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WO2011134911A2 - Dérivés hydroximoyle-tétrazole fongicides - Google Patents

Dérivés hydroximoyle-tétrazole fongicides Download PDF

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Publication number
WO2011134911A2
WO2011134911A2 PCT/EP2011/056497 EP2011056497W WO2011134911A2 WO 2011134911 A2 WO2011134911 A2 WO 2011134911A2 EP 2011056497 W EP2011056497 W EP 2011056497W WO 2011134911 A2 WO2011134911 A2 WO 2011134911A2
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Prior art keywords
substituted
alkyl
alkoxy
plants
diseases
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Ceased
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PCT/EP2011/056497
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English (en)
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WO2011134911A3 (fr
Inventor
Christian Beier
Jürgen BENTING
David Bernier
Pierre-Yves Coqueron
Philippe Desbordes
Christophe Dubost
Pierre Genix
Masahito Ito
Daniela Portz
Norio Sasaki
Ulrike Wachendorff-Neumann
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Bayer CropScience AG
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Bayer CropScience AG
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Publication of WO2011134911A2 publication Critical patent/WO2011134911A2/fr
Publication of WO2011134911A3 publication Critical patent/WO2011134911A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links

Definitions

  • the present invention relates to hydroximoyl-tetrazole derivatives, their process of preparation, preparation intermediate compounds, their use as fungicide active agents, particularly in the form of fungicide compositions and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions.
  • A represents a tetrazolyl group
  • Het represents either a particular pyridinyl group or a particular thiazolyl group.
  • W can be selected in a list of 15 various heterocycle groups.
  • the present invention provides hydroximoyl-tetrazole derivatives of formula (I) :
  • A represents a tetrazolyl group of formula (A 1 ) or (A 2 ):
  • Y represents a substituted or non-substituted C 3 -C 8 -cycloalkyl, a hydrogen atom, CR R 2 R 3 , substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C 2 -C 8 -alkenyl, or substituted or non-substituted C 2 -C 8 -alkynyl;
  • R o R , R 2 and R 3 are independently selected in the list consisting of hydrogen, halogen, [d-C 4 ]-alkyl, [d-d]-haloalkyl, [C 2 -C 4 ]-alkenyl, [C 2 -C 4 ]-haloalkenyl, [C 2 -C 4 ]-alkynyl, [C 2 -C 4 ]-haloalkynyl, [C 3 -C 5 ]-cycloalkyl, [C 3 -C 5 ]-halocycloalkyl, [C C 4 ]-alkoxy, [C C 4 ]- alkoxy-[Ci-C 4 ]-alkyl, [Ci-C 4 ]-alkoxy-[Ci-C 4 ]-alkoxy, [Ci-C 4 ]-haloalkoxy, [d-d]- haloalkoxy-[Ci-C 4 ]-alkyl, [C
  • R 3 represents a halogen atom, [d-C 4 ]-haloalkyl, [C 2 -C 4 ]-alkenyl, [C 2 -C 4 ]-haloalkenyl, [C 2 -C 4 ]-alkynyl, [C 2 -C 4 ]- haloalkynyl, [C 3 -C 5 ]-cycloalkyl, [C 3 -C 5 ]-halocycloalkyl, [Ci-C 4 ]-alkoxy, [Ci-C 4 ]-alkoxy- [Ci-C 4 ]-alkyl, [Ci-C 4 ]-alkoxy-[Ci-C 4 ]-alkoxy, [Ci-C 4 ]-haloalkoxy, [d-d]-haloalkoxy-[d- C 4 ]-alkyl, [Ci-C 6
  • Het represents a pyridyl group of formula (Het ) or a thiazolyl group of formula (Het 2 ) ;
  • o R represents a hydrogen atom or a halogen atom
  • o Z represents a hydrogen atom, an amino group, a halogen atom, a hydroxy group, substituted or non-substituted d-Ce-alkyl, substituted or non-substituted C 3 -C 8 - cycloalkyl, a substituted or non-substituted C 2 -C 8 -alkenyl, substituted or non- substituted C 2 -C 8 -alkynyl, substituted or non-substituted d-d-alkoxy, substituted or non-substituted d-d-alkylamino, substituted or non-substituted C 3 -dcr cycloalkylamino, substituted or non-substituted C 3 -d 0 -cycloalkenylamino, substituted or non-substituted C 5 -d 2 -fused bicycloalkylamino, substituted or non-substituted C 5
  • - Q represents a hydrogen atom, substituted or non-substituted Ci-C 8 -alkyl, substituted or non-substituted Ci-C 8 -cycloalkyl, a substituted or non-substituted C 2 -C 8 - alkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, substituted or non-substituted Ci-C 8 -alkoxy, substituted or non-substituted Ci-C 8 -alkylamino, substituted or non- substituted Ci-C 8 -alkylsulphenyl, substituted or non-substituted arylsulphenyl, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C 5 -Ci 2 -fused bicycloalkyl, substituted or non-substituted C 5
  • - U represents a oxygen atom or a sulphur atom
  • R a represents a hydrogen atom, substituted or non-substituted Ci-C 8 -alkyl, substituted or non-substituted Ci-C 8 -cycloalkyl, a substituted or non-substituted C 2 -C 8 - alkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, substituted or non-substituted aryl, or substituted or non-substituted heterocyclyl;
  • X independently represents a hydrogen atom, a halogen atom, substituted or non-substituted Ci-C 8 -alkyl, an Ci-C 8 -alkoxy group, a cyano group, a methanesulfonyl group, a nitro group, or a Ci-C 8 -halogenoalkyl having 1 to 5 halogen atoms or an aryl group ;
  • any of the compounds according to the invention can exist as one or more stereoisomers depending on the number of stereogenic units (as defined by the lUPAC rules) in the compound.
  • the invention thus relates equally to all the stereoisomers and to the mixtures of all the possible stereoisomers, in all proportions.
  • the stereoisomers can be separated according to the methods which are known per se by the man ordinary skilled in the art.
  • stereostructure of the oxime moiety present in the tetrazolyloxime derivative of formula (I) includes (E) or (Z) isomers and these stereoisomers form part of the present invention.
  • halogen means fluorine, chlorine, bromine or iodine ;
  • heteroatom can be nitrogen, oxygen or sulphur ;
  • a group or a substituent that is substituted according to the invention can be substituted by one or more of the following groups or atoms: a halogen atom, a nitro group, a hydroxy group, a cyano group, an amino group, a sulphenyl group, a pentafluoro- 6 -sulphenyl group, a formyl group, a substituted or non-substituted carbaldehyde 0-(Ci-C 8 -alkyl)oxime, a formyloxy group, a formylamino group, a carbamoyl group, a N- hydroxycarbamoyl group, a formylamino group, a (hydroxyimino)-Ci-C 6 -alkyl group, a Ci-C 8 - alkyl, a tri(d-C 8 -alkyl)silyl, a tri(Ci-C 8 -alkyl
  • aryl means phenyl or naphthyl
  • heterocyclyl means saturated or unsaturated 4-, 5-, 6-, 7-, 8-, 9-, 10- or 11- membered ring comprising up to 4 heteroatoms selected in the list consisting of N, O, S.
  • Preferred compounds of formula (I) according to the invention are those wherein Y represents a substituted or non-substituted C 3 -C 8 -cycloalkyl, CR R 2 R 3 , or substituted or non-substituted C 2 -C 8 - alkenyl.
  • More preferred compounds of formula (I) according to the invention are those wherein Y represents CR R 2 R 3 , substituted or non-substituted cyclopropyl, or substituted or non-substituted C 2 -C 3 -alkenyl.
