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WO2010119726A1 - Method for manufacturing wafer lens - Google Patents

Method for manufacturing wafer lens Download PDF

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Publication number
WO2010119726A1
WO2010119726A1 PCT/JP2010/052728 JP2010052728W WO2010119726A1 WO 2010119726 A1 WO2010119726 A1 WO 2010119726A1 JP 2010052728 W JP2010052728 W JP 2010052728W WO 2010119726 A1 WO2010119726 A1 WO 2010119726A1
Authority
WO
WIPO (PCT)
Prior art keywords
light
lens
manufacturing
resin
photocurable resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2010/052728
Other languages
French (fr)
Japanese (ja)
Inventor
雄一 藤井
明子 原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Konica Minolta Opto Inc
Original Assignee
Konica Minolta Opto Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Konica Minolta Opto Inc filed Critical Konica Minolta Opto Inc
Publication of WO2010119726A1 publication Critical patent/WO2010119726A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/003Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
    • B29C39/006Monomers or prepolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/22Component parts, details or accessories; Auxiliary operations
    • B29C39/40Compensating volume change, e.g. retraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • B29D11/00278Lenticular sheets
    • B29D11/00307Producing lens wafers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • B29D11/00432Auxiliary operations, e.g. machines for filling the moulds
    • B29D11/00442Curing the lens material
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00Simple or compound lenses
    • G02B3/0006Arrays
    • G02B3/0012Arrays characterised by the manufacturing method
    • G02B3/0031Replication or moulding, e.g. hot embossing, UV-casting, injection moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2011/00Optical elements, e.g. lenses, prisms
    • B29L2011/0016Lenses

