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WO2011069905A1 - Après-shampooing à phases multiples - Google Patents

Après-shampooing à phases multiples Download PDF

Info

Publication number
WO2011069905A1
WO2011069905A1 PCT/EP2010/068829 EP2010068829W WO2011069905A1 WO 2011069905 A1 WO2011069905 A1 WO 2011069905A1 EP 2010068829 W EP2010068829 W EP 2010068829W WO 2011069905 A1 WO2011069905 A1 WO 2011069905A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
composition according
water
distinct phases
chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/068829
Other languages
English (en)
Inventor
Tanapatr Barameesangpet
Busarin Kasemchainan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hindustan Unilever Ltd
Unilever NV
Original Assignee
Hindustan Unilever Ltd
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hindustan Unilever Ltd, Unilever NV filed Critical Hindustan Unilever Ltd
Priority to US13/512,898 priority Critical patent/US20120282209A1/en
Priority to JP2012542466A priority patent/JP2013513561A/ja
Priority to EP10787424A priority patent/EP2509573A1/fr
Priority to CN201080056174XA priority patent/CN102711723A/zh
Priority to BR112012012450A priority patent/BR112012012450A2/pt
Priority to EA201290483A priority patent/EA201290483A1/ru
Publication of WO2011069905A1 publication Critical patent/WO2011069905A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0233—Distinct layers, e.g. core/shell sticks
    • A61K8/0237—Striped compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a multiphase conditioning composition.
  • the present invention relates to a packaged multi-phase hair conditioner comprising at least two visibly distinct phases, said composition comprising a cationic surfactant and a water-swellable starch.
  • composition according to the invention presents visually distinct phases on extrusion immediately prior to use.
  • the visually distinct phases may be in contact in the package or they may be separated.
  • Examples of packaging which separates distinct phases which are extruded together include tubes with internal webs, side by side tube
  • Examples of packaging where at least some of the phases are in contact with one another inside the packaging are standard tubes whereby the distinct phases are co-extruded into the package in a pattern which reflects the pattern seen when the composition is extruded by the consumer immediately prior to use and the co-called shoulder-striping
  • At least one of the distinct phases is in contact with at least one other phase inside the packaging employed. More preferably, the arrangement of the phases inside the packaging employed reflects the
  • the composition has a viscosity of from 80 Pa.s to 200 Pa.s, preferably from 90 to 1 10 Pa.s as measured on a Brookfield viscometer at 30 C, 60 sec, cps (Brookfield RVT, Spindle TC, Speed 10 rpm, Helipath stand, 150 ml standard glass beaker).
  • a Brookfield viscometer at 30 C, 60 sec, cps (Brookfield RVT, Spindle TC, Speed 10 rpm, Helipath stand, 150 ml standard glass beaker).
  • the water swellable starch is non-ionic.
  • the water swellable starch is derived from maize.
  • the water swellable starch is a stabilized and cross-linked.
  • the water swellable starch is agglomerated pregelatinised starch.
  • the water swellable starch is hydroxypropylated.
  • Suitable water swellable starches include Structure XL ® ex. Akzo Nobel.
  • the composition is packaged in a deformable tube.
  • the tube will comprise a dispensing assembly which will comprise an exit orifice.
  • the exit orifice will have a diameter of from 7 to 10 mm so that the compositional arrangement of the visually distinct phases is maintained after extrusion immediately prior to use.
  • the visually distinct phases can be arranged in any pattern. Typical patterns include side by side, coaxial, striped and quartered.
  • the composition comprises two distinct phases which, when viewed in section transverse to the direction of extrusion from the package, are quartered.
  • quartered is meant that the face is cut into four sections by two transverse lines and the diagonally opposite sections, or quarters, are similarly coloured to each other and differently coloured to the other pair of quarters.
  • the composition comprises two distinct phases each of which may be present in from 1 to 4, preferably 2 portions.
  • the phases are present in equal measures.
  • the composition provides better manageability in dry hair.
  • composition according to the invention comprises one or more conditioning surfactants which are cosmetically acceptable and suitable for topical application to the hair.
  • Suitable conditioning surfactants are selected from cationic surfactants, used singly or in admixture. Examples include quaternary ammonium hydroxides or salts thereof, e.g. chlorides.
  • Suitable cationic surfactants for use in hair conditioners of the invention include cetyltrimethylammonium chloride, behenyltrimethylammonium chloride,
  • cetylpyridinium chloride tetramethylammonium chloride, tetraethylammonium chloride, octyltrimethylammonium chloride, dodecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, octyldimethylbenzylammonium chloride, decyldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride, didodecyldimethylammonium chloride, dioctadecyldimethylammonium chloride, tallowtrimethylammonium chloride, cocotrimethylammonium chloride, PEG-2 oleylammonium chloride and the corresponding hydroxides thereof.
  • Further suitable cationic surfactants include those materials having the CTFA designations
  • a particularly useful cationic surfactant for use in hair conditioners of the invention is cetyltrimethylammonium chloride, available commercially, for example as GENAMIN CTAC, ex Hoechst Celanese. Salts of primary, secondary, and tertiary fatty amines are also suitable cationic surfactants.
  • the alkyl groups of such amines preferably have from about 12 to about 22 carbon atoms, and can be substituted or unsubstituted. Particularly useful are amido substituted tertiary fatty amines.