  • Preferred compounds of formula (I) according to the invention are those wherein R , R 2 and R 3 are independently selected in the list consisting of hydrogen, halogen, [Ci-C 4 ]-alkyl, [Ci-C 4 ]-haloalkyl, [d- C 6 ]-alkoxy-carbonyl, [d-C 6 ]-alkoxy- carbonyl-[Ci-C 4 ]-alkyl, tri(Ci-C 8 -alkyl)silyl, tri(Ci-C 8 -alkyl)silyl-[Ci- C 4 ]-alkyl and cyano; or R and R 2 can form a 3- to 5-membered, saturated or unsaturated, carbo- or heterocycle.
  • More preferred compounds of formula (I) according to the invention are those wherein R , R 2 and R 3 are independently selected in the list consisting of hydrogen, halogen, [Ci-C 6 ]-alkoxy-carbonyl, and tri(Ci-C 8 -alkyl)silyl; or wherein R and R 2 can form a cyclopropyl ring;
  • Preferred compounds of formula (I) according to the invention are those wherein X independently represents a hydrogen atom, or a halogen atom;
  • More preferred compounds of formula (I) according to the invention are those wherein X independently represents a hydrogen atom;
  • Preferred compounds of formula (I) according to the invention are those wherein q represents 1 or 2. More preferably, q represents 1 .
  • Preferred compounds of formula (I) according to the invention are those wherein R represents a hydrogen atom.
  • Preferred compounds of formula (I) according to the invention are those wherein Q represents a hydrogen atom, substituted or non-substituted Ci-C 8 -alkyl, substituted or non-substituted Ci-C 8 - cycloalkyl, a substituted or non-substituted C 2 -C 8 -alkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, substituted or non-substituted Ci-C 8 -alkoxy, substituted or non-substituted Ci-C 8 -alkylsulphenyl, substituted or non-substituted arylsulphenyl, substituted or non-substituted aryl, substituted or non- substituted heterocyclyl, substituted or non-substituted C 5 -Ci 2 -fused bicycloalkyl, substituted or non- substituted C 5 -Ci 2 -fused bicycl
  • More preferred compounds of formula (I) according to the invention are those wherein Q represents substituted or non-substituted Ci-C 8 -alkyl, substituted or non-substituted Ci-C 8 -alkoxy, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, or substituted or non-substituted C 5 - Ci 2 -benzofused carbocyclyl.
  • Preferred compounds of formula (I) according to the invention are those wherein U represents an oxygen atom.
  • Preferred compounds of formula (I) according to the invention are those wherein R a represents a hydrogen atom or substituted or non-substituted Ci-C 8 -alkyl.
  • More preferred compounds of formula (I) according to the invention are those wherein R a represents a hydrogen atom.
  • R a represents a hydrogen atom.
  • the said preferred features can also be selected among the more preferred features of each of A, Het, X and q ; so as to form most preferred subclasses of compounds according to the invention.
  • the preferred features of the other substituents of the compounds according to the invention can also be part of such sub-classes of preferred compounds according to the invention, notably the groups of substituents Y, R , R 2 , R 3 , Z, R, Q, U, and R a .
  • the present invention also relates to a process for the preparation of compounds of formula (I).
  • a process P1 for the preparation of compounds of formula (I), as herein-defined as illustrated by the following reaction schemes.
  • LG represents a leaving group. Suitable leaving groups can be selected in the list consisting of a halogen atom or other customary nucleofugal groups such as triflate, mesylate or tosylate.
  • process P1 according to the invention can be completed by a further step comprising the additional modification of this group, notably by a reaction of acylation, alkoxycarbonylation, alkylaminocarbonylation, (thio)acylation, alkoxy(thi)
  • LG' represents a leaving group.
  • Suitable leaving groups can be selected in the list consisting of a halogen atom or other customary nucleofugal groups such as 440, hydroxide or cyanide.
  • Z represents a protected amino group, protected substituted or non-substituted Ci-C 8 -alkylamino, protected substituted or non-substituted C 3 -Ci 0 -cycloalkylamino, protected substituted or non- substituted C 3 -Cio-cycloalkenylamino, protected substituted or non-substituted C 5 -Ci 2 -fused bicycloalkylamino, protected substituted or non-substituted C 5 -Ci 2 -fused bicycloalkenylamino, protected substituted or non-substituted phenylamino, protected substituted or non-substituted heterocyclylamino, carrying out process P2 would previously require a deprotection step in order to yield the amino group.
  • a catalyst notably a transition metal catalyst, such as palladium salts or complexes for example palladium (II) chloride
  • the palladium complex is directly generated in the reaction mixture by separately adding to the reaction mixture a palladium salt and a complex ligand such as a phosphine, for example triethylphosphine, tri- tert-butylphosphine, tricyclohexylphosphine, 2-(dicyclohexylphosphine)biphenyl, 2-(di-tert- butylphosphin)biphenyl, 2-(dicyclohexylphosphine)-2'-(N,N-dimethylamino)-biphenyl, triphenylphosphine, tris-(o-tolyl)phosphine, sodium 3-(diphenylphosphino)benzolsulfonate, tris-2- (methoxyphenyl)phosphine, 2,2'-bis-(diphenylphosphine)-1 , 1 '-binaphthyl, 1
  • Zc represents a represents an amino group, a hydroxy group, substituted or non-substituted Ci-C 8 -alkyl, substituted or non-substituted Ci-C 8 -cycloalkyl, a substituted or non-substituted C 2 -C 8 -alkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, substituted or non-substituted Ci-C 8 -alkoxy, substituted or non-substituted Ci-C 8 -alkylamino, substituted or non-substituted C 3 -Cio-cycloalkylamino, substituted or non-substituted C 3 -Ci 0 -cycloalkenylamino, substituted or non-substituted C 5 -Ci 2 -fused bicycloalkylamino, substituted or non-substituted C 5 -Ci 2 -f
  • processes P1 to P3 can be performed if appropriate in the presence of a solvent and if appropriate in the presence of a base.
  • processes P1 and P2 can be performed if appropriate in the presence of a catalyst.
  • Suitable catalyst can be chosen as being 4-dimethyl-aminopyridine, 1 -hydroxy-benzotriazole or dimethylformamide.
  • the process P2 according to the present invention can be performed in the presence of condensing agent.
  • Suitable condensing agent can be chosen as being acid halide former, such as phosgene, phosphorous tri-bro-mide, phosphorous trichloride, phosphorous pentachloride, phosphorous trichloride oxide or thionyl chloride ; anhydride former, such as ethyl chloroformate, methyl chloroformate, isopropyl chloroformate, isobutyl chloroformate or methanesulfonyl chloride ; carbodiimides, such as ⁇ , ⁇ '-dicyclohexylcarbodiimide (DCC) or other customary condensing agents, such as phosphorous pentoxide, polyphosphoric acid , N,N'-carbonyl- diimidazole, 2-ethoxy-N-ethoxycarbonyl-1 ,2-dihydro
  • DCC ⁇ , ⁇
  • Suitable solvents for carrying out processes P1 to P3 according to the invention are customary inert organic solvents. Preference is given to using optionally halogenated aliphatic, alicyclic or aromatic hydrocarbons, such as petroleum ether, hexane, heptane, cyclohexane, methylcyclohexane, benzene, toluene, xylene or decalin ; chlorobenzene, dichlorobenzene, dichloromethane, chloroform, carbon tetrachloride, dichlorethane or trichlorethane ; ethers, such as diethyl ether, diisopropyl ether, methyl tert-butyl ether, methyl tert-amyl ether, dioxane, tetrahydrofuran, 1 ,2-dimethoxyethane, 1 ,2- diethoxyethane or anisole ; nitriles, such as
  • Suitable bases for carrying out processes P1 and P2 according to the invention are inorganic and organic bases which are customary for such reactions.