Definitions

  • the present invention relates to a method for manufacturing a wafer lens.
  • Patent Document 2 An example of a method for forming a resin lens portion on a glass substrate is disclosed in Patent Document 2.
  • a composition comprising a photocurable resin, a thermosetting resin, a photopolymerization agent and a thermal polymerization agent is applied to a substrate, the resin is photocured (light irradiation), and then shaped ( (Pressing of mold to resin) and thermosetting (see paragraphs 0069 to 0080).
  • a photocurable resin is filled between a glass substrate and a mold and light is irradiated in that state.
  • the optical surface of the lens unit is required to be transferred from the mold with high accuracy of the order of submicron or less.
  • the photo-curable resin generally has a property of shrinking by curing, and is cured while slightly shrinking inside the mold when irradiated with light.
  • a main object of the present invention is to provide a method of manufacturing an optical element capable of suppressing the occurrence of sink marks within the effective diameter range of the lens part, at least the lens part.
  • a method for manufacturing a wafer lens in which a plurality of lenses having a lens portion and a non-lens portion around the lens portion are formed on a substrate with a photocurable resin, Filling the photocurable resin between the mold and the substrate; A curing step of advancing curing of the photocurable resin by performing light irradiation on the photocurable resin, The curing step includes a first light irradiation step of irradiating the first region of the photocurable resin with light, and a second light irradiating the second region of the irradiation region wider than the first region.
  • a method for manufacturing a wafer lens comprising an irradiation step.
  • a method for manufacturing a wafer lens in which a plurality of lenses having a lens portion and a non-lens portion around the lens portion are formed on a substrate with a photocurable resin, Filling the photocurable resin between the mold and the substrate; A curing step of proceeding curing of the photocurable resin by irradiating the photocurable resin with light, and the curing step irradiates only a portion corresponding to the lens portion of the photocurable resin. And a second light irradiation step of irradiating a portion corresponding to a non-lens portion around the lens portion of the photocurable resin. Is done.
  • the present invention it is possible to suppress the occurrence of sink marks within the effective diameter within the lens portion, at least the lens portion.
  • the wafer lens 1 has a glass substrate 2.
  • the glass substrate 2 is an example of a substrate and has a wafer shape (circular shape) when viewed from above.
  • the resin part 4 is provided on the upper part of the glass substrate 2.
  • the resin part 4 includes a convex lens part 4a that is a part for converging or diverging incident light by refraction or diffraction action with respect to the incident light, and a non-lens part 4b that transmits the incident light as it is.
  • the convex lens portion 4a serving as a part that causes a refractive action constitutes a convex lens-shaped optical surface.
  • the non-lens part 4b is a part other than the convex lens part 4a and a part around the convex lens part 4a, and is configured in a flat plate shape to transmit substantially incident light as it is.
  • the non-lens portion 4b does not necessarily have a flat plate shape, and may be a portion that does not contribute to the optical function as the lens when the present invention is used as a lens of an imaging optical system.
  • the region has a function suitable as a spacer portion for defining the shape suitable for holding and the distance from other lens members and imaging element members for positioning and holding with other members. May be.
  • the thickness 4ath of the convex lens portion 4a is thicker than the thickness 4bth of the non-lens portion 4b because the convex lens portion 4a has a convex shape.
  • the resin part 6 is provided in the lower part of the glass substrate 2.
  • the resin portion 6 includes a concave lens portion 6a that is a portion for converging or diverging incident light by refraction or diffraction action with respect to incident light, and a non-lens portion 6b that transmits incident light as it is.
  • the concave lens portion 6a serving as a portion that causes a refractive action constitutes a concave lens-shaped optical surface.
  • the non-lens portion 6b is a portion other than the concave lens portion 6a and a portion around the concave lens portion 6a, and is configured in a flat plate shape to transmit substantially incident light as it is.
  • the non-lens portion 6b does not necessarily have a flat plate shape, and may be a portion in a range that does not contribute to the optical function as the lens when the present invention is used as a lens of an imaging optical system.
  • the region has a function suitable as a spacer portion for defining the shape suitable for holding and the distance from other lens members and imaging element members for positioning and holding with other members. May be.
  • the thickness 6ath of the concave lens portion 6a is thinner than the thickness 6bth of the non-lens portion 6b because the concave lens portion 6a has a concave shape.
  • the resin parts 4 and 6 are formed in a form in which the non-lens parts 4 b and 6 b between the adjacent lens parts 4 a and 6 a are connected, but the resin parts 4 and 6 are not necessarily limited thereto. That is, by individually dropping and molding a photo-curable resin on the part corresponding to the cavity of the mold during molding, each lens part 4a, 6a is formed with non-lens parts 4b, 6b around, It may be formed independently.
  • the wafer lens 1 is a so-called meniscus lens in which the convex lens portion 4a and the concave lens portion 6a are in a one-to-one correspondence. .
  • the resin part 4 and the resin part 6 are composed of resins 4A and 6A, respectively.
  • Resins 4A and 6A are photocurable resins, but the present invention is most effective for resins that can be cured by radical polymerization, such as acrylic resins that are highly contracted by curing.
  • the (meth) acrylate used for the polymerization reaction is not particularly limited, and the following (meth) acrylate produced by a general production method can be used. That is, ester (meth) acrylate, urethane (meth) acrylate, epoxy (meth) acrylate, ether (meth) acrylate, alkyl (meth) acrylate, alkylene (meth) acrylate, (meth) acrylate having an aromatic ring, alicyclic Examples include (meth) acrylate having a structure. One or more of these can be used.
  • (Meth) acrylate having an alicyclic structure is particularly preferable, and may be an alicyclic structure containing an oxygen atom or a nitrogen atom.
  • 2-alkyl-2-adamantyl (meth) acrylate see Japanese Patent Application Laid-Open No. 2002-193883
  • adamantyl di (meth) acrylate see Japanese Patent Application Laid-Open No. 57-5000785
  • diallyl adamantyl dicarboxylate Japanese Patent Application Laid-Open No. 60-10000537
  • perfluoroadamantyl acrylate see JP 2004-123687
  • (meth) acrylate for example, methyl acrylate, methyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isobutyl acrylate, isobutyl methacrylate, tert-butyl acrylate Tert-butyl methacrylate, phenyl acrylate, phenyl methacrylate, benzyl acrylate, benzyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, and the like.
  • polyfunctional (meth) acrylate examples include trimethylolpropane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, dipentaerythritol hexa (meth) acrylate, dipentaerythritol penta (meth) ) Acrylate, dipentaerythritol tetra (meth) acrylate, dipentaerythritol tri (meth) acrylate, tripentaerythritol octa (meth) acrylate, tripentaerythritol septa (meth) acrylate, tripentaerythritol hexa (meth) acrylate, tripenta Erythritol penta (meth) acrylate, tripentaerythritol tetra (meth) acrylate, tripent
  • an allyl resin or the like can be used as the resins 4A and 6A, and the resin can be cured by radical polymerization.
  • photocurable resins that can be used as the resins 4A and 6A include, for example, epoxy resins, and the resins can be cured by cationic polymerization.
  • the photocurable resin used in the present invention includes not only the photocurable resin as described above but also a thermal polymerization initiator in addition to the photopolymerization initiator, and is combined with curing by thermal polymerization by heating. Also included.
  • the light to be cured includes not only visible light and ultraviolet light but also electron beams. Furthermore, you may provide what is called a post-cure process which completes hardening by applying heat after the 2nd light irradiation process mentioned later. Even in the case of a photocurable resin containing only a photopolymerization initiator as a polymerization initiator, photocuring is accelerated by heating, but if a thermal polymerization initiator is further blended here, the acceleration is promoted. The effect is further increased.
  • the wafer lens manufacturing apparatus 30 has a base 32.
  • a protruding portion 34 that protrudes inward is formed on the upper portion of the base 30.
  • a guide 36 is erected between the bottom of the base 32 and the protrusion 34.
  • a stage 40 is provided between the guides 36.
  • a through hole 42 is formed in the stage 40, and the guide 36 passes through the through hole 42.
  • a geared motor 50 is provided on the base 32 and below the stage 40.
  • the geared motor 50 has a built-in potentiometer 51 indicated by a dotted line.
  • a shaft 52 is connected to the geared motor 50.
  • a load cell 44 for pressure detection is provided between the lower portion of the stage 40 and the shaft 52, and the tip of the shaft 52 is in contact with the load cell 44 by the weight of the stage 40.
  • the shaft 52 extends and contracts in the vertical direction by the operation of the geared motor 50, and accordingly, the stage 40 is movable in the vertical direction while being guided by the guide 36.
  • the recess 40 having a substantially hemispherical shape is formed on the stage 40.
  • a paralleling member 60 is embedded in the recess 46.
  • the paralleling member 60 can swing with respect to the recess 46 like a bowl floating on the water surface.
  • An XY stage 62 and a ⁇ stage 64 are provided on the parallel projecting member 60.
  • the XY stage 62 is movable on an XY plane (two-dimensional plane) on the stage 40, and the ⁇ stage 64 is rotatable about its central portion as a rotation axis.
  • a vacuum chuck device 70 is installed on the XY stage 62 and the ⁇ stage 64.
  • a concentric communication groove 72 is formed in the vacuum chuck device 70.
  • a suction mechanism (not shown) is connected to the communication groove 72, and air can be sucked from the communication groove 72 by the operation of the suction mechanism, and members on the vacuum chuck device 70 can be sucked and fixed. ing.
  • the mold 20 is disposed on the vacuum chuck device 70, and the mold 20 is sucked and fixed by the vacuum chuck device 70.
  • the mold 20 is a metal mold and is an example of a mold used for resin molding.
  • a resin (resin 4A or the like) to be molded is placed on the mold 20.
  • the substrate holder 80 is fixed to the upper part of the base 32.
  • a concentric communication groove 82 is formed at the end of the substrate holder 80, and a suction mechanism (not shown) is connected to the communication groove 82.
  • a suction mechanism (not shown) is connected to the communication groove 82.
  • the suction mechanism operates, the glass substrate 2 is sucked and fixed to the substrate holder 80 by sucking air from the communication groove 82.
  • a light source 90 is provided above the substrate holder 80. When the light source 90 is turned on, light passes through the glass substrate 2 and is irradiated onto a resin (resin 4A, etc.) on the mold 20.
  • a resin resin 4A, etc.
  • a high-pressure mercury lamp metal halide lamp, xenon lamp, halogen lamp, fluorescent lamp, black light, G lamp, F lamp, LED, or the like is used.
  • the high-pressure mercury lamp is a lamp having a narrow spectrum at 365 nm and 436 nm.
  • a metal halide lamp is a kind of mercury lamp, and its output in the ultraviolet region is several times higher than that of a high-pressure mercury lamp.
  • a xenon lamp is a lamp having a spectrum closest to sunlight.
  • Halogen lamps contain a lot of long-wavelength light and are mostly near-infrared light. Fluorescent lamps have uniform illumination intensity for the three primary colors of light. Black light has a peak top at 351 nm and emits near-ultraviolet light of 300 to 400 nm. LEDs have different emission colors depending on the materials used, and can produce LEDs that emit light in the infrared region, visible light region, and ultraviolet region.
  • the load cell 44, geared motor 50, potentiometer 51, parallelizing member 60, XY stage 62, ⁇ stage 64, vacuum chuck device 70 (suction mechanism), substrate holder 80 (suction mechanism), and light source 90 are controlled. It is connected to the device 100.
  • the control device 100 controls the operation of these members.
  • control device 100 controls the operation (rotation amount) of the geared motor 50 based on the output values of the load cell 44 and the potentiometer 51.
  • the glass substrate 2 is placed on the substrate holder 80 and sucked and fixed, and the mold 20 is placed on the vacuum chuck device 70 and the mold 20 is sucked and fixed.
  • the dropping method is also a method in which each cavity 22 is filled by dropping and spreading them on a predetermined location, or each cavity 22 of the mold 20 or each lens portion 4a of the glass substrate 2 is formed in advance.
  • a method may be used in which the liquid is dropped individually, and is filled by pressing them with the mold 20 or the glass substrate 2 facing each other.
  • the position of the mold 20 is controlled, the mold 20 is moved to a predetermined position with respect to the glass substrate 2, and the mold 20 is held at that position.
  • the geared motor 50 is operated to extend the shaft 52 upward, and the mold 20 is moved upward.
  • the control device 100 controls the operation of the geared motor 50 based on the output value of the potentiometer 51, and moves the mold 20 to a predetermined height position.
  • the height position of the mold 20 to be moved is set in the control device 100 in advance, and the control device 100 operates the geared motor 50 to a position where the mold 20 reaches the reference position S.
  • the operation of the geared motor 50 is stopped (position control step).
  • the resin 4A gradually receives the pressure from the mold 20 to the glass substrate 2 and spreads between the glass substrate 2 and the mold 20 (particularly, the cavity 22 of the mold 20).
  • a light shielding mask 120 is disposed above the glass substrate 2 and between the glass substrate 2 and the light source 90.
  • the light shielding mask 120 has a portion corresponding to the cavity 22 of the mold 20 (preferably the optical effective diameter range of the convex lens portion 4a in the cavity 22; in the case of configuring an imaging device, the lens portion is transmitted through the lens portion later.
  • An opening 122 in which an entrance pupil diameter range necessary for forming an image in an effective pixel region of the image sensor is opened is formed.
  • the light source 90 is turned on while the mold 20 is held at the position corresponding to the reference position S, and light is irradiated toward the resin 4A (first light irradiation step).
  • the portion of the resin 4A that receives the transfer of the cavity 22 of the mold 20 and that corresponds to the convex lens portion 4a is irradiated with light prior to other portions, and the convex lens portion 4a ( Preferably, it begins to cure selectively within the optical effective diameter range of the convex lens portion 4a.
  • the convex lens portion 4a is divided according to the size of the diameter from the center by changing the light shielding mask 120 (the opening diameter of the opening portion 122), and the outer periphery from the center region is divided. You may make it irradiate light sequentially toward an area
  • the convex lens portion 4a is divided into a region (1) and a region (2), the region (1) is irradiated with light first, and then the light shielding mask 120 is changed to change the region ( 2) is irradiated with light.
  • the illuminance is increased for light irradiation in a region including the center of the optical axis with a thick lens thickness (for example, the region (1)), and other regions (for example, In the irradiation of the light in the region (2), the illuminance may be decreased (the illuminance is made smaller than that of the previous light irradiation).
  • the light shielding mask 120 is removed, and the entire resin 4A is irradiated with light (second light irradiation step).
  • the light shielding mask 120 that shields the light from the light source 90 since the light shielding mask 120 that shields the light from the light source 90 is removed, the light from the light source 90 propagates directly toward the resin 4A without being shielded. As a result, in the resin 4A, the portion corresponding to the convex lens portion 4a and the portion corresponding to the non-lens portion 4b, that is, the entire resin 4A are irradiated with light, and the non-lens portion 4b is cured together with the convex lens portion 4a. Proceed.
  • the illuminance of light may be kept constant (irradiation pattern A1), or the first light irradiation step and the second light irradiation step.
  • the light source 90 may be temporarily turned off to reduce the illuminance of the light (irradiation pattern A2).
  • a light source that emits divergent light is used as the light source 90, and the light shielding mask 120 is moved upward without removing the light shielding mask 120 (the distance between the light shielding mask 120 and the resin 4A is increased). You may make it irradiate light to resin 4A whole, expanding rather than the time of a 1st light irradiation process.
  • the light shielding mask 120 is formed on the glass substrate 2 in advance as an aperture stop, light is irradiated from the mask side, that is, the aperture stop side in the first light irradiation step, and light shielding by the mask is performed in the second light irradiation step.
  • the light may be irradiated from the side of the glass substrate 2 opposite to the aperture stop where the function does not work.
  • the mold 20 at this time needs to be formed transparently, and light irradiation is performed through the mold 20. In this case, there is an advantage that the process can be performed efficiently because it can be performed regardless of the type of light source and without removing the light shielding mask 120 each time.
  • the mold 20 and the glass substrate 2 may be removed and passed through a UV furnace to be cured entirely. Further, after the second light irradiation step, heat may be applied to promote photocuring. This is a so-called post-cure process, and accelerates curing by photopolymerization. Furthermore, a thermal polymerization initiator can be blended in the resin, and further curing can be promoted by light irradiation and heating.
  • the geared motor 50 is operated to shrink the shaft 52 downward, and the mold 20 is returned to the original height position. As shown in FIG. Release from the mold 20 (release process).
  • the resin part 4 in which a plurality of convex lens parts 4 a are formed can be formed on the glass substrate 2.
  • the pressing force of the mold 20 against the glass substrate 2 (pressure value detected by the load cell 44) in the process from the installation of the mold 20 at the reference position S to the release of the resin 4A from the mold 20 is as follows. As shown in FIG. 6, after the light irradiation is started in the first light irradiation step, it continues to gradually decrease until the light irradiation is finished in the second light irradiation step, and the resin 4A is separated from the mold 20. It drops rapidly when molding (pressure pattern B1).
  • the reason why the pressing force of the mold 20 decreases from the start of light irradiation to the end thereof is considered to be due to the resin 4A being irradiated with light and being cured and contracted.
  • the gold mold is used in the mold release process from the start of the light irradiation in the first light irradiation process until the end of the light irradiation in the second light irradiation process.
  • the operation of the geared motor 50 is controlled so that the pressing force of the mold 20 against the glass substrate 2 is kept constant during light irradiation (pressure pattern B2 ) Or in the middle of light irradiation (pressure pattern B3) to improve the transferability of the mold 20 to the resin 4A.
  • the resin 4A after light irradiation is temporarily cooled (naturally) between the end of light irradiation in the second light irradiation step and the release of the resin 4A from the mold 20 in the release step. (Including neglected).
  • a resin that is reactively cured by cationic polymerization such as an epoxy resin, has a slow reaction rate. Therefore, the reaction does not end only by irradiating a predetermined amount of light. Therefore, it is desirable to maintain the molding state until the reaction ends.
  • the pressing force of the mold 20 against the glass substrate 2 continues to decrease during the light irradiation period and during the cooling period, and during the transition from the light irradiation period to the cooling period. It switches in steps (pressure pattern B4).
  • the pressing force of the mold 20 against the glass substrate 2 is controlled according to the pressure pattern B2 or B3.
  • the glass substrate 2 is turned over, and the glass substrate 2 is formed in the same manner as the resin portion 4 is formed on the glass substrate 2 (by repeating the processes from the preparation step to the release step).
  • the resin part 6 is formed for 2.
  • a mold 24 for molding the concave lens portion 6a is used instead of the mold 20, and a resin 6A is used instead of the resin 4A.
  • the resin 6A may be temporarily cooled (including natural standing).
  • the light irradiation is divided into two stages of a first light irradiation process and a second light irradiation process, and the light irradiation range is determined by the convex lens part 4a in the first light irradiation process. Only in the range of the optical effective diameter (preferably within the range of the optical effective diameter), in the subsequent second light irradiation step, the entire resin 4A is changed (see FIGS. 4A and 4B).
  • the convex lens portion 4a begins to harden first, and then the non-lens portion 4b hardens, the convex shrinkage of the convex lens portion 4a occurs first, and the non-lens portion 4b shrinks after that.
  • the pressing force of the mold 20 is controlled according to the pressure patterns B2 and B3, so that the transferability of the mold 20 to the resin 4A can be reliably improved.
  • the thickness 4bth of the non-lens part 4b is thinner than the thickness 4ath of the convex lens part 4a, more accurate transfer can be achieved by simultaneously irradiating the non-lens part 4b and the convex lens part 4a with light. Transferability was not always sufficient for lenses that required high performance. This is because the non-lens portion 4b hardens first, and even if it tries to press the mold 20, the non-lens portion 4b inhibits the movement of the mold 20, and the pressing of the mold 20 is sufficiently transmitted to the convex lens portion 4a. It is thought that it is not possible to do.
  • the convex lens portion 4a is selectively irradiated with light and the non-lens portion 4b is not irradiated with light in the first light irradiation step. It can be seen that there is no hindrance to the movement of the mold 20, the pressure of the mold 20 can be sufficiently transmitted to the convex lens portion 4a, and as a result, the transferability of the mold 20 to the resin 4A can be improved reliably. It was.
  • is an example in which sink marks are suppressed and shows good transferability
  • X is an example in which sink marks or transferability is not good.
  • in the item of “deviation from optical surface design value” is an evaluation content that the lens portion 4a falls within a range where the optical surface can be corrected.
  • light irradiation may be intermittently performed as shown in FIG. 10 (irradiation pattern A3).
  • the light irradiation pattern A3 is effective when a resin having a particularly high curing rate is selected as the resin 4A among the photocurable resins.
  • the light irradiation is divided into two stages of a first light irradiation process and a second light irradiation process, and the light irradiation range is a concave lens in the first light irradiation process. Only the portion 6a (preferably within the optical effective diameter range) is changed to the entire resin 6A in the subsequent second light irradiation step (see FIG. 4D).
  • the concave lens portion 6a is already cured, and the contraction accompanying the curing of the non-lens portion 6b is the concave lens portion. 6a can be reduced, and the occurrence of sink marks can be suppressed in the concave lens portion 6a as the resin 6A is cured.
  • the pressing force of the mold 24 is not controlled after the second light irradiation process according to the pressure patterns B5 and B6. Transferability of the mold 24 to the resin 6A can be reliably improved.
  • the mold 24 is pressed while simultaneously irradiating light to the concave lens part 6a and the non-lens part 6b. If it continues, the concave lens part 6a will harden
  • the pressing of the mold 24 is released and the pressure is not controlled, so that the concave lens portion 6a is delayed during the curing of the non-lens portion 6b. Without being pressed, the state formed in the first light irradiation step can be maintained almost as it is, and as a result, the transferability of the mold 24 to the resin 6A can be reliably improved.
  • the method that does not control the pressing force in the second light irradiation step is not only in the case of a concave lens, but also in the case of an optical element in which a projection for positioning or the like as a non-lens part is formed thicker than the lens part around the lens part. Is also applicable.
  • the resin portion 6 may be temporarily reduced during a predetermined period in the first light irradiation process (irradiation pattern A4). ).
  • the light irradiation patterns A1 to A4 are disclosed in accordance with the formation mode of the resin parts 4 and 6, but the light irradiation patterns A1 to A4 are the first every time the resin parts 4 and 6 are formed.
  • the light irradiation step and the second light irradiation step may be appropriately combined.
  • the resin parts 4 and 6 are separately formed using the molds 20 and 24. However, the resin parts 4 and 6 may be formed simultaneously.
  • a mold 20 is used for forming the resin part 4 and a light-transmitting resin mold 26 is used for forming the resin part 6.
  • the resin mold 26 is a resin mold and is another example of a mold used for resin molding.
  • the resin mold 26 includes a molding part 26a and a support part 26b.
  • the molding part 26a has a convex surface corresponding to the concave lens part 6a, and the support part 26b supports the molding part 26a and increases its strength.
  • the resin 4A is filled between the mold 20 and the glass substrate 2
  • the resin 6A is filled between the resin mold 26 and the glass substrate 2, and light is applied in the first and second light irradiation steps. Irradiation is sufficient.
  • the resin portion 28 may be used for forming the resin portion 4, and the resin die 26 may be used for forming the resin portion 6.
  • the resin mold 28 is also a resin mold and is another example of a mold used for resin molding.
  • the resin mold 28 has substantially the same configuration as the resin mold 26.
  • the molding part 28a has a concave surface corresponding to the convex lens part 4a, and the support part 28b supports the molding part 26a and increases its strength.
  • the resin 4A is filled between the resin mold 28 and the glass substrate 2
  • the resin 6A is filled between the resin mold 26 and the glass substrate 2, respectively, in the first and second light irradiation steps.
  • Light may be irradiated from both above and below.
  • the wafer lens 1 is disclosed in which only one resin portion 4 or 6 is formed on the glass substrate 2, but a plurality of resin portions 4 (resin portions 6) are provided on the large-diameter glass substrate 2. And this may be used as the wafer lens 1.
  • the resin portion 4 is sequentially formed on one surface of the glass substrate 2 according to a so-called step-and-repeat method, and then the resin portion 6 is formed on the other surface of the glass substrate 2. You should form sequentially.
  • the second embodiment is different from the first embodiment in the following points, and other technical matters are the same as those of the first embodiment.
  • the second embodiment is largely different from the first embodiment in that the light shielding mask 120 is not used in the first and second light irradiation steps.
  • a lens array 96 is provided below the light source 90.
  • the light source 90 is turned on and the light is condensed by the lens array 96, and the convex lens portion 4a of the resin 4A is collected.
  • the lens array 96 is moved downward (the distance between the lens array 96 and the resin 4A is narrower than that in the first light irradiation step). ) The entire resin 4A is irradiated with light.
  • a plurality of point light sources 92 are provided instead of the light source 90.
  • the point light source 92 is disposed in a region where the resin 4A (resin 6A) can be irradiated with light.
  • the point light source 92 facing the cavity 22 of the mold 20 is turned on among the plurality of point light sources 92.
  • the resin 4A light is selectively irradiated only to a portion corresponding to the convex lens portion 4a.
  • the remaining point light sources 92 are also turned on, and the entire resin 4A is irradiated with light.
  • a plurality of point light sources 94 that are movable in the optical axis direction or a plurality of point light sources 94 ′ with variable irradiation light amount are provided.
  • the point light source 94 is a region where light can be irradiated to the resin 4A (resin 6A) and is disposed at a position facing the cavity 22 (transfer portion of the optical surface).
  • the point light source 94 is a light source that emits divergent light.
  • each point light source 94 in the first light irradiation step, is turned on (see the center of FIG. 17) and corresponds to the convex lens portion 4a in the resin 4A.
  • each point light source 94 is moved upward (the distance between each point light source 94 and the resin 4A is changed from the time of the first light irradiation step).
  • the resin 4A is irradiated with light (see the left side in FIG. 17). Alternatively, as shown on the right side in FIG.
  • the amount of electric power supplied to each point light source 94 ' is increased (the illuminance of each point light source 94' is increased from that in the first light irradiation step), and light is applied to the entire resin 4A. Irradiate.
  • the light distribution of the point light source 94 ′ has the largest amount of light in the central optical axis direction and the light amount in the peripheral portion is small. Therefore, the amount of electric power given in the first light irradiation step may be set to an amount of electric power that is not so large as to cure the resin of the non-lens portion, and in the second light irradiation step, the amount of electric power to cure the resin of the non-lens portion. .
  • the point light sources 92, 94, 94 ′ LEDs or lasers having an emission wavelength at a wavelength corresponding to the photosensitive wavelength of the reaction initiator or reaction sensitizer contained in the photocurable resin are used. it can.

