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WO2011011521A3 - Method of producing coupled radical products - Google Patents

Method of producing coupled radical products Download PDF

Info

Publication number
WO2011011521A3
WO2011011521A3 PCT/US2010/042756 US2010042756W WO2011011521A3 WO 2011011521 A3 WO2011011521 A3 WO 2011011521A3 US 2010042756 W US2010042756 W US 2010042756W WO 2011011521 A3 WO2011011521 A3 WO 2011011521A3
Authority
WO
WIPO (PCT)
Prior art keywords
coupled radical
radicals
radical products
producing
metal salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/042756
Other languages
French (fr)
Other versions
WO2011011521A9 (en
WO2011011521A2 (en
Inventor
Sai Bhavaraju
Mukund Karanjikar
Ashok Joshi
David Hunt
Pallavi Chitta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ceramatec Inc
Original Assignee
Ceramatec Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceramatec Inc filed Critical Ceramatec Inc
Publication of WO2011011521A2 publication Critical patent/WO2011011521A2/en
Publication of WO2011011521A3 publication Critical patent/WO2011011521A3/en
Publication of WO2011011521A9 publication Critical patent/WO2011011521A9/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/29—Coupling reactions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

A method that produces coupled radical products. An alkali metal salt is used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
PCT/US2010/042756 2009-07-23 2010-07-21 Decarboxylation cell for production of coupled radical products Ceased WO2011011521A2 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US22807809P 2009-07-23 2009-07-23
US61/228,078 2009-07-23
US25855709P 2009-11-05 2009-11-05
US61/258,557 2009-11-05
US26096109P 2009-11-13 2009-11-13
US61/260,961 2009-11-13
US12/840,401 US20110024288A1 (en) 2009-07-23 2010-07-21 Decarboxylation cell for production of coupled radical products
US12/840,401 2010-07-21

Publications (3)

Publication Number Publication Date
WO2011011521A2 WO2011011521A2 (en) 2011-01-27
WO2011011521A3 true WO2011011521A3 (en) 2011-05-05
WO2011011521A9 WO2011011521A9 (en) 2011-07-07

Family

ID=43499646

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/042756 Ceased WO2011011521A2 (en) 2009-07-23 2010-07-21 Decarboxylation cell for production of coupled radical products

Country Status (2)

Country Link
US (1) US20110024288A1 (en)
WO (1) WO2011011521A2 (en)

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CN102317244A (en) 2009-01-29 2012-01-11 普林斯顿大学 Conversion of carbon dioxide to organic products
US9206515B2 (en) 2009-07-23 2015-12-08 Ceramatec, Inc. Method of producing coupled radical products via desulfoxylation
US9957622B2 (en) 2009-07-23 2018-05-01 Field Upgrading Limited Device and method of obtaining diols and other chemicals using decarboxylation
US8506789B2 (en) * 2009-07-23 2013-08-13 Ceramatec, Inc. Method of producing coupled radical products
US9051656B2 (en) * 2009-07-23 2015-06-09 Ceramatec, Inc. Electrochemical synthesis of aryl-alkyl surfacant precursor
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US9493882B2 (en) 2010-07-21 2016-11-15 Ceramatec, Inc. Custom ionic liquid electrolytes for electrolytic decarboxylation
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
WO2012018418A2 (en) 2010-08-05 2012-02-09 Ceramatec, Inc. Method and device for carboxylic acid production
US8980126B2 (en) * 2010-10-08 2015-03-17 Semiconductor Energy Laboratory Co., Ltd. Electrode material and method for manufacturing power storage device
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
US8853463B2 (en) 2011-01-25 2014-10-07 Ceramatec, Inc. Decarboxylation of levulinic acid to ketone solvents
US8821710B2 (en) 2011-01-25 2014-09-02 Ceramatec, Inc. Production of fuel from chemicals derived from biomass
US20130105304A1 (en) 2012-07-26 2013-05-02 Liquid Light, Inc. System and High Surface Area Electrodes for the Electrochemical Reduction of Carbon Dioxide
US20140206896A1 (en) 2012-07-26 2014-07-24 Liquid Light, Inc. Method and System for Production of Oxalic Acid and Oxalic Acid Reduction Products
US8647493B2 (en) 2012-07-26 2014-02-11 Liquid Light, Inc. Electrochemical co-production of chemicals employing the recycling of a hydrogen halide
US9175407B2 (en) 2012-07-26 2015-11-03 Liquid Light, Inc. Integrated process for producing carboxylic acids from carbon dioxide
US8641885B2 (en) 2012-07-26 2014-02-04 Liquid Light, Inc. Multiphase electrochemical reduction of CO2
US10329676B2 (en) 2012-07-26 2019-06-25 Avantium Knowledge Centre B.V. Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
WO2014043651A2 (en) 2012-09-14 2014-03-20 Liquid Light, Inc. High pressure electrochemical cell and process for the electrochemical reduction of carbon dioxide
AU2013318502A1 (en) * 2012-09-19 2015-03-26 Liquid Light, Inc. Electrochemical co-production of products with carbon-based reactant feed to anode
EP2964657A4 (en) * 2013-03-06 2016-10-19 Ceramatec Inc Method of producing coupled radical products via desulfoxylation
WO2014164523A1 (en) * 2013-03-12 2014-10-09 Dynamic Food Ingredients Corporation Methods for the electrolytic decarboxylation of sugars
EP2971255A4 (en) * 2013-03-15 2016-10-19 Ceramatec Inc Device and method for aryl-alkyl coupling using decarboxylation
KR20160062064A (en) 2013-09-24 2016-06-01 세라마테크, 인코오포레이티드 Molten carboxylate electrolytes for electrochemical decarboxylation processes
KR102163589B1 (en) * 2014-04-04 2020-10-08 에스케이이노베이션 주식회사 Electrolyte for Sodium Secondary Battery and Sodium Secondary Battery using thereof
BR112016029237A8 (en) * 2014-06-13 2018-08-14 Ceram Inc CONVERSION OF CARBOXYLIC ACIDS TO ALPHA-OLEFINS
CN107075698B (en) * 2014-07-15 2019-07-23 埃德沃克国际公司 For the high production rate Ke Erbei reaction process for being derived from the fatty acid of vegetable oil and animal tallow that is converted
DE102018000672A1 (en) 2018-01-29 2019-08-14 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Method for transferring a target substance between two liquid phases
CN110824807A (en) * 2019-12-13 2020-02-21 中国科学技术大学 A method for generating a speed-adjustable hydrogen radical beam source

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US9957622B2 (en) * 2009-07-23 2018-05-01 Field Upgrading Limited Device and method of obtaining diols and other chemicals using decarboxylation
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US5633400A (en) * 1993-01-06 1997-05-27 Hoechst Aktiengesellschaft Process for the preparation of biphenyl derivatives
US6362380B1 (en) * 1996-03-13 2002-03-26 Basf Aktiengesellschaft Preparation of nitrobiphenyls
US20080177114A1 (en) * 2005-05-10 2008-07-24 Studiengesellschaft Kohle Mbh Method For Decarboxylating C-C Cross-Linking Of Carboxylic Acids With Carbon Electrophiles

Also Published As

Publication number Publication date
WO2011011521A9 (en) 2011-07-07
US20110024288A1 (en) 2011-02-03
WO2011011521A2 (en) 2011-01-27

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