンプ72は空走し、性能低下や最悪の場合故障するケースが発生する。ポンプが故障した場合、電動浸漬ポンプ72は井戸68の下方に備え付けるため、その引き上げやメンテナンスに時間やコストが費やされることになる。
In addition, when the accompanying water to be pumped contains a large amount of gas such as methane in the form of bubbles, the
そこで、本実施の形態においては、随伴水の液中において気泡の量を検出する液中気泡検出器78と、液中気泡検出器78の検出信号に基づいて電動浸漬ポンプ72を停止させたり、吸込み流量を減少させたりする電動浸漬ポンプ制御装置82とを備えている。
Therefore, in the present embodiment, the
上述した本発明の随伴水濃縮システムの第5の実施の形態によれば、上述した第4の実施の形態と同様な効果を得ることができるとともに、スクリューポンプに替えて電動浸漬ポンプ72を用いたので、機械的に損失となる割合が少なくなり、メンテナンスも容易となる。この結果、ランニングコストを低減することが可能となる。
According to the fifth embodiment of the accompanying water concentration system of the present invention described above, the same effect as that of the fourth embodiment described above can be obtained, and the
また、上述した本発明の随伴水濃縮システムの第5の実施の形態によれば、液中微粒子検出器74と液中気泡検出器78と電動浸漬ポンプ制御装置とを備えたので、随伴水の中の固形微粒子や気泡を原因とする電動浸漬ポンプ72の性能低下や故障を早い段階で抑制することができる。この結果として、電動浸漬ポンプ72の引上げ作業やメンテナンスに費やされる時間やコストを低減することが可能となる。
Further, according to the fifth embodiment of the accompanying water concentration system of the present invention described above, since the in-
なお、本発明の実施の形態においては、逆浸透膜式濃縮装置12で濃縮された濃縮水16が供給される蒸発法濃縮装置18について説明したが、これに限るものではない。例えば、直接随伴水が原水10として供給される蒸発法濃縮装置18であっても良い。
In the embodiment of the present invention, the evaporation
10 原水
12 逆浸透膜式濃縮装置
14 淡水
16 濃縮水
18 蒸発法濃縮装置
20 発電設備
22 排ガス
24 蒸気
26 排熱回収ボイラ
28 間接熱交換器
30 淡水
32 高濃縮水
34 ため池
36 冷却水
38 冷却水供給手段
40 廃棄温水返送手段
42 冷却手段
44 廃棄温水
46 水温センサ
48 水温信号
50 制御装置
52 廃棄温水水温目標値
54 冷却水供給手段用インバータ
56 廃棄温水返送手段用インバータ
58 冷却手段操作信号
60 冷却水供給手段操作信号
62 冷却水供給手段動力
64 廃棄温水返送手段操作信号
66 廃棄温水返送手段動力
68 井戸
70 取水口
72 電動浸漬ポンプ
74 液中微粒子検出器
76 微粒子信号
78 液中気泡検出器
80 気泡信号
82 電動浸漬ポンプ制御装置
84 電動浸漬ポンプ動力
DESCRIPTION OF
Claims (12)
前記蒸発法濃縮装置(18)を冷却する冷却系統は、前記蒸発法濃縮装置(18)を冷却する間接熱交換器(28)と、
冷却に用いる前記冷却水(36)を井戸(68)又はため池(34)から取水し、前記間接熱交換器(28)に供給する冷却水供給手段(38)と前記間接熱交換器(28)とからなる閉回路と、
冷却後の廃棄温水(44)を前記井戸(68)又は前記ため池(34)に戻す廃棄温水返送手段(40)と前記間接熱交換器(28)とからなる閉回路とのうちのいずれか一方からなる閉回路で構成する
ことを特徴とする随伴水濃縮システム。 An associated water concentration system comprising an evaporation method concentration device (18) for concentrating associated water discharged together with coal bed gas from a coal bed,
The cooling system for cooling the evaporation method concentrator (18) includes an indirect heat exchanger (28) for cooling the evaporation method concentrator (18), and
The cooling water (36) used for cooling is taken from the well (68) or the pond (34) and supplied to the indirect heat exchanger (28) and the cooling water supply means (38) and the indirect heat exchanger (28). A closed circuit consisting of
Either one of the closed warm water return means (40) for returning the waste warm water (44) after cooling back to the well (68) or the reservoir (34) and the closed circuit comprising the indirect heat exchanger (28). An associated water concentrating system comprising a closed circuit consisting of
前記蒸発法濃縮装置(18)を冷却する冷却系統は、前記蒸発法濃縮装置(18)を冷却する間接熱交換器(28)と、
冷却に用いる冷却水(36)を井戸(68)又はため池(34)から取水し、前記間接熱交換器(28)に供給する冷却水供給手段(38)と、
冷却後の廃棄温水(44)を前記井戸(68)又は前記ため池(34)に戻す廃棄温水返送手段(40)とからなる閉回路で構成する
ことを特徴とする随伴水濃縮システム。 An associated water concentration system comprising an evaporation method concentration device (18) for concentrating associated water discharged together with coal bed gas from a coal bed,
The cooling system for cooling the evaporation method concentrator (18) includes an indirect heat exchanger (28) for cooling the evaporation method concentrator (18), and
Cooling water supply means (38) for taking cooling water (36) used for cooling from the well (68) or the reservoir (34) and supplying the cooling water (36) to the indirect heat exchanger (28);
An associated water concentration system comprising a closed circuit comprising waste warm water returning means (40) for returning the waste warm water (44) after cooling to the well (68) or the reservoir (34).