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Abstract

A method for manufacturing a wafer lens is provided for the purpose of suppressing generation of sink marks on a lens section. The method wherein the lens section composed of a photocurable resin is formed on a glass substrate achieves the purpose by means of: a step of applying a resin between a metal die and the glass substrate; a step of radiating first light to a resin portion that corresponds to the lens section; and a step of radiating second light to the resin portion that corresponds to the lens section and the resin portion that corresponds to the non-lens section at the periphery of the lens section.

Description

ウエハレンズの製造方法Wafer lens manufacturing method

 本発明はウエハレンズの製造方法に関する。 The present invention relates to a method for manufacturing a wafer lens.

 従来、光学レンズの製造分野においては、ガラス基板に対し樹脂製のレンズ部を設けて、耐熱性の高い光学レンズを得る技術が検討されている(例えば、特許文献1参照)。この技術を適用した光学レンズの製造方法の一例として、ガラス基板の表面に光硬化性樹脂からなる光学部材を複数設けたいわゆる「ウエハレンズ」を形成し、その後にレンズ部ごとにガラス基板をカットする方法が提案されている。 Conventionally, in the field of manufacturing optical lenses, a technique for obtaining a highly heat-resistant optical lens by providing a resin lens portion on a glass substrate has been studied (for example, see Patent Document 1). As an example of a manufacturing method of an optical lens to which this technology is applied, a so-called “wafer lens” in which a plurality of optical members made of a photocurable resin is provided on the surface of a glass substrate is formed, and then the glass substrate is cut for each lens portion. A method has been proposed.

 ガラス基板に対し樹脂製のレンズ部を形成する方法の一例が特許文献2に開示されている。特許文献2の技術では、基板に光硬化性樹脂と熱硬化性樹脂および光重合剤と熱重合剤からなる組成物を塗布してその樹脂を光硬化(光照射)し、その後に賦形(成形型の樹脂への押当て)、熱硬化の各処理を行っている(段落0069~0080参照)。 An example of a method for forming a resin lens portion on a glass substrate is disclosed in Patent Document 2. In the technique of Patent Document 2, a composition comprising a photocurable resin, a thermosetting resin, a photopolymerization agent and a thermal polymerization agent is applied to a substrate, the resin is photocured (light irradiation), and then shaped ( (Pressing of mold to resin) and thermosetting (see paragraphs 0069 to 0080).

 他の例としては、ガラス基板と成形型との間に光硬化性樹脂を充填してその状態で光照射する方法もある。この場合、光の照射時において、レンズ部の光学面には、サブミクロンオーダー以下の高い精度で成形型から転写されることが要求される。 As another example, there is a method in which a photocurable resin is filled between a glass substrate and a mold and light is irradiated in that state. In this case, at the time of light irradiation, the optical surface of the lens unit is required to be transferred from the mold with high accuracy of the order of submicron or less.

特許第3926380号公報Japanese Patent No. 3926380 特開2003-286301号公報JP 2003-286301 A

 しかしながら、光硬化性樹脂は一般に硬化により収縮する特性を有しており、光の照射を受けた場合に、成形型の内部でやや収縮しながら硬化する。 However, the photo-curable resin generally has a property of shrinking by curing, and is cured while slightly shrinking inside the mold when irradiated with light.

 この場合特に、レンズ部(入射光を屈折や回折作用により収束や拡散を生じさせる部分)の周辺の非レンズ部で収縮が起こると、その収縮がレンズ部におよんでレンズ部の樹脂が非レンズ部側に引っ張られ、レンズ部でヒケが発生する。この事は特にレンズ部でも有効径範囲内の部分で生じた場合、構成されるレンズとしての光学特性に影響を及ぼす。 In this case, in particular, when shrinkage occurs in the non-lens part around the lens part (the part where the incident light is converged or diffused by refraction or diffraction action), the shrinkage reaches the lens part and the resin in the lens part is non-lensed. Pulled to the side of the lens, sinks occur in the lens. This particularly affects the optical characteristics of the constructed lens when it occurs in the lens portion within the effective diameter range.

 したがって、本発明の主な目的は、レンズ部、少なくともレンズ部の中でも有効径の範囲内でヒケが発生するのを抑制することができる光学素子の製造方法を提供することにある。 Therefore, a main object of the present invention is to provide a method of manufacturing an optical element capable of suppressing the occurrence of sink marks within the effective diameter range of the lens part, at least the lens part.

 本発明の一態様によれば、
 基板に対しレンズ部とその周辺の非レンズ部とを有する複数のレンズを光硬化性樹脂で形成するウエハレンズの製造方法において、
 成形型と前記基板との間に前記光硬化性樹脂を充填する工程と、
 前記光硬化性樹脂に対して光照射を行う事で前記光硬化性樹脂の硬化を進める硬化工程と、を有し、
 前記硬化工程は、前記光硬化性樹脂の第1の領域に光を照射する第1光照射工程と、前記第1の領域よりも広い照射領域の第2の領域に光を照射する第2光照射工程とを有することを特徴とするウエハレンズの製造方法が提供される。
According to one aspect of the invention,
In a method for manufacturing a wafer lens, in which a plurality of lenses having a lens portion and a non-lens portion around the lens portion are formed on a substrate with a photocurable resin,
Filling the photocurable resin between the mold and the substrate;
A curing step of advancing curing of the photocurable resin by performing light irradiation on the photocurable resin,
The curing step includes a first light irradiation step of irradiating the first region of the photocurable resin with light, and a second light irradiating the second region of the irradiation region wider than the first region. There is provided a method for manufacturing a wafer lens, comprising an irradiation step.

 本発明の他の態様によれば、
 基板に対しレンズ部とその周辺の非レンズ部とを有する複数のレンズを光硬化性樹脂で形成するウエハレンズの製造方法において、
 成形型と前記基板との間に前記光硬化性樹脂を充填する工程と、
 前記光硬化性樹脂に対して光照射を行う事で前記光硬化性樹脂の硬化を進める硬化工程と、を有し
 前記硬化工程は、前記光硬化性樹脂のレンズ部に対応する部位のみを照射する第1光照射工程と、前記光硬化性樹脂の前記レンズ部の周囲の非レンズ部に対応する部位を照射する第2光照射工程とを有することを特徴とするウエハレンズの製造方法が提供される。
According to another aspect of the invention,
In a method for manufacturing a wafer lens, in which a plurality of lenses having a lens portion and a non-lens portion around the lens portion are formed on a substrate with a photocurable resin,
Filling the photocurable resin between the mold and the substrate;
A curing step of proceeding curing of the photocurable resin by irradiating the photocurable resin with light, and the curing step irradiates only a portion corresponding to the lens portion of the photocurable resin. And a second light irradiation step of irradiating a portion corresponding to a non-lens portion around the lens portion of the photocurable resin. Is done.

 本発明によれば、レンズ部、少なくともレンズ部の中でも有効径の範囲内でヒケが発生するのを抑制することができる。 According to the present invention, it is possible to suppress the occurrence of sink marks within the effective diameter within the lens portion, at least the lens portion.

本発明の好ましい実施形態(第1の実施形態)にかかるウエハレンズの概略構成を示す断面図である。It is sectional drawing which shows schematic structure of the wafer lens concerning preferable embodiment (1st Embodiment) of this invention. 第1の実施形態にかかるウエハレンズ製造装置の概略構成を示す図面である。It is drawing which shows schematic structure of the wafer lens manufacturing apparatus concerning 1st Embodiment. 第1の実施形態にかかるウエハレンズ製造装置の概略的な制御構成を示すブロック図である。It is a block diagram which shows the schematic control structure of the wafer lens manufacturing apparatus concerning 1st Embodiment. 第1の実施形態にかかるウエハレンズの製造方法を経時的に説明するための概略図である。It is the schematic for demonstrating with time the manufacturing method of the wafer lens concerning 1st Embodiment. 図4の製造方法における光の照射パターンの一例を示す概略図である。It is the schematic which shows an example of the irradiation pattern of the light in the manufacturing method of FIG. 図4の製造方法において樹脂部(凸レンズ部)を形成する際の圧力制御パターンの一例を示す概略図である。It is the schematic which shows an example of the pressure control pattern at the time of forming the resin part (convex lens part) in the manufacturing method of FIG. 図6の変形例を示す概略図である。It is the schematic which shows the modification of FIG. 図4の製造方法において樹脂部(凹レンズ部)を形成する際の圧力制御パターンの一例を示す概略図である。It is the schematic which shows an example of the pressure control pattern at the time of forming the resin part (concave lens part) in the manufacturing method of FIG. 図8の変形例を示す概略図である。It is the schematic which shows the modification of FIG. 図5の変形例を示す概略図である。It is the schematic which shows the modification of FIG. 図5の変形例を示す概略図である。It is the schematic which shows the modification of FIG. 第1の実施形態で使用される成形型の組合せを説明するための概略図である。It is the schematic for demonstrating the combination of the shaping | molding die used by 1st Embodiment. 図12の変形例を示す概略図である。It is the schematic which shows the modification of FIG. 図1のウエハレンズの変形例について説明するための概略図である。It is the schematic for demonstrating the modification of the wafer lens of FIG. 本発明の好ましい実施形態(第2の実施形態)にかかるウエハレンズ製造装置とそれを用いた製造方法を概略的に説明するための図面である。It is drawing for demonstrating schematically the wafer lens manufacturing apparatus concerning preferable embodiment (2nd Embodiment) of this invention, and a manufacturing method using the same. 図15の変形例を示す概略図である。It is the schematic which shows the modification of FIG. 図15の変形例を示す概略図である。It is the schematic which shows the modification of FIG.

 以下、図面を参照しながら本発明の好ましい実施形態について説明する。
[第1の実施形態]
 図1に示す通り、ウエハレンズ1はガラス基板2を有している。ガラス基板2は基板の一例であり、図の上方から見たときウエハ状(円形状)を呈している。
Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.
[First Embodiment]
As shown in FIG. 1, the wafer lens 1 has a glass substrate 2. The glass substrate 2 is an example of a substrate and has a wafer shape (circular shape) when viewed from above.

 ガラス基板2の上部には樹脂部4が設けられている。 The resin part 4 is provided on the upper part of the glass substrate 2.

 樹脂部4は、入射光に対して屈折作用や回折作用により入射光を収束や発散させる部分である凸レンズ部4aと、入射光をそのまま透過させる非レンズ部4bとから構成されている。図1では屈折作用を生じさせる部位としての凸レンズ部4aは、凸レンズ状の光学面を構成している。非レンズ部4bは、凸レンズ部4a以外の部位であって凸レンズ部4aの周辺の部位であり、平板状に構成されて実質入射光をそのまま透過させる。 The resin part 4 includes a convex lens part 4a that is a part for converging or diverging incident light by refraction or diffraction action with respect to the incident light, and a non-lens part 4b that transmits the incident light as it is. In FIG. 1, the convex lens portion 4a serving as a part that causes a refractive action constitutes a convex lens-shaped optical surface. The non-lens part 4b is a part other than the convex lens part 4a and a part around the convex lens part 4a, and is configured in a flat plate shape to transmit substantially incident light as it is.

 なお、非レンズ部4bとしては、必ずしも平板状である必要はなく、本発明を撮像光学系のレンズとして用いた場合に、当該レンズとしての光学機能に寄与しない範囲の部位であればよく、従って、当該領域には他の部材との位置決めや保持等のため、保持に適した形状や、他のレンズ部材や撮像素子部材との間隔を規定するためのスペーサー部分としての機能を有するものであっても良い。 The non-lens portion 4b does not necessarily have a flat plate shape, and may be a portion that does not contribute to the optical function as the lens when the present invention is used as a lens of an imaging optical system. The region has a function suitable as a spacer portion for defining the shape suitable for holding and the distance from other lens members and imaging element members for positioning and holding with other members. May be.

 凸レンズ部4aの厚さ4athは、凸レンズ部4aが凸状を呈しているため非レンズ部4bの厚さ4bthより肉厚となっている。 The thickness 4ath of the convex lens portion 4a is thicker than the thickness 4bth of the non-lens portion 4b because the convex lens portion 4a has a convex shape.

 ガラス基板2の下部には樹脂部6が設けられている。 The resin part 6 is provided in the lower part of the glass substrate 2.

 樹脂部6は、入射光に対して屈折作用や回折作用により入射光を収束や発散させる部分である凹レンズ部6aと、入射光をそのまま透過させる非レンズ部6bとから構成されている。図1では屈折作用を生じさせる部位としての凹レンズ部6aは、凹レンズ状の光学面を構成している。非レンズ部6bは、凹レンズ部6a以外の部位であって凹レンズ部6aの周辺の部位であり、平板状に構成されて実質入射光をそのまま透過させる。 The resin portion 6 includes a concave lens portion 6a that is a portion for converging or diverging incident light by refraction or diffraction action with respect to incident light, and a non-lens portion 6b that transmits incident light as it is. In FIG. 1, the concave lens portion 6a serving as a portion that causes a refractive action constitutes a concave lens-shaped optical surface. The non-lens portion 6b is a portion other than the concave lens portion 6a and a portion around the concave lens portion 6a, and is configured in a flat plate shape to transmit substantially incident light as it is.

 なお、非レンズ部6bとしては、必ずしも平板状である必要はなく、本発明を撮像光学系のレンズとして用いた場合に、当該レンズとしての光学機能に寄与しない範囲の部位であればよく、従って、当該領域には他の部材との位置決めや保持等のため、保持に適した形状や、他のレンズ部材や撮像素子部材との間隔を規定するためのスペーサー部分としての機能を有するものであっても良い。 The non-lens portion 6b does not necessarily have a flat plate shape, and may be a portion in a range that does not contribute to the optical function as the lens when the present invention is used as a lens of an imaging optical system. The region has a function suitable as a spacer portion for defining the shape suitable for holding and the distance from other lens members and imaging element members for positioning and holding with other members. May be.

 凹レンズ部6aの厚さ6athは、凹レンズ部6aが凹状を呈しているため非レンズ部6bの厚さ6bthより肉薄となっている。 The thickness 6ath of the concave lens portion 6a is thinner than the thickness 6bth of the non-lens portion 6b because the concave lens portion 6a has a concave shape.

