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WO2011071237A3 - 프로필렌 중합용 고체촉매의 제조 방법 - Google Patents

프로필렌 중합용 고체촉매의 제조 방법 Download PDF

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Publication number
WO2011071237A3
WO2011071237A3 PCT/KR2010/006720 KR2010006720W WO2011071237A3 WO 2011071237 A3 WO2011071237 A3 WO 2011071237A3 KR 2010006720 W KR2010006720 W KR 2010006720W WO 2011071237 A3 WO2011071237 A3 WO 2011071237A3
Authority
WO
WIPO (PCT)
Prior art keywords
manufacturing
solid catalyst
propylene polymerization
tacticity
superior
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2010/006720
Other languages
English (en)
French (fr)
Other versions
WO2011071237A2 (ko
Inventor
김상열
박준려
김은일
이진우
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanwha TotalEnergies Petrochemical Co Ltd
Original Assignee
Samsung Total Petrochemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Total Petrochemicals Co Ltd filed Critical Samsung Total Petrochemicals Co Ltd
Priority to EP10836133.8A priority Critical patent/EP2511303B1/en
Priority to US13/514,673 priority patent/US8664142B2/en
Priority to JP2012539796A priority patent/JP5554416B2/ja
Priority to CN201080061607.0A priority patent/CN102712705B/zh
Publication of WO2011071237A2 publication Critical patent/WO2011071237A2/ko
Publication of WO2011071237A3 publication Critical patent/WO2011071237A3/ko
Anticipated expiration legal-status Critical
Priority to US14/016,537 priority patent/US9062135B2/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

본 발명은 프로필렌 중합용 고체촉매의 제조 방법에 관한 것으로서, 보다 상세하게는 높은 용융흐름지수와 넓은 분자량분포를 나타내고, 입체규칙성이 우수한 폴리프로필렌을 높은 수율로 중합할 수 있는 프로필렌 중합용 고체촉매의 제조 방법에 관한 것이다.
PCT/KR2010/006720 2009-12-08 2010-10-01 프로필렌 중합용 고체촉매의 제조 방법 Ceased WO2011071237A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP10836133.8A EP2511303B1 (en) 2009-12-08 2010-10-01 Manufacturing method of solid catalyst for propylene polymerization
US13/514,673 US8664142B2 (en) 2009-12-08 2010-10-01 Manufacturing method of solid catalyst for propylene polymerization
JP2012539796A JP5554416B2 (ja) 2009-12-08 2010-10-01 プロピレン重合用固体触媒の製造方法
CN201080061607.0A CN102712705B (zh) 2009-12-08 2010-10-01 丙烯聚合用固体催化剂的制备方法
US14/016,537 US9062135B2 (en) 2009-12-08 2013-09-03 Manufacturing method of solid catalyst for propylene polymerization

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020090121300A KR101114073B1 (ko) 2009-12-08 2009-12-08 프로필렌 중합용 고체촉매의 제조 방법
KR10-2009-0121300 2009-12-08

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/514,673 A-371-Of-International US8664142B2 (en) 2009-12-08 2010-10-01 Manufacturing method of solid catalyst for propylene polymerization
US14/016,537 Division US9062135B2 (en) 2009-12-08 2013-09-03 Manufacturing method of solid catalyst for propylene polymerization

Publications (2)

Publication Number Publication Date
WO2011071237A2 WO2011071237A2 (ko) 2011-06-16
WO2011071237A3 true WO2011071237A3 (ko) 2011-08-25

Family

ID=44146001

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/006720 Ceased WO2011071237A2 (ko) 2009-12-08 2010-10-01 프로필렌 중합용 고체촉매의 제조 방법

Country Status (6)

