[go: up one dir, main page]

WO2010124172A3 - A metal air battery system - Google Patents

A metal air battery system Download PDF

Info

Publication number
WO2010124172A3
WO2010124172A3 PCT/US2010/032182 US2010032182W WO2010124172A3 WO 2010124172 A3 WO2010124172 A3 WO 2010124172A3 US 2010032182 W US2010032182 W US 2010032182W WO 2010124172 A3 WO2010124172 A3 WO 2010124172A3
Authority
WO
WIPO (PCT)
Prior art keywords
solvent
oxygen
dissolution
metal oxide
electrodes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/032182
Other languages
French (fr)
Other versions
WO2010124172A2 (en
Inventor
Rachid Yazami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
California Institute of Technology
Original Assignee
Centre National de la Recherche Scientifique CNRS
California Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/612,409 external-priority patent/US20100141211A1/en
Application filed by Centre National de la Recherche Scientifique CNRS, California Institute of Technology filed Critical Centre National de la Recherche Scientifique CNRS
Publication of WO2010124172A2 publication Critical patent/WO2010124172A2/en
Publication of WO2010124172A3 publication Critical patent/WO2010124172A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H01M4/608—Polymers containing aromatic main chain polymers containing heterocyclic rings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/72—Grids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/808—Foamed, spongy materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Inert Electrodes (AREA)
  • Secondary Cells (AREA)

Abstract

Described herein are electrodes comprising a fluorinated or metalloprotein oxygen dissolution enhancer provided in a solvent for enhancing dissolution of oxygen in the solvent. In related embodiments, a metal oxide dissolution enhancer is provided in the solvent for enhancing dissolution of metal oxide formed via reaction of oxygen with metal ions in the solvent. The oxygen and metal oxide dissolution enhancers of electrodes and electrochemical generators described herein enable an increased oxidation and/or reduction rate and enhance the stability and efficiency of the electrochemical generators described herein. Positive electrodes described herein, for example, are highly versatile and compatible with a wide range of solid state and liquid anode and electrolyte systems, including anodes comprising readily available and inexpensive materials such as solvated electron solutions as well as a range of solid state anodes.
PCT/US2010/032182 2009-04-23 2010-04-23 A metal air battery system Ceased WO2010124172A2 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US17211409P 2009-04-23 2009-04-23
US61/172,114 2009-04-23
US24788209P 2009-10-01 2009-10-01
US61/247,882 2009-10-01
US12/612,409 US20100141211A1 (en) 2008-11-04 2009-11-04 Hybrid electrochemical generator with a soluble anode
US12/612,409 2009-11-04
PCT/US2009/063235 WO2010053962A1 (en) 2008-11-04 2009-11-04 Hybrid electrochemical generator with a soluble anode
USPCT/US2009/063235 2009-11-04

Publications (2)

Publication Number Publication Date
WO2010124172A2 WO2010124172A2 (en) 2010-10-28
WO2010124172A3 true WO2010124172A3 (en) 2011-01-20

Family

ID=43011761

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/032182 Ceased WO2010124172A2 (en) 2009-04-23 2010-04-23 A metal air battery system

Country Status (1)

Country Link
WO (1) WO2010124172A2 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9431660B2 (en) 2010-09-23 2016-08-30 Robert Bosch Gmbh Lithium battery with charging redox couple
KR20140096983A (en) * 2011-11-22 2014-08-06 로베르트 보쉬 게엠베하 Lithium battery with charging redox couple
CN102794200B (en) * 2012-08-31 2014-11-05 华南师范大学 Preparation method of anode catalyst used for microbial fuel cells and application thereof
WO2014133466A1 (en) * 2013-02-28 2014-09-04 Nanyang Technological University Ionic liquid electrolyte and fluorinated carbon electrode
US10611020B2 (en) 2013-12-19 2020-04-07 Roam Robotics Inc. Pneumatic exomuscle system and method
ES2969892T3 (en) 2017-02-03 2024-05-23 Roam Robotics Inc System and method for user intent recognition
EP3648726B1 (en) 2017-08-29 2025-08-27 Roam Robotics Inc. Semi-supervised intent recognition system and method
CN111755670B (en) * 2019-03-28 2021-11-30 中国科学院物理研究所 Anode material, preparation method and application of lithium battery
ES3039928T3 (en) 2019-12-13 2025-10-27 Roam Robotics Inc Powered device to benefit a wearer during skiing
US11695176B2 (en) * 2020-05-06 2023-07-04 Revolution Power Inc. Zinc-air battery compositions and methods
US20210370495A1 (en) 2020-05-27 2021-12-02 Roam Robotics Inc. Powered medical device and methods for improved user mobility and treatment
CA3179856A1 (en) 2020-05-27 2021-12-02 Callum Lamb Fit and suspension systems and methods for a mobile robot
CN112382769B (en) * 2020-11-04 2021-10-15 江苏科技大学 A high-performance metal-air battery cathode catalyst and preparation method thereof
JP2024534808A (en) 2021-08-17 2024-09-26 ローム ロボティクス インコーポレイテッド Maritime Applications for Mobile Robots
WO2023023567A1 (en) 2021-08-17 2023-02-23 Roam Robotics Inc. Mobile power source for a mobile robot

