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WO2011116141A3 - Clean steel production process using carbon-free renewable energy source - Google Patents

Clean steel production process using carbon-free renewable energy source Download PDF

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Publication number
WO2011116141A3
WO2011116141A3 PCT/US2011/028737 US2011028737W WO2011116141A3 WO 2011116141 A3 WO2011116141 A3 WO 2011116141A3 US 2011028737 W US2011028737 W US 2011028737W WO 2011116141 A3 WO2011116141 A3 WO 2011116141A3
Authority
WO
WIPO (PCT)
Prior art keywords
heat
hydrogen
renewable energy
oxy
energy source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/028737
Other languages
French (fr)
Other versions
WO2011116141A2 (en
Inventor
Victor Joseph
Amjiad Huda
Pia A. Victor
Joy J Victor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUN HYDROGEN Inc
Original Assignee
SUN HYDROGEN Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUN HYDROGEN Inc filed Critical SUN HYDROGEN Inc
Publication of WO2011116141A2 publication Critical patent/WO2011116141A2/en
Publication of WO2011116141A3 publication Critical patent/WO2011116141A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/042—Decomposition of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0073—Selection or treatment of the reducing gases
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • C21B13/023—Making spongy iron or liquid steel, by direct processes in shaft furnaces wherein iron or steel is obtained in a molten state
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B5/00—Making pig-iron in the blast furnace
    • C21B5/001—Injecting additional fuel or reducing agents
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00—Solar heat collectors specially adapted for particular uses or environments
    • F24S20/20—Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70—Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • F24S23/71—Arrangements for concentrating solar-rays for solar heat collectors with reflectors with parabolic reflective surfaces
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00—Subject matter not provided for in other groups of this subclass
    • F27D99/0001—Heating elements or systems
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/40—Solar thermal energy, e.g. solar towers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Nanotechnology (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

Systems and methods for producing steel comprise using a renewable energy source, such as solar energy, to heat a heat-releasing energy storage medium, such as MgF2. Heat from the heat-releasing energy storage medium is used to generate steam from liquid water. Next, H2 and O2 are generated from steam via electrolysis or direct thermal decomposition at >2400°C. The energy required for the electrolysis of steam may be provided from one or more renewable energy sources, such as one or more wind turbines and/or fuel cells. A fraction of the H2 and O2 formed via electrolysis is used to generate oxy-hydrogen, which is subsequently used to form steel in an oxy-hydrogen steel smelter. The oxy-hydrogen steel smelter uses iron formed in a hydrogen-based blast furnace, which uses H2 formed from the dissociation of water to reduce iron oxide.
PCT/US2011/028737 2010-03-18 2011-03-16 Clean steel production process using carbon-free renewable energy source Ceased WO2011116141A2 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US31536210P 2010-03-18 2010-03-18
US61/315,362 2010-03-18
US38553810P 2010-09-22 2010-09-22
US61/385,538 2010-09-22
US201161438498P 2011-02-01 2011-02-01
US61/438,498 2011-02-01

Publications (2)

Publication Number Publication Date
WO2011116141A2 WO2011116141A2 (en) 2011-09-22
WO2011116141A3 true WO2011116141A3 (en) 2012-01-12

Family

ID=44649815

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/028737 Ceased WO2011116141A2 (en) 2010-03-18 2011-03-16 Clean steel production process using carbon-free renewable energy source

Country Status (1)