  • alkaline earth metal alkali metal hydride, alkali metal hydroxides or alkali metal alkoxides, such as sodium hydroxide, sodium hydride, calcium hydroxide, potassium hydroxide, potassium tert-butoxide or other ammonium hydroxide
  • alkali metal carbonates such as sodium carbonate, potassium carbonate, potassium bicarbonate, sodium bicarbonate, cesium carbonate
  • alkali metal or alkaline earth metal acetates such as sodium acetate, potassium acetate, calcium acetate and also tertiary amines, such as trimethylamine, triethylamine, diisopropylethylamine, tributylamine, A/,A/-dimethylaniline, pyridine, /V-methylpiperidine, A/,A/-dimethylaminopyridine, 1
  • Processes P1 to P3 according to the invention are generally independently carried out under atmospheric pressure. However, it is also possible to operate under elevated or reduced pressure.
  • reaction mixture is treated with water and the organic phase is separated off and, after drying, concentrated under reduced pressure. If appropriate, the remaining residue can be freed by customary methods, such as chromatography or recrystallization, from any impurities that can still be present.
  • the compounds of formula (II), useful as a starting material can be prepared, for example, by reacting hydroxylamine with the corresponding ketones that can be prepared, for example, according to the method described by R. Raap (Can. J. Chem. 1971 , 49, 2139) by addition of a tetrazolyl lithium species to esters of the following formula
  • A represents a group of formula (A 2 ), as herein-described
  • the compounds of formula (II) useful as a starting material can be prepared, for example from oximes of the following formula and 5-substituted tetrazole according to the method described by J. Plenkiewicz et al. (Bull. Soc. Chim. Belg. 1987, 96, 675).
  • the present invention relates to compounds of formula (II) 1 useful as intermediate compounds or materials for the process of preparation according to the invention.
  • the present invention thus provides compounds of formula (II) 1 wherein Y, X and q are as herein- defined.
  • the present invention also relates to a fungicide composition
  • a fungicide composition comprising an effective and non-phytotoxic amount of an active compound of formula (I).
  • fungicide composition comprising, as an active ingredient, an effective amount of a compound of formula (I) as herein defined and an agriculturally acceptable support, carrier or filler.
  • the term "support” denotes a natural or synthetic organic or inorganic compound with which the active compound of formula (I) is combined or associated to make it easier to apply, notably to the parts of the plant.
  • This support is thus generally inert and should be agriculturally acceptable.
  • the support can be a solid or a liquid.
  • suitable supports include clays, natural or synthetic silicates, silica, resins, waxes, solid fertilisers, water, alcohols, in particular butanol organic solvents, mineral and plant oils and derivatives thereof. Mixtures of such supports can also be used.
  • the composition according to the invention can also comprise additional components. In particular, the composition can further comprise a surfactant.
  • the surfactant can be an emulsifier, a dispersing agent or a wetting agent of ionic or non-ionic type or a mixture of such surfactants.
  • surfactant content can be comprised from 5% to 40% by weight of the composition.
  • additional components can also be included, e.g . protective colloids, adhesives, thickeners, thixotropic agents, penetration agents, stabilisers, sequestering agents.
  • the active compounds can be combined with any solid or liquid additive, which complies with the usual formulation techniques.
  • composition according to the invention can contain from 0.05 to 99% by weight of active compound, preferably 10 to 70% by weight.
  • compositions according to the invention can be used in various forms such as aerosol dispenser, capsule suspension, cold fogging concentrate, dustable powder, emulsifiable concentrate, emulsion oil in water, emulsion water in oil, encapsulated granule, fine granule, flowable concentrate for seed treatment, gas (under pressure),gas generating product, granule, hot fogging concentrate, macrogranule, microgranule, oil dispersible powder, oil miscible flowable concentrate, oil miscible liquid, paste, plant rodlet, powder for dry seed treatment, seed coated with a pesticide, soluble concentrate, soluble powder, solution for seed treatment, suspension concentrate (flowable concentrate), ultra low volume (ULV) liquid, ultra low volume (ULV) suspension, water dispersible granules or tablets, water dispersible powder for slurry treatment, water soluble granules or tablets, water soluble powder for seed treatment and wettable powder.
  • These compositions include not only compositions which are ready to be applied to the plant or seed to
  • the compounds according to the invention can also be mixed with one or more insecticide, fungicide, bactericide, attractant, acaricide or pheromone active substance or other compounds with biological activity.
  • the mixtures thus obtained have a broadened spectrum of activity.
  • the mixtures with other fungicide compounds are particularly advantageous.
  • the composition according to the invention comprising a mixture of a compound of formula (I) with a bactericide compound can also be particularly advantageous
  • fungicide mixing partners can be selected in the following lists:
  • Inhibitors of the ergosterol biosynthesis for example (1.1) aldimorph (1704-28-5), (1.2) azaconazole (60207-31-0), (1.3) bitertanol (55179-31-2), (1.4) bromuconazole (116255-48-2), (1.5) cyproconazole (113096-99-4), (1.6) diclobutrazole (75736-33-3), (1.7) difenoconazole (119446-68-3), (1.8)diniconazole (83657-24-3), (1.9) diniconazole-M (83657-18-5), (1.10) dodemorph (1593-77-7),
  • inhibitors of the respiratory chain at complex I or II for example (2.1) bixafen (581809-46-3), (2.2) boscalid (188425-85-6), (2.3) carboxin (5234-68-4), (2.4) diflumetorim (130339-07-0), (2.5) fenfuram (24691-80-3), (2.6) fluopyram (658066-35-4), (2.7) flutolanil (66332-96-5), (2.8) fluxapyroxad (907204- 31-3), (2.9) furametpyr (123572-88-3), (2.10) furmecyclox (60568-05-0), (2.11) isopyrazam (mixture of syn-epimeric racemate 1RS,4SR,9RS and anti-epimeric racemate 1RS,4SR,9SR) (881685-58-1),
  • inhibitors of the respiratory chain at complex III for example (3.1 ) ametoctradin (865318-97-4), (3.2) amisulbrom (348635-87-0), (3.3) azoxystrobin (131860-33-8), (3.4) cyazofamid (1201 16-88-3), (3.5) coumethoxystrobin (850881-30-0), (3.6) coumoxystrobin (850881-70-8), (3.7) dimoxystrobin (141600-52-4), (3.8) enestroburin (238410-1 1-2) (WO 2004/058723), (3.9) famoxadone (131807-57-3) (WO 2004/058723), (3.10) fenamidone (161326-34-7) (WO 2004/058723), (3.1 1 ) fenoxystrobin (918162-02-4), (3.12) fluoxastrobin (361377-29-9) (WO 2004/058723), (3.13) kresoxim-methyl (14339
  • Inhibitors of the mitosis and cell division for example (4.1 ) benomyl (17804-35-2), (4.2) carbendazim (10605-21-7), (4.3) chlorfenazole (3574-96-7), (4.4) diethofencarb (87130-20-9), (4.5) ethaboxam (162650-77-3), (4.6) fluopicolide (2391 10-15-7), (4.7) fuberidazole (3878-19-1 ), (4.8) pencycuron (66063-05-6), (4.9) thiabendazole (148-79-8), (4.10) thiophanate-methyl (23564-05-8), (4.1 1 ) thiophanate (23564-06-9), (4.12) zoxamide (156052-68-5), (4.13) 5-chloro-7-(4-methylpiperidin- 1-yl)-6-(2,4,6-trifluorophenyl)[1 ,2,4]triazolo[1 ,5-a]pyrimidine (214706)
  • Inhibitors of the amino acid and/or protein biosynthesis for example (7.1 ) andoprim (23951-85-1 ), (7.2) blasticidin-S (2079-00-7), (7.3) cyprodinil (121552-61-2), (7.4) kasugamycin (6980-18-3), (7.5) kasugamycin hydrochloride hydrate (19408-46-9), (7.6) mepanipyrim (1 10235-47-7), (7.7) pyrimethanil (531 12-28-0) and (7.8) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline (861647- 32-7) (WO2005070917).
  • Inhibitors of the ATP production for example (8.1 ) fentin acetate (900-95-8), (8.2) fentin chloride (639-58-7), (8.3) fentin hydroxide (76-87-9) and (8.4) silthiofam (175217-20-6).
