WO2010121517A1 - High-elongation rate aluminum alloy material for cable and preparation method thereof - Google Patents
High-elongation rate aluminum alloy material for cable and preparation method thereof Download PDFInfo
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- WO2010121517A1 WO2010121517A1 PCT/CN2010/071654 CN2010071654W WO2010121517A1 WO 2010121517 A1 WO2010121517 A1 WO 2010121517A1 CN 2010071654 W CN2010071654 W CN 2010071654W WO 2010121517 A1 WO2010121517 A1 WO 2010121517A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/002—Castings of light metals
- B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
Definitions
- the invention belongs to the field of non-ferrous metal materials, and particularly relates to a high elongation aluminum alloy material for cables and a preparation method thereof.
- the wire and cable have a high elongation and high safety and stability in use.
- a high elongation aluminum alloy material for cable which comprises the following components in a percentage by weight: 0.30 to 1.20% iron, 0.03 to 0.10% silicon, 0.01 ⁇ 0.30% of rare earth elements, the rare earth elements are lanthanum and cerium, and the balance is aluminum and unavoidable impurities.
- Another object of the present invention is to provide a method of preparing a high elongation aluminum alloy material comprising the steps of:
- the aluminum alloy body obtained by the semi-annealing treatment is kept at 280-380 ° C for 4 to 10 hours, and then taken out and naturally cooled to ambient temperature.
- the aluminum alloy material further includes unavoidable impurity elements, and the total content of impurities in the aluminum alloy is ⁇ 0.3% by weight.
- the content of calcium in the impurities is ⁇ 0.02%, and the content of other single impurity elements is ⁇ 0.01% to reduce the influence of the impurity element on the electrical conductivity of the aluminum alloy.
- the high elongation aluminum alloy for cable used in the present invention is a novel Al-Fe alloy material, and has the following advantages:
- the content of iron in the invention is controlled between 0.30 and 1.20%, which can improve the strength of the aluminum alloy, and also improve the creep resistance and thermal stability of the aluminum alloy, and the creep resistance is improved by 300 compared with the ordinary electrician. %; and iron can also enhance the toughness of the aluminum alloy, ensuring that the compaction coefficient of the aluminum alloy in the process of tightening and twisting reaches 0.93 or more, which is not achievable by ordinary electrician aluminum, and is made of the aluminum alloy.
- the compacted core can increase the conductor cross section, improve the electrical conductivity of the conductor and increase the stability of the conductor, and can save processing costs.
- the content of silicon in the present invention is controlled between 0.03% and 0.10%, which ensures a certain amount of silicon to enhance the strength of the aluminum alloy.
- the rare earth element in the present invention can reduce the content of silicon, thereby reducing the influence of iron, especially silicon, on the electrical conductivity of the aluminum alloy to a very low level, and the addition of the rare earth element also improves the crystal in the aluminum alloy material.
- the structure of the structure improves the process performance of the aluminum alloy and is beneficial to the processing of the aluminum alloy.
- the rare earth element in the present invention is mainly composed of lanthanum and cerium, and the performance in 3) can be satisfactorily achieved.
- the boron element in the present invention can react with impurity elements such as Ti, V, Mn, Cr, etc., and is precipitated after being formed, thereby reducing the influence of impurity elements such as Ti, V, Mn, Cr on the electrical conductivity of the aluminum alloy. Conducive to improve the electrical conductivity of aluminum alloy.
- the alloy material is semi-annealed to improve the adverse effect of the stress on the conductor structure during the drawing and stranding process, so that the conductivity reaches or exceeds 61% IACS (for ordinary electricians)
- the conductivity standard of the aluminum conductor is 61% IACS
- the annealing treatment can greatly improve the elongation and flexibility of the aluminum alloy.
- the elongation of the cable made of the aluminum alloy of the invention reaches 30%, and the flexibility is better than that of the copper cable.
- the height is 25%, the bending radius is only 7 times the outer diameter, and the bending radius of the copper cable is 15 times the outer diameter.
- the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
- the temperature is controlled at 710-750 °C; when adding rare earth aluminum alloy and boron aluminum alloy to the above aluminum alloy liquid, the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
- the aluminum alloy rod rolled from the aluminum alloy material is kept at 280 ° C to 300 ° C for 10 hours in an annealing furnace, and then taken out and naturally cooled to ambient temperature.
- the aluminum alloy material thus obtained contains, according to the weight percentage, the following components: Fe 0.3%, Si 0.03%, Ce 0.008%, La 0.002%, B0.005%, Ca 0.015%, Cu 0.002%, Mg 0.005%, Zn 0.002%, Ti 0.002%, V0.005%, Mn 0.002%, Cr 0.001%, and the balance is Al.
- the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
- the content of impurities in the aluminum alloy material is ⁇ 0.3% in total, and the content of other single impurity elements is ⁇ 0.01% except for Ca ⁇ 0.02%.
- Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM.
- the test method described in B193 the flexibility is in accordance with the test method of "partial discharge test after bending test” described in GB 12706.1, and the creep is tested according to the creep test of the "Wire and Cable” manual.
- the temperature is controlled at 710-750 °C; when adding rare earth aluminum alloy and boron aluminum alloy to the above aluminum alloy liquid, the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
- Rare earth treatment and boronization treatment 4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling. 4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling. The rare earth aluminum alloy and the boron aluminum alloy are added in different time periods in order to make the rare earth and boron elements fully function and improve the effect. 4.3 The position of the rare earth aluminum alloy and the boron aluminum alloy is uniformly distributed in the holding furnace.
- refining de-slag, degassing, stirring, slag
- the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
- 2.3 kg of powder refining agent (23% Na 3 Al•F6+47%KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through a high-purity nitrogen gas through the pipeline.
- the bottom of the aluminum alloy liquid moves, so that the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes.
- the floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
- the aluminum alloy rod rolled from the aluminum alloy material is kept in an annealing furnace at 360 ° C to 380 ° C for 4 hours, and then taken out and naturally cooled to ambient temperature.
- the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
- the content of impurities in the aluminum alloy material is ⁇ 0.3% in total, and the content of other single impurity elements is ⁇ 0.01% except for Ca ⁇ 0.02%.
- the performance test data of the high elongation aluminum alloy material in this example is as follows:
- Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM.
- the test method described in B193 the flexibility is in accordance with the test method of "partial discharge test after bending test” described in GB12706.1, and the creep is in accordance with the method of creep test of the "Wire and Cable” manual.