前記蒸発法濃縮装置(18)の熱源として排熱を利用できる発電設備(20)と、排熱回収ボイラ(26)とを備える
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to claim 1 or 2,
An accompanying water concentration system comprising: a power generation facility (20) that can use exhaust heat as a heat source of the evaporation method concentration device (18); and an exhaust heat recovery boiler (26).
前記蒸発法濃縮装置(18)の前段に逆浸透膜式濃縮装置(12)を備え、前記逆浸透膜式濃縮装置(12)からの濃縮水(16)を前記蒸発法濃縮装置(18)の原水(10)として供給する
ことを特徴とする随伴水濃縮システム。 In the accompanying water concentration system according to any one of claims 1 to 3,
A reverse osmosis membrane type concentrating device (12) is provided in front of the evaporation method concentrating device (18), and the concentrated water (16) from the reverse osmosis membrane type concentrating device (12) is supplied to the evaporation method concentrating device (18). An accompanying water concentration system, characterized in that it is supplied as raw water (10).
前記間接熱交換器(28)で冷却後に排出される前記廃棄温水(44)の水温を計測する水温計測手段(46)と、
前記水温計測手段(46)で計測した前記廃棄温水(44)の水温があらかじめ設定した所定の値以下となるように前記冷却水供給手段(38)の流量及び/または前記廃棄温水返送手段(40)の流量を制御する制御装置(50)とを備える
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to any one of claims 1 to 4,
Water temperature measuring means (46) for measuring the water temperature of the waste warm water (44) discharged after cooling by the indirect heat exchanger (28);
The flow rate of the cooling water supply means (38) and / or the waste warm water return means (40) so that the water temperature of the waste warm water (44) measured by the water temperature measuring means (46) is below a predetermined value set in advance. And a control device (50) for controlling the flow rate of the adjoining water.
前記冷却水供給手段(38)の流量及び/または前記廃棄温水返送手段(40)の流量を制御する為に、前記制御装置(50)の出力に応じて前記冷却水供給手段(38)及び/または前記廃棄温水返送手段(40)に動力を出力するインバータ(54),(56)を用いる
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to claim 5,
In order to control the flow rate of the cooling water supply means (38) and / or the flow rate of the waste warm water return means (40), the cooling water supply means (38) and / or the output of the control device (50) is controlled. Or the accompanying water concentration system using the inverters (54) and (56) which output motive power to the said waste warm water return means (40).
前記蒸発法濃縮装置(18)に供給する前段に前記冷却水(36)を冷却する冷却手段(42)を備える
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to any one of claims 1 to 6,
A companion water concentration system comprising cooling means (42) for cooling the cooling water (36) in a previous stage to be supplied to the evaporation method concentration device (18).
前記ため池(34)で所定の水深範囲を設け、前記水深範囲より下部に前記冷却水(36)の取水口(70)を設ける
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to any one of claims 1 to 7,
The associated water concentration system, wherein a predetermined water depth range is provided in the pond (34), and a water intake (70) for the cooling water (36) is provided below the water depth range.