 なお、図1では隣り合うレンズ部4a,6a間の非レンズ部4b,6bがつながった形で樹脂部4,6が形成されているが、必ずしもこれには限定されない。即ち、成型時に光硬化性樹脂を成形型のキャビティに対応する部分に個別に滴下して成形する事により、各々のレンズ部4a,6aは周囲に非レンズ部4b,6bは形成されても、個別に独立して形成されるものであっても良い。 In FIG. 1, the resin parts 4 and 6 are formed in a form in which the non-lens parts 4 b and 6 b between the adjacent lens parts 4 a and 6 a are connected, but the resin parts 4 and 6 are not necessarily limited thereto. That is, by individually dropping and molding a photo-curable resin on the part corresponding to the cavity of the mold during molding, each lens part 4a, 6a is formed with non-lens parts 4b, 6b around, It may be formed independently.

 ウエハレンズ1は、凸レンズ部4aと凹レンズ部6aとが1対1で対応した、いわゆるメニスカスレンズであり、凸レンズ部4a,凹レンズ部6aごとに断片化され撮像装置などに組み込まれるようになっている。 The wafer lens 1 is a so-called meniscus lens in which the convex lens portion 4a and the concave lens portion 6a are in a one-to-one correspondence. .

 樹脂部4と樹脂部6とはそれぞれ樹脂4A,6Aから構成されている。 The resin part 4 and the resin part 6 are composed of resins 4A and 6A, respectively.

 樹脂4A,6Aは光硬化性樹脂であるが、本発明がもっとも効果を発揮するのは、硬化により収縮が大きいアクリル樹脂など、特にラジカル重合により硬化させることができる樹脂である。 Resins 4A and 6A are photocurable resins, but the present invention is most effective for resins that can be cured by radical polymerization, such as acrylic resins that are highly contracted by curing.

 当該アクリル樹脂の具体例は下記の通りである。
[アクリル樹脂]
 重合反応に用いられる(メタ)アクリレートは特に制限はなく、一般的な製造方法により製造された下記(メタ)アクリレートを使用することができる。すなわち、エステル(メタ)アクリレート、ウレタン(メタ)アクリレート、エポキシ(メタ)アクリレート、エーテル(メタ)アクリレート、アルキル(メタ)アクリレート、アルキレン(メタ)アクリレート、芳香環を有する(メタ)アクリレート、脂環式構造を有する(メタ)アクリレートが挙げられる。これらを1種類又は2種類以上を用いることができる。
Specific examples of the acrylic resin are as follows.
[acrylic resin]
The (meth) acrylate used for the polymerization reaction is not particularly limited, and the following (meth) acrylate produced by a general production method can be used. That is, ester (meth) acrylate, urethane (meth) acrylate, epoxy (meth) acrylate, ether (meth) acrylate, alkyl (meth) acrylate, alkylene (meth) acrylate, (meth) acrylate having an aromatic ring, alicyclic Examples include (meth) acrylate having a structure. One or more of these can be used.

 特に脂環式構造を持つ(メタ)アクリレートが好ましく、酸素原子や窒素原子を含む脂環構造であってもよい。例えば、シクロヘキシル(メタ)アクリレート、シクロペンチル(メタ)アクリレート、シクロヘプチル(メタ)アクリレート、ビシクロヘプチル(メタ)アクリレート、トリシクロデシル(メタ)アクリレート、トリシクロデカンジメタノール(メタ)アクリレートや、イソボロニル(メタ)アクリレート、水添ビスフェノール類のジ(メタ)アクリレート等が挙げられる。また特にアダマンタン骨格を持つと好ましい。例えば、2-アルキル-2-アダマンチル(メタ)アクリレート(特開2002-193883号公報参照)、アダマンチルジ(メタ)アクリレート(特開昭57-500785号公報参照)、アダマンチルジカルボン酸ジアリル(特開昭60-100537号公報参照)、パーフルオロアダマンチルアクリル酸エステル(特開2004-123687号公報参照)、新中村化学製 2-メチル-2-アダマンチルメタクリレート、1,3-アダマンタンジオールジアクリレート、1,3,5-アダマンタントリオールトリアクリレート、不飽和カルボン酸アダマンチルエステル(特開2000-119220号公報参照)、3,3′-ジアルコキシカルボニル-1,1′ビアダマンタン(特開2001-253835号公報参照)、1,1′-ビアダマンタン化合物(米国特許第3342880号明細書参照)、テトラアダマンタン(特開2006-169177号公報参照)、2-アルキル-2-ヒドロキシアダマンタン、2-アルキレンアダマンタン、1,3-アダマンタンジカルボン酸ジ-tert-ブチル等の芳香環を有しないアダマンタン骨格を有する硬化性樹脂(特開2001-322950号公報参照)、ビス(ヒドロキシフェニル)アダマンタン類やビス(グリシジルオキシフェニル)アダマンタン(特開平11-35522号公報、特開平10-130371号公報参照)等が挙げられる。 (Meth) acrylate having an alicyclic structure is particularly preferable, and may be an alicyclic structure containing an oxygen atom or a nitrogen atom. For example, cyclohexyl (meth) acrylate, cyclopentyl (meth) acrylate, cycloheptyl (meth) acrylate, bicycloheptyl (meth) acrylate, tricyclodecyl (meth) acrylate, tricyclodecane dimethanol (meth) acrylate, isoboronyl (meth) ) Acrylate, di (meth) acrylate of hydrogenated bisphenols, and the like. In particular, it preferably has an adamantane skeleton. For example, 2-alkyl-2-adamantyl (meth) acrylate (see Japanese Patent Application Laid-Open No. 2002-193883), adamantyl di (meth) acrylate (see Japanese Patent Application Laid-Open No. 57-5000785), diallyl adamantyl dicarboxylate (Japanese Patent Application Laid-Open No. 60-10000537), perfluoroadamantyl acrylate (see JP 2004-123687), Shin-Nakamura Chemical Co., Ltd. 2-methyl-2-adamantyl methacrylate, 1,3-adamantanediol diacrylate, 1,3 , 5-adamantanetriol triacrylate, unsaturated carboxylic acid adamantyl ester (see JP 2000-119220 A), 3,3′-dialkoxycarbonyl-1,1 ′ biadamantane (see JP 2001-253835 A) , 1,1 -Biadamantane compound (see US Pat. No. 3,342,880), tetraadamantane (see JP 2006-169177), 2-alkyl-2-hydroxyadamantane, 2-alkyleneadamantane, 1,3-adamantane dicarboxylic acid diacid Curable resins having an adamantane skeleton having no aromatic ring such as tert-butyl (see JP-A-2001-322950), bis (hydroxyphenyl) adamantanes and bis (glycidyloxyphenyl) adamantane (JP-A-11-35522) And Japanese Patent Laid-Open No. 10-130371).

 また、その他反応性単量体を含有することも可能である。(メタ)アクリレートであれば、例えば、メチルアクリレート、メチルメタアクリレート、n-ブチルアクリレート、n-ブチルメタアクリレート、2-エチルヘキシルアクリレート、2-エチルヘキシルメタアクリレート、イソブチルアクリレート、イソブチルメタアクリレート、tert-ブチルアクリレート、tert-ブチルメタアクリレート、フェニルアクリレート、フェニルメタアクリレート、ベンジルアクリレート、ベンジルメタアクリレート、シクロヘキシルアクリレート、シクロヘキシルメタアクリレート、などが挙げられる。 It is also possible to contain other reactive monomers. In the case of (meth) acrylate, for example, methyl acrylate, methyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isobutyl acrylate, isobutyl methacrylate, tert-butyl acrylate Tert-butyl methacrylate, phenyl acrylate, phenyl methacrylate, benzyl acrylate, benzyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, and the like.

 多官能(メタ)アクリレートとして、例えば、トリメチロールプロパントリ(メタ)アクリレート、ペンタエリスリトールテトラ(メタ)アクリレート、ペンタエリスリトールトリ(メタ)アクリレート、ジペンタエリスリトールヘキサ(メタ)アクリレート、ジペンタエリスリトールペンタ(メタ)アクリレート、ジペンタエリスリトールテトラ(メタ)アクリレート、ジペンタエリスリトールトリ(メタ)アクリレート、トリペンタエリスリトールオクタ(メタ)アクリレート、トリペンタエリスリトールセプタ(メタ)アクリレート、トリペンタエリスリトールヘキサ(メタ)アクリレート、トリペンタエリスリトールペンタ(メタ)アクリレート、トリペンタエリスリトールテトラ(メタ)アクリレート、トリペンタエリスリトールトリ(メタ)アクリレートなどが挙げられる。 Examples of the polyfunctional (meth) acrylate include trimethylolpropane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, dipentaerythritol hexa (meth) acrylate, dipentaerythritol penta (meth) ) Acrylate, dipentaerythritol tetra (meth) acrylate, dipentaerythritol tri (meth) acrylate, tripentaerythritol octa (meth) acrylate, tripentaerythritol septa (meth) acrylate, tripentaerythritol hexa (meth) acrylate, tripenta Erythritol penta (meth) acrylate, tripentaerythritol tetra (meth) acrylate, tripentaerythritol And tri (meth) acrylate.

 なお、樹脂4A,6Aとしてアリル樹脂などを用いることができ、当該樹脂もラジカル重合により硬化させることができる。 In addition, an allyl resin or the like can be used as the resins 4A and 6A, and the resin can be cured by radical polymerization.

 その他、樹脂4A,6Aとして使用可能な光硬化性樹脂には、例えばエポキシ系の樹脂などがあり、当該樹脂はカチオン重合により硬化させることができる。 In addition, photocurable resins that can be used as the resins 4A and 6A include, for example, epoxy resins, and the resins can be cured by cationic polymerization.

 ここで、本発明に使用する光硬化性樹脂には、上述のごとき光硬化性樹脂のみならず、光重合開始剤に加えて熱重合開始剤を含み、加熱による熱重合での硬化が併用されるものも含む。 Here, the photocurable resin used in the present invention includes not only the photocurable resin as described above but also a thermal polymerization initiator in addition to the photopolymerization initiator, and is combined with curing by thermal polymerization by heating. Also included.

 また、硬化させる光は、可視光、紫外光のみならず電子線なども含む。さらに、後述する第2の光照射工程の後に熱を加えて硬化を完了させる、いわゆるポストキュア工程を設けてもよい。重合開始剤として光重合開始剤のみを含む光硬化性樹脂の場合であっても、加熱によって光硬化が促進されるのであるが、ここにさらに熱重合開始剤も配合されていると、その促進効果はさらに増す。 Further, the light to be cured includes not only visible light and ultraviolet light but also electron beams. Furthermore, you may provide what is called a post-cure process which completes hardening by applying heat after the 2nd light irradiation process mentioned later. Even in the case of a photocurable resin containing only a photopolymerization initiator as a polymerization initiator, photocuring is accelerated by heating, but if a thermal polymerization initiator is further blended here, the acceleration is promoted. The effect is further increased.

 続いて、ウエハレンズ1を製造する際に使用されるウエハレンズ製造装置(30)の一例について説明する。 Subsequently, an example of a wafer lens manufacturing apparatus (30) used when manufacturing the wafer lens 1 will be described.

 図2に示す通り、ウエハレンズ製造装置30はベース32を有している。 As shown in FIG. 2, the wafer lens manufacturing apparatus 30 has a base 32.

 ベース30の上部には内側に突出する突出部34が形成されている。ベース32の底部と突出部34との間にはガイド36が立設されている。ガイド36間にはステージ40が設けられている。ステージ40には貫通孔42が形成されており、ガイド36が貫通孔42を貫通している。 A protruding portion 34 that protrudes inward is formed on the upper portion of the base 30. A guide 36 is erected between the bottom of the base 32 and the protrusion 34. A stage 40 is provided between the guides 36. A through hole 42 is formed in the stage 40, and the guide 36 passes through the through hole 42.

 ベース32上であってステージ40の下方にはギヤードモータ50が設けられている。ギヤードモータ50は点線で示すポテンショメータ51を内蔵している。ギヤードモータ50にはシャフト52が連結されている。 A geared motor 50 is provided on the base 32 and below the stage 40. The geared motor 50 has a built-in potentiometer 51 indicated by a dotted line. A shaft 52 is connected to the geared motor 50.

 ステージ40の下部とシャフト52の間には圧力検出用のロードセル44が設けられており、ステージ40の自重でシャフト52の先端部がロードセル44と当接している。 A load cell 44 for pressure detection is provided between the lower portion of the stage 40 and the shaft 52, and the tip of the shaft 52 is in contact with the load cell 44 by the weight of the stage 40.

 このウエハレンズ製造装置30は、ギヤードモータ50の作動によりシャフト52が上下方向に伸縮するようになっており、これに伴いステージ40がガイド36に案内されながら上下方向に移動可能となっている。 In this wafer lens manufacturing apparatus 30, the shaft 52 extends and contracts in the vertical direction by the operation of the geared motor 50, and accordingly, the stage 40 is movable in the vertical direction while being guided by the guide 36.

 ステージ40にはほぼ半球形状を呈した凹部46が形成されている。凹部46には平行出し部材60が埋設されている。平行出し部材60は水面に浮かぶお椀のように凹部46に対し揺動可能となっている。 The recess 40 having a substantially hemispherical shape is formed on the stage 40. A paralleling member 60 is embedded in the recess 46. The paralleling member 60 can swing with respect to the recess 46 like a bowl floating on the water surface.

 平行出し部材60上にはXYステージ62,θステージ64が設けられている。XYステージ62はステージ40上のXY平面(2次元平面)において移動可能となっており、θステージ64はその中心部を回転軸として回動可能となっている。 An XY stage 62 and a θ stage 64 are provided on the parallel projecting member 60. The XY stage 62 is movable on an XY plane (two-dimensional plane) on the stage 40, and the θ stage 64 is rotatable about its central portion as a rotation axis.

 XYステージ62,θステージ64上には真空チャック装置70が設置されている。真空チャック装置70には同心円状の連通溝72が形成されている。連通溝72には吸引機構(図示略)が連結されており、当該吸引機構の作動により連通溝72からエアを吸引し、真空チャック装置70上の部材を吸引・固定することができるようになっている。 A vacuum chuck device 70 is installed on the XY stage 62 and the θ stage 64. A concentric communication groove 72 is formed in the vacuum chuck device 70. A suction mechanism (not shown) is connected to the communication groove 72, and air can be sucked from the communication groove 72 by the operation of the suction mechanism, and members on the vacuum chuck device 70 can be sucked and fixed. ing.

