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WO2011028523A3 - Procédé et système catalyseur de fabrication de polydiène - Google Patents

Procédé et système catalyseur de fabrication de polydiène Download PDF

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Publication number
WO2011028523A3
WO2011028523A3 PCT/US2010/046482 US2010046482W WO2011028523A3 WO 2011028523 A3 WO2011028523 A3 WO 2011028523A3 US 2010046482 W US2010046482 W US 2010046482W WO 2011028523 A3 WO2011028523 A3 WO 2011028523A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst system
polydiene
production
polydiene production
allylvinylsilane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/046482
Other languages
English (en)
Other versions
WO2011028523A2 (fr
Inventor
Steven Luo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BR112012004109A priority Critical patent/BR112012004109B1/pt
Priority to KR1020127007539A priority patent/KR101685232B1/ko
Priority to JP2012526913A priority patent/JP5791607B2/ja
Priority to CN201080048068.7A priority patent/CN102597026B/zh
Priority to EP10814240.7A priority patent/EP2470574B1/fr
Priority to RU2012111258/04A priority patent/RU2539596C2/ru
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to US13/391,463 priority patent/US8765887B2/en
Publication of WO2011028523A2 publication Critical patent/WO2011028523A2/fr
Publication of WO2011028523A3 publication Critical patent/WO2011028523A3/fr
Priority to ZA2012/01302A priority patent/ZA201201302B/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612—Pretreating with metals or metal-containing compounds
    • C08F4/616—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

L'invention porte sur un procédé de fabrication d'un polydiène, le procédé comportant l'étape consistant à polymériser un monomère diénique conjugué avec un système catalyseur à base de lanthanide en présence d'un vinylsilane, d'un allylsilane ou d'un allylvinylsilane.
PCT/US2010/046482 2009-08-24 2010-08-24 Procédé et système catalyseur de fabrication de polydiène Ceased WO2011028523A2 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1020127007539A KR101685232B1 (ko) 2009-08-24 2010-08-24 폴리디엔 제조를 위한 방법 및 촉매 시스템
JP2012526913A JP5791607B2 (ja) 2009-08-24 2010-08-24 ポリジエン製造用の方法および触媒システム
CN201080048068.7A CN102597026B (zh) 2009-08-24 2010-08-24 用于聚二烯烃生产的方法和催化剂体系
EP10814240.7A EP2470574B1 (fr) 2009-08-24 2010-08-24 Procédé et système catalyseur de fabrication de polydiène
RU2012111258/04A RU2539596C2 (ru) 2009-08-24 2010-08-24 Способ и система катализатора для получения полидиена
BR112012004109A BR112012004109B1 (pt) 2009-08-24 2010-08-24 processo e sistema catalisador para produção de polidieno
US13/391,463 US8765887B2 (en) 2009-08-24 2010-08-24 Process and catalyst system for polydiene production
ZA2012/01302A ZA201201302B (en) 2009-08-24 2012-02-21 Process and catalyst system for polydiene production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23616809P 2009-08-24 2009-08-24
US61/236,168 2009-08-24

Publications (2)

Publication Number Publication Date
WO2011028523A2 WO2011028523A2 (fr) 2011-03-10
WO2011028523A3 true WO2011028523A3 (fr) 2011-06-16

Family

ID=43649892

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/046482 Ceased WO2011028523A2 (fr) 2009-08-24 2010-08-24 Procédé et système catalyseur de fabrication de polydiène

Country Status (10)

Country Link
US (1) US8765887B2 (fr)
EP (1) EP2470574B1 (fr)
JP (1) JP5791607B2 (fr)
KR (1) KR101685232B1 (fr)
CN (1) CN102597026B (fr)
BR (1) BR112012004109B1 (fr)
CZ (1) CZ306310B6 (fr)
RU (2) RU2539596C2 (fr)
WO (1) WO2011028523A2 (fr)
ZA (1) ZA201201302B (fr)

