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WO2011003767A3 - Method for transesterification using an inductively heated heating medium - Google Patents

Method for transesterification using an inductively heated heating medium Download PDF

Info

Publication number
WO2011003767A3
WO2011003767A3 PCT/EP2010/059154 EP2010059154W WO2011003767A3 WO 2011003767 A3 WO2011003767 A3 WO 2011003767A3 EP 2010059154 W EP2010059154 W EP 2010059154W WO 2011003767 A3 WO2011003767 A3 WO 2011003767A3
Authority
WO
WIPO (PCT)
Prior art keywords
transesterification
heating medium
inductively heated
heated heating
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/059154
Other languages
German (de)
French (fr)
Other versions
WO2011003767A2 (en
Inventor
Carsten Friese
Andreas Kirschning
Ludovic Coutable
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO2011003767A2 publication Critical patent/WO2011003767A2/en
Publication of WO2011003767A3 publication Critical patent/WO2011003767A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00327—Controlling the temperature by direct heat exchange
    • B01J2208/00336—Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
    • B01J2208/0038—Solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00433—Controlling the temperature using electromagnetic heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00433—Controlling the temperature using electromagnetic heating
    • B01J2208/00469—Radiofrequency
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00139—Controlling the temperature using electromagnetic heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00139—Controlling the temperature using electromagnetic heating
    • B01J2219/00148—Radiofrequency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention relates to a method for performing a transesterification reaction by heating a reaction mixture comprising at least one carboxylic acid ester and at least one alcohol as reactants in a reactor, wherein the transesterification reaction is performed in the presence of at least one metal catalyst substantially insoluble in the reaction mixture under the reaction conditions. The reaction mixture is in contact with a heating medium present within the reactor that can be heated in the present method by electromagnetic induction, and said medium is heated by electromagnetic induction by means of an inductor.
PCT/EP2010/059154 2009-07-08 2010-06-28 Method for transesterification using an inductively heated heating medium Ceased WO2011003767A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009027546.0 2009-07-08
DE102009027546A DE102009027546A1 (en) 2009-07-08 2009-07-08 Process for transesterification by means of an inductively heated heating medium

Publications (2)

Publication Number Publication Date
WO2011003767A2 WO2011003767A2 (en) 2011-01-13
WO2011003767A3 true WO2011003767A3 (en) 2011-04-28

Family

ID=43307651

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/059154 Ceased WO2011003767A2 (en) 2009-07-08 2010-06-28 Method for transesterification using an inductively heated heating medium

Country Status (2)

Country Link
DE (1) DE102009027546A1 (en)
WO (1) WO2011003767A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2839875A1 (en) * 2013-08-19 2015-02-25 Alnico Technologies Limited Magnet enhancement of chemical processes and magnetic field implementation for liquid quality enhancement

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5072027A (en) * 1988-10-06 1991-12-10 Hitachi Chemical Company, Ltd. Process for producing methacrylic acid esters
WO2003055837A1 (en) * 2002-01-04 2003-07-10 Röhm GmbH & Co. KG Method for the continuous production of alkyl (meth)acrylates
WO2003090669A2 (en) * 2002-04-25 2003-11-06 Aldivia S.A. Transesterification, esterification, interesterification me thods using dielectric heating
WO2009074373A1 (en) * 2007-12-11 2009-06-18 Henkel Ag & Co. Kgaa Method for carrying out chemical reactions with the aid of an inductively heated heating medium

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5183930A (en) * 1992-06-17 1993-02-02 Rohm And Haas Company Transesterification catalyst
DE10163399A1 (en) 2001-12-21 2003-07-10 Sustech Gmbh & Co Kg Nanoparticulate preparation
US7640477B2 (en) 2005-05-12 2009-12-29 Agilent Technologies, Inc. Calibration system that can be utilized with a plurality of test system topologies
DE102005051637A1 (en) 2005-10-26 2007-05-03 Atotech Deutschland Gmbh Reactor system with a microstructured reactor and method for carrying out a chemical reaction in such a reactor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5072027A (en) * 1988-10-06 1991-12-10 Hitachi Chemical Company, Ltd. Process for producing methacrylic acid esters
WO2003055837A1 (en) * 2002-01-04 2003-07-10 Röhm GmbH & Co. KG Method for the continuous production of alkyl (meth)acrylates
WO2003090669A2 (en) * 2002-04-25 2003-11-06 Aldivia S.A. Transesterification, esterification, interesterification me thods using dielectric heating
WO2009074373A1 (en) * 2007-12-11 2009-06-18 Henkel Ag & Co. Kgaa Method for carrying out chemical reactions with the aid of an inductively heated heating medium

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CLAUDINE BLANDY ET AL: "HOMOGENEOUS AND SUPPORTED TITANATES AS CATALYSTS FOR TRANSESTERIFICATION OF ACRYLIC ESTERS", CATALYSIS LETTERS, vol. 43, 1997, pages 139 - 142, XP002624270 *
GAUDINO M C ET AL: "Titanium-based solid catalysts for transesterification of methyl-methacrylate by 1-butanol: the homogeneous catalysis contribution", APPLIED CATALYSIS A: GENERAL, vol. 280, no. 2, 8 March 2005 (2005-03-08), pages 157 - 164, XP004739933 *

Also Published As

Publication number Publication date
DE102009027546A1 (en) 2011-01-13
WO2011003767A2 (en) 2011-01-13

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