- the performance of the aluminum alloy material with high conductivity, high elongation, high flexibility and high creep resistance in this example is: partial discharge test after tensile strength 92 MPa, elongation 36%, electrical conductivity 61.0% IACS, 7 times bending radius Qualified and creep resistant is increased by 330% compared to electrical aluminum.
- the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
- the temperature is controlled at 710-750 °C.
- the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
- Rare earth treatment and boronization treatment 4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling. 4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling. 4.3 The location of the rare earth aluminum alloy and boron aluminum alloy should be evenly distributed in the holding furnace.
- refining de-slag, degassing, stirring, slag
- the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
- 2.8 kg of powder refining agent (23% Na 3 Al•F 6+47% KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through high-purity nitrogen through a pipe, and the inlet should be blown.
- the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes.
- the floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
- the aluminum alloy rod rolled from the aluminum alloy material is kept in an annealing furnace at 300 ° C to 320 ° C for 8 hours, and then taken out and naturally cooled to ambient temperature.
- the aluminum alloy material thus obtained contains the following components in terms of weight percentage: Fe 0.55%, Si 0.10%, Ce 0.15%, La 0.06%, B0.007%, Ca 0.013%, Cu 0.003%, Mg 0.004%, Zn 0.004%, Ti 0.002%, V 0.004%, Mn 0.003%, Cr 0.002%, and the balance is Al.
- the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
- the content of impurities in the aluminum alloy material is ⁇ 0.3% in total, and the content of other single impurity elements is ⁇ 0.01% except for Ca ⁇ 0.02%.
- Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM.
- the test method described in B193 the flexibility according to the test method of "partial discharge test after bending test” described in GB 12706.1, creep according to the "wire and cable” manual creep test method.
- the properties of the high elongation aluminum alloy material in this example are: tensile strength 110 MPa, elongation 30.2%, electrical conductivity 62.6% IACS, 6 times bending radius after partial discharge test pass, creep resistance is increased by 330% compared with electrical aluminum.
- the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
- the temperature is controlled at 710-750 °C.
- the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
- Rare earth treatment and boronization treatment 4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling. 4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling. 4.3 The location of the rare earth aluminum alloy and boron aluminum alloy should be evenly distributed in the holding furnace.
- refining de-slag, degassing, stirring, slag
- the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
- 2.0kg of powder refining agent (23% Na 3 Al•F6+47%KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through high-purity nitrogen gas through the pipeline.
- the bottom of the aluminum alloy liquid moves, so that the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes.
- the floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
- the aluminum alloy rod rolled from the aluminum alloy material is incubated at 340 ° C to 360 ° C for 6 hours in an annealing furnace, and then taken out and naturally cooled to ambient temperature.
- the aluminum alloy material thus obtained contains the following components in terms of weight percent: Fe 0.80%, Si 0.04%, Ce 0.10%, La 0.06%, B0.008%, Ca 0.011%, Cu 0.005%, Mg 0.004%, Zn0.006% Ti 0.003%, V0.003%, Mn 0.005%, Cr 0.002%, and the balance is Al.
- the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
- the content of impurities in the aluminum alloy material is ⁇ 0.3% in total, and the content of other single impurity elements is ⁇ 0.01% except for Ca ⁇ 0.02%.
- the performance test data of the high elongation aluminum alloy material in this example is as follows:
- Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM.
- the test method described in B193 the flexibility according to the test method of "partial discharge test after bending test” described in GB 12706.1, creep according to the "wire and cable” manual creep test method.
- the properties of the high elongation aluminum alloy material in this example are: tensile strength 97 MPa, elongation 35.2%, electrical conductivity After 62.0% IACS, 6 times bending radius, the partial discharge test was qualified, and the creep resistance was increased by 330% compared with the electrical aluminum.
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Abstract
Description
本发明属于有色金属材料领域,具体涉及一种电缆用高延伸率铝合金材料及其制备方法。 The invention belongs to the field of non-ferrous metal materials, and particularly relates to a high elongation aluminum alloy material for cables and a preparation method thereof.
目前电线电缆大部分采用铜作为导体,由于铜资源匮乏、铜价过高以及铜缆安装成本高从而限制了电线电缆的发展。因为铝资源丰富且成本低,以铝代替铜作为导体用于电线电缆将是一种趋势。 At present, most of the wire and cable use copper as a conductor, which limits the development of wire and cable due to lack of copper resources, high copper price and high installation cost of copper cables. Because aluminum is rich in resources and low in cost, it is a trend to use aluminum instead of copper as a conductor for wire and cable.
但是用普通电工铝作为导体时电线电缆的延伸率、柔韧性和抗蠕变性能都较差,且使用安全稳定性低,因而使用普通电工铝代替铜作为导体无法满足电线电缆发展的需要。 However, when ordinary electrical aluminum is used as the conductor, the elongation, flexibility and creep resistance of the wire and cable are poor, and the safety and stability of use are low. Therefore, the use of ordinary electrical aluminum instead of copper as a conductor cannot meet the development of wire and cable.
本发明的目的是提供一种电缆用高延伸率铝合金材料,采用本发明中的铝合金作为导体时电线电缆具有较高的延伸率,且使用安全稳定性高。 It is an object of the present invention to provide a high elongation aluminum alloy material for a cable. When the aluminum alloy of the present invention is used as a conductor, the wire and cable have a high elongation and high safety and stability in use.
为实现上述目的,本发明采用了以下技术方案:一种电缆用高延伸率铝合金材料,按重量百分比含量,其包括下列组分:0.30~1.20%的铁,0.03~0.10%的硅,0.01~0.30%的稀土元素,所述的稀土元素为铈和镧,余量为铝以及不可避免的杂质。In order to achieve the above object, the present invention adopts the following technical solution: a high elongation aluminum alloy material for cable, which comprises the following components in a percentage by weight: 0.30 to 1.20% iron, 0.03 to 0.10% silicon, 0.01 ~0.30% of rare earth elements, the rare earth elements are lanthanum and cerium, and the balance is aluminum and unavoidable impurities.