  • Inhibitors of the cell wall synthesis for example (9.1 ) benthiavalicarb (177406-68-7), (9.2) dimethomorph (1 10488-70-5), (9.3) flumorph (21 1867-47-9), (9.4) iprovalicarb (140923-17-7), (9.5) mandipropamid (374726-62-2), (9.6) polyoxins (1 1 1 13-80-7), (9.7) polyoxorim (22976-86-9), (9.8) validamycin A (37248-47-8) and (9.9) valifenalate (283159-94-4; 283159-90-0).
  • Inhibitors of the lipid and membrane synthesis for example (10.1 ) biphenyl (92-52-4), (10.2) chloroneb (2675-77-6), (10.3) dicloran (99-30-9), (10.4) edifenphos (17109-49-8), (10.5) etridiazole (2593-15-9), (10.6) iodocarb (55406-53-6), (10.7) iprobenfos (26087-47-8), (10.8) isoprothiolane (50512-35-1 ), (10.9) propamocarb (25606-41-1 ), (10.10) propamocarb hydrochloride (25606-41-1 ), (10.1 1 ) prothiocarb (19622-08-3), (10.12) pyrazophos (13457-18-6), (10.13) quintozene (82-68-8), (10.14) tecnazene (1 17-18-0) and (10.15) tolclofos-m ethyl (57018-04-9).
  • Inhibitors of the melanine biosynthesis for example (1 1.1 ) carpropamid (104030-54-8), (1 1.2) diclocymet (139920-32-4), (1 1.3) fenoxanil (1 15852-48-7), (1 1 .4) phthalide (27355-22-2), (1 1.5) pyroquilon (57369-32-1 ), (1 1 .6) tricyclazole (41814-78-2) and (1 1.7) 2,2,2-trifluoroethyl ⁇ 3-methyl-1- [(4-methylbenzoyl)amino]butan-2-yl ⁇ carbamate (851524-22-6) (WO2005042474).
  • Inhibitors of the nucleic acid synthesis for example (12.1 ) benalaxyl (71626-1 1-4), (12.2) benalaxyl-M (kiralaxyl) (98243-83-5), (12.3) bupirimate (41483-43-6), (12.4) clozylacon (67932-85-8),
  • Inhibitors of the signal transduction for example (13.1 ) chlozolinate (84332-86-5), (13.2) fenpiclonil (74738-17-3), (13.3) fludioxonil (131341-86-1 ), (13.4) iprodione (36734-19-7), (13.5) procymidone (32809-16-8), (13.6) quinoxyfen (124495-18-7) and (13.7) vinclozolin (50471-44-8).
  • thiazole-4-carboxamide (922514-48-5) (WO 2007014290), (15.90) pentyl ⁇ 6-[( ⁇ [(1-methyl-1 H-tetrazol- 5-yl)(phenyl)methylidene]amino ⁇ oxy)methyl]pyridin-2-yl ⁇ carbamate, (15.91 ) phenazine-1-carboxylic acid, (15.92) quinolin-8-ol (134-31-6), (15.93) quinolin-8-ol sulfate (2: 1 ) (134-31-6) and (15.94) tert- butyl ⁇ 6-[( ⁇ [(1-methyl-1 H-tetrazol-5-yl)(phenyl)m
  • a method for controlling the phytopathogenic fungi of plants, crops or seeds characterized in that an agronomically effective and substantially non-phytotoxic quantity of a pesticide composition according to the invention is applied as seed treatment, foliar application, stem application, drench or drip application (chemigation) to the seed, the plant or to the fruit of the plant or to soil or to inert substrate (e.g. inorganic substrates like sand, rockwool, glasswool; expanded minerals like perlite, vermiculite, zeolite or expanded clay), Pumice, Pyroclastic materials or stuff, synthetic organic substrates (e.g. polyurethane) organic substrates (e.g.
  • a liquid substrate e.g . floating hydroponic systems, Nutrient Film Technique, Aeroponics
  • the method according to the invention can either be a curing, preventing or eradicating method.
  • a composition used can be prepared beforehand by mixing the two or more active compounds according to the invention.
  • a lower dose can offer adequate protection.
  • Certain climatic conditions, resistance or other factors like the nature of the phytopathogenic fungi or the degree of infestation, for example, of the plants with these fungi, can require higher doses of combined active ingredients.
  • the optimum dose usually depends on several factors, for example on the type of phytopathogenic fungus to be treated, on the type or level of development of the infested plant, on the density of vegetation or alternatively on the method of application.
  • the crop treated with the pesticide composition or combination according to the invention is, for example, grapevine, but this could be cereals, vegetables, lucerne, soybean, market garden crops, turf, wood, tree or horticultural plants.
  • the method of treatment according to the invention can also be useful to treat propagation material such as tubers or rhizomes, but also seeds, seedlings or seedlings pricking out and plants or plants pricking out. This method of treatment can also be useful to treat roots.
  • the method of treatment according to the invention can also be useful to treat the over-ground parts of the plant such as trunks, stems or stalks, leaves, flowers and fruit of the concerned plant.
  • cotton Among the plants that can be protected by the method according to the invention, mention can be made of cotton; flax; vine; fruit or vegetable crops such as Rosaceae sp. (for instance pip fruit such as apples and pears, but also stone fruit such as apricots, almonds and peaches), Ribesioidae sp. , Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp.
  • Rosaceae sp. for instance pip fruit such as apples and pears, but also stone fruit such as apricots, almonds and peaches
  • Rosaceae sp. for instance pip fruit such as apples and pears, but also stone fruit such as apricots, almonds and peaches
  • Rubiaceae sp. for instance banana trees and plantins
  • Rubiaceae sp. Theaceae sp., Sterculiceae sp., Rutaceae sp. (for instance lemons oranges and grapefruit); Solanaceae sp. (for instance tomatoes), Liliaceae sp., Asteraceae sp. (for instance lettuces), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp., Papilionaceae sp. (for instance peas), Rosaceae sp. (for instance strawberries); major crops such as Graminae sp.
  • Asteraceae sp. for instance sunflower
  • Cruciferae sp. for instance colza
  • Fabacae sp. for instance peanuts
  • Papilionaceae sp. for instance soybean
  • Solanaceae sp. for instance potatoes
  • Chenopodiaceae sp. for instance beetroots
  • horticultural and forest crops as well as genetically modified homologues of these crops.
  • the method of treatment according to the invention can be used in the treatment of genetically modified organisms (GMOs), e.g. plants or seeds.
  • GMOs genetically modified organisms
  • Genetically modified plants are plants in which a heterologous gene has been stably integrated into the genome.
  • the expression "heterologous gene” essentially means a gene which is provided or assembled outside the plant and when introduced in the nuclear, chloroplastic or mitochondrial genome gives the transformed plant new or improved agronomic or other properties by expressing a protein or polypeptide of interest or by downregulating or silencing other gene(s) which are present in the plant (using for example, antisense technology, co suppression technology or RNA interference - RNAi - technology).
  • a heterologous gene that is located in the genome is also called a transgene.
  • a transgene that is defined by its particular location in the plant genome is called a transformation or transgenic event.
  • the treatment according to the invention may also result in superadditive (“synergistic") effects.
  • superadditive for example, reduced application rates and/or a widening of the activity spectrum and/or an increase in the activity of the active compounds and compositions which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, bigger fruits, larger plant height, greener leaf color, earlier flowering, higher quality and/or a higher nutritional value of the harvested products, higher sugar concentration within the fruits, better storage stability and/or processability of the harvested products are possible, which exceed the effects which were actually to be expected.
  • the active compound combinations according to the invention may also have a strengthening effect in plants. Accordingly, they are also suitable for mobilizing the defense system of the plant against attack by unwanted phytopathogenic fungi and/ or microorganisms and/or viruses. This may, if appropriate, be one of the reasons of the enhanced activity of the combinations according to the invention, for example against fungi.