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WO2012106694A2 (fr) * 2011-02-05 2012-08-09 Bridgestone Corporation Catalyseur à base de complexes lanthanides et procédé de polymérisation utilisant de catalyseur
US9260593B2 (en) 2011-12-13 2016-02-16 Tsrc Corporation Conjugated diene rubber modified with polar alkoxysilane, method and composition thereof
RU2621683C2 (ru) * 2012-01-31 2017-06-07 Асахи Касеи Кемикалз Корпорейшн Каталитическая композиция для полимеризации сопряженного диенового мономера
KR101993024B1 (ko) * 2012-03-14 2019-06-25 가부시키가이샤 브리지스톤 폴리디엔을 생산하는 방법
JP6157806B2 (ja) * 2012-05-15 2017-07-05 住友化学株式会社 共役ジエン系重合体変性物及び重合体組成物
MX2016005026A (es) * 2013-10-18 2016-08-17 Trinseo Europe Gmbh Vinilsilanos para su uso en polimeros elastomericos funcionalizados.
JP6287519B2 (ja) * 2014-04-15 2018-03-07 Jsr株式会社 新規なケイ素化合物及び重合体
PL3059240T3 (pl) 2015-02-18 2020-03-31 Trinseo Europe Gmbh Wielowinyloaminosilany jako środki rozgałęziające dla funkcjonalizowanych polimerów elastomerowych
KR20170000757A (ko) 2015-06-24 2017-01-03 주식회사 엘지화학 공액 디엔계 중합체 제조용 촉매 조성물 및 이를 이용하여 제조된 공액 디엔계 중합체
WO2016209043A1 (fr) * 2015-06-24 2016-12-29 주식회사 엘지화학 Composition de catalyseur pour la préparation d'un polymère de diène conjugué et polymère de diène conjugué ainsi préparé
WO2017063116A1 (fr) 2015-10-12 2017-04-20 中国科学院化学研究所 Utilisation de siloxane organique, et résine polyoléfinique et son procédé de préparation
EP3363825B1 (fr) 2015-10-12 2021-04-14 Institute Of Chemistry, Chinese Academy Of Sciences Utilisation de siloxane organique, et alliage de polyoléfine en réacteur et son procédé de préparation
EP3363821B1 (fr) * 2015-10-12 2021-05-19 Institute Of Chemistry, Chinese Academy Of Sciences Catalyseur de polymérisation d'oléfines, procédé pour sa préparation, système catalytique de polymérisation d'oléfines, application correspondante et procédé de préparation de résine polyoléfinique
HUE039540T2 (hu) * 2015-10-21 2019-01-28 Trinseo Europe Gmbh Elasztomer polimerek funkcionalizálása során történõ alkalmazásra szolgáló aminoszilán-funkcionalizált diének
KR102019841B1 (ko) * 2015-12-22 2019-09-10 주식회사 엘지화학 변성 공액 디엔계 중합체의 제조방법 및 이에 의해 제조된 변성 공액 디엔계 중합체
US10059788B2 (en) 2016-04-29 2018-08-28 Exxonmobil Chemical Patents Inc. Organoaluminum activators on clays
ES2717151T3 (es) 2016-06-17 2019-06-19 Trinseo Europe Gmbh Potenciamiento mediado por silano de la estabilidad de almacenamiento de caucho
CN109715680B (zh) * 2016-07-29 2021-10-19 株式会社普利司通 用基于镧系元素的催化剂组合物制备高顺式-1,4-聚二烯的方法
WO2018045291A1 (fr) * 2016-09-02 2018-03-08 Bridgestone Corporation Production de cis-1,4-polydiènes avec de multiples groupes fonctionnels silane préparés par hydrosilylation in situ de polymère-ciment
KR101825613B1 (ko) * 2016-09-19 2018-02-05 한화토탈 주식회사 저취기 특성을 나타내는 플라스틱 병뚜껑용 폴리에틸렌 수지 조성물의 제조방법 및 이로부터 제조된 성형품
KR102187173B1 (ko) * 2016-12-23 2020-12-07 주식회사 엘지화학 고무 조성물 및 이의 제조방법
CN109320638B (zh) * 2018-09-29 2021-03-26 四川锦成化学催化剂有限公司 乙烯聚合用Ziegler-Natta催化剂组分和催化剂
US10947380B2 (en) 2018-12-20 2021-03-16 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire
EP3938412B1 (fr) 2019-03-10 2024-04-24 Bridgestone Corporation Polymère de polydiène à haute teneur en cis modifié, procédés associés et compositions de caoutchouc
US11767388B1 (en) 2019-09-18 2023-09-26 The Goodyear Tire & Rubber Company Silicon-functionalized rubber
WO2022020705A1 (fr) * 2020-07-24 2022-01-27 Versum Materials Us, Llc Compositions et leurs procédés d'utlisation pour couche germe de germanium
CN119431666A (zh) * 2023-07-28 2025-02-14 中国石油化工股份有限公司 一种高顺式聚丁二烯弹性体及其制备方法和应用

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US20070149728A1 (en) * 2003-12-19 2007-06-28 Torvald Vestberg Process for producing olefin polymers
US20080146745A1 (en) * 2006-12-19 2008-06-19 Steven Luo Polymers functionalized with protected oxime compounds
EP1939221A2 (fr) * 2006-12-28 2008-07-02 Bridgestone Corporation Procédé de production de polydiènes cis- 1,4 fonctionnalisés ayant un fort contenu de liaison cis-1,4 et une fonctionnalité élevée

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US20020026013A1 (en) * 2000-08-22 2002-02-28 Lundquist Eric G. Matrix and process for polyolefin production
US20070149728A1 (en) * 2003-12-19 2007-06-28 Torvald Vestberg Process for producing olefin polymers
US20080146745A1 (en) * 2006-12-19 2008-06-19 Steven Luo Polymers functionalized with protected oxime compounds
EP1939221A2 (fr) * 2006-12-28 2008-07-02 Bridgestone Corporation Procédé de production de polydiènes cis- 1,4 fonctionnalisés ayant un fort contenu de liaison cis-1,4 et une fonctionnalité élevée

Also Published As

Publication number Publication date
EP2470574B1 (fr) 2014-09-17
EP2470574A2 (fr) 2012-07-04
EP2470574A4 (fr) 2013-07-31
CZ2012126A3 (cs) 2012-07-04
RU2014147736A3 (fr) 2018-03-30
US8765887B2 (en) 2014-07-01
RU2539596C2 (ru) 2015-01-20
ZA201201302B (en) 2012-10-31
JP5791607B2 (ja) 2015-10-07
CN102597026B (zh) 2014-11-26
RU2014147736A (ru) 2016-06-20
RU2012111258A (ru) 2013-10-10
BR112012004109A2 (pt) 2017-09-26
JP2013502508A (ja) 2013-01-24
KR101685232B1 (ko) 2016-12-09
CZ306310B6 (cs) 2016-11-23
CN102597026A (zh) 2012-07-18
KR20120068885A (ko) 2012-06-27
RU2655029C2 (ru) 2018-05-25
US20120165484A1 (en) 2012-06-28
WO2011028523A2 (fr) 2011-03-10
BR112012004109B1 (pt) 2019-08-13

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