  • Such amines, useful herein, include stearamidopropyldimethylamine,
  • arachidamidopropyldiethylamine arachidamidoethyldiethylamine
  • arachidamidoethyldimethylamine diethylaminoethylstearamide.
  • dimethylstearamine dimethylsoyamine, soyamine, myristylamine, tridecylamine, ethylstearylannine, N-tallowpropane diamine, ethoxylated (with 5 moles of ethylene oxide) stearylamine, dihydroxyethylstearylamine, and arachidyl behenylamine.
  • These amines are typically used in combination with an acid to provide the cationic species.
  • the preferred acid useful herein includes L- glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, L-glutamic hydrochloride, and mixtures thereof; more preferably L- glutamic acid, lactic acid, citric acid.
  • Cationic amine surfactants included among those useful in the present invention are disclosed in U.S. Patent 4,275,055 to Nachtigal, et al., issued June 23, 1981 .
  • the molar ratio of protonatable amines to H + from the acid is preferably from about 1 :0.3 to 1 :1 .2, and more preferably from about 1 :0.5 to about 1 :1 .1 .
  • the level of cationic surfactant is preferably from 0.01 to 10, more preferably 0.05 to 5, most preferably 0.1 to 2 wt% of the total
  • the conditioning composition may comprise any of a number of ingredients commonly found in conditioning compositions.
  • Conditioners of the invention preferably incorporate a fatty alcohol material.
  • fatty alcohol materials and cationic surfactants in conditioning compositions is believed to be especially advantageous, because this leads to the formation of a lamellar phase, in which the cationic surfactant is dispersed.
  • Representative fatty alcohols comprise from 8 to 22 carbon atoms, more preferably 16 to 20.
  • suitable fatty alcohols include cetyl alcohol, stearyl alcohol and mixtures thereof. The use of these materials is also advantageous in that they contribute to the overall conditioning properties of compositions of the invention.
  • the level of fatty alcohol material in conditioners of the invention is conveniently from 0.01 to 10, preferably from 0.1 to 5 wt% by weight of the total composition.
  • the weight ratio of cationic surfactant to fatty alcohol is suitably from 10:1 to 1 :10, preferably from 4:1 to 1 :8, optimally from 1 :1 to 1 :4.
  • the composition comprises silicones. Silicones which impart a
  • Suitable silicones have an average particle size of from 0.01 to 1 micron.
  • compositions of this invention may contain any other ingredient normally used in hair treatment formulations.
  • these other ingredients may include viscosity modifiers, preservatives, colouring agents, polyols such as glycerine and polypropylene glycol, chelating agents such as EDTA, antioxidants, fragrances, antimicrobials and sunscreens.
  • chelating agents such as EDTA
  • antioxidants such as glycerine
  • fragrances such as glycerine and polypropylene glycol
  • chelating agents such as EDTA
  • antioxidants such as glycerine and polypropylene glycol
  • chelating agents such as EDTA
  • antioxidants antioxidants
  • fragrances such as glycerine
  • sunscreens sunscreens.
  • Each of these ingredients will be present in an amount effective to accomplish its purpose.
  • these optional ingredients are included individually at a level of up to 5 wt% of the total composition.
  • compositions of this invention also contain adjuvants suitable for hair care.
  • such ingredients are
  • Suitable hair care adjuvants are:
  • natural hair root nutrients such as amino acids and sugars.
  • suitable amino acids include arginine, cysteine, glutamine, glutamic acid, isoleucine, leucine, methionine, serine and valine, and/or precursors and derivatives thereof.
  • the amino acids may be added singly, in mixtures, or in the form of peptides, e.g. di- and tripeptides.
  • the amino acids may also be added in the form of a protein hydrolysate, such as a keratin or collagen hydrolysate.
  • Suitable sugars are glucose, dextrose and fructose. These may be added singly or in the form of, e.g. fruit extracts.
  • a particularly preferred combination of natural hair root nutrients for inclusion in compositions of the invention is isoleucine and glucose.
  • a particularly preferred amino acid nutrient is arginine.
  • hair fibre benefit agents are: - ceramides, for moisturising the fibre and maintaining cuticle integrity.
  • Ceramides are available by extraction from natural sources, or as synthetic ceramides and pseudoceramides.
  • a preferred ceramide is Ceramide II, ex Quest. Mixtures of ceramides may also be suitable, such as Ceramides LS, ex Laboratoires Serobi Listes.
  • the composition comprises less than 5% wt. anionic surfactant. More preferably the composition comprises less than 3% wt. anionic surfactant and most preferably less than 1 % wt. anionic surfactant.
  • the invention will now be described with reference to the following non-limiting examples.
  • EXAMPLE 1 The following is a multi-phase conditioning composition.
  • composition according to example 1 is made by the following process. Add hot water (75-80°C) in the main mixer at medium speed.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention porte sur un après-shampooing à phases multiples, conditionné, qui comporte au moins deux phases visiblement distinctes, ladite composition comportant un surfactant non ionique et un amidon pouvant gonfler dans l'eau.
PCT/EP2010/068829 2009-12-11 2010-12-03 Après-shampooing à phases multiples Ceased WO2011069905A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US13/512,898 US20120282209A1 (en) 2009-12-11 2010-12-03 Multi-phase hair conditioner
JP2012542466A JP2013513561A (ja) 2009-12-11 2010-12-03 多相ヘアコンディショナー
EP10787424A EP2509573A1 (fr) 2009-12-11 2010-12-03 Après-shampooing à phases multiples
CN201080056174XA CN102711723A (zh) 2009-12-11 2010-12-03 多相头发调理剂
BR112012012450A BR112012012450A2 (pt) 2009-12-11 2010-12-03 "condicionador de cabelo multifásico"
EA201290483A EA201290483A1 (ru) 2009-12-11 2010-12-03 Многофазный кондиционер для волос