 本実施形態では、真空チャック装置70上に金型20が配置され真空チャック装置70により金型20が吸引・固定される。金型20は金属製の成形型であり、樹脂の成形に用いられる成形型の一例である。金型20上には成形しようとする樹脂(樹脂4Aなど)が配置される。 In this embodiment, the mold 20 is disposed on the vacuum chuck device 70, and the mold 20 is sucked and fixed by the vacuum chuck device 70. The mold 20 is a metal mold and is an example of a mold used for resin molding. A resin (resin 4A or the like) to be molded is placed on the mold 20.

 ベース32の上部には基板ホルダ80が固定されている。基板ホルダ80の端部には同心円状の連通溝82が形成されており、連通溝82には吸引機構(図示略)が連結されている。真空チャック装置70の作動時と同様に、当該吸引機構が作動すると、連通溝82からエアを吸引してガラス基板2が基板ホルダ80に吸引・固定される。 The substrate holder 80 is fixed to the upper part of the base 32. A concentric communication groove 82 is formed at the end of the substrate holder 80, and a suction mechanism (not shown) is connected to the communication groove 82. Similarly to the operation of the vacuum chuck device 70, when the suction mechanism operates, the glass substrate 2 is sucked and fixed to the substrate holder 80 by sucking air from the communication groove 82.

 基板ホルダ80の上方には光源90が設けられており、光源90の点灯により光がガラス基板2を透過して金型20上の樹脂(樹脂4Aなど)に照射されるようになっている。 A light source 90 is provided above the substrate holder 80. When the light source 90 is turned on, light passes through the glass substrate 2 and is irradiated onto a resin (resin 4A, etc.) on the mold 20.

 光源90としては高圧水銀ランプ,メタルハライドランプ,キセノンランプ,ハロゲンランプ,蛍光灯,ブラックライト,Gランプ,Fランプ,LED等が使用される。 As the light source 90, a high-pressure mercury lamp, metal halide lamp, xenon lamp, halogen lamp, fluorescent lamp, black light, G lamp, F lamp, LED, or the like is used.

 高圧水銀ランプは、365nm,436nmに狭いスペクトルを持つランプである。メタルハライドランプは、水銀灯の一種で、紫外域における出力は高圧水銀ランプよりも数倍高い。キセノンランプは、最も太陽光に近いスペクトルを持つランプである。ハロゲンランプは長波長の光を多く含んでおり、近赤外光がほとんどであるランプである。蛍光灯は光の三原色に均等な照射強度を持っている。ブラックライトはピークトップを351nmに持ち、300~400nmの近紫外光を放射するライトである。LEDは、用いる材料によって発光色が異なり、赤外線領域から可視光域、紫外線領域で発光するものまで製造することができる。 The high-pressure mercury lamp is a lamp having a narrow spectrum at 365 nm and 436 nm. A metal halide lamp is a kind of mercury lamp, and its output in the ultraviolet region is several times higher than that of a high-pressure mercury lamp. A xenon lamp is a lamp having a spectrum closest to sunlight. Halogen lamps contain a lot of long-wavelength light and are mostly near-infrared light. Fluorescent lamps have uniform illumination intensity for the three primary colors of light. Black light has a peak top at 351 nm and emits near-ultraviolet light of 300 to 400 nm. LEDs have different emission colors depending on the materials used, and can produce LEDs that emit light in the infrared region, visible light region, and ultraviolet region.

 図3に示す通り、ロードセル44,ギヤードモータ50,ポテンショメータ51,平行出し部材60,XYステージ62,θステージ64,真空チャック装置70(吸引機構),基板ホルダ80(吸引機構),光源90は制御装置100に接続されている。制御装置100はこれら部材の動作を制御する。 As shown in FIG. 3, the load cell 44, geared motor 50, potentiometer 51, parallelizing member 60, XY stage 62, θ stage 64, vacuum chuck device 70 (suction mechanism), substrate holder 80 (suction mechanism), and light source 90 are controlled. It is connected to the device 100. The control device 100 controls the operation of these members.

 特に本実施形態では、制御装置100はロードセル44,ポテンショメータ51の出力値に基づきギヤードモータ50の動作(回転量)を制御するようになっている。 Particularly in the present embodiment, the control device 100 controls the operation (rotation amount) of the geared motor 50 based on the output values of the load cell 44 and the potentiometer 51.

 続いて、ウエハレンズ製造装置30を用いたウエハレンズ1の製造方法について説明する。 Subsequently, a method for manufacturing the wafer lens 1 using the wafer lens manufacturing apparatus 30 will be described.

 図2に示す通り、はじめに、基板ホルダ80に対しガラス基板2を設置して吸引・固定するとともに、真空チャック装置70に対し金型20を設置して金型20を吸引・固定する。 As shown in FIG. 2, first, the glass substrate 2 is placed on the substrate holder 80 and sucked and fixed, and the mold 20 is placed on the vacuum chuck device 70 and the mold 20 is sucked and fixed.

 その後、金型20上に所定量の樹脂4Aを滴下する。そして、制御装置100により平行出し部材60,XYステージ62,θステージ64を制御して、ガラス基板2の下面と金型20の上面とを平行にする(準備工程)。 Thereafter, a predetermined amount of resin 4A is dropped on the mold 20. And the paralleling member 60, XY stage 62, and (theta) stage 64 are controlled by the control apparatus 100, and the lower surface of the glass substrate 2 and the upper surface of the metal mold | die 20 are made parallel (preparation process).

 なお、ここでは樹脂4Aを金型20上に滴下しているが、本発明はこれに限定されず、ガラス基板2上に滴下しても良い。また滴下の方法も所定箇所に滴下して、それらを押し広げる事で各キャビティ22に充填する方法や、予め金型20の各キャビティ22や、ガラス基板2の各レンズ部4aが形成される箇所に個別に滴下し、それらを対向配置された金型20やガラス基板2で押圧することによって充填する方法であっても良い。 In addition, although resin 4A is dripped on the metal mold | die 20 here, this invention is not limited to this, You may dripping on the glass substrate 2. FIG. In addition, the dropping method is also a method in which each cavity 22 is filled by dropping and spreading them on a predetermined location, or each cavity 22 of the mold 20 or each lens portion 4a of the glass substrate 2 is formed in advance. Alternatively, a method may be used in which the liquid is dropped individually, and is filled by pressing them with the mold 20 or the glass substrate 2 facing each other.

 この状態において、金型20を位置制御して、ガラス基板2に対し金型20を所定位置まで移動させ、金型20をその位置で保持する。 In this state, the position of the mold 20 is controlled, the mold 20 is moved to a predetermined position with respect to the glass substrate 2, and the mold 20 is held at that position.

 具体的には、ギヤードモータ50を作動させてシャフト52を上方に伸ばし、金型20を上方に移動させる。この場合、制御装置100がポテンショメータ51の出力値に基づきギヤードモータ50の作動を制御し、金型20を所定の高さ位置まで移動させる。 Specifically, the geared motor 50 is operated to extend the shaft 52 upward, and the mold 20 is moved upward. In this case, the control device 100 controls the operation of the geared motor 50 based on the output value of the potentiometer 51, and moves the mold 20 to a predetermined height position.

 移動させようとする金型20の高さ位置は、制御装置100に予め設定されており、制御装置100は金型20が基準位置Sに到達する位置までギヤードモータ50を作動させ、金型20が基準位置Sに到達したらギヤードモータ50の作動を停止させる(位置制御工程)。 The height position of the mold 20 to be moved is set in the control device 100 in advance, and the control device 100 operates the geared motor 50 to a position where the mold 20 reaches the reference position S. When reaching the reference position S, the operation of the geared motor 50 is stopped (position control step).

 その結果、樹脂4Aが、金型20からガラス基板2への押圧を受けて徐々に広がり、ガラス基板2と金型20との間(特に金型20のキャビティ22)に充填される。 As a result, the resin 4A gradually receives the pressure from the mold 20 to the glass substrate 2 and spreads between the glass substrate 2 and the mold 20 (particularly, the cavity 22 of the mold 20).

 その後、図4(a)に示す通り、ガラス基板2の上方であってガラス基板2と光源90との間に遮光マスク120を配置する。遮光マスク120には、金型20のキャビティ22に対応する部分(好ましくはキャビティ22中で凸レンズ部4aの光学有効径範囲:撮像装置を構成する場合には、当該レンズ部を透過して後段の撮像センサの有効画素領域に結像するのに必要な入射瞳径の範囲)が開口した開口部122が形成されている。 Thereafter, as shown in FIG. 4A, a light shielding mask 120 is disposed above the glass substrate 2 and between the glass substrate 2 and the light source 90. The light shielding mask 120 has a portion corresponding to the cavity 22 of the mold 20 (preferably the optical effective diameter range of the convex lens portion 4a in the cavity 22; in the case of configuring an imaging device, the lens portion is transmitted through the lens portion later. An opening 122 in which an entrance pupil diameter range necessary for forming an image in an effective pixel region of the image sensor is opened is formed.

 その後、金型20を基準位置Sに対応する位置で保持したまま、光源90を点灯させ、樹脂4Aに向けて光を照射する(第1の光照射工程)。 Thereafter, the light source 90 is turned on while the mold 20 is held at the position corresponding to the reference position S, and light is irradiated toward the resin 4A (first light irradiation step).

 第1の光照射工程では、遮光マスク120に開口部122が形成されているから、光源90の光は開口部122ではこれを透過して樹脂4Aに到達し、開口部122以外の部位では遮光される。これにより、樹脂4Aのうち、金型20のキャビティ22の転写を受ける部位であって凸レンズ部4aに対応する部位に、それ以外の部位に先行して光を照射することとなり、凸レンズ部4a(好ましくは凸レンズ部4aの光学有効径の範囲内)を選択的に硬化させ始める。 In the first light irradiation process, since the opening 122 is formed in the light shielding mask 120, the light from the light source 90 passes through the opening 122 and reaches the resin 4 </ b> A, and is shielded at a portion other than the opening 122. Is done. As a result, the portion of the resin 4A that receives the transfer of the cavity 22 of the mold 20 and that corresponds to the convex lens portion 4a is irradiated with light prior to other portions, and the convex lens portion 4a ( Preferably, it begins to cure selectively within the optical effective diameter range of the convex lens portion 4a.

 なお、第1の光照射工程では、遮光マスク120(開口部122の開口径)を変更することで、凸レンズ部4aを中心からの径の大きさに応じて分割し、中心の領域から外周の領域に向けて順次光を照射するようにしてもよい。 In the first light irradiation step, the convex lens portion 4a is divided according to the size of the diameter from the center by changing the light shielding mask 120 (the opening diameter of the opening portion 122), and the outer periphery from the center region is divided. You may make it irradiate light sequentially toward an area | region.

 例えば、図4(a)に示す通り、凸レンズ部4aを領域(1)と領域(2)とにわけ、領域(1)に先に光を照射し、その後遮光マスク120を変更して領域(2)に光を照射する。 For example, as shown in FIG. 4A, the convex lens portion 4a is divided into a region (1) and a region (2), the region (1) is irradiated with light first, and then the light shielding mask 120 is changed to change the region ( 2) is irradiated with light.

 この場合、好ましくは、凸レンズ部4aの分割後の領域のうち、レンズ厚の厚い光軸中心を含む領域(例えば領域(1))の光の照射には照度を大きくし、その他の領域(例えば領域(2))の光の照射には照度を低下させて(先の光の照射より照度を小さくして)もよい。 In this case, preferably, in the region after the division of the convex lens portion 4a, the illuminance is increased for light irradiation in a region including the center of the optical axis with a thick lens thickness (for example, the region (1)), and other regions (for example, In the irradiation of the light in the region (2), the illuminance may be decreased (the illuminance is made smaller than that of the previous light irradiation).

 その後、図4(b)に示す通り、遮光マスク120を取り除き、樹脂4A全体に対し光を照射する(第2の光照射工程)。 Thereafter, as shown in FIG. 4B, the light shielding mask 120 is removed, and the entire resin 4A is irradiated with light (second light irradiation step).

 第2の光照射工程では、光源90の光を遮光する遮光マスク120が取り除かれるから、光源90の光は遮光されずにそのまま樹脂4Aに向けて伝播する。これにより、樹脂4Aのうち、凸レンズ部4aに対応する部位と非レンズ部4bに対応する部位とに、すなわち樹脂4A全体に光を照射することとなり、凸レンズ部4aと共に非レンズ部4bの硬化も進める。 In the second light irradiation step, since the light shielding mask 120 that shields the light from the light source 90 is removed, the light from the light source 90 propagates directly toward the resin 4A without being shielded. As a result, in the resin 4A, the portion corresponding to the convex lens portion 4a and the portion corresponding to the non-lens portion 4b, that is, the entire resin 4A are irradiated with light, and the non-lens portion 4b is cured together with the convex lens portion 4a. Proceed.

 第1,第2の光照射工程では、図5に示す通り、光の照度を一定に保持し続けてもよいし(照射パターンA1)、第1の光照射工程と第2の光照射工程との切替え時点で(遮光マスク120を取り除く際に)、一時的に光源90を消灯させ光の照度を低下させてもよい(照射パターンA2)。 In the first and second light irradiation steps, as shown in FIG. 5, the illuminance of light may be kept constant (irradiation pattern A1), or the first light irradiation step and the second light irradiation step. At the time of switching (when removing the light shielding mask 120), the light source 90 may be temporarily turned off to reduce the illuminance of the light (irradiation pattern A2).

 なお、第2の光照射工程では、光源90として発散光を照射する光源を使用し、遮光マスク120を取り除かずに、遮光マスク120を上方に移動させ(遮光マスク120と樹脂4Aとの距離を第1の光照射工程時よりも広げ)、樹脂4A全体に光を照射するようにしてもよい。 In the second light irradiation step, a light source that emits divergent light is used as the light source 90, and the light shielding mask 120 is moved upward without removing the light shielding mask 120 (the distance between the light shielding mask 120 and the resin 4A is increased). You may make it irradiate light to resin 4A whole, expanding rather than the time of a 1st light irradiation process.

