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WO2010109492A8 - Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia - Google Patents

Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia Download PDF

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Publication number
WO2010109492A8
WO2010109492A8 PCT/IN2010/000194 IN2010000194W WO2010109492A8 WO 2010109492 A8 WO2010109492 A8 WO 2010109492A8 IN 2010000194 W IN2010000194 W IN 2010000194W WO 2010109492 A8 WO2010109492 A8 WO 2010109492A8
Authority
WO
WIPO (PCT)
Prior art keywords
schoenite
liquor
ammonia
mixed salt
mgcl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IN2010/000194
Other languages
French (fr)
Other versions
WO2010109492A1 (en
Inventor
Pushpito Kumar Ghosh
Haresh Mahipatlal Mody
Jatin Rameshchandra Chunawala
Maheshkumar Ramniklal Gandhi
Hari Chand Bajaj
Pratyush Maiti
Himanshu Labhshanker Joshi
Hasina Hajibhai Deraiya
Upendra Padmakant Saraiya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Council of Scientific and Industrial Research CSIR
Original Assignee
Council of Scientific and Industrial Research CSIR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2012501508A priority Critical patent/JP5509310B2/en
Priority to EP10719792.3A priority patent/EP2411330B1/en
Priority to AU2010228846A priority patent/AU2010228846B2/en
Priority to CA2756763A priority patent/CA2756763C/en
Priority to CN201080019037.9A priority patent/CN102421707B/en
Priority to US13/981,957 priority patent/US8721999B2/en
Priority to ES10719792T priority patent/ES2435008T3/en
Priority to BRPI1009805A priority patent/BRPI1009805A2/en
Application filed by Council of Scientific and Industrial Research CSIR filed Critical Council of Scientific and Industrial Research CSIR
Priority to MX2011010165A priority patent/MX2011010165A/en
Publication of WO2010109492A1 publication Critical patent/WO2010109492A1/en
Publication of WO2010109492A8 publication Critical patent/WO2010109492A8/en
Priority to IL215391A priority patent/IL215391A/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/24—Sulfates of ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/06—Preparation of sulfates by double decomposition
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/02—Magnesia
    • C01F5/06—Magnesia by thermal decomposition of magnesium compounds
    • C01F5/08—Magnesia by thermal decomposition of magnesium compounds by calcining magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/14—Magnesium hydroxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

The present invention provides an integrated process for the recovery of sulphate of potash (SOP), ammonium sulphate and surface modified magnesium hydroxide and/or magnesium oxide utilizing kainite mixed salt and ammonia as the only consumable raw materials. The process involves treating kainite mixed salt with water to obtain solid schoenite and a schoenite end liquor. The latter is desulphated using CaCl2 generated in the process itself and thereafter evaporated to obtain carnallite crystals from which KCl is recovered while the liquor rich in MgCl2 serves as a source of MgCL. The gypsum produced during desulphatation is reacted with aqueous ammonia and CO2 to produce ammonium sulphate and calcium carbonate. The calcium carbonate so obtained is then calcined to obtained CaO and CO2. The CaO is then slaked in decarbonated water and reacted with the MgCl2-rich liquor generated above to produce slurry of Mg(OH)2 in aqueous CaCl2. To this surface modifying agent is added under hot condition and, after cooling, the slurry is more easily filterable and yields surface modified Mg(OH)2. The filtrate rich in CaCl2 is then recycled for desulphatation process above. The solid surface modified Mg(OH)2 is then calcined to produced MgO or used as such in appropriate applications. The schoenite and KCl are reacted to produce SOP in solid form while the liquor is recycled in the schoenite production step.
PCT/IN2010/000194 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia Ceased WO2010109492A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
ES10719792T ES2435008T3 (en) 2009-03-27 2010-03-29 Process for the simultaneous production of potassium sulfate, ammonium sulfate, magnesium hydroxide and / or magnesium oxide from a mixed salt of kainite and ammonia
AU2010228846A AU2010228846B2 (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia
CA2756763A CA2756763C (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia
CN201080019037.9A CN102421707B (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia
US13/981,957 US8721999B2 (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia
JP2012501508A JP5509310B2 (en) 2009-03-27 2010-03-29 Method for simultaneous production of potassium sulfate, ammonium sulfate, magnesium hydroxide and / or magnesium oxide from kainite mixed salt and ammonia
EP10719792.3A EP2411330B1 (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia
BRPI1009805A BRPI1009805A2 (en) 2009-03-27 2010-03-29 process for the simultaneous production of potassium sulphate, ammonium sulphate, magnesium hydroxide and / or magnesium oxide from a mixed salt of cainite and ammonia
MX2011010165A MX2011010165A (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia.
IL215391A IL215391A (en) 2009-03-27 2011-09-26 Process for simultaneous production of potassium sulphate, ammonium sulphate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN618DE2009 2009-03-27
IN618/DEL/2009 2009-03-27