本发明的另外一个目的是提供一种制备高延伸率铝合金材料的方法,包括如下步骤:Another object of the present invention is to provide a method of preparing a high elongation aluminum alloy material comprising the steps of:
1)熔铸
先加92~98重量份的含硅、铁的铝合金和0.73~5.26重量份的铝铁合金,加热至710~750℃熔化;再加热至720~760℃,投加1~3重量份的稀土铝合金以及0.17~0.67重量份的硼铝合金,所述稀土铝合金为铝与稀土元素铈和镧的合金;随后投加0.04~0.06重量份的精炼剂精炼8~20分钟;然后静置保温20~40分钟后,进行铸造;1) First, add 92-98 parts by weight of aluminum-containing and iron-containing aluminum alloy and 0.73 to 5.26 parts by weight of aluminum-iron alloy, and heat to 710-750 ° C for melting; then heat to 720-760 ° C, add 1 to 3 weight. a rare earth aluminum alloy and 0.17 to 0.67 parts by weight of a boron aluminum alloy, the rare earth aluminum alloy being an alloy of aluminum and a rare earth element lanthanum and cerium; and then adding 0.04 to 0.06 parts by weight of a refining agent for 8 to 20 minutes; After standing for 20 to 40 minutes, casting is performed;
2)半退火处理
铸造所得铝合金体在280~380℃下保温4~10个小时,然后取出自然冷却至环境温度。2) The aluminum alloy body obtained by the semi-annealing treatment is kept at 280-380 ° C for 4 to 10 hours, and then taken out and naturally cooled to ambient temperature.
所述铝合金材料还包括不可避免的杂质元素,按照重量百分比含量,铝合金中的杂质的总含量<0.3%。The aluminum alloy material further includes unavoidable impurity elements, and the total content of impurities in the aluminum alloy is <0.3% by weight.
进一步的,杂质中钙的含量<0.02%,其它单种杂质元素的含量<0.01%,以降低杂质元素对铝合金导电率的影响。Further, the content of calcium in the impurities is <0.02%, and the content of other single impurity elements is <0.01% to reduce the influence of the impurity element on the electrical conductivity of the aluminum alloy.
本发明所得的电缆用高延伸率铝合金为新型的Al-Fe系合金材料,具有如下优点:The high elongation aluminum alloy for cable used in the present invention is a novel Al-Fe alloy material, and has the following advantages:
1)本发明中铁的含量控制在0.30~1.20%之间,能提高铝合金的强度,同时还提高了铝合金的抗蠕变性和热稳定性,抗蠕变性相对普通电工用铝提高300%;而且铁还能使铝合金的韧性增强,保证了铝合金在紧压绞制过程中的紧压系数达到0.93以上,而普通电工用铝是无法达到的,用这种铝合金制成的紧压线芯相比于同等导体外径条件下的普通电工用铝导体,能增大导体截面,提高导体的导电性能和增加导体的稳定性并且能节约加工成本。1) The content of iron in the invention is controlled between 0.30 and 1.20%, which can improve the strength of the aluminum alloy, and also improve the creep resistance and thermal stability of the aluminum alloy, and the creep resistance is improved by 300 compared with the ordinary electrician. %; and iron can also enhance the toughness of the aluminum alloy, ensuring that the compaction coefficient of the aluminum alloy in the process of tightening and twisting reaches 0.93 or more, which is not achievable by ordinary electrician aluminum, and is made of the aluminum alloy. Compared with the ordinary electrical aluminum conductor under the condition of the outer diameter of the same conductor, the compacted core can increase the conductor cross section, improve the electrical conductivity of the conductor and increase the stability of the conductor, and can save processing costs.
2)本发明中硅的含量控制在0.03%-0.10%之间,保证了一定量的硅对铝合金强度的增强作用。2) The content of silicon in the present invention is controlled between 0.03% and 0.10%, which ensures a certain amount of silicon to enhance the strength of the aluminum alloy.
3)本发明中的稀土元素能降低硅的含量,从而将铁、尤其是硅对铝合金导电率的影响减小至非常低的水平,同时稀土元素的加入还改善了铝合金材料中晶体的组织结构,提高了铝合金的工艺性能,有利于铝合金的加工处理。3) The rare earth element in the present invention can reduce the content of silicon, thereby reducing the influence of iron, especially silicon, on the electrical conductivity of the aluminum alloy to a very low level, and the addition of the rare earth element also improves the crystal in the aluminum alloy material. The structure of the structure improves the process performance of the aluminum alloy and is beneficial to the processing of the aluminum alloy.
4)本发明中的稀土元素以铈和镧为主,能够良好的实现3)中的性能。4) The rare earth element in the present invention is mainly composed of lanthanum and cerium, and the performance in 3) can be satisfactorily achieved.
5)本发明中的硼元素可与Ti、V、Mn、Cr等杂质元素反应,形成化合物后被沉淀排除,从而降低Ti、V、Mn、Cr等杂质元素对铝合金导电率的影响,有利于提高铝合金的导电率。5) The boron element in the present invention can react with impurity elements such as Ti, V, Mn, Cr, etc., and is precipitated after being formed, thereby reducing the influence of impurity elements such as Ti, V, Mn, Cr on the electrical conductivity of the aluminum alloy. Conducive to improve the electrical conductivity of aluminum alloy.
6)本发明中制备铝合金时对合金材料进行了半退火处理,改善了拉制、绞制过程中应力作用对导体组织结构的不利影响,使导电率达到甚至超过61%IACS(普通电工用铝导体的导电率标准是61%IACS),同时退火处理能极大的提高铝合金的延伸率和柔韧性,本发明的铝合金制成的电缆的延伸率达到30%,柔韧性比铜缆高25%,弯曲半径仅为7倍外径,而铜缆的弯曲半径为15倍外径。6) In the preparation of the aluminum alloy in the invention, the alloy material is semi-annealed to improve the adverse effect of the stress on the conductor structure during the drawing and stranding process, so that the conductivity reaches or exceeds 61% IACS (for ordinary electricians) The conductivity standard of the aluminum conductor is 61% IACS), and the annealing treatment can greatly improve the elongation and flexibility of the aluminum alloy. The elongation of the cable made of the aluminum alloy of the invention reaches 30%, and the flexibility is better than that of the copper cable. The height is 25%, the bending radius is only 7 times the outer diameter, and the bending radius of the copper cable is 15 times the outer diameter.
实施例1:Example 1:
一、熔铸工艺First, the melting process
1、配料
5100kg的铝锭(0.07%Si含量,0.13%Fe含量)、40.4kg铝铁合金(22%Fe含量)、5.6kg稀土合金(10%稀土含量)、8.8kg硼铝合金(3.5%
B含量)、2.3kg精炼剂(23%Na3Al•F6+47%KCl+30%NaCl)。1, ingredients
5100kg aluminum ingot (0.07% Si content, 0.13% Fe content), 40.4kg aluminum-iron alloy (22% Fe content), 5.6kg rare earth alloy (10% rare earth content), 8.8kg boron aluminum alloy (3.5% B content), 2.3 kg of refining agent (23% Na 3 Al•F6+47% KCl+30% NaCl).