Country Link
WO (1) WO2011116141A2 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5879091B2 (en) * 2011-10-24 2016-03-08 日立造船株式会社 Combined thermal power generation system
CN102424873B (en) * 2011-12-03 2013-01-30 石家庄市新华工业炉有限公司 Method and device for solar reduction iron making
CN102517087B (en) * 2011-12-03 2013-11-27 石家庄新华能源环保科技股份有限公司 Device for coproducing coal gas during solar calcining of material
US9328426B2 (en) * 2012-03-26 2016-05-03 General Electric Company Systems and methods for generating oxygen and hydrogen for plant equipment
GB2507246A (en) * 2012-07-31 2014-04-30 David Andrew Johnston Direct reduction of iron using a carbon monoxide-hydrogen mixture derived from carbon dioxide and water
KR20150063075A (en) * 2012-09-14 2015-06-08 뵈스트알파인 스탈 게엠베하 Method for Producing Steel
DE102013113950A1 (en) * 2013-12-12 2015-06-18 Thyssenkrupp Ag Plant network for steelmaking and process for operating the plant network
DE102013113921A1 (en) * 2013-12-12 2015-06-18 Thyssenkrupp Ag Plant network for steelmaking and process for operating the plant network
DE102013113913A1 (en) 2013-12-12 2015-06-18 Thyssenkrupp Ag Plant network for steelmaking and process for operating the plant network
DE102013113958A1 (en) * 2013-12-12 2015-06-18 Thyssenkrupp Ag Plant network for steelmaking and process for operating the plant network
DE102014206423A1 (en) * 2014-04-03 2015-10-08 Evonik Degussa Gmbh Apparatus and method for using electrical energy for iron production from oxidic iron ores
HUE057873T2 (en) * 2017-07-03 2022-06-28 Air Liquide Method for operating an iron-or steelmaking-plant
WO2019042574A1 (en) * 2017-09-04 2019-03-07 Outotec (Finland) Oy Plant and method for the thermal treatment of solids
WO2019219340A1 (en) * 2018-05-15 2019-11-21 Tata Steel Nederland Technology B.V. Method for the direct reduction of iron ore
ES2834923T3 (en) * 2018-08-29 2021-06-21 Doosan Lentjes Gmbh Incineration apparatus and method
NL2022045B1 (en) * 2018-11-21 2020-06-03 Green Vision Holding Bv Method for generating heat from water electrolysis
IT201900008019A1 (en) * 2019-06-04 2020-12-04 Tenova Spa Method and system for the production of steel or cast materials containing iron with reduced emissions
MX2021014435A (en) * 2019-06-06 2022-01-06 Midrex Technologies Inc DIRECT REDUCTION PROCESS USING HYDROGEN.
EP3736347A1 (en) * 2019-10-14 2020-11-11 Primetals Technologies Austria GmbH Use of oxygen from water electrolysis in iron and / or steel production
WO2022119882A1 (en) * 2020-12-03 2022-06-09 Ohmium International, Inc. System and method for reducing ore using hydrogen as a reducing agent
US20220274077A1 (en) * 2021-02-25 2022-09-01 Blueshift, LLC dba Outward Technologies Solar Concentrator Reactor for High Temperature Thermochemical Processes
CN113481338A (en) * 2021-07-07 2021-10-08 山西晋南钢铁集团有限公司 High-valued cascade utilization method of ethylene glycol by-product hydrogen
DE102022115857A1 (en) * 2022-06-24 2024-01-04 Sms Group Gmbh Method and device for reducing metal oxide by means of a reducing gas or gas mixture using solar thermal energy
CN114561499A (en) * 2022-01-20 2022-05-31 E&E有限公司 Method and apparatus for producing iron with low carbon using mixed gas of hydrogen and oxygen
DE102022201918A1 (en) * 2022-02-24 2023-08-24 Sms Group Gmbh Metallurgical production plant and method for its operation
KR102784845B1 (en) * 2022-04-14 2025-03-21 이화여자대학교 산학협력단 Hot blast stove system combined with thermochemical redox cycel for producing hydrogen
EP4544086A1 (en) * 2022-06-24 2025-04-30 SMS Group GmbH Method and apparatus for reducing metal oxide by means of a reducing gas or gas mixture generated using solar thermal energy
CN115522003B (en) * 2022-08-18 2023-04-21 昌黎县兴国精密机件有限公司 Hydrogen-rich blast furnace ironmaking system based on energy conversion and production control method thereof
WO2024152036A1 (en) * 2023-01-15 2024-07-18 Erthos IP LLC Hydrox fueled polysilicon smelting and production

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140168A (en) * 1961-05-31 1964-07-07 Inland Steel Co Reduction of iron ore with hydrogen
US5454853A (en) * 1994-06-10 1995-10-03 Borealis Technical Incorporated Limited Method for the production of steel
US5464464A (en) * 1994-06-10 1995-11-07 Borealis Technical Incorporated Limited Method for reducing particulate iron ore to molten iron with hydrogen as reductant
US20050183962A1 (en) * 2004-02-24 2005-08-25 Oakes Thomas W. System and method for generating hydrogen gas using renewable energy
US20090249922A1 (en) * 2008-04-02 2009-10-08 Bristlecone International, Llc Process for the production of steel using a locally produced hydrogen as the reducing agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140168A (en) * 1961-05-31 1964-07-07 Inland Steel Co Reduction of iron ore with hydrogen
US5454853A (en) * 1994-06-10 1995-10-03 Borealis Technical Incorporated Limited Method for the production of steel
US5464464A (en) * 1994-06-10 1995-11-07 Borealis Technical Incorporated Limited Method for reducing particulate iron ore to molten iron with hydrogen as reductant
US20050183962A1 (en) * 2004-02-24 2005-08-25 Oakes Thomas W. System and method for generating hydrogen gas using renewable energy
US20090249922A1 (en) * 2008-04-02 2009-10-08 Bristlecone International, Llc Process for the production of steel using a locally produced hydrogen as the reducing agent

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