 また、遮光マスク120を開口絞りとしてあらかじめガラス基板2上に形成し、第1の光照射工程では当該マスク側、即ち開口絞り側から光を照射し、第2の光照射工程では当該マスクによる遮光機能が働かない、開口絞りとは反対のガラス基板2側から光を照射するものであっても良い。但し、この際の金型20は透明に形成する必要があり、この金型20を通して光照射を行う。この場合、光源の種類によらず、また遮光マスク120をその都度取り外さずに行う事ができるため工程が効率的に行える、というメリットを有する。 Further, the light shielding mask 120 is formed on the glass substrate 2 in advance as an aperture stop, light is irradiated from the mask side, that is, the aperture stop side in the first light irradiation step, and light shielding by the mask is performed in the second light irradiation step. The light may be irradiated from the side of the glass substrate 2 opposite to the aperture stop where the function does not work. However, the mold 20 at this time needs to be formed transparently, and light irradiation is performed through the mold 20. In this case, there is an advantage that the process can be performed efficiently because it can be performed regardless of the type of light source and without removing the light shielding mask 120 each time.

 さらに、第1の光照射工程を終えた後、金型20とガラス基板2を取り外してUV炉を通し、全体を硬化させてもよい。また、第2の光照射工程の後に、熱を加えて光硬化を促進させてもよい。これはいわゆるポストキュア工程と呼ばれるものであり、光重合による硬化の促進を行うものである。さらには樹脂中に熱重合開始剤を配合し、光照射と加熱とによりさらなる硬化の促進を図ることもできる。 Furthermore, after finishing the first light irradiation step, the mold 20 and the glass substrate 2 may be removed and passed through a UV furnace to be cured entirely. Further, after the second light irradiation step, heat may be applied to promote photocuring. This is a so-called post-cure process, and accelerates curing by photopolymerization. Furthermore, a thermal polymerization initiator can be blended in the resin, and further curing can be promoted by light irradiation and heating.

 次いで、ギヤードモータ50を作動させてシャフト52を下方に縮ませ、金型20をもとの高さ位置に戻し、図4(c)に示す通り、硬化後の樹脂4Aをガラス基板2とともに金型20から離型する(離型工程)。 Next, the geared motor 50 is operated to shrink the shaft 52 downward, and the mold 20 is returned to the original height position. As shown in FIG. Release from the mold 20 (release process).

 その結果、ガラス基板2に対し、複数の凸レンズ部4aが形成された樹脂部4を形成することができる。 As a result, the resin part 4 in which a plurality of convex lens parts 4 a are formed can be formed on the glass substrate 2.

 ここで、金型20を基準位置Sに設置してから樹脂4Aを金型20から離型するまでの工程において、ガラス基板2に対する金型20の押圧力(ロードセル44が検出する圧力値)は、図6に示す通り、第1の光照射工程で光の照射を開始してから第2の光照射工程で光の照射を終了するまで緩やかに低下し続け、金型20から樹脂4Aを離型するときに急激に低下する(圧力パターンB1)。 Here, the pressing force of the mold 20 against the glass substrate 2 (pressure value detected by the load cell 44) in the process from the installation of the mold 20 at the reference position S to the release of the resin 4A from the mold 20 is as follows. As shown in FIG. 6, after the light irradiation is started in the first light irradiation step, it continues to gradually decrease until the light irradiation is finished in the second light irradiation step, and the resin 4A is separated from the mold 20. It drops rapidly when molding (pressure pattern B1).

 光の照射開始からその終了まで金型20の押圧力が低下するのは、樹脂4Aが光の照射を受けて硬化収縮することによるものと考えられる。 The reason why the pressing force of the mold 20 decreases from the start of light irradiation to the end thereof is considered to be due to the resin 4A being irradiated with light and being cured and contracted.

 そのため、本実施形態では、図6に示す通り、第1の光照射工程で光の照射を開始してから第2の光照射工程で光の照射を終了するまで、好ましくは離型工程で金型20から樹脂4Aを離型するまで、ギヤードモータ50の作動を制御して、ガラス基板2に対する金型20の押圧力を、光の照射中は一定の値に維持し続けるか(圧力パターンB2)、又は光の照射の途中から上昇させ(圧力パターンB3)、金型20の樹脂4Aへの転写性を高める。 Therefore, in the present embodiment, as shown in FIG. 6, it is preferable that the gold mold is used in the mold release process from the start of the light irradiation in the first light irradiation process until the end of the light irradiation in the second light irradiation process. Until the resin 4A is released from the mold 20, the operation of the geared motor 50 is controlled so that the pressing force of the mold 20 against the glass substrate 2 is kept constant during light irradiation (pressure pattern B2 ) Or in the middle of light irradiation (pressure pattern B3) to improve the transferability of the mold 20 to the resin 4A.

 なお、第2の光照射工程で光の照射を終了してから離型工程で樹脂4Aを金型20から離型するまでの間に、光の照射後の樹脂4Aを一時的に冷却(自然放置を含む。)してもよい。特にエポキシ樹脂など、カチオン重合によって反応硬化する樹脂は反応速度が遅いため、所定の光量を照射しただけでは反応が終了しないので、反応が終了するまで成形状態を維持することが望ましい。 It should be noted that the resin 4A after light irradiation is temporarily cooled (naturally) between the end of light irradiation in the second light irradiation step and the release of the resin 4A from the mold 20 in the release step. (Including neglected). In particular, a resin that is reactively cured by cationic polymerization, such as an epoxy resin, has a slow reaction rate. Therefore, the reaction does not end only by irradiating a predetermined amount of light. Therefore, it is desirable to maintain the molding state until the reaction ends.

 この場合、図7に示す通り、ガラス基板2に対する金型20の押圧力は、光の照射期間中と冷却期間中とでそれぞれ低下し続け、光の照射期間から冷却期間への移行の際に段階的に切り替わる(圧力パターンB4)。 In this case, as shown in FIG. 7, the pressing force of the mold 20 against the glass substrate 2 continues to decrease during the light irradiation period and during the cooling period, and during the transition from the light irradiation period to the cooling period. It switches in steps (pressure pattern B4).

 この場合においても、冷却期間中は樹脂4Aが収縮すると考えられるから、好ましくは、圧力パターンB2,又はB3にしたがい、ガラス基板2に対する金型20の押圧力を制御する。 Also in this case, since the resin 4A is considered to shrink during the cooling period, preferably, the pressing force of the mold 20 against the glass substrate 2 is controlled according to the pressure pattern B2 or B3.

 その後、図4(c)に示す通り、ガラス基板2を裏返し、ガラス基板2に対し樹脂部4を形成したのと同様にして(準備工程から離型工程までの処理を繰り返して)、ガラス基板2に対し樹脂部6を形成する。 Thereafter, as shown in FIG. 4C, the glass substrate 2 is turned over, and the glass substrate 2 is formed in the same manner as the resin portion 4 is formed on the glass substrate 2 (by repeating the processes from the preparation step to the release step). The resin part 6 is formed for 2.

 ただし、この場合、図4(d)に示す通り、金型20に代えて、凹レンズ部6aを成形するための金型24を使用するとともに、樹脂4Aに代えて樹脂6Aを使用する。 However, in this case, as shown in FIG. 4D, a mold 24 for molding the concave lens portion 6a is used instead of the mold 20, and a resin 6A is used instead of the resin 4A.

 さらに、金型24を基準位置Sに相当する位置に設置してから樹脂6Aを金型24から離型するまでの工程において、図8に示す通り、第1の光照射工程で光の照射を開始してからその照射を終了するまでは、ギヤードモータ50の作動を制御して、ガラス基板2に対する金型24の押圧力を、光の照射中は一定の値に維持し、その後の第2の光照射工程で光の照射を開始してからその照射を終了するまで、好ましくは離型工程で金型24から樹脂6Aを離型するまでは、ギヤードモータ50を作動させずに、ガラス基板2に対する金型24の押圧力を、制御しない(圧力パターンB5)。すなわち、樹脂6Aの収縮により押圧力が低下するままにしておく。 Further, in the process from installing the mold 24 at a position corresponding to the reference position S to releasing the resin 6A from the mold 24, as shown in FIG. 8, light irradiation is performed in the first light irradiation process. From the start to the end of the irradiation, the operation of the geared motor 50 is controlled to maintain the pressing force of the mold 24 against the glass substrate 2 at a constant value during the light irradiation, and the second time thereafter. From the start of the light irradiation in the light irradiation step to the end of the irradiation, preferably until the resin 6A is released from the mold 24 in the release step, the glass substrate is not operated. 2 is not controlled (pressure pattern B5). That is, the pressing force is kept lowered by the contraction of the resin 6A.

 もちろん、樹脂部6を形成する場合においても、第2の光照射工程で光の照射を終了してから離型工程で樹脂6Aを金型24から離型するまでの間に、光の照射後の樹脂6Aを一時的に冷却(自然放置を含む。)してもよい。 Of course, even when the resin portion 6 is formed, after the light irradiation in the second light irradiation process and after the resin 6A is released from the mold 24 in the mold release process, after the light irradiation. The resin 6A may be temporarily cooled (including natural standing).

 この場合においても、図9に示す通り、樹脂6Aを冷却している期間中は、ギヤードモータ50を作動させずに、ガラス基板2に対する金型24の押圧力を、制御しない(圧力パターンB6)。このように、圧力パターンB5、B6で圧力を制御しない理由については後述する。 Also in this case, as shown in FIG. 9, during the period of cooling the resin 6A, the pressing force of the mold 24 against the glass substrate 2 is not controlled without operating the geared motor 50 (pressure pattern B6). . The reason why the pressure is not controlled by the pressure patterns B5 and B6 will be described later.

 以上の本実施形態では下記のような作用・効果を奏する。 In the above embodiment, the following operations and effects are achieved.

 まず、樹脂部4を形成する場合、光の照射を第1の光照射工程と第2の光照射工程との2段階にわけ、光の照射範囲を、第1の光照射工程では凸レンズ部4a(好ましくは光学有効径の範囲内)のみに、その後の第2の光照射工程では樹脂4A全体に変更している(図4(a),(b)参照)。 First, when the resin part 4 is formed, the light irradiation is divided into two stages of a first light irradiation process and a second light irradiation process, and the light irradiation range is determined by the convex lens part 4a in the first light irradiation process. Only in the range of the optical effective diameter (preferably within the range of the optical effective diameter), in the subsequent second light irradiation step, the entire resin 4A is changed (see FIGS. 4A and 4B).

 この場合、凸レンズ部4aが先に硬化し始め、その後に非レンズ部4bが硬化するから、凸レンズ部4aの硬化収縮が先に起こり、それに遅れて非レンズ部4bの硬化収縮が起こる。 In this case, since the convex lens portion 4a begins to harden first, and then the non-lens portion 4b hardens, the convex shrinkage of the convex lens portion 4a occurs first, and the non-lens portion 4b shrinks after that.

 そのため、非レンズ部4bが硬化収縮してもそのときには凸レンズ部4aはすでに硬化が進行しており、非レンズ部4bの硬化に伴う収縮が、凸レンズ部4aに影響するのを軽減でき、樹脂4Aの硬化に伴い凸レンズ部4aでヒケが発生するのを抑制することができる。 Therefore, even if the non-lens part 4b is cured and contracted, the curing of the convex lens part 4a has already progressed at that time, and the shrinkage accompanying the curing of the non-lens part 4b can be reduced from affecting the convex lens part 4a. It is possible to suppress the occurrence of sink marks in the convex lens portion 4a as the resin is cured.

 さらに、光の照射を2段階とすることに加え、金型20の押圧力を圧力パターンB2,B3に従い制御するから、金型20の樹脂4Aへの転写性を確実に向上させることができる。 Furthermore, in addition to the light irradiation being performed in two stages, the pressing force of the mold 20 is controlled according to the pressure patterns B2 and B3, so that the transferability of the mold 20 to the resin 4A can be reliably improved.

 すなわち、樹脂部4では、非レンズ部4bの厚さ4bthが凸レンズ部4aの厚さ4athより肉薄であるから、非レンズ部4bと凸レンズ部4aとに同時に光を照射すると、より高精度の転写性が求められるレンズにおいては転写性が必ずしも充分とはいえなかった。この原因は非レンズ部4bが先に硬化して、金型20を押圧しようとしてもその非レンズ部4bが金型20の移動を阻害し、金型20の押圧を凸レンズ部4aに十分に伝達することができないためと考えられる。 That is, in the resin part 4, since the thickness 4bth of the non-lens part 4b is thinner than the thickness 4ath of the convex lens part 4a, more accurate transfer can be achieved by simultaneously irradiating the non-lens part 4b and the convex lens part 4a with light. Transferability was not always sufficient for lenses that required high performance. This is because the non-lens portion 4b hardens first, and even if it tries to press the mold 20, the non-lens portion 4b inhibits the movement of the mold 20, and the pressing of the mold 20 is sufficiently transmitted to the convex lens portion 4a. It is thought that it is not possible to do.

 これに対し、本実施形態では、第1の光照射工程で凸レンズ部4aに対し選択的に光を照射し非レンズ部4bに対しては光を照射しないから、その間は少なくとも非レンズ部4bによる金型20の移動阻害はなく、金型20の押圧を凸レンズ部4aに十分に伝達することができ、結果的に金型20の樹脂4Aへの転写性を確実に向上させることができることが分かった。 On the other hand, in the present embodiment, the convex lens portion 4a is selectively irradiated with light and the non-lens portion 4b is not irradiated with light in the first light irradiation step. It can be seen that there is no hindrance to the movement of the mold 20, the pressure of the mold 20 can be sufficiently transmitted to the convex lens portion 4a, and as a result, the transferability of the mold 20 to the resin 4A can be improved reliably. It was.

 このような内容を簡単にまとめると、表1に示す通り、光の2段階照射により凸レンズ部4aのヒケの発生を抑制でき、さらに、金型20の圧力制御により金型20の樹脂4Aへの転写性を向上させる(凸レンズ部4aの光学面における設計値からのズレを抑制する)ことができるといえる。 Summarizing such contents, as shown in Table 1, it is possible to suppress the occurrence of sink marks in the convex lens portion 4a by two-stage irradiation of light, and further, by controlling the pressure of the mold 20, the resin 20 of the mold 20 is applied to the resin 4A. It can be said that transferability can be improved (a shift from a design value on the optical surface of the convex lens portion 4a can be suppressed).