  • Plant-strengthening (resistance-inducing) substances are to be understood as meaning, in the present context, those substances or combinations of substances which are capable of stimulating the defense system of plants in such a way that, when subsequently inoculated with unwanted phytopathogenic fungi and/ or microorganisms and/or viruses, the treated plants display a substantial degree of resistance to these unwanted phytopathogenic fungi and/ or microorganisms and/or viruses.
  • unwanted phytopathogenic fungi and/ or microorganisms and/or viruses are to be understood as meaning phytopathogenic fungi, bacteria and viruses.
  • the substances according to the invention can be employed for protecting plants against attack by the abovementioned pathogens within a certain period of time after the treatment.
  • the period of time within which protection is effected generally extends from 1 to 10 days, preferably 1 to 7 days, after the treatment of the plants with the active compounds.
  • Plants and plant cultivars which are preferably to be treated according to the invention include all plants which have genetic material which impart particularly advantageous, useful traits to these plants (whether obtained by breeding and/or biotechnological means).
  • Plants and plant cultivars which are also preferably to be treated according to the invention are resistant against one or more biotic stresses, i.e. said plants show a better defense against animal and microbial pests, such as against nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and/or viroids.
  • Plants and plant cultivars which may also be treated according to the invention are those plants which are resistant to one or more abiotic stresses.
  • Abiotic stress conditions may include, for example, drought, cold temperature exposure, heat exposure, osmotic stress, flooding, increased soil salinity, increased mineral exposure, ozon exposure, high light exposure, limited availability of nitrogen nutrients, limited availability of phosphorus nutrients, shade avoidance.
  • Plants and plant cultivars which may also be treated according to the invention are those plants characterized by enhanced yield characteristics. Increased yield in said plants can be the result of, for example, improved plant physiology, growth and development, such as water use efficiency, water retention efficiency, improved nitrogen use, enhanced carbon assimilation, improved photosynthesis, increased germination efficiency and accelerated maturation.
  • Yield can furthermore be affected by improved plant architecture (under stress and non-stress conditions), including but not limited to, early flowering , flowering control for hybrid seed production, seedling vigor, plant size, internode number and distance, root growth, seed size, fruit size, pod size, pod or ear number, seed number per pod or ear, seed mass, enhanced seed filling, reduced seed dispersal, reduced pod dehiscence and lodging resistance.
  • Further yield traits include seed composition, such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction in anti-nutritional compounds, improved processability and better storage stability.
  • Plants that may be treated according to the invention are hybrid plants that already express the characteristic of heterosis or hybrid vigor which results in generally higher yield, vigor, health and resistance towards biotic and abiotic stress factors. Such plants are typically made by crossing an inbred male-sterile parent line (the female parent) with another inbred male-fertile parent line (the male parent). Hybrid seed is typically harvested from the male sterile plants and sold to growers. Male sterile plants can sometimes (e.g. in corn) be produced by detasseling, i.e. the mechanical removal of the male reproductive organs (or males flowers) but, more typically, male sterility is the result of genetic determinants in the plant genome.
  • cytoplasmic male sterility were for instance described in Brassica species (WO 1992/005251 , WO 1995/009910, WO 1998/27806, WO
  • male sterile plants can also be obtained by plant biotechnology methods such as genetic engineering.
  • a particularly useful means of obtaining male- sterile plants is described in WO 1989/10396 in which, for example, a ribonuclease such as barnase is selectively expressed in the tapetum cells in the stamens. Fertility can then be restored by expression in the tapetum cells of a ribonuclease inhibitor such as barstar (e.g. WO 1991/002069).
  • Plants or plant cultivars obtained by plant biotechnology methods such as genetic engineering which may be treated according to the invention are herbicide-tolerant plants, i.e. plants made tolerant to one or more given herbicides. Such plants can be obtained either by genetic transformation, or by selection of plants containing a mutation imparting such herbicide tolerance.
  • Herbicide-tolerant plants are for example glyphosate-tolerant plants, i.e. plants made tolerant to the herbicide glyphosate or salts thereof. Plants can be made tolerant to glyphosate through different means.
  • glyphosate-tolerant plants can be obtained by transforming the plant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS).
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • Examples of such EPSPS genes are the AroA gene (mutant CT7) of the bacterium Salmonella typhimurium (Comai et al. , Science (1983), 221 , 370-371 ), the CP4 gene of the bacterium Agrobacterium sp. (Barry et al.
  • Glyphosate- tolerant plants can also be obtained by expressing a gene that encodes a glyphosate oxido-reductase enzyme as described in US 5,776,760 and US 5,463, 175.
  • Glyphosate-tolerant plants can also be obtained by expressing a gene that encodes a glyphosate acetyl transferase enzyme as described in for example WO 2002/036782, WO 2003/092360, WO 2005/012515 and WO 2007/024782.
  • Glyphosate-tolerant plants can also be obtained by selecting plants containing naturally-occurring mutations of the above-mentioned genes, as described in for example WO 2001/024615 or WO 2003/013226.
  • herbicide resistant plants are for example plants that are made tolerant to herbicides inhibiting the enzyme glutamine synthase, such as bialaphos, phosphinothricin or glufosinate.
  • Such plants can be obtained by expressing an enzyme detoxifying the herbicide or a mutant glutamine synthase enzyme that is resistant to inhibition.
  • One such efficient detoxifying enzyme is an enzyme encoding a phosphinothricin acetyltransferase (such as the bar or pat protein from Streptomyces species). Plants expressing an exogenous phosphinothricin acetyltransferase are for example described in US
  • hydroxyphenylpyruvatedioxygenase HPPD
  • Hydroxyphenylpyruvatedioxygenases are enzymes that catalyze the reaction in which para-hydroxyphenylpyruvate (HPP) is transformed into homogentisate.
  • Plants tolerant to HPPD-inhibitors can be transformed with a gene encoding a naturally-occurring resistant HPPD enzyme, or a gene encoding a mutated HPPD enzyme as described in WO 1996/038567, WO 1999/024585 and WO 1999/024586.
  • Tolerance to HPPD- inhibitors can also be obtained by transforming plants with genes encoding certain enzymes enabling the formation of homogentisate despite the inhibition of the native HPPD enzyme by the HPPD- inhibitor. Such plants and genes are described in WO 1999/034008 and WO 2002/36787. Tolerance of plants to HPPD inhibitors can also be improved by transforming plants with a gene encoding an enzyme prephenate dehydrogenase in addition to a gene encoding an HPPD-tolerant enzyme, as described in WO 2004/024928. Still further herbicide resistant plants are plants that are made tolerant to acetolactate synthase (ALS) inhibitors.
  • ALS acetolactate synthase
  • ALS-inhibitors include, for example, sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy(thio)benzoates, and/or sulfonylaminocarbonyltriazolinone herbicides.
  • Different mutations in the ALS enzyme also known as acetohydroxyacid synthase, AHAS
  • AHAS acetohydroxyacid synthase
  • plants tolerant to imidazolinone and/or sulfonylurea can be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or mutation breeding as described for example for soybeans in US 5,084,082, for rice in WO 1997/41218, for sugar beet in US 5,773,702 and WO 1999/057965 , for lettuce in US 5,198,599, or for sunflower in WO 2001/065922.
  • Plants or plant cultivars obtained by plant biotechnology methods such as genetic engineering which may also be treated according to the invention are insect-resistant transgenic plants, i.e. plants made resistant to attack by certain target insects. Such plants can be obtained by genetic transformation, or by selection of plants containing a mutation imparting such insect resistance.