Publications (2)

Publication Number Publication Date
WO2010109492A1 WO2010109492A1 (en) 2010-09-30
WO2010109492A8 true WO2010109492A8 (en) 2011-03-24

Family

ID=42315399

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2010/000194 Ceased WO2010109492A1 (en) 2009-03-27 2010-03-29 Process for simultaneous production of potassium sulphate, ammonium sulfate, magnesium hydroxide and/or magnesium oxide from kainite mixed salt and ammonia

Country Status (11)

Country Link
US (1) US8721999B2 (en)
EP (1) EP2411330B1 (en)
JP (1) JP5509310B2 (en)
CN (1) CN102421707B (en)
AU (1) AU2010228846B2 (en)
BR (1) BRPI1009805A2 (en)
CA (1) CA2756763C (en)
ES (1) ES2435008T3 (en)
IL (1) IL215391A (en)
MX (1) MX2011010165A (en)
WO (1) WO2010109492A1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102139892A (en) * 2010-11-25 2011-08-03 汪晋强 Method for preparing potassium carbonate and ammonium sulfate from waste obtained by producing sodium cyanate by urea method
CN102167356B (en) * 2011-03-23 2012-12-19 北京国电龙源环保工程有限公司 Device and method for improving ammonium sulfate crystal quality
JP5807284B2 (en) * 2011-07-15 2015-11-10 コリア インスティテュート オブ ジオサイエンス アンド ミネラル リソーシズＫｏｒｅａ Ｉｎｓｔｉｔｕｔｅ Ｏｆ Ｇｅｏｓｃｉｅｎｃｅ Ａｎｄ Ｍｉｎｅｒａｌ Ｒｅｓｏｕｒｃｅｓ Method for producing high-purity ammonium sulfate and calcite using gypsum
WO2014033687A1 (en) 2012-09-02 2014-03-06 Council Research Scientific Industrial Research Integrated process of production of potassium sulphate and ammonium sulfate from kainite mixed salt
CN102825058B (en) * 2012-09-05 2015-01-21 山东东佳集团股份有限公司 Method for recycling calcium sulfate waste residues generated in titanium dioxide acidic waste water
KR101482017B1 (en) 2013-05-23 2015-01-14 한국지질자원연구원 Method for synthesizing high purity calcite from fgd gypsum with carbonation reaction using the intermediate product (ammonium carbamate) of captured co2
CN103397201B (en) * 2013-07-26 2014-12-17 中国科学院青海盐湖研究所 Method for statically leaching and extracting potassium from polyhalite and preparing potassium sulphate
US9193601B2 (en) 2013-09-30 2015-11-24 Council Of Scientific & Industrial Research Method of recycling of by-products for the production of soda ash and ammonium sulphate
AU2013234427B2 (en) * 2013-09-30 2017-10-12 Council Of Scientific & Industrial Research Method of Recycling of By-Products for the Production of Soda Ash and Ammonium Sulphate
US20180230065A1 (en) * 2014-10-16 2018-08-16 Council Of Scientific & Industrial Research A process of production of potassium ammonium sulfate compound fertilizer in cost-effective manner directly from concentrated sea bittern
US9682868B2 (en) * 2015-01-30 2017-06-20 Sparstane Technologies LLC Partially continuous countercurrent process for converting gypsum to ammonium sulfate and calcium carbonate
JP7313002B2 (en) * 2019-04-19 2023-07-24 学校法人早稲田大学 Carbon dioxide fixation method
CN111732115B (en) * 2020-07-07 2021-06-01 辽宁镁誉新材料股份有限公司 Preparation method and application of metallurgical precipitation grade magnesium oxide
EP4299554A1 (en) * 2022-06-30 2024-01-03 SABIC Global Technologies B.V. Methods for preparation of ca nutrient to support carbon neutrality
EP4299553A1 (en) * 2022-06-30 2024-01-03 SABIC Global Technologies B.V. Production of nitrogen, potassium, sulfur nutrient through de-carbonization and utilization of calcium sulfate
CN117263724B (en) * 2023-09-20 2025-09-26 天津科技大学 A method for extracting potassium magnesium sulfate fertilizer by evaporating and converting bittern from seawater for salt production