前記井戸(68)から前記冷却水(36)を取水するための装置として、電動浸漬ポンプ(72)を用いる
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to any one of claims 1 to 8,
An accompanying water concentration system using an electric dipping pump (72) as an apparatus for taking the cooling water (36) from the well (68).
前記随伴水の液中において固形微粒子の量を検出する液中微粒子検出器と、前記液中微粒子検出器の出力である固形微粒子信号に基づいて前記電動浸漬ポンプを停止あるいは吸込み流量を減少させる電動浸漬ポンプ制御装置とを備える
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to claim 9,
An in-liquid particle detector that detects the amount of solid particles in the accompanying water liquid, and an electric motor that stops or reduces the suction flow rate based on a solid particle signal that is an output of the in-liquid particle detector. An accompanying water concentration system comprising an immersion pump control device.
前記随伴水の液中において気泡の量を検出する液中気泡検出器と、前記液中気泡検出器の出力である気泡信号に基づいて前記電動浸漬ポンプを停止あるいは吸込み流量を減少させる電動浸漬ポンプ制御装置とを備える
ことを特徴とする随伴水濃縮システム。 The accompanying water concentration system according to claim 9,
A submerged bubble detector for detecting the amount of bubbles in the liquid of the accompanying water, and an electric submerged pump for stopping the electric submersible pump or reducing the suction flow rate based on a bubble signal that is an output of the submerged bubble detector An accompanying water concentration system comprising: a control device.
前記蒸発法濃縮装置(18)を冷却する冷却工程は、
冷却に用いる冷却水(36)を井戸(68)又はため池(34)から取水し、前記蒸発法濃縮装置(18)を冷却する間接熱交換器(28)に供給する冷却水供給工程と、
冷却後の廃棄温水(44)を前記井戸(68)又は前記ため池(34)に戻す廃棄温水返送工程とを有する
ことを特徴とする随伴水濃縮方法。 An accompanying water concentration method by an evaporation method concentration device (18) for concentrating accompanying water discharged from a coal bed together with coal bed gas,
The cooling step of cooling the evaporation method concentration device (18)
A cooling water supply step of taking cooling water (36) used for cooling from the well (68) or the reservoir (34) and supplying the cooling water (36) to the indirect heat exchanger (28) for cooling the evaporation method concentrator (18);
A method for concentrating waste water, comprising a step of returning the waste warm water (44) after cooling to the well (68) or the reservoir (34).
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2010/061804 WO2012008014A1 (en) | 2010-07-12 | 2010-07-12 | Associated-water concentration system and associated-water concentration method |
| AU2010357341A AU2010357341B2 (en) | 2010-07-12 | 2010-07-12 | Associated-water concentration system and associated-water concentration method |
| JP2012524357A JP5495404B2 (en) | 2010-07-12 | 2010-07-12 | Accompanying water concentration system and accompanying water concentration method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| PCT/JP2010/061804 WO2012008014A1 (en) | 2010-07-12 | 2010-07-12 | Associated-water concentration system and associated-water concentration method |
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| Publication Number | Publication Date |
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| WO2012008014A1 true WO2012008014A1 (en) | 2012-01-19 |
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| PCT/JP2010/061804 Ceased WO2012008014A1 (en) | 2010-07-12 | 2010-07-12 | Associated-water concentration system and associated-water concentration method |
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| Country | Link |
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| JP (1) | JP5495404B2 (en) |
| AU (1) | AU2010357341B2 (en) |
| WO (1) | WO2012008014A1 (en) |
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| WO2014007032A1 (en) * | 2012-07-06 | 2014-01-09 | 株式会社 日立製作所 | Method and device for treating saline wastewater |
| JP2014001085A (en) * | 2012-06-15 | 2014-01-09 | Sasakura Engineering Co Ltd | Recovery system and recovery method of sodium hydrogen carbonate |
| WO2022071153A1 (en) * | 2020-09-30 | 2022-04-07 | 日東電工株式会社 | Method for treating oil-containing drainage water |
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- 2010-07-12 WO PCT/JP2010/061804 patent/WO2012008014A1/en not_active Ceased
- 2010-07-12 JP JP2012524357A patent/JP5495404B2/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
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| JPWO2012008014A1 (en) | 2013-09-05 |
| AU2010357341A1 (en) | 2013-05-16 |
| JP5495404B2 (en) | 2014-05-21 |
| AU2010357341B2 (en) | 2014-06-05 |
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