2、加料方式
加料时铝铁合金随铝锭搭配均匀分批地从冲天炉加入,以保证成分尽可能的均匀。2. When the feeding method is added, the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
3、保温工艺
铝合金液体流入保温炉时温度控制在710~750℃;向前述铝合金液体中加入稀土铝合金和硼铝合金时温度应提升至720~760℃,且温度不得超过760℃,此时升高温度有利于稀土铝合金和硼铝合金的熔融,从而提高了稀土和硼的处理效果。3. Insulation process When the aluminum alloy liquid flows into the holding furnace, the temperature is controlled at 710-750 °C; when adding rare earth aluminum alloy and boron aluminum alloy to the above aluminum alloy liquid, the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
4、稀土处理和硼化处理
4.1保温炉铝合金液体充满前30分钟加入1/3稀土铝合金。
4.2保温炉铝合金液体充满前5分钟加入其余2/3稀土铝合金和硼铝合金。
在不同时间段内加入稀土铝合金和硼铝合金是为了使稀土和硼元素能充分发挥作用,提高其作用效果。
4.3稀土铝合金和硼铝合金投加的位置在保温炉内均匀的分布。4. Rare earth treatment and boronization treatment
4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling.
4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling.
The rare earth aluminum alloy and the boron aluminum alloy are added in different time periods in order to make the rare earth and boron elements fully function and improve the effect.
4.3 The position of the rare earth aluminum alloy and the boron aluminum alloy is uniformly distributed in the holding furnace.
5、精炼(除渣、除气、搅拌、扒渣)
5.1为了保证整炉铝合金液体的成分分布均匀,应对铝合金液体进行搅拌,并搅拌到炉的边角,搅拌时间为5分钟。
5.2当铝合金液体充满炉后,通过管道由高纯度氮气将2.3kg的粉末精炼剂(23%Na3Al•F6+47%KCl+30%NaCl)吹入铝合金液体底部,吹入口应在铝合金液体的底部移动,使气体及夹渣物沿铝合金液体的表面均匀地上浮,时间为3~5分钟。上浮的氧化铝渣应全部扒出炉外,以尽量减少精炼剂所引入的新杂质。5, refining (de-slag, degassing, stirring, slag)
5.1 In order to ensure uniform distribution of the composition of the aluminum alloy liquid in the whole furnace, the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
5.2 When the aluminum alloy liquid is filled in the furnace, 2.3 kg of powder refining agent (23% Na 3 Al•F6+47%KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through a high-purity nitrogen gas through the pipeline. The bottom of the aluminum alloy liquid moves, so that the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes. The floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
6、炉前快速分析及静置保温
当扒渣后的铝合金液体的铁含量符合要求时,静置时间20~40分钟。6. Rapid analysis and static insulation before the furnace When the iron content of the aluminum alloy liquid after the slag is in compliance with the requirements, the standing time is 20 to 40 minutes.
7、连铸连轧工艺控制
7.1温度控制
7.1.1上浇包温度:720~730℃
7.1.2进轧机铸条温度:450~490℃
7.1.3铝杆终轧温度300℃左右
7.2连铸机冷却水的控制
连铸轮内外水量之比3:2,二次冷却水量根据铸条温度作适当调整。
7.3铸机电压:60~90V
7.4轧机电流:200~280A;轧机速度:7.5~8.5m/min。7. Continuous casting and rolling process control
7.1 temperature control
7.1.1 Top ladle temperature: 720 ~ 730 ° C
7.1.2 Casting mill temperature of the rolling mill: 450 ~ 490 ° C
7.1.3 Aluminum rod finishing temperature is about 300 °C
7.2 Control of cooling water of continuous casting machine The ratio of water volume inside and outside the casting wheel is 3:2, and the amount of secondary cooling water is adjusted according to the temperature of the casting bar.
7.3 caster voltage: 60 ~ 90V
7.4 rolling mill current: 200 ~ 280A; rolling mill speed: 7.5 ~ 8.5m / min.
二、半退火工艺Second, semi-annealing process
由铝合金材料轧制成的铝合金杆在退火炉中,于280℃~300℃下保温10个小时,然后取出自然冷却至环境温度。The aluminum alloy rod rolled from the aluminum alloy material is kept at 280 ° C to 300 ° C for 10 hours in an annealing furnace, and then taken out and naturally cooled to ambient temperature.
由此获得的铝合金材料,按照重量百分含量,包含下述组分:Fe0.3%、Si0.03%、Ce0.008%、La0.002%、B0.005%、Ca0.015%、Cu0.002%、Mg0.005%、Zn0.002%、Ti0.002%、V0.005%、Mn0.002%、Cr0.001%,其余为Al。The aluminum alloy material thus obtained contains, according to the weight percentage, the following components: Fe 0.3%, Si 0.03%, Ce 0.008%, La 0.002%, B0.005%, Ca 0.015%, Cu 0.002%, Mg 0.005%, Zn 0.002%, Ti 0.002%, V0.005%, Mn 0.002%, Cr 0.001%, and the balance is Al.
由于硼(B)元素与Ti、V、Mn、Cr等杂质元素反应,形成化合物后被沉淀排除,因此最终所得的铝合金材料中硼元素的含量低于实际加入的量。Since the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
由上述可见,铝合金材料中的杂质含量合计<0.3%,除Ca<0.02%外,其它单种杂质元素的含量均<0.01%。It can be seen from the above that the content of impurities in the aluminum alloy material is <0.3% in total, and the content of other single impurity elements is <0.01% except for Ca < 0.02%.
本实例中高延伸率铝合金材料的性能检测数据如下:The performance test data of the high elongation aluminum alloy material in this example is as follows:
抗拉强度、延伸率的检测按照ASTM B577所述的试验方法,导电率检测按照ASTM B193所述的试验方法,柔韧性按照GB 12706.1所述的“弯曲试验后的局部放电试验”的试验方法,蠕变按照《电线电缆》手册蠕变试验的方法。Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM. The test method described in B193, the flexibility is in accordance with the test method of "partial discharge test after bending test" described in GB 12706.1, and the creep is tested according to the creep test of the "Wire and Cable" manual.
本实例高延伸率铝合金材料的性能为:抗拉强度106MPa、延伸率28%、导电率63.0%IACS、6倍弯曲半径后局部放电试验合格、抗蠕变相对电工用铝提高310%。The performance of the high elongation aluminum alloy material in this example is: tensile strength 106 MPa, elongation 28%, electrical conductivity 63.0% IACS, 6 times bending radius after partial discharge test pass, creep resistance is increased by 310% compared with electrical aluminum.
