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WO2012056184A3 - Method of purifying carbon nanotubes - Google Patents

Method of purifying carbon nanotubes Download PDF

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Publication number
WO2012056184A3
WO2012056184A3 PCT/FR2011/052519 FR2011052519W WO2012056184A3 WO 2012056184 A3 WO2012056184 A3 WO 2012056184A3 FR 2011052519 W FR2011052519 W FR 2011052519W WO 2012056184 A3 WO2012056184 A3 WO 2012056184A3
Authority
WO
WIPO (PCT)
Prior art keywords
dihalogen
gas
interhalogen
carbon nanotubes
interhalogen gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2011/052519
Other languages
French (fr)
Other versions
WO2012056184A2 (en
Inventor
Guillaume Mercier
Jean-François MARECHE
Sébastien CAHEN
Claire Herold
Brigitte Vigolo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Institut National Polytechnique de Lorraine
Original Assignee
Centre National de la Recherche Scientifique CNRS
Institut National Polytechnique de Lorraine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Institut National Polytechnique de Lorraine filed Critical Centre National de la Recherche Scientifique CNRS
Publication of WO2012056184A2 publication Critical patent/WO2012056184A2/en
Publication of WO2012056184A3 publication Critical patent/WO2012056184A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • C01B32/17—Purification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The present invention relates to a process for purifying carbon nanotubes and applications thereof, especially for the manufacture of composites, of electronic components and of biomaterials. The process of the invention is characterized in that it comprises a step of treating a sample of carbon nanotubes in the presence of dihalogen gas and/or an interhalogen gas at 200-2000°C, and in the absence of H2O and HCl, without a separate oxidation step and without prior exfoliation of the carbon-based multilayer shells in the sample. The present invention also relates to a device for purifying carbon nanotubes comprising: - a system for introducing a dihalogen gas and/or an interhalogen gas, - a thermal compartment in which temperatures of 200-2000°C may be used, and a system that makes it possible to control the diffusion of the dihalogen and/or interhalogen gas into the carbon-based layers of the samples of nanotubes to be purified, selected from a system for purifying the dihalogen and/or interhalogen gas, a system for controlling the concentration of the dihalogen and/or interhalogen gas, a system for controlling the pressure of the dihalogen and/or interhalogen gas, a system for controlling the flow rate of the dihalogen and/or interhalogen gas, or any combination of two or more of the aforementioned systems.
PCT/FR2011/052519 2010-10-28 2011-10-27 Method of purifying carbon nanotubes Ceased WO2012056184A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1058904 2010-10-28
FR1058904A FR2966815B1 (en) 2010-10-28 2010-10-28 METHOD OF PURIFYING CARBON NANOTUBES

Publications (2)

Publication Number Publication Date
WO2012056184A2 WO2012056184A2 (en) 2012-05-03
WO2012056184A3 true WO2012056184A3 (en) 2012-10-26

Family

ID=44148881

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2011/052519 Ceased WO2012056184A2 (en) 2010-10-28 2011-10-27 Method of purifying carbon nanotubes

Country Status (2)

Country Link
FR (1) FR2966815B1 (en)
WO (1) WO2012056184A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5814094B2 (en) * 2011-11-30 2015-11-17 ふたみ青果株式会社 Freeze-drying method and apparatus using far-infrared heater
FR3064623B1 (en) * 2017-03-31 2025-06-20 Arkema France PURIFICATION PROCESS OF RAW CARBON NANOTUBE
CN110642243B (en) * 2019-10-28 2021-03-16 成都科汇机电技术有限公司 Carbon nano tube purified by rotary binary secondary gas phase method and purification method
WO2023097336A2 (en) * 2021-11-29 2023-06-01 Czero, Inc. Thermal purification of carbon
US20250066201A1 (en) * 2022-01-07 2025-02-27 The Johns Hopkins University Reclamation of metal from coked catalyst
CN118978890A (en) * 2024-10-18 2024-11-19 浙江纳科纳米新材料有限公司 A method for preparing single-walled carbon nanotube antistatic emulsion

