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WO2011069933A3 - Verfahren zur regenerierung eines ruthenium-haltigen geträgerten hydrierkatalysators - Google Patents

Verfahren zur regenerierung eines ruthenium-haltigen geträgerten hydrierkatalysators Download PDF

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Publication number
WO2011069933A3
WO2011069933A3 PCT/EP2010/068911 EP2010068911W WO2011069933A3 WO 2011069933 A3 WO2011069933 A3 WO 2011069933A3 EP 2010068911 W EP2010068911 W EP 2010068911W WO 2011069933 A3 WO2011069933 A3 WO 2011069933A3
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WO
WIPO (PCT)
Prior art keywords
containing ruthenium
catalyst containing
regenerating
hydrogenation catalyst
supported hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/068911
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English (en)
French (fr)
Other versions
WO2011069933A2 (de
Inventor
Daniela Mirk
Christoph Schappert
Uwe Stabel
Eberhardt Gaffron
Roman Prochazka
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BASF SE
Original Assignee
BASF SE
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Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP10787119A priority Critical patent/EP2509712A2/de
Priority to CN2010800560855A priority patent/CN102652037A/zh
Publication of WO2011069933A2 publication Critical patent/WO2011069933A2/de
Publication of WO2011069933A3 publication Critical patent/WO2011069933A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/06—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Verfahren zur Regenerierung eines Ruthenium-haltigen geträgerten Hydrierkatalysators, wobei der Katalysator mit Wasserdampf behandelt und danach getrocknet wird. Integriertes Verfahren zur Hydrierung von Benzol zu Cyclohexan in Gegenwart eines Ruthenium-haltigen geträgerten Katalysators, umfassend neben dem Hydrierschritt die Katalysator-Regenerierungsschritte.
PCT/EP2010/068911 2009-12-11 2010-12-06 Verfahren zur regenerierung eines ruthenium-haltigen geträgerten hydrierkatalysators Ceased WO2011069933A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP10787119A EP2509712A2 (de) 2009-12-11 2010-12-06 Verfahren zur regenerierung eines ruthenium-haltigen geträgerten hydrierkatalysators
CN2010800560855A CN102652037A (zh) 2009-12-11 2010-12-06 再生含钌的负载型氢化催化剂的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09178939 2009-12-11
EP09178939.6 2009-12-11

Publications (2)

Publication Number Publication Date
WO2011069933A2 WO2011069933A2 (de) 2011-06-16
WO2011069933A3 true WO2011069933A3 (de) 2011-10-13

Family

ID=43971286

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/068911 Ceased WO2011069933A2 (de) 2009-12-11 2010-12-06 Verfahren zur regenerierung eines ruthenium-haltigen geträgerten hydrierkatalysators

Country Status (4)

