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WO2011035064A3 - Triazole catalysts and methods of making and using the same - Google Patents

Triazole catalysts and methods of making and using the same Download PDF

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Publication number
WO2011035064A3
WO2011035064A3 PCT/US2010/049178 US2010049178W WO2011035064A3 WO 2011035064 A3 WO2011035064 A3 WO 2011035064A3 US 2010049178 W US2010049178 W US 2010049178W WO 2011035064 A3 WO2011035064 A3 WO 2011035064A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalysts
catalyze
triazole
methods
making
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/049178
Other languages
French (fr)
Other versions
WO2011035064A2 (en
Inventor
Ramez A. Elgammal
Shane Foister
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Tennessee Research Foundation
Original Assignee
University of Tennessee Research Foundation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Tennessee Research Foundation filed Critical University of Tennessee Research Foundation
Publication of WO2011035064A2 publication Critical patent/WO2011035064A2/en
Publication of WO2011035064A3 publication Critical patent/WO2011035064A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Homogenous and heterogenous catalysts comprising 1,2,4-triazole ligands and transition metals are described. The catalysts can be used to catalyze the oxidation of hydrocarbons and other reactions. In particular, the catalysts can be used to catalyze the selective oxidation of methane to methanol and/or other C1 and C2 oxidation products under mild conditions. The catalysts can also be used to catalyze aziridation and the formation of aminoalcohols from alkenes and to catalyze the degradation of cellulosic substrates. Efficient methods of synthesizing the catalysts are described, as well.
PCT/US2010/049178 2009-09-16 2010-09-16 Triazole catalysts and methods of making and using the same Ceased WO2011035064A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US24300609P 2009-09-16 2009-09-16
US61/243,006 2009-09-16

Publications (2)

Publication Number Publication Date
WO2011035064A2 WO2011035064A2 (en) 2011-03-24
WO2011035064A3 true WO2011035064A3 (en) 2011-07-28

Family

ID=43759278

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/049178 Ceased WO2011035064A2 (en) 2009-09-16 2010-09-16 Triazole catalysts and methods of making and using the same

Country Status (1)

Country Link
WO (1) WO2011035064A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103333076B (en) * 2013-07-02 2015-12-23 扬州大学 Replace 2 hydroxy ethylamine compounds novel synthesis
TWI625164B (en) 2013-10-04 2018-06-01 中央研究院 Molecular catalysts capable of catalyzing oxidation of hydrocarbons and method for oxidizing hydrocarbons
WO2016043736A1 (en) * 2014-09-17 2016-03-24 Novoform Technologies Llc Methods and catalysts for converting methane to methanol
CN105585535A (en) * 2016-01-05 2016-05-18 天津师范大学 4-(4-nitrophenyl)-4H-1,2,4-triazole single crystal and application
US10490825B2 (en) 2016-12-06 2019-11-26 Savannah River Nuclear Solutions, Llc Non-platinum group oxygen reduction reaction catalysts
IL297569B2 (en) * 2017-02-22 2025-04-01 Hadasit Med Res Service Compounds for the treatment of glycogen storage disorders
CN112390704B (en) * 2019-08-13 2021-11-02 中国科学院大连化学物理研究所 A kind of method for directly converting methane into methanol and acetic acid
CN111825201A (en) * 2020-07-20 2020-10-27 上海相出净流环保科技开发有限公司 Preparation method and application of self-adaptive liquid Fenton reaction catalyst for industrial wastewater treatment
CN113797976B (en) * 2020-11-17 2022-08-23 江南大学 Iridium catalyst for catalytic preparation of substituted ketone compound
CN116836172A (en) * 2023-07-05 2023-10-03 北京八亿时空液晶科技股份有限公司 A triazole derivative and its application

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BHATTACHARYA, SANTANU ET AL.: "Metallomicelles as potent catalysts for the ester hydrolysis reactions in water", COORDINATION CHEMISTRY REVIEWS 2009, vol. 253, 24 January 2009 (2009-01-24), pages 2133 - 2149 *
CHENG, LIN ET AL.: "In Situ Solvothermal Generation of 1,2,4-Triazolates and Related Compounds from Organonitrile and Hydrazine Hydrate: A Mechanism Study", INORG. CHEM., vol. 46, 13 January 2007 (2007-01-13), pages 1135 - 1143 *
LIGTENBARG, ALETTE G.J. ET AL.: "Catalytic oxidations by vanadium complexes", COORDINATION CHEMISTRY REVIEWS 2003, vol. 237, 28 February 2003 (2003-02-28), pages 89 - 101 *
RORGERS, MICHELLE M. ET AL.: "N-Heterocyclic Carbenes as Ligands for High- Oxidation-State Metal Complexes and Oxidation Catalysis", TOP ORGANOMET CHEM., 5 July 2006 (2006-07-05) *

Also Published As

Publication number Publication date
WO2011035064A2 (en) 2011-03-24

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