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1046613A2 (en) * 1999-04-21 2000-10-25 Iljin Nanotech Co., Ltd. Method of forming carbon nanotubes
WO2002064868A1 (en) * 2001-02-12 2002-08-22 William Marsh Rice University Gas-phase process for purifying single-wall carbon nanotubes and compositions thereof
WO2002064869A1 (en) * 2001-02-12 2002-08-22 William Marsh Rice University Process for purifying single-wall carbon nanotubes and compositions thereof
WO2007055707A2 (en) * 2004-12-01 2007-05-18 William Marsh Rice University Multi-step purification of single-wall carbon nanotubes
EP2135842A1 (en) * 2007-03-13 2009-12-23 Toyo Tanso Co., Ltd. Method for purifying carbon material containing carbon nanotube, carbon material obtained by the purification method, and resin molded body, fiber, heat sink, sliding member, field emission source material, conductive assistant for electrode, catalyst supporting member and conductive film, each using the carbon material

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003081616A (en) 2001-07-05 2003-03-19 Honda Motor Co Ltd Purification method of single-walled carbon nanotube
ITMI20021737A1 (en) 2002-08-01 2004-02-02 Univ Degli Studi Trieste PURIFICATION PROCESS OF CARBON NANOTUBES.
FR2864454B1 (en) 2003-12-30 2006-02-03 Centre Nat Rech Scient PROCESS FOR DISSOLVING CARBON NANOTUBES AND APPLICATIONS THEREOF
WO2005089422A2 (en) 2004-03-17 2005-09-29 California Institute Of Technology Methods for purifying carbon materials
FR2870251B1 (en) 2004-05-11 2010-09-17 Arkema COMPOSITE MATERIALS BASED ON CARBON NANOTUBES AND POLYMERIC MATRICES AND METHODS OF OBTAINING THEM
WO2006136715A1 (en) 2005-06-24 2006-12-28 Arkema France Polymer materials containing carbon nanotubes, method for preparing same from a premix with a dispersant
KR100745752B1 (en) 2005-06-28 2007-08-02 삼성전자주식회사 Method for Purifying Carbonaceous Impurities in Carbon Nanotubes
WO2008054869A2 (en) 2006-05-05 2008-05-08 William Marsh Rice University Facile purification of carbon nanotubes with liquid bromine at room temperature

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1046613A2 (en) * 1999-04-21 2000-10-25 Iljin Nanotech Co., Ltd. Method of forming carbon nanotubes
WO2002064868A1 (en) * 2001-02-12 2002-08-22 William Marsh Rice University Gas-phase process for purifying single-wall carbon nanotubes and compositions thereof
WO2002064869A1 (en) * 2001-02-12 2002-08-22 William Marsh Rice University Process for purifying single-wall carbon nanotubes and compositions thereof
WO2007055707A2 (en) * 2004-12-01 2007-05-18 William Marsh Rice University Multi-step purification of single-wall carbon nanotubes
EP2135842A1 (en) * 2007-03-13 2009-12-23 Toyo Tanso Co., Ltd. Method for purifying carbon material containing carbon nanotube, carbon material obtained by the purification method, and resin molded body, fiber, heat sink, sliding member, field emission source material, conductive assistant for electrode, catalyst supporting member and conductive film, each using the carbon material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
J. ZIMMERMAN, R. KELLEY BRADLEY, C. HUFFMAN, R. HAUGE, J. MARGRAVE: "Gas-Phase Purification of Single-Wall Carbon Nanotubes", CHEMISTRY OF MATERIALS, vol. 12, 4 July 2000 (2000-07-04), pages 1361 - 1366, XP002644867 *

Also Published As

Publication number Publication date
WO2012056184A2 (en) 2012-05-03
FR2966815B1 (en) 2013-05-31
FR2966815A1 (en) 2012-05-04

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