  • An "insect-resistant transgenic plant”, as used herein, includes any plant containing at least one transgene comprising a coding sequence encoding:
  • an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal portion thereof such as the insecticidal crystal proteins listed by Crickmore et al., Microbiology and Molecular Biology Reviews (1998), 62, 807-813, updated by Crickmore et al. (2005) at the Bacillus thuringiensis toxin nomenclature, online at:
  • insecticidal portions thereof e.g., proteins of the Cry protein classes CrylAb, CrylAc, Cryl F, Cry2Ab, Cry3Aa, or Cry3Bb or insecticidal portions thereof; or
  • a crystal protein from Bacillus thuringiensis or a portion thereof which is insecticidal in the presence of a second other crystal protein from Bacillus thuringiensis or a portion thereof, such as the binary toxin made up of the Cry34 and Cry35 crystal proteins (Moellenbeck et al., Nat. Biotechnol. (2001 ), 19, 668-72; Schnepf et al., Applied Environm. Microbiol. (2006), 71 , 1765-1774); or
  • a hybrid insecticidal protein comprising parts of different insecticidal crystal proteins from Bacillus thuringiensis, such as a hybrid of the proteins of 1 ) above or a hybrid of the proteins of 2) above, e.g., the Cry1A.105 protein produced by corn event MON98034 (WO
  • VIP vegetative insecticidal
  • a secreted protein from Bacillus thuringiensis or Bacillus cereus which is insecticidal in the presence of a second secreted protein from Bacillus thuringiensis or B. cereus, such as the binary toxin made up of the VIPI A and VIP2A proteins (WO 1994/21795); or
  • a hybrid insecticidal protein comprising parts from different secreted proteins from Bacillus thuringiensis or Bacillus cereus, such as a hybrid of the proteins in 1 ) above or a hybrid of the proteins in 2) above; or
  • 8) a protein of any one of 1 ) to 3) above wherein some, particularly 1 to 10, amino acids have been replaced by another amino acid to obtain a higher insecticidal activity to a target insect species, and/or to expand the range of target insect species affected, and/or because of changes introduced into the encoding DNA during cloning or transformation (while still encoding an insecticidal protein), such as the VIP3Aa protein in cotton event COT102.
  • an insect-resistant transgenic plant also includes any plant comprising a combination of genes encoding the proteins of any one of the above classes 1 to 8.
  • any plant comprising a combination of genes encoding the proteins of any one of the above classes 1 to 8.
  • an insect-resistant plant contains more than one transgene encoding a protein of any one of the above classes 1 to 8, to expand the range of target insect species affected when using different proteins directed at different target insect species, or to delay insect resistance development to the plants by using different proteins insecticidal to the same target insect species but having a different mode of action, such as binding to different receptor binding sites in the insect.
  • Plants or plant cultivars obtained by plant biotechnology methods such as genetic engineering) which may also be treated according to the invention are tolerant to abiotic stresses. Such plants can be obtained by genetic transformation, or by selection of plants containing a mutation imparting such stress resistance.
  • Particularly useful stress tolerance plants include: a.
  • plants which contain a transgene capable of reducing the expression and/or the activity of poly(ADP-ribose)polymerase (PARP) gene in the plant cells or plants as described in WO 2000/004173 or WO2006/045633 or PCT/EP07/004142.
  • PARP poly(ADP-ribose)polymerase
  • plants which contain a stress tolerance enhancing transgene capable of reducing the expression and/or the activity of the PARG encoding genes of the plants or plants cells, as described e.g. in WO 2004/090140.
  • plants which contain a stress tolerance enhancing transgene coding for a plant- functional enzyme of the nicotinamide adenine dinucleotide salvage synthesis pathway including nicotinamidase, nicotinate phosphoribosyltransferase, nicotinic acid mononucleotide adenyl transferase, nicotinamide adenine dinucleotide synthetase or nicotine amide phosphoribosyltransferase as described e.g. in
  • Plants or plant cultivars obtained by plant biotechnology methods such as genetic engineering which may also be treated according to the invention show altered quantity, quality and/or storage-stability of the harvested product and/or altered properties of specific ingredients of the harvested product such as :
  • transgenic plants which synthesize a modified starch, which in its physical-chemical characteristics, in particular the amylose content or the amylose/amylopectin ratio, the degree of branching , the average chain length, the side chain distribution, the viscosity behaviour, the gelling strength, the starch grain size and/or the starch grain morphology, is changed in comparison with the synthesised starch in wild type plant cells or plants, so that this is better suited for special applications.
  • a modified starch which in its physical-chemical characteristics, in particular the amylose content or the amylose/amylopectin ratio, the degree of branching , the average chain length, the side chain distribution, the viscosity behaviour, the gelling strength, the starch grain size and/or the starch grain morphology, is changed in comparison with the synthesised starch in wild type plant cells or plants, so that this is better suited for special applications.
  • transgenic plants synthesizing a modified starch are disclosed, for example, in EP 0571427, WO 1995/004826, EP 0719338, WO 1996/15248, WO 1996/19581 , WO 1996/27674, WO 1997/1 1 188, WO 1997/26362, WO 1997/32985, WO 1997/42328, WO 1997/44472, WO 1997/45545, WO 1998/27212, WO 1998/40503,
  • transgenic plants which synthesize non starch carbohydrate polymers or which synthesize non starch carbohydrate polymers with altered properties in comparison to wild type plants without genetic modification.
  • Examples are plants producing polyfructose, especially of the inulin and levan-type, as disclosed in EP 0663956, WO 1996/001904, WO 1996/021023, WO
  • Plants or plant cultivars which may also be treated according to the invention are plants, such as cotton plants, with altered fiber characteristics.
  • plants can be obtained by genetic transformation, or by selection of plants contain a mutation imparting such altered fiber characteristics and include:
  • Plants such as cotton plants, having fibers with altered reactivity, e.g. through the expression of N-acteylglucosaminetransferase gene including nodC and chitinsynthase genes as described in WO2006/136351
  • Plants or plant cultivars which may also be treated according to the invention are plants, such as oilseed rape or related Brassica plants, with altered oil profile characteristics. Such plants can be obtained by genetic transformation or by selection of plants contain a mutation imparting such altered oil characteristics and include:
  • transgenic plants which may be treated according to the invention are plants which comprise one or more genes which encode one or more toxins, such as the following which are sold under the trade names YIELD GARD® (for example maize, cotton, soya beans), KnockOut® (for example maize), BiteGard® (for example maize), Bt-Xtra® (for example maize), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton), Nucotn 33B®(cotton), NatureGard® (for example maize), Protecta® and NewLeaf® (potato).
  • YIELD GARD® for example maize, cotton, soya beans
  • KnockOut® for example maize
  • BiteGard® for example maize
  • Bt-Xtra® for example maize
  • StarLink® for example maize
  • Bollgard® cotton
  • Nucotn® cotton
  • Nucotn 33B® cotton
  • NatureGard® for example maize
  • herbicide-tolerant plants which may be mentioned are maize varieties, cotton varieties and soya bean varieties which are sold under the trade names Roundup Ready® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link® (tolerance to phosphinotricin, for example oilseed rape), IMI® (tolerance to
  • Herbicide-resistant plants plants bred in a conventional manner for herbicide tolerance
  • Clearfield® for example maize
  • transgenic plants which may be treated according to the invention are plants containing transformation events, or combination of transformation events, that are listed for example in the databases from various national or regional regulatory agencies (see for example
  • the composition according to the invention can also be used against fungal diseases liable to grow on or inside timber.
  • the term "timber" means all types of species of wood and all types of working of this wood intended for construction, for example solid wood, high-density wood, laminated wood and plywood.
  • the method for treating timber according to the invention mainly consists in contacting one or more compounds according to the invention or a composition according to the invention; this includes for example direct application, spraying, dipping, injection or any other suitable means.