实施例2Example 2
一、熔铸工艺First, the melting process
1、配料
5110kg的铝锭(0.10%Si含量,0.13%Fe含量)、258kg铝铁合金(23.2%Fe含量)、166.5kg稀土合金(9.8%稀土含量)、10kg硼铝合金(3.3%B含量)、2.3kg精炼剂(23%Na3Al•F6+47%KCl+30%NaCl)1, ingredients
5110kg aluminum ingot (0.10% Si content, 0.13% Fe content), 258kg aluminum-iron alloy (23.2% Fe content), 166.5kg rare earth alloy (9.8% rare earth content), 10kg boron aluminum alloy (3.3% B content), 2.3kg Refining agent (23% Na 3 Al•F6+47%KCl+30% NaCl)
2、加料方式
加料时铝铁合金随铝锭搭配均匀分批地从冲天炉加入,以保证成分尽可能的均匀。2. When the feeding method is added, the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
3、保温工艺
铝合金液体流入保温炉时温度控制在710~750℃;向前述铝合金液体中加入稀土铝合金和硼铝合金时温度应提升至720~760℃,且温度不得超过760℃,此时升高温度有利于稀土铝合金和硼铝合金的熔融,从而提高了稀土和硼的处理效果。3. Insulation process When the aluminum alloy liquid flows into the holding furnace, the temperature is controlled at 710-750 °C; when adding rare earth aluminum alloy and boron aluminum alloy to the above aluminum alloy liquid, the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
4、稀土处理和硼化处理
4.1保温炉铝合金液体充满前30分钟加入1/3稀土铝合金。
4.2保温炉铝合金液体充满前5分钟加入其余2/3稀土铝合金和硼铝合金。
在不同时间段内加入稀土铝合金和硼铝合金是为了使稀土和硼元素能充分发挥作用,提高其作用效果。
4.3稀土铝合金和硼铝合金投加的位置在保温炉内均匀的分布。4. Rare earth treatment and boronization treatment
4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling.
4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling.
The rare earth aluminum alloy and the boron aluminum alloy are added in different time periods in order to make the rare earth and boron elements fully function and improve the effect.
4.3 The position of the rare earth aluminum alloy and the boron aluminum alloy is uniformly distributed in the holding furnace.
5、精炼(除渣、除气、搅拌、扒渣)
5.1为了保证整炉铝合金液体的成分分布均匀,应对铝合金液体进行搅拌,并搅拌到炉的边角,搅拌时间为5分钟。
5.2当铝合金液体充满炉后,通过管道由高纯度氮气将2.3kg的粉末精炼剂(23%Na3Al•F6+47%KCl+30%NaCl)吹入铝合金液体底部,吹入口应在铝合金液体的底部移动,使气体及夹渣物沿铝合金液体的表面均匀地上浮,时间为3~5分钟。上浮的氧化铝渣应全部扒出炉外,以尽量减少精炼剂所引入的新杂质。5, refining (de-slag, degassing, stirring, slag)
5.1 In order to ensure uniform distribution of the composition of the aluminum alloy liquid in the whole furnace, the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
5.2 When the aluminum alloy liquid is filled in the furnace, 2.3 kg of powder refining agent (23% Na 3 Al•F6+47%KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through a high-purity nitrogen gas through the pipeline. The bottom of the aluminum alloy liquid moves, so that the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes. The floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
6、炉前快速分析及静置保温
当扒渣后的铝合金液体的铁含量符合要求时,静置时间20~40分钟。6. Rapid analysis and static insulation before the furnace When the iron content of the aluminum alloy liquid after the slag is in compliance with the requirements, the standing time is 20 to 40 minutes.
7、连铸连轧工艺控制
7.1温度控制
7.1.1上浇包温度:720~730℃
7.1.2进轧机铸条温度:450~490℃
7.1.3铝杆终轧温度300℃左右
7.2连铸机冷却水的控制
连铸轮内外水量之比3:2,二次冷却水量根据铸条温度作适当调整。
7.3铸机电压:60~90V
7.4轧机电流:200~280A;轧机速度:7.5~8.5m/min。7. Continuous casting and rolling process control
7.1 temperature control
7.1.1 Top ladle temperature: 720 ~ 730 ° C
7.1.2 Casting mill temperature of the rolling mill: 450 ~ 490 ° C
7.1.3 Aluminum rod finishing temperature is about 300 °C
7.2 Control of cooling water of continuous casting machine The ratio of water volume inside and outside the casting wheel is 3:2, and the amount of secondary cooling water is adjusted according to the temperature of the casting bar.
7.3 caster voltage: 60 ~ 90V
7.4 rolling mill current: 200 ~ 280A; rolling mill speed: 7.5 ~ 8.5m / min.
二、半退火工艺Second, semi-annealing process
由铝合金材料轧制成的铝合金杆在退火炉中,于360℃~380℃下保温4个小时,然后取出自然冷却至环境温度。The aluminum alloy rod rolled from the aluminum alloy material is kept in an annealing furnace at 360 ° C to 380 ° C for 4 hours, and then taken out and naturally cooled to ambient temperature.
由此获得的铝合金材料,按照重量百分含量,包含下述组分:Fe1.2%、Si0.08%、Ce0.19%、La0.10%、B0.004%、Ca0.01%、Cu0.002%、Mg0.004%、Zn0.003%、Ti0.002%、V0.002%、Mn0.005%、Cr0.002%,其余为Al。The aluminum alloy material thus obtained contains, according to the weight percentage, the following components: Fe 1.2%, Si 0.08%, Ce 0.19%, La 0.10%, B 0.004%, Ca 0.01%, Cu 0.002%, Mg 0.004%, Zn 0.003%, Ti 0.002%, V0.002%, Mn 0.005%, Cr 0.002%, and the balance is Al.
由于硼(B)元素与Ti、V、Mn、Cr等杂质元素反应,形成化合物后被沉淀排除,因此最终所得的铝合金材料中硼元素的含量低于实际加入的量。Since the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
由上述可见,铝合金材料中的杂质含量合计<0.3%,除Ca<0.02%外,其它单种杂质元素的含量均<0.01%。It can be seen from the above that the content of impurities in the aluminum alloy material is <0.3% in total, and the content of other single impurity elements is <0.01% except for Ca < 0.02%.
本实例高延伸率铝合金材料的性能检测数据如下:The performance test data of the high elongation aluminum alloy material in this example is as follows:
抗拉强度、延伸率的检测按照ASTM B577所述的试验方法,导电率检测按照ASTM B193所述的试验方法,柔韧性按照GB12706.1所述的“弯曲试验后的局部放电试验”的试验方法,蠕变按照《电线电缆》手册蠕变试验的方法。Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM. The test method described in B193, the flexibility is in accordance with the test method of "partial discharge test after bending test" described in GB12706.1, and the creep is in accordance with the method of creep test of the "Wire and Cable" manual.