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3207576A (en) * 1960-12-12 1965-09-21 Montedison Spa Process for producing potassium sulfate from kainite through the intermediate formation of schoenite and langbeinite
ES295016A1 (en) * 1963-01-15 1964-07-01 Montedison Spa Process for recovering potassium sulfate from ffinal mother liquors of kaineite
US3436175A (en) * 1964-06-19 1969-04-01 Duval Corp Method of producing ammonium sulfate,potassium sulfate and magnesium oxide from langbeinite
JPS5016696A (en) * 1973-06-18 1975-02-21
CH635870A5 (en) * 1978-08-04 1983-04-29 Sulzer Ag Method for producing magnesium from a magnesium sulphate containing salt solution.
JPS57129823A (en) * 1981-09-19 1982-08-12 Nio Kosan Kk Manufacture of magnesium potassium sulfate by simultaneous chemical reaction of magnesium hydroxide, potassium chloride and sulfuric acid, and manufacture of potassium sulfate
CN100439247C (en) * 2003-12-31 2008-12-03 科学与工业研究委员会 Simultaneous recovery of potassium chloride and KCl-rich edible salt
US7041268B2 (en) * 2004-03-30 2006-05-09 Council Of Scientific And Industrial Research Process for recovery of sulphate of potash
CN1880224A (en) * 2005-06-13 2006-12-20 陈栋才 Gypsum-ammonia circulation method for combined production of barium chloride, potassium sulfate
DE602005022506D1 (en) * 2005-11-10 2010-09-02 Council Scient Ind Res IMPROVED METHOD OF OBTAINING CALIUM SULPHATE (SOP, SULPHATE OF POTASH) FROM SULPHATE-MADE NUTSOLE
CN101679058B (en) 2007-03-30 2012-11-14 宇部材料工业株式会社 Magnesium hydroxide powder and method for producing the same
CN101173115B (en) * 2007-10-27 2010-06-02 太原理工大学 Superfine Magnesium Hydroxide Surface Modification Method

Also Published As

Publication number Publication date
EP2411330A1 (en) 2012-02-01
JP2012521945A (en) 2012-09-20
CN102421707B (en) 2015-04-01
WO2010109492A1 (en) 2010-09-30
AU2010228846B2 (en) 2014-01-16
ES2435008T3 (en) 2013-12-18
AU2010228846A1 (en) 2011-10-20
CA2756763C (en) 2017-03-21
US8721999B2 (en) 2014-05-13
IL215391A0 (en) 2011-12-29
BRPI1009805A2 (en) 2016-11-22
CN102421707A (en) 2012-04-18
IL215391A (en) 2015-01-29
EP2411330B1 (en) 2013-08-14
MX2011010165A (en) 2011-10-11
JP5509310B2 (en) 2014-06-04
CA2756763A1 (en) 2010-09-30
US20130315805A1 (en) 2013-11-28

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Free format text: APRESENTE DOCUMENTOS COMPROBATORIOS QUE EXPLIQUEM A DIVERGENCIA NO NOME DE UM DOS INVENTORES QUE CONSTA NA PUBLICACAO INTERNACIONAL WO/2010/109492 DE 30/09/2010, "HIMANSHU LABHSHANKER JOSHI" E O CONSTANTE DA PETICAO INICIAL NO 020110100279 DE 27/09/2011, "HIMANSHU LABHSHANKAR JOSHI"

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