Country Link
US (1) US20110144398A1 (de)
EP (1) EP2509712A2 (de)
CN (1) CN102652037A (de)
WO (1) WO2011069933A2 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102753266B (zh) 2009-12-15 2015-09-02 巴斯夫欧洲公司 用于氢化芳族化合物的催化剂和方法
US8933262B2 (en) 2011-05-24 2015-01-13 Basf Se Process for preparing polyisocyanates from biomass
WO2013103392A1 (en) 2012-01-06 2013-07-11 Celanese International Corporation Hydrogenation catalyst and process for producing ethanol using the catalyst
WO2013103393A1 (en) 2012-01-06 2013-07-11 Celanese International Corporation Processes for making catalysts comprising precious metal and active metal modified support
US8815768B2 (en) 2012-01-06 2014-08-26 Celanese International Corporation Processes for making catalysts with acidic precursors
US8865609B2 (en) 2012-01-06 2014-10-21 Celanese International Corporation Hydrogenation catalysts
US8841230B2 (en) 2012-01-06 2014-09-23 Celanese International Corporation Processes for making catalysts with metal halide precursors
AU2012363796A1 (en) 2012-01-06 2014-07-03 Celanese International Corporation Cobalt-containing hydrogenation catalysts and processes for making same
US8980789B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Modified catalyst supports
CN109382095A (zh) * 2018-11-13 2019-02-26 江西理工大学 乙苯加氢制备乙基环己烷的催化剂及制备方法、应用
ES3014723T3 (en) * 2020-12-18 2025-04-24 Evonik Oxeno Gmbh & Co Kg Method for regenerating hydrogenation catalysts
US11918989B2 (en) 2020-12-18 2024-03-05 Evonik Operations Gmbh Process for regeneration of hydrogenation catalysts
CN114522707B (zh) * 2022-02-22 2023-07-21 中南大学 一种碱土金属碳酸盐负载纳米钌复合材料及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3753926A (en) * 1971-03-08 1973-08-21 Universal Oil Prod Co Regeneration of a coke deactivated catalyst comprising a combination of platinum rhenium and halogen with a porous carrier material
GB1452087A (en) * 1972-11-13 1976-10-06 Shell Int Research Process for regenerating a deactivated reforming catalyst
US5495055A (en) * 1994-08-12 1996-02-27 Arco Chemical Technology, L.P. Acetone hydrogenation using a supported ruthenium catalyst
DE102005029200A1 (de) * 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2757128A (en) * 1951-04-27 1956-07-31 Exxon Research Engineering Co Low pressure hydrogenation and hydrogen regeneration of the catalyst
US3245919A (en) * 1961-05-22 1966-04-12 Sinclair Refining Co Boehmite base precursor
US3851004A (en) * 1973-09-27 1974-11-26 Union Carbide Corp Hydrocarbon alkylation process using catalyst regeneration
US4431750A (en) * 1982-05-19 1984-02-14 Phillips Petroleum Company Platinum group metal catalyst on the surface of a support and a process for preparing same
CA1284982C (en) 1986-05-02 1991-06-18 Carmo Joseph Pereira Hydroprocessing catalyst and support having bidisperse pore structure
DE4128629A1 (de) 1991-08-29 1993-03-04 Basf Ag Silberhaltiger traegerkatalysator und verfahren zur katalytischen zersetzung von distickstoffmonoxid
US5817589A (en) 1996-04-02 1998-10-06 Intevep, S.A. Regeneration of catalyst comprising flushing with inert gas followed by flushing with hydrogen
US6248924B1 (en) 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
DE19917051A1 (de) 1999-04-15 2000-10-19 Basf Ag Verfahren zur Hydrierung von unsubstituierten oder alkylsubstituierten Aromaten unter Verwendung eines Makroporen aufweisenden Katalysators
DE10128205A1 (de) 2001-06-11 2002-12-12 Basf Ag Ruthenium-Katalysatoren
US7230035B2 (en) * 2002-12-30 2007-06-12 Conocophillips Company Catalysts for the conversion of methane to synthesis gas
DE10361157A1 (de) * 2003-12-22 2005-07-21 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I
WO2008015103A2 (de) 2006-07-31 2008-02-07 Basf Se Verfahren zur regenerierung von für die hydrierung geeigneten rutheniumkatalysatoren
WO2008015170A2 (de) 2006-07-31 2008-02-07 Basf Se Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol
JP4754519B2 (ja) 2007-03-27 2011-08-24 Ｊｘ日鉱日石エネルギー株式会社 改質触媒の再生方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3753926A (en) * 1971-03-08 1973-08-21 Universal Oil Prod Co Regeneration of a coke deactivated catalyst comprising a combination of platinum rhenium and halogen with a porous carrier material
GB1452087A (en) * 1972-11-13 1976-10-06 Shell Int Research Process for regenerating a deactivated reforming catalyst
US5495055A (en) * 1994-08-12 1996-02-27 Arco Chemical Technology, L.P. Acetone hydrogenation using a supported ruthenium catalyst
DE102005029200A1 (de) * 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen

Also Published As

Publication number Publication date
WO2011069933A2 (de) 2011-06-16
CN102652037A (zh) 2012-08-29
US20110144398A1 (en) 2011-06-16
EP2509712A2 (de) 2012-10-17

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