Country Link
US (2) US8664142B2 (ko)
EP (1) EP2511303B1 (ko)
JP (1) JP5554416B2 (ko)
KR (1) KR101114073B1 (ko)
CN (1) CN102712705B (ko)
WO (1) WO2011071237A2 (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013125504A1 (ja) * 2012-02-20 2013-08-29 サンアロマー株式会社 シート成形用ポリプロピレン系樹脂組成物
US9593184B2 (en) 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
US10339268B2 (en) * 2014-12-30 2019-07-02 Covidien Lp System and method for cytopathological and genetic data based treatment protocol identification and tracking
CN106317268A (zh) * 2015-06-19 2017-01-11 中国石油天然气股份有限公司 一种用于合成高流动聚丙烯的催化剂及其制备方法与应用
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US9815920B1 (en) 2016-10-14 2017-11-14 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US10822438B2 (en) 2017-05-09 2020-11-03 Formosa Plastics Corporation Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
US10124324B1 (en) 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
JP7429097B2 (ja) * 2019-06-07 2024-02-07 サンアロマー株式会社 ポリプロピレン系樹脂組成物の製造方法及びシート成形体の製造方法
CN117430735B (zh) * 2022-07-13 2025-10-14 中国石油化工股份有限公司 一种用于丙烯聚合的催化剂组分及其制备方法、催化剂和应用
US20250066513A1 (en) 2023-08-23 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization
US20250066514A1 (en) 2023-08-24 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
US20250115687A1 (en) 2023-10-06 2025-04-10 Formosa Plastics Corporation, U.S.A. Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins
US20250115686A1 (en) 2023-10-09 2025-04-10 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate
US20250297039A1 (en) 2024-03-19 2025-09-25 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5436213A (en) * 1991-10-02 1995-07-25 Borealis Holding A/S Procatalyst composition containing substituted maleic or fumaric acid esters as an electron donor for olefin polymerization
US6818583B1 (en) * 1999-04-15 2004-11-16 Basell Poliolefine Italia S.P.A. Components and catalysts for the polymerization of olefins
US20050080290A1 (en) * 2002-08-05 2005-04-14 Basell Poliolefine Italia S.P.A. Process for preparing alkylidene-substituted-1, 4-dions derivatives
US6914153B2 (en) * 2001-06-07 2005-07-05 Bassell Poliolefine Italia S.P.A. Process for preparing alkylidene substituted succinic acid esters
EP1272533B1 (en) * 2000-10-13 2008-09-03 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58138709A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS6155104A (ja) 1984-08-24 1986-03-19 Toho Titanium Co Ltd オレフィン類重合用触媒成分
EP0284005B1 (en) 1987-03-23 1991-12-18 Idemitsu Petrochemical Co. Ltd. Method of production of polyolefins
JP3399067B2 (ja) * 1992-12-23 2003-04-21 フイナ・テクノロジー・インコーポレーテツド ポリオレフインの多分散度の制御を行うためのチグラー・ナツタ触媒と組み合わせる電子供与体
JP3690765B2 (ja) * 1996-11-20 2005-08-31 三井化学株式会社 オレフィン重合用触媒、予備重合触媒、オレフィンの重合方法
US6376628B1 (en) 1998-05-21 2002-04-23 Grand Polymer Co., Ltd. Process for polymerization of alpha-olefin and alpha-olefin polymer
US6962889B2 (en) * 2004-01-28 2005-11-08 Engelhard Corporation Spherical catalyst for olefin polymerization

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5436213A (en) * 1991-10-02 1995-07-25 Borealis Holding A/S Procatalyst composition containing substituted maleic or fumaric acid esters as an electron donor for olefin polymerization
US6818583B1 (en) * 1999-04-15 2004-11-16 Basell Poliolefine Italia S.P.A. Components and catalysts for the polymerization of olefins
EP1272533B1 (en) * 2000-10-13 2008-09-03 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
US6914153B2 (en) * 2001-06-07 2005-07-05 Bassell Poliolefine Italia S.P.A. Process for preparing alkylidene substituted succinic acid esters
US20050080290A1 (en) * 2002-08-05 2005-04-14 Basell Poliolefine Italia S.P.A. Process for preparing alkylidene-substituted-1, 4-dions derivatives

Also Published As

Publication number Publication date
US8664142B2 (en) 2014-03-04
US9062135B2 (en) 2015-06-23
WO2011071237A2 (ko) 2011-06-16
EP2511303B1 (en) 2014-10-15
JP2013510941A (ja) 2013-03-28
JP5554416B2 (ja) 2014-07-23
EP2511303A4 (en) 2013-11-06
US20140005038A1 (en) 2014-01-02
KR101114073B1 (ko) 2012-02-22
EP2511303A2 (en) 2012-10-17
CN102712705A (zh) 2012-10-03
CN102712705B (zh) 2014-03-12
US20120264593A1 (en) 2012-10-18
KR20110064618A (ko) 2011-06-15

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