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WO2011011492A3 - Cellule de décarboxylation pour production de produits à radicaux couplés - Google Patents

Cellule de décarboxylation pour production de produits à radicaux couplés Download PDF

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Publication number
WO2011011492A3
WO2011011492A3 PCT/US2010/042715 US2010042715W WO2011011492A3 WO 2011011492 A3 WO2011011492 A3 WO 2011011492A3 US 2010042715 W US2010042715 W US 2010042715W WO 2011011492 A3 WO2011011492 A3 WO 2011011492A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal salt
radicals
alkali metal
coupled radical
electrolytic cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/042715
Other languages
English (en)
Other versions
WO2011011492A2 (fr
Inventor
Sai Bhavaraju
Mukund Karanjikar
Ashok Joshi
Joel Hunt
Pallavi Chitta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ceramatec Inc
Original Assignee
Ceramatec Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceramatec Inc filed Critical Ceramatec Inc
Priority to CN201080024541.8A priority Critical patent/CN102471903B/zh
Priority to BR112012001505-2A priority patent/BR112012001505A2/pt
Publication of WO2011011492A2 publication Critical patent/WO2011011492A2/fr
Publication of WO2011011492A3 publication Critical patent/WO2011011492A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/29—Coupling reactions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

L'invention porte sur une cellule électrolytique produisant des produits à radicaux couplés. Le procédé consiste à obtenir de l'acide carboxylique à partir d'une biomasse et à le convertir en sel de métal alcalin. Le sel de métal alcalin est ensuite utilisé dans un anolyte faisant partie d'une cellule électrolytique. La cellule électrolytique peut comprendre une membrane conductrice d'ions alcalins (telle qu'une membrane NaSICON). Lors du fonctionnement de la cellule, le sel de métal alcalin de l'acide carboxylique se décarboxyle et forme des radicaux. Ces radicaux sont ensuite liés à d'autres radicaux, donnant un produit à radicaux couplés tels qu'un hydrocarbure. L'hydrocarbure ainsi obtenu peut être par exemple saturé, insaturé, ramifié, ou non ramifié, selon le matériau de départ.
PCT/US2010/042715 2009-07-23 2010-07-21 Cellule de décarboxylation pour production de produits à radicaux couplés Ceased WO2011011492A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201080024541.8A CN102471903B (zh) 2009-07-23 2010-07-21 用于制备偶联自由基产物的脱羧电池
BR112012001505-2A BR112012001505A2 (pt) 2009-07-23 2010-07-21 célula de descarboxilação para produção de produtos radicais acoplados

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US22807809P 2009-07-23 2009-07-23
US61/228,078 2009-07-23
US25855709P 2009-11-05 2009-11-05
US61/258,557 2009-11-05
US26096109P 2009-11-13 2009-11-13
US61/260,961 2009-11-13

Publications (2)

Publication Number Publication Date
WO2011011492A2 WO2011011492A2 (fr) 2011-01-27
WO2011011492A3 true WO2011011492A3 (fr) 2011-06-16

Family

ID=43499642

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/042715 Ceased WO2011011492A2 (fr) 2009-07-23 2010-07-21 Cellule de décarboxylation pour production de produits à radicaux couplés

Country Status (4)

Country Link
CN (1) CN102471903B (fr)
BR (1) BR112012001505A2 (fr)
MY (1) MY155642A (fr)
WO (1) WO2011011492A2 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8853463B2 (en) 2011-01-25 2014-10-07 Ceramatec, Inc. Decarboxylation of levulinic acid to ketone solvents
WO2013096225A1 (fr) * 2011-12-19 2013-06-27 Ceramatec, Inc. Décarboxylation d'acide lévulinique en solvants de type cétone
CN104099120A (zh) * 2013-04-11 2014-10-15 中国科学院青岛生物能源与过程研究所 一种利用生物柴油制备航空液体燃料的方法
EP3194638B1 (fr) * 2014-09-15 2019-09-25 Advonex International Corp. Production d'hydrocarbures par décarboxylation par réaction de kolbe d'un mélange d'acides gras saturés et insaturés
CN110016689B (zh) * 2019-04-08 2021-01-15 天津大学 一种烯丙醇的电化学制备方法
CN110042420B (zh) * 2019-04-08 2021-01-15 天津大学 一种甲烷的电化学制备方法
CN110042419B (zh) * 2019-04-08 2021-01-15 天津大学 一种由衣康酸电解制备丙烷的方法
CN110016688B (zh) * 2019-04-08 2020-11-06 天津大学 一种醇类物质的电化学制备方法
CN110029355B (zh) * 2019-04-08 2021-01-15 天津大学 一种丙烷的电化学制备方法
CN109913891B (zh) * 2019-04-08 2021-01-15 天津大学 一种由丁二酸溶液电解制备甲烷的方法
CN110042418B (zh) * 2019-04-08 2021-01-15 天津大学 一种1,3,5-己三烯的电化学制备方法
CN110079821B (zh) * 2019-04-08 2021-01-15 天津大学 一种由低浓度己二酸溶液电解制备丙烷的方法
CN110004458B (zh) * 2019-04-08 2020-11-10 天津大学 一种丙烯醛的电化学制备方法
CN119177472B (zh) * 2024-11-22 2025-09-02 苏州大学 一种以无机固态电解质为隔膜进行电化学合成反应的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290405A (en) * 1991-05-24 1994-03-01 Ceramatec, Inc. NaOH production from ceramic electrolytic cell
US20050177008A1 (en) * 2003-12-11 2005-08-11 Shekar Balagopal Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes
US20090074611A1 (en) * 2005-09-15 2009-03-19 Battelle Memorial Institute Photolytic generation of hydrogen peroxide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7955489B2 (en) * 2006-02-08 2011-06-07 Dynamic Food Ingredients Corporation Methods for the electrolytic production of erythrose or erythritol
CN101089231A (zh) * 2007-07-16 2007-12-19 云南大学 芳基－1,3－二羰基化合物的电解氧化偶联及四氢呋喃类高效paf拮抗剂(反)－2,5－二(3,4,5－三甲氧基苯基)四氢呋喃及其类似物的合成方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290405A (en) * 1991-05-24 1994-03-01 Ceramatec, Inc. NaOH production from ceramic electrolytic cell
US20050177008A1 (en) * 2003-12-11 2005-08-11 Shekar Balagopal Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes
US20090074611A1 (en) * 2005-09-15 2009-03-19 Battelle Memorial Institute Photolytic generation of hydrogen peroxide

Also Published As

Publication number Publication date
CN102471903A (zh) 2012-05-23
WO2011011492A2 (fr) 2011-01-27
CN102471903B (zh) 2015-03-11
BR112012001505A2 (pt) 2020-10-27
MY155642A (en) 2015-11-13

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