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09178961.0 2009-12-11
EP09178961 2009-12-11

Publications (1)

Publication Number Publication Date
WO2011069905A1 true WO2011069905A1 (fr) 2011-06-16

Family

ID=42124627

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/068829 Ceased WO2011069905A1 (fr) 2009-12-11 2010-12-03 Après-shampooing à phases multiples

Country Status (8)

Country Link
US (1) US20120282209A1 (fr)
EP (1) EP2509573A1 (fr)
JP (1) JP2013513561A (fr)
CN (1) CN102711723A (fr)
BR (1) BR112012012450A2 (fr)
EA (1) EA201290483A1 (fr)
TW (1) TW201143811A (fr)
WO (1) WO2011069905A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010138710A3 (fr) * 2009-05-29 2012-01-05 Johnson & Johnson Consumer Companies, Inc. Compositions topiques de soin de la peau

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292979A (zh) * 2014-07-28 2015-01-21 蚌埠首创滤清器有限公司 一种超滑易流动的丙烯酸树脂印刷油墨

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4275055A (en) 1979-06-22 1981-06-23 Conair Corporation Hair conditioner having a stabilized, pearlescent effect
US20050113269A1 (en) * 2003-11-26 2005-05-26 Landa Peter A. Increased moisturization efficacy using hydroxyalkylurea
WO2005065638A1 (fr) * 2003-12-24 2005-07-21 The Procter & Gamble Company Compositions de nettoyage personnel a phases multiples comprenant une phase de nettoyage moussant et une phase aqueuse structuree non moussante
WO2005105033A1 (fr) * 2004-04-21 2005-11-10 The Procter & Gamble Company Compositions de soins personnels deposant des agents benefiques hydrophiles
WO2006042183A1 (fr) * 2004-10-08 2006-04-20 The Procter & Gamble Company Composition de soins personnels stable multiphase
WO2006102113A2 (fr) * 2005-03-21 2006-09-28 The Procter & Gamble Company Composition de soin personnel a phases multiples comprenant des phases visuellement distinctes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2824733B1 (fr) * 2001-05-18 2005-12-09 Oreal Compositions cosmetiques contenant un amidon et un ester et leurs utilisations
JP4250104B2 (ja) * 2004-03-15 2009-04-08 ポーラ化成工業株式会社 アウトバス・トリートメント
US7976234B2 (en) * 2006-04-28 2011-07-12 James Alexander Corporation Multi-chambered dispenser and process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4275055A (en) 1979-06-22 1981-06-23 Conair Corporation Hair conditioner having a stabilized, pearlescent effect
US20050113269A1 (en) * 2003-11-26 2005-05-26 Landa Peter A. Increased moisturization efficacy using hydroxyalkylurea
WO2005065638A1 (fr) * 2003-12-24 2005-07-21 The Procter & Gamble Company Compositions de nettoyage personnel a phases multiples comprenant une phase de nettoyage moussant et une phase aqueuse structuree non moussante
WO2005105033A1 (fr) * 2004-04-21 2005-11-10 The Procter & Gamble Company Compositions de soins personnels deposant des agents benefiques hydrophiles
WO2006042183A1 (fr) * 2004-10-08 2006-04-20 The Procter & Gamble Company Composition de soins personnels stable multiphase
WO2006102113A2 (fr) * 2005-03-21 2006-09-28 The Procter & Gamble Company Composition de soin personnel a phases multiples comprenant des phases visuellement distinctes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010138710A3 (fr) * 2009-05-29 2012-01-05 Johnson & Johnson Consumer Companies, Inc. Compositions topiques de soin de la peau

Also Published As

Publication number Publication date
CN102711723A (zh) 2012-10-03
EP2509573A1 (fr) 2012-10-17
TW201143811A (en) 2011-12-16
US20120282209A1 (en) 2012-11-08
BR112012012450A2 (pt) 2019-09-24
JP2013513561A (ja) 2013-04-22
EA201290483A1 (ru) 2012-11-30

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