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WO2011037332A3 - 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물 - Google Patents

신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물 Download PDF

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Publication number
WO2011037332A3
WO2011037332A3 PCT/KR2010/005871 KR2010005871W WO2011037332A3 WO 2011037332 A3 WO2011037332 A3 WO 2011037332A3 KR 2010005871 W KR2010005871 W KR 2010005871W WO 2011037332 A3 WO2011037332 A3 WO 2011037332A3
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WO
WIPO (PCT)
Prior art keywords
silica particles
hard coating
composition containing
coating composition
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2010/005871
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English (en)
French (fr)
Other versions
WO2011037332A2 (ko
Inventor
권동주
김원국
강양구
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LX Hausys Ltd
Original Assignee
LG Hausys Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Hausys Ltd filed Critical LG Hausys Ltd
Priority to DE112010003739.6T priority Critical patent/DE112010003739B4/de
Priority to CN201080035651.4A priority patent/CN102548897B/zh
Priority to JP2012529655A priority patent/JP5601672B2/ja
Priority to US13/388,501 priority patent/US9512009B2/en
Publication of WO2011037332A2 publication Critical patent/WO2011037332A2/ko
Publication of WO2011037332A3 publication Critical patent/WO2011037332A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/146—After-treatment of sols
    • C01B33/149—Coating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/146—After-treatment of sols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141—Preparation of hydrosols or aqueous dispersions
    • C01B33/142—Preparation of hydrosols or aqueous dispersions by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3893—Low-molecular-weight compounds having heteroatoms other than oxygen containing silicon
    • C08G18/3895—Inorganic compounds, e.g. aqueous alkalimetalsilicate solutions; Organic derivatives thereof containing no direct silicon-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Laminated Bodies (AREA)
  • Silicon Compounds (AREA)

Abstract

본 발명은 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물에 관한 것으로, 보다 상세하게는 실리카 입자의 표면의 히드록시기(-OH)에 개시제를 화학적으로 결합시킨 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드코팅 조성물에 관한 것이다. 본 발명에 따른 유-무기 실리카 입자를 포함하는 하드코팅 조성물은 내마모성, 내스크래치성 등이 우수한 하드코팅 필름을 제조할 수 있다.
PCT/KR2010/005871 2009-09-22 2010-08-31 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물 Ceased WO2011037332A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE112010003739.6T DE112010003739B4 (de) 2009-09-22 2010-08-31 Neuartige organisch-anorganische Siliciumdioxidteilchen und Verfahren zu deren Herstellung
CN201080035651.4A CN102548897B (zh) 2009-09-22 2010-08-31 有机-无机二氧化硅粒子、制造方法及硬涂组合物
JP2012529655A JP5601672B2 (ja) 2009-09-22 2010-08-31 新規の有機−無機シリカ粒子、その製造方法及びこれを含むハードコーティング組成物
US13/388,501 US9512009B2 (en) 2009-09-22 2010-08-31 Organic-inorganic silica particles, method of preparing the same, and hard coating composition containing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020090089655A KR101181564B1 (ko) 2009-09-22 2009-09-22 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물
KR10-2009-0089655 2009-09-22

Publications (2)

Publication Number Publication Date
WO2011037332A2 WO2011037332A2 (ko) 2011-03-31
WO2011037332A3 true WO2011037332A3 (ko) 2011-07-21

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ID=43796331

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PCT/KR2010/005871 Ceased WO2011037332A2 (ko) 2009-09-22 2010-08-31 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물

Country Status (6)

Country Link
US (1) US9512009B2 (ko)
JP (1) JP5601672B2 (ko)
KR (1) KR101181564B1 (ko)
CN (1) CN102548897B (ko)
DE (1) DE112010003739B4 (ko)
WO (1) WO2011037332A2 (ko)

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US9458326B2 (en) * 2009-09-09 2016-10-04 Felix Winkelmann Polymer materials comprising coupled components
JP2011157435A (ja) * 2010-01-29 2011-08-18 Dic Corp 無機粒子分散体の製造方法
EP2439219A1 (de) * 2010-10-06 2012-04-11 Sika Technology AG Verringerung des Anteils an Isocyanatgruppen aufweisenden Monomeren in feuchtigkeitshärtenden Polyurethanzusammensetzungen
EP2683770B1 (de) * 2011-03-09 2024-07-31 Felix Winkelmann Verfahren zur Herstellung von Zwischenprodukten für polymere Werkstoffe mit Additionskomponenten oder Bauteilen daraus, Verfahren zur Herstellung von polymeren Werkstoffen auf Basis von Zwischenprodukten, Verwendung von polymeren Werkstoffen und Verwendung von Bauteilen aus polymeren Werkstoffen
KR101291937B1 (ko) * 2011-04-15 2013-07-31 (주)엘지하우시스 하드코팅용 조성물 및 이를 이용한 저온 성형성 및 슬립성이 우수한 하드코팅 형성용 시트
KR101512881B1 (ko) * 2012-05-31 2015-04-16 주식회사 엘지화학 가스 차단 필름 및 이의 제조방법
CN102993782B (zh) * 2012-12-12 2014-04-16 江南大学 一种聚氨酯丙烯酸酯类低聚物表面改性二氧化硅的制备方法
JP2015078339A (ja) * 2013-09-10 2015-04-23 昭和電工株式会社 有機無機複合体の製造方法、硬化性組成物、硬化性組成物の製造方法、硬化性組成物の硬化物、ハードコート材、及びハードコート膜
CN104725549B (zh) * 2014-02-24 2018-09-04 长兴化学工业(中国)有限公司 高性能纳米复合乳胶
KR101745676B1 (ko) 2014-05-30 2017-06-09 주식회사 엘지화학 시아네이트계 수지에 대한 분산성이 우수한 실리카졸 조성물 및 이의 제조 방법
KR101745410B1 (ko) 2015-05-12 2017-06-09 엘지전자 주식회사 고분자 기반 초흡습성 코팅 조성물 및 그 이용
CN105585272A (zh) * 2015-10-22 2016-05-18 湖州绿色建材开发有限公司 一种新型混凝土增强剂
KR102184393B1 (ko) * 2017-08-24 2020-11-30 주식회사 엘지화학 유무기 하이브리드 코팅층을 포함하는 기능성 필름
WO2019235206A1 (ja) * 2018-06-05 2019-12-12 Dic株式会社 活性エネルギー線硬化性組成物及びそれを用いたフィルム
EP3845490A4 (en) * 2019-05-14 2021-12-08 Nissan Chemical Corporation KETONE SOLVENT DISPERSION SILICA SOL AND RESIN COMPOSITION
JP6956909B2 (ja) * 2020-03-23 2021-11-02 デクセリアルズ株式会社 光学積層体および物品
CN114605662B (zh) * 2022-04-24 2023-03-24 嘉鱼县宇威新材料科技有限公司 一种丁腈橡胶增韧剂及其制备方法和应用

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Also Published As

Publication number Publication date
CN102548897A (zh) 2012-07-04
DE112010003739B4 (de) 2018-05-17
JP5601672B2 (ja) 2014-10-08
US20120135216A1 (en) 2012-05-31
JP2013504512A (ja) 2013-02-07
US9512009B2 (en) 2016-12-06
KR101181564B1 (ko) 2012-09-10
KR20110032258A (ko) 2011-03-30
WO2011037332A2 (ko) 2011-03-31
CN102548897B (zh) 2015-02-11
DE112010003739T5 (de) 2013-05-02

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