本实例高导电、高延伸率、高柔韧性和高抗蠕变性能的铝合金材料的性能为:抗拉强度92MPa、延伸率36%、导电率61.0%IACS、7倍弯曲半径后局部放电试验合格、抗蠕变相对电工铝提高330%。The performance of the aluminum alloy material with high conductivity, high elongation, high flexibility and high creep resistance in this example is: partial discharge test after tensile strength 92 MPa, elongation 36%, electrical conductivity 61.0% IACS, 7 times bending radius Qualified and creep resistant is increased by 330% compared to electrical aluminum.
实施例3Example 3
一、熔铸工艺First, the melting process
1、配料
5125kg的铝锭(0.12%Si含量,0.12%Fe含量)、107kg铝铁合金(21.9%Fe含量)、118kg稀土合金(10.1%稀土含量)、14.8kg硼铝合金(3.0%B含量)、2.8kg精炼剂(23%Na3Al•F6+
47%KCl +30%NaCl)。1, ingredients
5125kg aluminum ingot (0.12% Si content, 0.12% Fe content), 107kg aluminum-iron alloy (21.9% Fe content), 118kg rare earth alloy (10.1% rare earth content), 14.8kg boron aluminum alloy (3.0% B content), 2.8kg Refining agent (23% Na 3 Al•F6+ 47% KCl + 30% NaCl).
2、加料方式
加料时铝铁合金随铝锭搭配均匀分批地从冲天炉加入,以保证成分尽可能的均匀。2. When the feeding method is added, the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
3、保温工艺
铝合金液体流入保温炉时温度控制在710~750℃,向前述铝合金液体中加入稀土铝合金和硼铝合金时温度应提升至720~760℃,且温度不得超过760℃,此时升高温度有利于稀土铝合金和硼铝合金的熔融,从而提高了稀土和硼的处理效果。3. Insulation process When the aluminum alloy liquid flows into the holding furnace, the temperature is controlled at 710-750 °C. When adding rare earth aluminum alloy and boron aluminum alloy to the above aluminum alloy liquid, the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
4、稀土处理和硼化处理
4.1保温炉铝合金液体充满前30分钟加入1/3稀土铝合金。
4.2保温炉铝合金液体充满前5分钟加入其余2/3稀土铝合金和硼铝合金。
4.3稀土铝合金和硼铝合金投加的位置应在保温炉内均匀的分布。4. Rare earth treatment and boronization treatment
4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling.
4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling.
4.3 The location of the rare earth aluminum alloy and boron aluminum alloy should be evenly distributed in the holding furnace.
5、精炼(除渣、除气、搅拌、扒渣)
5.1为了保证整炉铝合金液体的成分分布均匀,应对铝合金液体进行搅拌,并搅拌到炉的边角,搅拌时间为5分钟。
5.2当铝合金液体充满炉后,通过管道由高纯度氮气将2.8kg的粉末精炼剂(23%Na3Al•F
6+47%KCl+30%NaCl)吹入铝合金液体底部,吹入口应在铝合金液体的底部移动,使气体及夹渣物沿铝合金液体的表面均匀地上浮,时间为3~5分钟。上浮的氧化铝渣应全部扒出炉外,以尽量减少精炼剂所引入的新杂质。5, refining (de-slag, degassing, stirring, slag)
5.1 In order to ensure uniform distribution of the composition of the aluminum alloy liquid in the whole furnace, the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
5.2 When the aluminum alloy liquid is filled in the furnace, 2.8 kg of powder refining agent (23% Na 3 Al•F 6+47% KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through high-purity nitrogen through a pipe, and the inlet should be blown. Moving at the bottom of the aluminum alloy liquid, the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes. The floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
6、炉前快速分析及静置保温
当扒渣后的铝合金液体的铁含量符合要求时,静置时间20~40分钟。6. Rapid analysis and static insulation before the furnace When the iron content of the aluminum alloy liquid after the slag is in compliance with the requirements, the standing time is 20 to 40 minutes.
7、连铸连轧工艺控制
7.1温度控制
7.1.1上浇包温度:720~730℃
7.1.2进轧机铸条温度:450~490℃
7.1.3铝杆终轧温度300℃左右
7.2连铸机冷却水的控制
连铸轮内外水量之比3:2,二次冷却水量根据铸条温度作适当调整。
7.3铸机电压:60~90V
7.4轧机电流:200~280A;轧机速度:7.5~8.5m/min。7. Continuous casting and rolling process control
7.1 temperature control
7.1.1 Top ladle temperature: 720 ~ 730 ° C
7.1.2 Casting mill temperature of the rolling mill: 450 ~ 490 ° C
7.1.3 Aluminum rod finishing temperature is about 300 °C
7.2 Control of cooling water of continuous casting machine The ratio of water volume inside and outside the casting wheel is 3:2, and the amount of secondary cooling water is adjusted according to the temperature of the casting bar.
7.3 caster voltage: 60 ~ 90V
7.4 rolling mill current: 200 ~ 280A; rolling mill speed: 7.5 ~ 8.5m / min.
二、半退火工艺Second, semi-annealing process
由铝合金材料轧制成的铝合金杆在退火炉中,于300℃~320℃下保温8个小时,然后取出自然冷却至环境温度。The aluminum alloy rod rolled from the aluminum alloy material is kept in an annealing furnace at 300 ° C to 320 ° C for 8 hours, and then taken out and naturally cooled to ambient temperature.
由此获得的铝合金材料,按照重量百分含量,包含下述组分:Fe0.55%、Si0.10%、Ce0.15%、La0.06%、B0.007%、Ca0.013%、Cu0.003%、Mg0.004%、Zn0.004%、Ti0.002%、V0.004%、Mn0.003%、Cr0.002%,其余为Al。The aluminum alloy material thus obtained contains the following components in terms of weight percentage: Fe 0.55%, Si 0.10%, Ce 0.15%, La 0.06%, B0.007%, Ca 0.013%, Cu 0.003%, Mg 0.004%, Zn 0.004%, Ti 0.002%, V 0.004%, Mn 0.003%, Cr 0.002%, and the balance is Al.
由于硼(B)元素与Ti、V、Mn、Cr等杂质元素反应,形成化合物后被沉淀排除,因此最终所得的铝合金材料中硼元素的含量低于实际加入的量。Since the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
由上述可见,铝合金材料中的杂质含量合计<0.3%,除Ca<0.02%外,其它单种杂质元素的含量均<0.01%。It can be seen from the above that the content of impurities in the aluminum alloy material is <0.3% in total, and the content of other single impurity elements is <0.01% except for Ca < 0.02%.