  • Powdery mildew diseases such as :
  • Blumeria diseases caused for example by Blumeria graminis ;
  • Podosphaera diseases caused for example by Podosphaera leucotricha ;
  • Sphaerotheca diseases caused for example by Sphaerotheca fuliginea ;
  • Uncinula diseases caused for example by Uncinula necator ;
  • Rust diseases such as :
  • Gymnosporangium diseases caused for example by Gymnosporangium sabinae ;
  • Hemileia diseases caused for example by Hemileia vastatrix ;
  • Phakopsora diseases caused for example by Phakopsora pachyrhizi or Phakopsora meibomiae ;
  • Puccinia diseases caused for example by Puccinia recondite, Puccinia graminis or
  • Uromyces diseases caused for example by Uromyces appendiculatus ;
  • Oomycete diseases such as :
  • Albugo diseases caused for example by Albugo Candida
  • Bremia diseases caused for example by Bremia lactucae ;
  • Peronospora diseases caused for example by Peronospora pisi or P. brassicae ;
  • Phytophthora diseases caused for example by Phytophthora infestans ; Plasmopara diseases, caused for example by Plasmopara viticola ;
  • Pseudoperonospora diseases caused for example by Pseudoperonospora humuli or
  • Pythium diseases caused for example by Pythium ultimum ;
  • Leafspot, leaf blotch and leaf blight diseases such as :
  • Alternaria diseases caused for example by Alternaria solani ;
  • Cercospora diseases caused for example by Cercospora beticola ;
  • Cladiosporum diseases caused for example by Cladiosporium cucumerinum ;
  • Cochliobolus diseases caused for example by Cochliobolus sativus (Conidiaform: Drechslera, Syn: Helminthosporium) or Cochliobolus miyabeanus ;
  • Colletotrichum diseases caused for example by Colletotrichum lindemuthanium ;
  • Cycloconium diseases caused for example by Cycloconium oleaginum ;
  • Diaporthe diseases caused for example by Diaporthe citri ;
  • Elsinoe diseases caused for example by Elsinoe fawcettii ;
  • Gloeosporium diseases caused for example by Gloeosporium laeticolor ;
  • Glomerella diseases caused for example by Glomerella cingulata ;
  • Guignardia diseases caused for example by Guignardia bidwelli ;
  • Leptosphaeria diseases caused for example by Leptosphaeria maculans ; Leptosphaeria nodorum ; Magnaporthe diseases, caused for example by Magnaporthe grisea ;
  • Mycosphaerella diseases caused for example by Mycosphaerella graminicola ; Mycosphaerella arachidicola ; Mycosphaerella fijiensis ;
  • Phaeosphaeria diseases caused for example by Phaeosphaeria nodorum ;
  • Pyrenophora diseases caused for example by Pyrenophora teres, or Pyrenophora tritici repentis;
  • Ramularia diseases caused for example by Ramularia collo-cygni , or Ramularia areola;
  • Rhynchosporium diseases caused for example by Rhynchosporium secalis ;
  • Septoria diseases caused for example by Septoria apii or Septoria lycopercisi ;
  • Typhula diseases caused for example by Typhula incarnata ;
  • Venturia diseases caused for example by Venturia inaequalis ;
  • Root, Sheath and stem diseases such as :
  • Corticium diseases caused for example by Corticium graminearum ;
  • Fusarium diseases caused for example by Fusarium oxysporum ;
  • Gaeumannomyces diseases caused for example by Gaeumannomyces graminis ;
  • Rhizoctonia diseases caused for example by Rhizoctonia solani ;
  • Sarocladium diseases caused for example by Sarocladium oryzae;
  • Sclerotium diseases caused for example by Sclerotium oryzae
  • Tapesia diseases caused for example by Tapesia acuformis ;
  • Thielaviopsis diseases caused for example by Thielaviopsis basicola ;
  • Ear and panicle diseases such as :
  • Alternaria diseases caused for example by Alternaria spp. ; Aspergillus diseases, caused for example by Aspergillus flavus ;
  • Cladosporium diseases caused for example by Cladosporium spp. ;
  • Claviceps diseases caused for example by Claviceps purpurea ;
  • Fusarium diseases caused for example by Fusarium culmorum ;
  • Gibberella diseases caused for example by Gibberella zeae ;
  • Monographella diseases caused for example by Monographella nivalis ; Smut and bunt diseases such as :
  • Sphacelotheca diseases caused for example by Sphacelotheca reiliana ;
  • Tilletia diseases caused for example by Tilletia caries ;
  • Urocystis diseases caused for example by Urocystis occulta ;
  • Ustilago diseases caused for example by Ustilago nuda ;
  • Aspergillus diseases caused for example by Aspergillus flavus ;
  • Botrytis diseases caused for example by Botrytis cinerea ;
  • Penicillium diseases caused for example by Penicillium expansum ;
  • Rhizopus diseases caused by example by Rhizopus stolonifer
  • Sclerotinia diseases caused for example by Sclerotinia sclerotiorum ;
  • Verticilium diseases caused for example by Verticilium alboatrum ;
  • Seed and soilborne decay, mould, wilt, rot and dam ping-off diseases Seed and soilborne decay, mould, wilt, rot and dam ping-off diseases :
  • Alternaria diseases caused for example by Alternaria brassicicola Aphanomyces diseases, caused for example by Aphanomyces euteiches Ascochyta diseases, caused for example by Ascochyta lentis
  • Cladosporium diseases caused for example by Cladosporium herbarum
  • Cochliobolus diseases caused for example by Cochliobolus sativus (Conidiaform: Drechslera, Bipolaris Syn: Helminthosporium);
  • Colletotrichum diseases caused for example by Colletotrichum coccodes
  • Fusarium diseases caused for example by Fusarium culmorum
  • Gibberella diseases caused for example by Gibberella zeae
  • Macrophomina diseases caused for example by Macrophomina phaseolina Monographella diseases, caused for example by Monographella nivalis; Penicillium diseases, caused for example by Penicillium expansum Phoma diseases, caused for example by Phoma lingam
  • Phomopsis diseases caused for example by Phomopsis sojae
  • Phytophthora diseases caused for example by Phytophthora cactorum
  • Pyrenophora diseases caused for example by Pyrenophora graminea
  • Pyricularia diseases caused for example by Pyricularia oryzae
  • Pythium diseases caused for example by Pythium ultimum
  • Rhizoctonia diseases caused for example by Rhizoctonia solani
  • Rhizopus diseases caused for example by Rhizopus oryzae
  • Sclerotium diseases caused for example by Sclerotium rolfsii;
  • Septoria diseases caused for example by Septoria nodorum
  • Typhula diseases caused for example by Typhula incarnata
  • Verticillium diseases caused for example by Verticillium dahliae ;
  • Canker, broom and dieback diseases such as :
  • Nectria diseases caused for example by Nectria galligena ;
  • Blight diseases such as :
  • Monilinia diseases caused for example by Monilinia laxa ;
  • Leaf blister or leaf curl diseases such as :
  • Exobasidium diseases caused for example by Exobasidium vexans
  • Taphrina diseases caused for example by Taphrina deformans ;
  • Esca diseases caused for example by Phaemoniella clamydospora ;
  • Eutypa dyeback caused for example by Eutypa lata ;
  • Ganoderma diseases caused for example by Ganoderma boninense
  • Rigidoporus diseases caused for example by Rigidoporus lignosus
  • Botrytis diseases caused for example by Botrytis cinerea
  • Rhizoctonia diseases caused for example by Rhizoctonia solani;
  • Helminthosporium diseases caused for example by Helminthosporium solani;
  • Plasmodiophora diseases cause for example by Plamodiophora brassicae.
  • Xanthomonas species for example Xanthomonas campestris pv. oryzae;
  • Pseudomonas species for example Pseudomonas syringae pv. lachrymans;
  • Erwinia species for example Erwinia amylovora.
  • the compounds according to the invention can also be used for the preparation of composition useful to curatively or preventively treat human or animal fungal diseases such as, for example, mycoses, dermatoses, trichophyton diseases and candidiases or diseases caused by Aspergillus spp., for example Aspergillus fumigatus.
  • fungal diseases such as, for example, mycoses, dermatoses, trichophyton diseases and candidiases or diseases caused by Aspergillus spp., for example Aspergillus fumigatus.