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

 表1中、「○」はヒケが抑制され良好な転写性を示した例であり、「×」はヒケ、あるいは転写性が良好でない例である。また、「光学面設計値からのズレ」の項目における「△」は、レンズ部4aにおいて光学面の補正が可能な範囲に収まるという評価内容である。 In Table 1, “◯” is an example in which sink marks are suppressed and shows good transferability, and “X” is an example in which sink marks or transferability is not good. Further, “Δ” in the item of “deviation from optical surface design value” is an evaluation content that the lens portion 4a falls within a range where the optical surface can be corrected.

 樹脂部4を形成する場合には、光の照射パターンA1,A2に代えて、図10に示す通り、光の照射を断続的に行ってもよい(照射パターンA3)。 When forming the resin part 4, instead of the light irradiation patterns A1 and A2, light irradiation may be intermittently performed as shown in FIG. 10 (irradiation pattern A3).

 この場合、樹脂4Aの硬化が段階的に進行して硬化速度が相対的に遅延するから、金型20の圧力制御を容易にすることができ、さらに金型20の樹脂4Aへの転写性を向上させることができる。 In this case, since the curing of the resin 4A proceeds stepwise and the curing speed is relatively delayed, the pressure control of the mold 20 can be facilitated, and the transfer property of the mold 20 to the resin 4A can be further improved. Can be improved.

 そのため、光の照射パターンA3は、光硬化性樹脂のなかでも樹脂4Aとして特に硬化速度の大きい樹脂を選択した場合に有効である。 Therefore, the light irradiation pattern A3 is effective when a resin having a particularly high curing rate is selected as the resin 4A among the photocurable resins.

 他方、樹脂部6を形成する場合においても、光の照射を第1の光照射工程と第2の光照射工程との2段階にわけ、光の照射範囲を、第1の光照射工程では凹レンズ部6a(好ましくは光学有効径の範囲内)のみに、その後の第2の光照射工程では樹脂6A全体に変更している(図4(d)参照)。 On the other hand, even when the resin portion 6 is formed, the light irradiation is divided into two stages of a first light irradiation process and a second light irradiation process, and the light irradiation range is a concave lens in the first light irradiation process. Only the portion 6a (preferably within the optical effective diameter range) is changed to the entire resin 6A in the subsequent second light irradiation step (see FIG. 4D).

 そのため、樹脂部4を形成するときと同様に、非レンズ部6bが硬化収縮してもそのときには凹レンズ部6aはすでに硬化が進行しており、非レンズ部6bの硬化に伴う収縮が、凹レンズ部6aに影響するのを軽減でき、樹脂6Aの硬化に伴い凹レンズ部6aでヒケが発生するのを抑制することができる。 Therefore, as in the case of forming the resin portion 4, even when the non-lens portion 6b is cured and contracted, the concave lens portion 6a is already cured, and the contraction accompanying the curing of the non-lens portion 6b is the concave lens portion. 6a can be reduced, and the occurrence of sink marks can be suppressed in the concave lens portion 6a as the resin 6A is cured.

 さらに、樹脂部6を形成する場合にも、光の照射を2段階とすることに加え、金型24の押圧力を圧力パターンB5,B6にしたがい第2の光照射工程以降では制御しないから、金型24の樹脂6Aへの転写性を確実に向上させることができる。 Further, when forming the resin portion 6, in addition to the light irradiation in two stages, the pressing force of the mold 24 is not controlled after the second light irradiation process according to the pressure patterns B5 and B6. Transferability of the mold 24 to the resin 6A can be reliably improved.

 すなわち、樹脂部6では、凹レンズ部6aの厚さ6athが非レンズ部6bの厚さ6bthより肉薄であるから、凹レンズ部6aと非レンズ部6bとに同時に光を照射しながら金型24を押圧し続ければ、凹レンズ部6aは非レンズ部6bより先に硬化するが、これに遅延して硬化する非レンズ部6bの硬化中も、金型24の押圧を受け続ける。この場合、硬化後の凹レンズ部6aに過度な負担がかかり、凹レンズ部6bが歪み、場合によっては割れてしまう可能性がある。 That is, in the resin part 6, since the thickness 6ath of the concave lens part 6a is thinner than the thickness 6bth of the non-lens part 6b, the mold 24 is pressed while simultaneously irradiating light to the concave lens part 6a and the non-lens part 6b. If it continues, the concave lens part 6a will harden | cure ahead of the non-lens part 6b, but it will continue to receive the press of the metal mold | die 24 also during hardening of the non-lens part 6b which delays and cures to this. In this case, an excessive burden is applied to the cured concave lens portion 6a, and the concave lens portion 6b may be distorted and possibly cracked.

 これに対し、本実施形態では、第2の光照射工程以降では金型24の押圧を解除し圧力制御しないから、凹レンズ部6aはこれに遅延する非レンズ部6bの硬化中は金型24の押圧を受けず、第1の光照射工程で形成された状態をほぼそのまま維持することができ、結果的に金型24の樹脂6Aへの転写性を確実に向上させることができる。 On the other hand, in the present embodiment, after the second light irradiation step, the pressing of the mold 24 is released and the pressure is not controlled, so that the concave lens portion 6a is delayed during the curing of the non-lens portion 6b. Without being pressed, the state formed in the first light irradiation step can be maintained almost as it is, and as a result, the transferability of the mold 24 to the resin 6A can be reliably improved.

 この第2の光照射工程で押圧力を制御しない方式は、凹レンズのみならず、レンズ部の周りに非レンズ部として位置決め用などの突起がレンズ部より肉厚で形成された光学素子の場合にも適用できる。 The method that does not control the pressing force in the second light irradiation step is not only in the case of a concave lens, but also in the case of an optical element in which a projection for positioning or the like as a non-lens part is formed thicker than the lens part around the lens part. Is also applicable.

 樹脂部6を形成する場合には、光の照射パターンA1,A2に代えて、図11に示す通り、第1の光照射工程における所定期間中は一時的に低下させてもよい(照射パターンA4)。 When the resin portion 6 is formed, instead of the light irradiation patterns A1 and A2, as shown in FIG. 11, the resin portion 6 may be temporarily reduced during a predetermined period in the first light irradiation process (irradiation pattern A4). ).

 この場合、第1の光照射工程で樹脂6Aの硬化が遅延するから、金型24の圧力制御を容易にすることができ、さらに金型24の樹脂6Aへの転写性を向上させることができる。 In this case, since the curing of the resin 6A is delayed in the first light irradiation step, the pressure control of the mold 24 can be facilitated, and the transferability of the mold 24 to the resin 6A can be improved. .

 なお、本実施形態では、樹脂部4,6の形成態様に応じて光の照射パターンA1~A4を開示したが、光の照射パターンA1~A4は、樹脂部4,6の形成ごとに第1の光照射工程と第2の光照射工程とで適宜組み合わせてもよい。 In the present embodiment, the light irradiation patterns A1 to A4 are disclosed in accordance with the formation mode of the resin parts 4 and 6, but the light irradiation patterns A1 to A4 are the first every time the resin parts 4 and 6 are formed. The light irradiation step and the second light irradiation step may be appropriately combined.

 また、本実施形態では、金型20,24を用いて樹脂部4,6を別個に形成したが、樹脂部4,6を同時に形成してもよい。 In this embodiment, the resin parts 4 and 6 are separately formed using the molds 20 and 24. However, the resin parts 4 and 6 may be formed simultaneously.

 例えば、図12に示す通り、樹脂部4の形成には金型20を、樹脂部6の形成には光透過性の樹脂型26を使用する。樹脂型26は樹脂製の成形型であり、樹脂の成形に用いられる成形型の他例である。樹脂型26は成形部26aと支持部26bとから構成されている。成形部26aは表面が凹レンズ部6aに対応した凸状を呈しており、支持部26bは成形部26aを支持しその強度を高めている。 For example, as shown in FIG. 12, a mold 20 is used for forming the resin part 4 and a light-transmitting resin mold 26 is used for forming the resin part 6. The resin mold 26 is a resin mold and is another example of a mold used for resin molding. The resin mold 26 includes a molding part 26a and a support part 26b. The molding part 26a has a convex surface corresponding to the concave lens part 6a, and the support part 26b supports the molding part 26a and increases its strength.

 この場合、樹脂4Aを金型20とガラス基板2との間に、樹脂6Aを樹脂型26とガラス基板2との間に、それぞれ充填したまま、第1,第2の光照射工程で光を照射すればよい。 In this case, the resin 4A is filled between the mold 20 and the glass substrate 2, and the resin 6A is filled between the resin mold 26 and the glass substrate 2, and light is applied in the first and second light irradiation steps. Irradiation is sufficient.

 また、図13に示す変形例のように、樹脂部4の形成には光透過性の樹脂型28を、樹脂部6の形成には樹脂型26を使用してもよい。樹脂型28も樹脂製の成形型であり、樹脂の成形に用いられる成形型の他例である。樹脂型28は樹脂型26とほぼ同様の構成を有している。成形部28aは表面が凸レンズ部4aに対応した凹状を呈しており、支持部28bは成形部26aを支持しその強度を高めている。 Further, as in the modification shown in FIG. 13, the resin portion 28 may be used for forming the resin portion 4, and the resin die 26 may be used for forming the resin portion 6. The resin mold 28 is also a resin mold and is another example of a mold used for resin molding. The resin mold 28 has substantially the same configuration as the resin mold 26. The molding part 28a has a concave surface corresponding to the convex lens part 4a, and the support part 28b supports the molding part 26a and increases its strength.

 この場合には、樹脂4Aを樹脂型28とガラス基板2との間に、樹脂6Aを樹脂型26とガラス基板2との間に、それぞれ充填したまま、第1,第2の光照射工程で上方と下方との両方から光を照射すればよい。 In this case, the resin 4A is filled between the resin mold 28 and the glass substrate 2, and the resin 6A is filled between the resin mold 26 and the glass substrate 2, respectively, in the first and second light irradiation steps. Light may be irradiated from both above and below.

 さらに、本実施形態では、ガラス基板2に対し単に1部の樹脂部4,6を形成したウエハレンズ1を開示したが、大径のガラス基板2に対し複数の樹脂部4(樹脂部6)を形成しこれをウエハレンズ1としてもよい。 Further, in the present embodiment, the wafer lens 1 is disclosed in which only one resin portion 4 or 6 is formed on the glass substrate 2, but a plurality of resin portions 4 (resin portions 6) are provided on the large-diameter glass substrate 2. And this may be used as the wafer lens 1.

 この場合、図14に示す通り、いわゆるステップアンドリピート方式に従い、ガラス基板2の一方の面に対し樹脂部4を順次形成していき、その後にガラス基板2の他方の面に対し樹脂部6を順次形成していけばよい。
[第2の実施形態]
 第2の実施形態は下記の点で第1の実施形態と異なっており、それ以外の技術的事項は第1の実施形態と同様である。
In this case, as shown in FIG. 14, the resin portion 4 is sequentially formed on one surface of the glass substrate 2 according to a so-called step-and-repeat method, and then the resin portion 6 is formed on the other surface of the glass substrate 2. You should form sequentially.
[Second Embodiment]
The second embodiment is different from the first embodiment in the following points, and other technical matters are the same as those of the first embodiment.

 第2の実施形態では、主には、第1,第2の光照射工程で遮光マスク120を使用しない点で第1の実施形態と大きく異なっている。 The second embodiment is largely different from the first embodiment in that the light shielding mask 120 is not used in the first and second light irradiation steps.

 そして一例として、図15に示す第2の実施形態では、光源90の下方にレンズアレイ96が設けられている。 As an example, in the second embodiment shown in FIG. 15, a lens array 96 is provided below the light source 90.

 この場合(樹脂部4を形成するときを例にすれば)、第1の光照射工程では、光源90を点灯させてレンズアレイ96でその光を集光し、樹脂4Aのうち、凸レンズ部4aに対応する部位に選択的に光を照射し、第2の光照射工程では、レンズアレイ96を下方に移動させ(レンズアレイ96と樹脂4Aとの距離を第1の光照射工程時よりも狭め)樹脂4A全体に光を照射する。 In this case (for example, when the resin portion 4 is formed), in the first light irradiation step, the light source 90 is turned on and the light is condensed by the lens array 96, and the convex lens portion 4a of the resin 4A is collected. In the second light irradiation step, the lens array 96 is moved downward (the distance between the lens array 96 and the resin 4A is narrower than that in the first light irradiation step). ) The entire resin 4A is irradiated with light.

 図16に示す他の例では、光源90に代えて、複数の点状光源92が設けられている。点状光源92は樹脂4A(樹脂6A)への光の照射可能領域に配置されている。 In another example shown in FIG. 16, a plurality of point light sources 92 are provided instead of the light source 90. The point light source 92 is disposed in a region where the resin 4A (resin 6A) can be irradiated with light.

 この場合(樹脂部4を形成するときを例にすれば)、第1の光照射工程では、複数の点状光源92のうち、金型20のキャビティ22に対向する点状光源92を点灯させ、樹脂4Aのうち、凸レンズ部4aに対応する部位にのみ選択的に光を照射し、第2の光照射工程では、残りの点状光源92も点灯させ、樹脂4A全体に光を照射する。 In this case (for example, when the resin portion 4 is formed), in the first light irradiation process, the point light source 92 facing the cavity 22 of the mold 20 is turned on among the plurality of point light sources 92. In the resin 4A, light is selectively irradiated only to a portion corresponding to the convex lens portion 4a. In the second light irradiation step, the remaining point light sources 92 are also turned on, and the entire resin 4A is irradiated with light.

 図17に示すさらに他の例では、光源90に代えて、光軸方向に可動な複数の点状光源94、あるいは照射光量可変の複数の点状光源94′、が設けられている。点状光源94は、樹脂4A(樹脂6A)への光の照射可能領域であってキャビティ22(光学面の転写部)に対向する位置に配置されている。点状光源94は発散光を照射する光源である。 In still another example shown in FIG. 17, instead of the light source 90, a plurality of point light sources 94 that are movable in the optical axis direction or a plurality of point light sources 94 ′ with variable irradiation light amount are provided. The point light source 94 is a region where light can be irradiated to the resin 4A (resin 6A) and is disposed at a position facing the cavity 22 (transfer portion of the optical surface). The point light source 94 is a light source that emits divergent light.