本实例高延伸率铝合金材料的性能检测数据如下:The performance test data of the high elongation aluminum alloy material in this example is as follows:
抗拉强度、延伸率的检测按照ASTM B577所述的试验方法,导电率检测按照ASTM B193所述的试验方法,柔韧性按照GB 12706.1所述的“弯曲试验后的局部放电试验”的试验方法、蠕变按照《电线电缆》手册蠕变试验的方法。Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM. The test method described in B193, the flexibility according to the test method of "partial discharge test after bending test" described in GB 12706.1, creep according to the "wire and cable" manual creep test method.
本实例高延伸率铝合金材料的性能为:抗拉强度110MPa、延伸率30.2%、导电率62.6%IACS、6倍弯曲半径后局部放电试验合格、抗蠕变相对电工用铝提高330%。The properties of the high elongation aluminum alloy material in this example are: tensile strength 110 MPa, elongation 30.2%, electrical conductivity 62.6% IACS, 6 times bending radius after partial discharge test pass, creep resistance is increased by 330% compared with electrical aluminum.
实施例4Example 4
一、熔铸工艺First, the melting process
1、配料
5005kg的铝锭(0.08%Si含量,0.13%Fe含量)、182kg铝铁合金(21%
Fe含量)、90.5kg稀土合金(9.8%稀土含量)、30kg硼铝合金(3.5%B含量)、2.0kg精炼剂(23%Na3Al•F6+47%KCl+30%NaCl)。1, ingredients
5005kg aluminum ingot (0.08% Si content, 0.13% Fe content), 182kg aluminum-iron alloy (21% Fe content), 90.5kg rare earth alloy (9.8% rare earth content), 30kg boron aluminum alloy (3.5% B content), 2.0kg Refining agent (23% Na 3 Al•F6+47% KCl+30% NaCl).
2、加料方式
加料时铝铁合金随铝锭搭配均匀分批地从冲天炉加入,以保证成分尽可能的均匀。2. When the feeding method is added, the aluminum-iron alloy is added with the aluminum ingots evenly and batchwise from the cupola to ensure the composition is as uniform as possible.
3、保温工艺
铝合金液体流入保温炉时温度控制在710~750℃,向前述铝合金液体中加入稀土铝合金和硼铝合金时温度应提升至720~760℃,且温度不得超过760℃,此时升高温度有利于稀土铝合金和硼铝合金的熔融,从而提高了稀土和硼的处理效果。3. Insulation process When the aluminum alloy liquid flows into the holding furnace, the temperature is controlled at 710-750 °C. When adding rare earth aluminum alloy and boron aluminum alloy to the above aluminum alloy liquid, the temperature should be raised to 720-760 °C, and the temperature should not exceed 760 °C. Increasing the temperature at this time is beneficial to the melting of the rare earth aluminum alloy and the boron aluminum alloy, thereby improving the treatment effect of the rare earth and boron.
4、稀土处理和硼化处理
4.1保温炉铝合金液体充满前30分钟加入1/3稀土铝合金。
4.2保温炉铝合金液体充满前5分钟加入其余2/3稀土铝合金和硼铝合金。
4.3稀土铝合金和硼铝合金投加的位置应在保温炉内均匀的分布。4. Rare earth treatment and boronization treatment
4.1 Adding 1/3 rare earth aluminum alloy to the holding furnace aluminum alloy liquid 30 minutes before filling.
4.2 The remaining 2/3 rare earth aluminum alloy and boron aluminum alloy were added to the holding furnace aluminum alloy liquid 5 minutes before filling.
4.3 The location of the rare earth aluminum alloy and boron aluminum alloy should be evenly distributed in the holding furnace.
5、精炼(除渣、除气、搅拌、扒渣)
5.1为了保证整炉铝合金液体的成分分布均匀,应对铝合金液体进行搅拌,并搅拌到炉的边角,搅拌时间为5分钟。
5.2当铝合金液体充满炉后,通过管道由高纯度氮气将2.0kg的粉末精炼剂(23%Na3Al•F6+47%KCl+30%NaCl)吹入铝合金液体底部,吹入口应在铝合金液体的底部移动,使气体及夹渣物沿铝合金液体的表面均匀地上浮,时间为3~5分钟。上浮的氧化铝渣应全部扒出炉外,以尽量减少精炼剂所引入的新杂质。5, refining (de-slag, degassing, stirring, slag)
5.1 In order to ensure uniform distribution of the composition of the aluminum alloy liquid in the whole furnace, the aluminum alloy liquid should be stirred and stirred to the corner of the furnace for 5 minutes.
5.2 When the aluminum alloy liquid is filled in the furnace, 2.0kg of powder refining agent (23% Na 3 Al•F6+47%KCl+30% NaCl) is blown into the bottom of the aluminum alloy liquid through high-purity nitrogen gas through the pipeline. The bottom of the aluminum alloy liquid moves, so that the gas and the slag are uniformly floated along the surface of the aluminum alloy liquid for 3 to 5 minutes. The floating alumina slag should be completely removed from the furnace to minimize the introduction of new impurities introduced by the refining agent.
6、炉前快速分析及静置保温
当扒渣后的铝合金液体的铁含量符合要求时,静置时间20~40分钟。6. Rapid analysis and static insulation before the furnace When the iron content of the aluminum alloy liquid after the slag is in compliance with the requirements, the standing time is 20 to 40 minutes.
7、连铸连轧工艺控制
7.1温度控制
7.1.1上浇包温度:720~730℃
7.1.2进轧机铸条温度:450~490℃
7.1.3铝杆终轧温度300℃左右
7.2连铸机冷却水的控制
连铸轮内外水量之比3:2,二次冷却水量根据铸条温度作适当调整。
7.3铸机电压:60~90V
7.4轧机电流:200~280A;轧机速度:7.5~8.5m/min。7. Continuous casting and rolling process control
7.1 temperature control
7.1.1 Top ladle temperature: 720 ~ 730 ° C
7.1.2 Casting mill temperature of the rolling mill: 450 ~ 490 ° C
7.1.3 Aluminum rod finishing temperature is about 300 °C
7.2 Control of cooling water of continuous casting machine The ratio of water volume inside and outside the casting wheel is 3:2, and the amount of secondary cooling water is adjusted according to the temperature of the casting bar.
7.3 caster voltage: 60 ~ 90V
7.4 rolling mill current: 200 ~ 280A; rolling mill speed: 7.5 ~ 8.5m / min.