  • Measurement of logP values was performed according EEC directive 79/831 Annex V.A8 by HPLC (High Performance Liquid Chromatography) on reversed phase columns with the following methods: measurement of LC-MS was done at pH 2,7 with 0, 1 % formic acid in water and with acetonitrile (contains 0, 1 % formic acid) as eluent with a linear Calibration was done with not branched alkan2- ones (with 3 to 16 carbon atoms) with known logP-values (measurement of logP values using retention times with linear interpolation between successive alkanones). lambda-maX-values were determined using UV-spectra from 200 nm to 400 nm and the peak values of the chromatographic signals.
  • M+H means the molecular ion peak, plus or minus 1 a.m.u. (atomic mass unit) respectively, as observed in mass spectroscopy and M (Apcl+) means the molecular ion peak as it was found via positive atmospheric pressure chemical ionisation in mass spectroscopy.
  • H-NMR data of selected examples of table 1 are written in form of 1 H-NMR-peak lists in the following NMR peak list table. To each signal peak are listed the ⁇ -value in ppm and the signal intensity in the form "delta-i (intensity- ⁇ ); delta 2 (intensity 2 ); ...delta n (intensity n )":
  • Example 10 [DMSO-D 6 ] 1 1.8822 2.24;7.5479 0.33;7.5358 0.63;7.5267 1.20;7.5210 1 .06;7.5125 1.41 ;7.5053 1.14;7.4936 1 .24;7.4726 5.81 ;7.4673 6.07;7.4599 8.15;7.2291 4.52;5.7639 2.48;5.5519 8.1 1 ;5.2297 7.25;4.2561 2.24;4.2399 4.76;4.2237 2.29;3.5587 16.00;3.3322 8.36;2.9298 1 .48;2.9234 3.1 1 ;2.9169 1.60;2.6015 1 .44;2.5950 1.58;2.5853 2.96;2.5788 2.92;2.5692 1 .58;2.5627 1.45;2.5451
  • Example 13 [DMSO-D 6 ] 9.8147 1.07;7.7694 0.68;7.7513 0.71 ;7.7269 0.89;7.7075 0.41 ;7.5260 0.51 ;7.5202 0.48;7.51 19 0.46;7.4588 1.72;7.4527 1.82;7.4452 3.1 1 ;7.0423 0.66;7.0248 0.62;5.2721 2.52;3.8404 0.41 ;3.8308 0.35;3.3356 5.18;2.5155 2.05;2.51 13 4.07;2.5069 5.44;2.5024 3.91 ;2.4982
  • Example 17 [DMSO-D 6 ] 9.6697 1.21 ;7.7706 1.46;7.7596 2.06;7.5205 0.42;7.5136 0.35;7.5060 0.47;7.4989 0.40;7.4856 0.42;7.4643 1.87;7.4575 2.05;7.4505 3.1 1 ;7.4394 0.38;7.0170 0.56;7.0069 0.81 ;6.9963 0.53;5.7643 3.36;5.6914 2.93;5.2613 2.77;3.5592 5.90;3.3334 2.04;2.5108 8.62;2.5064
  • Example 20 [DMSO-D 6 ] 7.5451 0.41 ;7.5356 0.85;7.5334 0.82;7.5235 1.92;7.51 19 1 .87;7.5022 1.90:7.4918 0.78;7.4873 0.76;7.4837 0.77;7.4650 16.00;7.4541 10.91 ;6.9741 6.02;6.6019 5.69;5.0863 1.05:5.0752 10.41 ;3.9004 0.48;3.8898 0.88;3.8832 1.01 ;3.8729 1.83:3.8639 1.05:3.8563 0.87;3.8450 0.48:3.3372 20.24;2.5154 9.28;2.51 1 1 18.30;2.5067 24.16;2.5022 17.28;2.4981 8.05; 1.0701
  • Example 21 [DMSO-D 6 ] 8.5972 0.25;8.5900 0.30;8.5735 0.33;7.7936 0.25;7.5627 0.65;7.5551 0.65:7.5371 1.30;7.5277 1.95;7.5167 3.41 ;7.5085 2.60;7.4951 1.83;7.4728 8.28;7.4620 4.33;7.4528 3.00:7.4228 0.65;7.4176 0.86;7.4004 0.54;7.3943 0.81 ;7.3870 0.57;7.3646 0.40;6.9714 3.12;6.9028 0.26:6.8026 0.32;6.5845 2.79:6.5422 0.51 :6.5127 1.36;6.2635 0.32;5.6835 1 .91 ;5.6681 0.83;5.6322 0.40:5.6027 5.48:5.4956 0.37;5.0552 5.54;5.0365 1.47;4.9955 1.71 ;4.8582 0.72;4.3517 0.31 ;4.2533 0.40:4.
  • Example 22 [DMSO-D 6 ] 7.9572 0.43;7.6943 0.50;7.6764 0.66;7.6728 0.49;7.6313 0.36;7.6260 0.47;7.6183 0.44;7.6150 0.40;7.6068 0.59;7.6039 0.48;7.5852 0.34;7.5461 0.98;7.5392 0.94;7.5354 1.29:7.5303 1.38;7.5248 3.21 ;7.5209 2.08;7.5183 2.06;7.5123 2.22;7.51 1 1 2.25;7.5036 2.08;7.4925 0.83:7.4826 1.31 ;7.4798 1.23;7.4749 1 .19;7.4601 12.79;7.4578 12.65;7.4488 16.00;7.4393 2.33;7.4198 2.41 ;7.4005 1.47;6.5870 0.36;6.5686 0.57;6.5188 2.84;6.5009 2.71 ;6.4329 2.47;6.4121 2.33;6.1
  • Example 23 [DMSO-D 6 ] 7.6401 0.27;7.5439 0.63;7.5323 0.46;7.5256 0.86;7.5189 0.84;7.5064 1.38:7.5036 1.34;7.4917 1.41 ;7.4646 5.17;7.4596 4.89;7.4461 4.02;7.4260 0.74;7.4166 1 .43;7.3836 0.94;6.4876 1.51 ;6.4586 1 .52;6.4464 1.47;6.4130 1.29;6.3967 0.41 ;6.3643 0.32;6.2181 0.45;6.1057 0.54;5.8612 0.39;5.7669 4.65;5.7584 5.77;5.1882 0.45;5.1339 5.42;4.8910 0.38;3.6545 1.10;3.5743 12.50:3.5478 0.31 ;3.3556 0.50;2.5223 1 .16;2.5152 2.37;2.5079 3.17;2.5007 2.22;2.4937 0.99; 1.9950 0.27;1 .86
  • Emulsifier 1 part by weight of Alkylarylpolyglycolether
  • active compound 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
  • the test is evaluated 7 days after the inoculation. 0% means an efficacy which corresponds to that of the untreated control, while an efficacy of 100% means that no disease is observed.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
  • young plants are sprayed with the preparation of active compound at the stated rate of application. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of Plasmopara viticola and then remain for 1 day in an incubation cabinet at approximately 20°C and a relative atmospheric humidity of 100 %. The plant is subsequently placed for 4 days in a greenhouse at approximately 21 °C and a relative atmospheric humidity of approximately 90 %. The plants are then misted and placed for 1 day in an incubation cabinet.

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  • Life Sciences & Earth Sciences (AREA)
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  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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Abstract

L'invention concerne des dérivés hydroximoyle-hétérocycle de formule (I) dans laquelle Het représente un groupe pyridyle ou thiazolyle, A représente un groupe tétrazolyle, et X représente des substituants variés.
PCT/EP2011/056497 2010-04-28 2011-04-22 Dérivés hydroximoyle-tétrazole fongicides Ceased WO2011134911A2 (fr)

Applications Claiming Priority (4)

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EP10356013 2010-04-28
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US34547710P 2010-06-14 2010-06-14
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9556143B2 (en) 2011-06-19 2017-01-31 Viamet Pharmaceuticals, Inc. Metalloenzyme inhibitor compounds
US11051514B2 (en) 2015-05-18 2021-07-06 Mycovia Pharmaceuticals, Inc. Antifungal compounds

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