 この場合(樹脂部4を形成するときを例にすれば)、第1の光照射工程では、各点状光源94を点灯させ(図17中央参照)、樹脂4Aのうち、凸レンズ部4aに対応する部位に選択的に光を照射し、第2の光照射工程では、各点状光源94を上方に移動させ(各点状光源94と樹脂4Aとの距離を第1の光照射工程時よりも広げ)樹脂4A全体に光を照射する(図17中左側参照)。又は図17中右側に示すように各点状光源94′に供給する電力量を増大させ(各点状光源94′の照度を第1の光照射工程時よりも上げ)樹脂4A全体に光を照射する。点状光源94′の配光分布は中央の光軸方向がもっとも光量が大きく、周辺部の光量は少ない。そのため第1の光照射工程で与えられる電力量を非レンズ部の樹脂を硬化させるほど大きくない電力量とし、第2の光照射工程では、非レンズ部の樹脂も硬化させる電力量とすればよい。 In this case (for example, when the resin portion 4 is formed), in the first light irradiation step, each point light source 94 is turned on (see the center of FIG. 17) and corresponds to the convex lens portion 4a in the resin 4A. In the second light irradiation step, each point light source 94 is moved upward (the distance between each point light source 94 and the resin 4A is changed from the time of the first light irradiation step). The resin 4A is irradiated with light (see the left side in FIG. 17). Alternatively, as shown on the right side in FIG. 17, the amount of electric power supplied to each point light source 94 'is increased (the illuminance of each point light source 94' is increased from that in the first light irradiation step), and light is applied to the entire resin 4A. Irradiate. The light distribution of the point light source 94 ′ has the largest amount of light in the central optical axis direction and the light amount in the peripheral portion is small. Therefore, the amount of electric power given in the first light irradiation step may be set to an amount of electric power that is not so large as to cure the resin of the non-lens portion, and in the second light irradiation step, the amount of electric power to cure the resin of the non-lens portion. .

 点状光源92,94,94′として具体的には、光硬化性樹脂に含まれる反応開始剤や反応増感剤の感光波長に対応した波長に発光波長を持つLEDやレーザーなどを用いることができる。 Specifically, as the point light sources 92, 94, 94 ′, LEDs or lasers having an emission wavelength at a wavelength corresponding to the photosensitive wavelength of the reaction initiator or reaction sensitizer contained in the photocurable resin are used. it can.

 1 ウエハレンズ
 2 ガラス基板
 4 樹脂部
 4a 凸レンズ部
 4b 非レンズ部
 6 樹脂部
 6a 凹レンズ部
 6b 非レンズ部
 20 金型
 22 キャビティ
 24 金型
 26 樹脂型
 26a 成形部
 26b 支持部
 28 樹脂型
 28a 成形部
 28b 支持部
 30 ウエハレンズ製造装置
 32 ベース
 34 突出部
 36 ガイド
 40 ステージ
 42 貫通孔
 44 ロードセル
 46 凹部
 50 ギヤードモータ
 51 ポテンショメータ
 52 シャフト
 60 平行出し部材
 62 XYステージ
 64 θステージ
 70 真空チャック装置
 72 連通溝
 80 スタンプホルダ
 82 連通溝
 90 光源
 92,94,94′ 点状光源
 96 レンズアレイ
 100 制御装置
DESCRIPTION OF SYMBOLS 1 Wafer lens 2 Glass substrate 4 Resin part 4a Convex lens part 4b Non lens part 6 Resin part 6a Concave lens part 6b Non lens part 20 Mold 22 Cavity 24 Mold 26 Resin mold 26a Molding part 26b Support part 28 Resin mold 28a Molding part 28b Support section 30 Wafer lens manufacturing apparatus 32 Base 34 Projection section 36 Guide 40 Stage 42 Through hole 44 Load cell 46 Recess 50 Geared motor 51 Potentiometer 52 Shaft 60 Paralleling member 62 XY stage 64 θ stage 70 Vacuum chuck apparatus 72 Communication groove 80 Stamp holder 82 communication groove 90 light source 92, 94, 94 'point light source 96 lens array 100 control device

Claims (16)

 基板に対しレンズ部とその周辺の非レンズ部とを有する複数のレンズを光硬化性樹脂で形成するウエハレンズの製造方法において、
 成形型と前記基板との間に前記光硬化性樹脂を充填する工程と、
 前記光硬化性樹脂に対して光照射を行う事で前記光硬化性樹脂の硬化を進める硬化工程と、を有し、
 前記硬化工程は、前記光硬化性樹脂の第1の領域に光を照射する第1光照射工程と、前記第1の領域よりも広い照射領域の第2の領域に光を照射する第2光照射工程とを有することを特徴とするウエハレンズの製造方法。
In the method of manufacturing a wafer lens, in which a plurality of lenses having a lens portion and a non-lens portion around the lens portion are formed on a substrate with a photocurable resin,
Filling the photocurable resin between the mold and the substrate;
A curing step of advancing curing of the photocurable resin by performing light irradiation on the photocurable resin,
The curing step includes a first light irradiation step of irradiating the first region of the photocurable resin with light, and a second light irradiating the second region of the irradiation region wider than the first region. A method of manufacturing a wafer lens, comprising: an irradiation step.
 基板に対しレンズ部とその周辺の非レンズ部とを有する複数のレンズを光硬化性樹脂で形成するウエハレンズの製造方法において、
 成形型と前記基板との間に前記光硬化性樹脂を充填する工程と、
 前記光硬化性樹脂に対して光照射を行う事で前記光硬化性樹脂の硬化を進める硬化工程と、を有し
 前記硬化工程は、前記光硬化性樹脂のレンズ部に対応する部位のみを照射する第1光照射工程と、前記光硬化性樹脂の前記レンズ部の周囲の非レンズ部に対応する部位を照射する第2光照射工程とを有することを特徴とするウエハレンズの製造方法。
In a method for manufacturing a wafer lens, in which a plurality of lenses having a lens portion and a non-lens portion around the lens portion are formed on a substrate with a photocurable resin,
Filling the photocurable resin between the mold and the substrate;
A curing step of proceeding curing of the photocurable resin by irradiating the photocurable resin with light, and the curing step irradiates only a portion corresponding to the lens portion of the photocurable resin. And a second light irradiating step of irradiating a portion corresponding to the non-lens portion around the lens portion of the photocurable resin.
 請求項1に記載のウエハレンズの製造方法において、
 前記第1の領域は、前記レンズ部の有効径範囲に対応する部位であり、
 前記第2の領域は、前記レンズ部の有効径範囲及びその周辺部を含む部位であることを特徴とするウエハレンズの製造方法。
In the manufacturing method of the wafer lens according to claim 1,
The first region is a portion corresponding to an effective diameter range of the lens unit,
The method of manufacturing a wafer lens, wherein the second region is a portion including an effective diameter range of the lens portion and a peripheral portion thereof.
 請求項1に記載のウエハレンズの製造方法において、
 前記第1の領域は、前記レンズ部に対応する部位であり、
 前記第2の領域は、前記レンズ部に対応する部位及び前記レンズ部の周囲の非レンズ部に対応する部位であることを特徴とするウエハレンズの製造方法。
In the manufacturing method of the wafer lens according to claim 1,
The first region is a part corresponding to the lens unit,
The method of manufacturing a wafer lens, wherein the second region is a portion corresponding to the lens portion and a portion corresponding to a non-lens portion around the lens portion.
 請求項1~4のいずれか一項に記載のウエハレンズの製造方法において、
 前記第1光照射工程では、照射領域以外を遮光マスクを用いて光照射を遮蔽することを特徴とするウエハレンズの製造方法。
In the method for manufacturing a wafer lens according to any one of claims 1 to 4,
In the first light irradiation step, the light irradiation is shielded by using a light shielding mask outside the irradiation region.
 請求項5に記載のウエハレンズの製造方法において、
 前記遮光マスクは、レンズの開口絞りであることを特徴とするウエハレンズの製造方法。
In the manufacturing method of the wafer lens according to claim 5,
The method of manufacturing a wafer lens, wherein the light shielding mask is an aperture stop of a lens.
 請求項5に記載のウエハレンズの製造方法において、
 前記第2光照射工程では、前記遮光マスクを用いずに、光を照射することを特徴とするウエハレンズの製造方法。
In the manufacturing method of the wafer lens according to claim 5,
In the second light irradiation step, the wafer lens is manufactured by irradiating light without using the light shielding mask.
 請求項5に記載のウエハレンズの製造方法において、
 光源として発散光を照射する光源を使用し、前記第2光照射工程では、前記光硬化性樹脂と前記遮光マスクとの距離を、前記第1光照射工程の時の距離よりも、広げることを特徴とするウエハレンズの製造方法。
In the manufacturing method of the wafer lens according to claim 5,
A light source that emits divergent light is used as a light source, and in the second light irradiation step, the distance between the photocurable resin and the light-shielding mask is made wider than the distance in the first light irradiation step. A method for manufacturing a wafer lens.
 請求項1~4のいずれか一項に記載のウエハレンズの製造方法において、
 前記光硬化性樹脂への光の照射可能領域であって前記レンズ部に対応する部位に対向する位置に集光レンズアレイを有する光源を配置するとともに、
 前記第2光照射工程では、前記光硬化性樹脂と前記集光レンズとの距離を、前記第1光照射工程時よりも、狭めることを特徴とするウエハレンズの製造方法。
In the method for manufacturing a wafer lens according to any one of claims 1 to 4,
While arranging a light source having a condensing lens array at a position facing the portion corresponding to the lens portion in a region where light can be irradiated to the photocurable resin,
In the second light irradiation step, the distance between the photocurable resin and the condenser lens is narrower than that in the first light irradiation step.
 請求項1~4のいずれか一項に記載のウエハレンズの製造方法において、
 前記光硬化性樹脂への光の照射可能領域に複数の点状光源を配置し、
 前記第1光照射工程では、前記光硬化性樹脂のうち、前記レンズ部に対応する部位に対向する前記点状光源だけを点灯させることを特徴とするウエハレンズの製造方法。
In the method for manufacturing a wafer lens according to any one of claims 1 to 4,
Arranging a plurality of point light sources in the light irradiable area to the photocurable resin,
In the first light irradiation step, only the point light source facing the portion corresponding to the lens portion in the photocurable resin is turned on.
 請求項1~4のいずれか一項に記載のウエハレンズの製造方法において、
 前記光硬化性樹脂への光の照射可能領域であって前記レンズ部に対応する部位に対向する位置に点状光源を配置するとともに、前記点状光源として発散光を照射する光源を使用し、
 前記第2光照射工程では、前記光硬化性樹脂と前記点状光源との距離を、前記第1光照射工程時よりも、広げることを特徴とするウエハレンズの製造方法。
In the method for manufacturing a wafer lens according to any one of claims 1 to 4,
Using a light source that irradiates divergent light as the point light source, while arranging a point light source at a position facing the portion corresponding to the lens portion in the light irradiable region to the photocurable resin,
In the second light irradiation step, the wafer lens manufacturing method is characterized in that the distance between the photocurable resin and the point light source is wider than that in the first light irradiation step.
 請求項1~4のいずれか一項に記載のウエハレンズの製造方法において、
 前記光硬化性樹脂への光の照射可能領域であって前記レンズ部に対応する部位に対向する位置に点状光源を配置するとともに、前記点状光源として発散光を照射する光源を使用し、
 前記第2光照射工程では、前記点状光源の照度を、前記第1光照射工程時の照度よりも、上げることを特徴とするウエハレンズの製造方法。
In the method for manufacturing a wafer lens according to any one of claims 1 to 4,
Using a light source that irradiates divergent light as the point light source, while arranging a point light source at a position facing the portion corresponding to the lens part in the light irradiable region to the photocurable resin,
In the second light irradiation step, the illuminance of the point light source is made higher than the illuminance at the time of the first light irradiation step.
 請求項1~12のいずれか一項に記載のウエハレンズの製造方法において、
 前記第1,第2光照射工程の少なくとも一方の工程では、光を断続的に照射することを特徴とするウエハレンズの製造方法。
The method of manufacturing a wafer lens according to any one of claims 1 to 12,
In at least one of the first and second light irradiation steps, light is intermittently irradiated.
 請求項1~13のいずれか一項に記載のウエハレンズの製造方法において、
 前記レンズ部の厚さが前記非レンズ部の厚さより肉厚であり、
 前記第1光照射工程と前記第2光照射工程とで、前記光硬化性樹脂に対する圧力を所定の圧力に保持するように制御することを特徴とするウエハレンズの製造方法。
The method for producing a wafer lens according to any one of claims 1 to 13,
The thickness of the lens part is thicker than the thickness of the non-lens part,
A method of manufacturing a wafer lens, wherein the first light irradiation step and the second light irradiation step are controlled so that a pressure on the photocurable resin is maintained at a predetermined pressure.
 請求項1~13のいずれか一項に記載のウエハレンズの製造方法において、
 前記レンズ部の厚さが前記非レンズ部の厚さより肉薄であり、
 前記第1光照射工程では、前記光硬化性樹脂に対する圧力を所定の圧力に保持するように制御し、
 前記第2光照射工程では、前記光硬化性樹脂に対する前記圧力の制御を解除することを特徴とするウエハレンズの製造方法。
The method for producing a wafer lens according to any one of claims 1 to 13,
The thickness of the lens part is thinner than the thickness of the non-lens part,
In the first light irradiation step, the pressure to the photocurable resin is controlled to be maintained at a predetermined pressure,
In the second light irradiation step, the control of the pressure with respect to the photocurable resin is released.
 請求項1~15のいずれか一項に記載のウエハレンズの製造方法において、
 前記基板がガラス基板であることを特徴とするウエハレンズの製造方法。
In the method for manufacturing a wafer lens according to any one of claims 1 to 15,
A method for producing a wafer lens, wherein the substrate is a glass substrate.
PCT/JP2010/052728 2009-04-13 2010-02-23 Method for manufacturing wafer lens Ceased WO2010119726A1 (en)

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