二、半退火工艺Second, semi-annealing process
由铝合金材料轧制成的铝合金杆在退火炉中,于340℃~360℃下保温6个小时,然后取出自然冷却至环境温度。The aluminum alloy rod rolled from the aluminum alloy material is incubated at 340 ° C to 360 ° C for 6 hours in an annealing furnace, and then taken out and naturally cooled to ambient temperature.
由此获得的铝合金材料,按照重量百分含量,包含下述组分:Fe0.80%、Si0.04%、Ce0.10%、La0.06%、B0.008%、Ca 0.011%、Cu 0.005%、Mg 0.004%、Zn0.006% 、Ti0.003%、V0.003%、Mn0.005%、Cr0.002%,其余为Al。The aluminum alloy material thus obtained contains the following components in terms of weight percent: Fe 0.80%, Si 0.04%, Ce 0.10%, La 0.06%, B0.008%, Ca 0.011%, Cu 0.005%, Mg 0.004%, Zn0.006% Ti 0.003%, V0.003%, Mn 0.005%, Cr 0.002%, and the balance is Al.
由于硼(B)元素与Ti、V、Mn、Cr等杂质元素反应,形成化合物后被沉淀排除,因此最终所得的铝合金材料中硼元素的含量低于实际加入的量。Since the boron (B) element reacts with an impurity element such as Ti, V, Mn, Cr, etc., the compound is formed and precipitated, and thus the content of boron element in the finally obtained aluminum alloy material is lower than the actually added amount.
由上述可见,铝合金材料中的杂质含量合计<0.3%,除Ca<0.02%外,其它单种杂质元素的含量均<0.01%。It can be seen from the above that the content of impurities in the aluminum alloy material is <0.3% in total, and the content of other single impurity elements is <0.01% except for Ca < 0.02%.
本实例高延伸率铝合金材料的性能检测数据如下:The performance test data of the high elongation aluminum alloy material in this example is as follows:
抗拉强度、延伸率的检测按照ASTM B577所述的试验方法,导电率检测按照ASTM B193所述的试验方法,柔韧性按照GB 12706.1所述的“弯曲试验后的局部放电试验”的试验方法、蠕变按照《电线电缆》手册蠕变试验的方法。 Tensile strength and elongation are tested according to the test method described in ASTM B577. Conductivity is measured according to ASTM. The test method described in B193, the flexibility according to the test method of "partial discharge test after bending test" described in GB 12706.1, creep according to the "wire and cable" manual creep test method.
本实例高延伸率铝合金材料的性能为:抗拉强度97MPa、延伸率35.2%、导电率 62.0%IACS、6倍弯曲半径后局部放电试验合格、抗蠕变相对电工用铝提高330%。The properties of the high elongation aluminum alloy material in this example are: tensile strength 97 MPa, elongation 35.2%, electrical conductivity After 62.0% IACS, 6 times bending radius, the partial discharge test was qualified, and the creep resistance was increased by 330% compared with the electrical aluminum.
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| JP2012506317A JP2012524837A (en) | 2009-04-24 | 2010-04-09 | Aluminum alloy material having high stretchability for cable and method for producing the same |
| RU2011147346/02A RU2550063C2 (en) | 2009-04-24 | 2010-04-09 | Cable material based on aluminium alloy with high degree of elongation, and method for its obtaining |
| CA2773050A CA2773050A1 (en) | 2009-04-24 | 2010-04-09 | High-elongation rate aluminum alloy material for cable and preparation method thereof |
| EP10766607.5A EP2468907A4 (en) | 2009-04-24 | 2010-04-09 | High-elongation rate aluminum alloy material for cable and preparation method thereof |
| AU2010239014A AU2010239014B2 (en) | 2009-04-24 | 2010-04-09 | High-elongation rate aluminum alloy material for cable and preparation method thereof |
| US13/395,423 US20120211130A1 (en) | 2009-04-24 | 2010-04-09 | High-elongation rate aluminum alloy material for cable and preparation method thereof |
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- 2010-04-09 JP JP2012506317A patent/JP2012524837A/en active Pending
- 2010-04-09 AU AU2010239014A patent/AU2010239014B2/en active Active
- 2010-04-09 WO PCT/CN2010/071654 patent/WO2010121517A1/en not_active Ceased
- 2010-04-09 US US13/395,423 patent/US20120211130A1/en not_active Abandoned
- 2010-04-09 RU RU2011147346/02A patent/RU2550063C2/en active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| GB1457697A (en) * | 1974-03-05 | 1976-12-08 | Southwire Co | Aluminium alloy wire |
| US5080728A (en) * | 1989-04-28 | 1992-01-14 | Vereinigte Aluminium-Werke Aktiengellschaft | Rolled aluminum product and method for its production |
| JP2001063232A (en) * | 1999-08-27 | 2001-03-13 | Mitsubishi Alum Co Ltd | Aluminum alloy substrate for ps plate and its manufacture |
| CN1693992A (en) * | 2005-05-20 | 2005-11-09 | 东北轻合金有限责任公司 | Manufacturing method of aluminous plate for PS plate substrate for printing |
| CN101525709A (en) * | 2009-04-24 | 2009-09-09 | 安徽欣意电缆有限公司 | High-elongation aluminum alloy material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103060647A (en) * | 2011-10-24 | 2013-04-24 | 贵州华科铝材料工程技术研究有限公司 | Ruthenium carbonyl complex modified high-performance aluminum alloy material and preparation method thereof |
| CN115449730A (en) * | 2022-09-06 | 2022-12-09 | 合肥通用机械研究院有限公司 | A method to effectively reduce the corrosion rate of low-silicon cast aluminum alloys |
| CN115896653A (en) * | 2022-12-21 | 2023-04-04 | 广东领胜新材料科技有限公司 | Continuous casting and rolling device and method for high-strength aluminum alloy round rod |
| CN115896653B (en) * | 2022-12-21 | 2024-04-02 | 广东领胜新材料科技有限公司 | Continuous casting and rolling device and method for high-strength aluminum alloy round rod |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2010239014B2 (en) | 2014-06-26 |
| JP2012524837A (en) | 2012-10-18 |
| CN101525709A (en) | 2009-09-09 |
| EP2468907A4 (en) | 2013-11-20 |
| US20120211130A1 (en) | 2012-08-23 |
| CN101525709B (en) | 2010-08-11 |
| RU2011147346A (en) | 2013-05-27 |
| EP2468907A1 (en) | 2012-06-27 |
| AU2010239014A1 (en) | 2011-08-11 |
| CA2773050A1 (en) | 2010-10-28 |
| RU2550063C2 (en) | 2015-05-10 |
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