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6376123B1 (en) * 1994-11-23 2002-04-23 Polyplus Battery Company Rechargeable positive electrodes
US20020155330A1 (en) * 2001-02-20 2002-10-24 Hideaki Tanaka Fuel cell system and hydrogen-generating system therefor
US20070269688A1 (en) * 2004-05-19 2007-11-22 Sri International Liquid anode electrochemical cell
US20080280191A1 (en) * 2007-05-09 2008-11-13 Rachid Yazami Lithium fluoropolymer and fluoro-organic batteries

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6376123B1 (en) * 1994-11-23 2002-04-23 Polyplus Battery Company Rechargeable positive electrodes
US20020155330A1 (en) * 2001-02-20 2002-10-24 Hideaki Tanaka Fuel cell system and hydrogen-generating system therefor
US20070269688A1 (en) * 2004-05-19 2007-11-22 Sri International Liquid anode electrochemical cell
US20080280191A1 (en) * 2007-05-09 2008-11-13 Rachid Yazami Lithium fluoropolymer and fluoro-organic batteries

Also Published As

Publication number Publication date
WO2010124172A2 (en) 2010-10-28

Similar Documents

Publication Publication Date Title
WO2010124172A3 (en) A metal air battery system
Xu et al. Optimizing the power of enzyme-based membrane-less hydrogen fuel cells for hydrogen-rich H 2–air mixtures
Leong et al. Doubling the power output of a Mg-air battery with an acid-salt dual-electrolyte configuration
AU2012364773B2 (en) Aluminum-based metal-air batteries
WO2009139947A3 (en) Permselective membrane-free direct fuel cell and components thereof
WO2005038962A3 (en) Ionically conductive membranes for protection of active metal anodes and battery cells
US20130202954A1 (en) Magnesium battery
MX2011011501A (en) Single wall carbon nanotube based air cathodes.
WO2005048385A3 (en) Active metal fuel cells
WO2005038953A3 (en) Active metal/aqueous electrochemical cells and systems
WO2010005686A3 (en) Aqueous lithium/air battery cells
WO2005083829A3 (en) Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
ZA200708836B (en) Alkaline cell anode casing
WO2014014548A3 (en) Metal-air flow batteries using oxygen enriched electrolyte
WO2004033760A3 (en) Electrochemical reduction of metal oxides
EP2096695A3 (en) Solid oxide electrochemical cell and processes for producing the same
JP2018521462A5 (en)
EP2727882A8 (en) Carbon dioxide enrichment device
SG10201901001YA (en) A battery system
MX379432B (en) Electrolytic generation of manganese (iii) ions in strong sulfuric acid
JP2010182435A (en) Magnesium cell
WO2011149908A3 (en) System and method for energy storage and recovery
CA2642544A1 (en) Proton conductive electrolyte and electrochemical cell having the same
EP1536505A3 (en) Fuel electrode for solid oxide fuel cell and solid oxide fuel cell using the same
MX375866B (en) ELECTROCHEMICAL SYSTEMS THAT INCORPORATE HIGH NEGATIVE HALF-CELL POTENTIALS.

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10767820

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 10767820

Country of ref document: EP

Kind code of ref document: A2