WO2010142480A1 - Odor-imparting detergent, cleaning or care product - Google Patents

Abstract

The invention relates to an odor-imparting detergent, cleaning or care product which contains odoriferous aldehydes and (optionally substituted) ethylene diamine and/or (optionally substituted) propylene diamine, allowing surprising odor advantages of the objects treated therewith, especially in terms of intensity and lasting nature of the odor impression. The total amount of perfume which the product should contain can even be reduced and yet odor advantages can be achieved on the objects.

Description

 Scented washing, cleaning or care products

The present invention relates to a washing, cleaning or care agent containing ethylenediamines and / or propylenediamines. It further relates to a textile cleaning or conditioning method in which the textile to be cleaned is subjected to a textile washing using an appropriate washing, cleaning or care agent. It relates to the use of such an agent for cleaning and / or conditioning of textile fabrics, in particular in an automatic washing machine. It relates to the use of ethylenediamine and / or propylenediamine to extend the fragrance effect of the washing, cleaning or care product as well as to achieve a long-lasting fresh scent when using the washing, cleaning or care product.

In the application of washing, cleaning or care products, the consumer not only pursues the goal of washing, cleaning or caring for the objects to be treated, but also desires that the treated objects, e.g. Textiles, like to smell good after washing. For this reason in particular, most commercially available washing, cleaning or care products contain fragrances.

When using conventional washing, cleaning or care products, however, often remains after use, especially after washing, but only a relatively weak scent on the treated object, in particular the laundry, back. Therefore, there is a continuing need for washing, cleaning or care products on the consumer side, which allow improved object scenting, in particular textile fragrancing, especially with regard to the scent intensity, in particular with regard to a sense of freshness.

The object of the present invention was therefore to provide washing, cleaning or care products which show improved fragrance intensity during use, in particular in connection with textile treatment.

This object has been achieved by a washing, cleaning or care product containing

(a) fragrance aldehydes as well

(b) (optionally substituted) ethylenediamines and / or (optionally substituted) propylenediamines. It has surprisingly been found that the washing, cleaning or care agents according to the invention exhibit an improved fragrance intensity during use, in particular in connection with the textile treatment. For example, when using a laundry treatment agent according to the invention, such as detergents and fabric softeners, an improved fragrance intensity of the treated laundry could be found. This applies to both wet and especially dry laundry. Here also a better durability of the scent impression was found, ie the desired scent impression lasted longer. Furthermore, corresponding products have a particularly good storage stability. In addition, the compositions according to the invention make it possible to reduce the total amount of perfume which is contained on average, and nevertheless to achieve odor advantages on the laundered textiles, in particular with regard to the sensation of freshness.

In a preferred embodiment of the invention, an agent according to the invention is characterized in that component (a) and component (b) are added separately to the washing, cleaning or care agent matrix. In this procedure, particularly advantageous scent intensities in the sense of the invention are made possible. It is e.g. According to the invention possible to introduce the component (a) with the rest of perfuming in the product and to introduce the component (b) in a separate step. Furthermore, it is also possible according to the invention to introduce components (a) and (b) into the product in a single step, e.g. together with the remainder of the perfume, provided that components (a) and (b) are separate when added, e.g. as separate components of a perfume oil.

In accordance with another preferred embodiment, the component (b) 1, 2-diaminoethane, propane-1, 3-diamine, 1, 2-dianilinoethane, N, N ^{'-dimethylethylenediamine,} N, N'-diethyl ethyl-1, 3-diamine , N, N'-Diisopropylethyl-1, 3-diamine, N, N ^{'-Dimethylpropan-1,} 3-diamine, N, N'-diethylpropane-1, 3-diamine and / or N, N'-Diisopropylpropan-1 , 3-diamine used.

As fragrance aldehydes, it is possible to use all customary fragrant aldehydes which are typically used to produce a pleasant scent sensation. Suitable fragrance aldehydes are known to the person skilled in the art. Suitable fragrance aldehydes may be any aldehydes, especially those which impart a desired fresh scent or sensation of freshness. Because this is particularly desirable according to the invention, especially with a view to a particularly intense and long-lasting feeling of freshness. It may be individual aldehydes or aldehyde mixtures. The fragrance aldehydes may in particular have an aliphatic, cycloaliphatic, aromatic, ethylenically unsaturated structure or a combination of these structures. There may also be other heteroatoms or polycyclic structures. The structures may have suitable substituents such as hydroxyl or amino groups. When in the agent according to the invention as component (a) a fragrance aldehyde is used, selected from Adoxal, Anisaldehyd, Cymal, Ethylvanillin, Florhydral, Helional, Heliotropin, Hydroxycitronellal, Koavon, Lauraldehyd, Lyral, Methylnonylacetaldehyd, PT Bucinal, Phenylacetaldehyd, Undecylenaldehyd, Vanillin, 2,6,10-trimethyl-9-undecenal, 3-dodecene-1-al, alpha-n-amyl-cinnamic aldehyde, 4-methoxybenzaldehyde, benzaldehyde, 3- (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal, 3-phenyl-2-propenal, cis- / trans-3, 7-dimethyl-2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-dimethyl-6-octenyl) oxy] acetaldehyde, 4-isopropylbenzaldehyde, 1, 2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2-methyl-3- (isopropyl-phenyl ) propanal, 1-decanal, decyl aldehyde, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2,6)] decylidene-8) -butanal, octahydro-4,7-methane-1 H-indenecarboxaldehyde, 3 -Ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alphadimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamaldehyde, m-cymene-7-carboxaldehyde, alpha Methylphenylacetaldehyde, 7-hydroxy-3,7-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3) (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7-methoxy-3,7-dimethyloctan-1-al 2-methylun decanal, 2-methyldecanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3- (4-tert-butyl) propanal, dihydrocinnamaldehyde, 1-methyl 4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6-methoxy-hexahydro-4,7-methanindan-1 or 2-carboxaldehyde, 3,7-dimethyloctan-1-al , 1-undecanal, 10-undecene-1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3-cyclohexenecarboxaldehyde, 7-hydroxy-3,7-dimethyl-octanal, trans -4- Decenal, 2,6-nonadienal, para-tolylacetaldehyde, 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde, S. δ, θ-trimethyl-S-cyclohexene-carboxaldehyde, 3,7-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6,10-dimethyl-3-) oxa-5,9-undecadiene-1-al), hexahydro-4,7-methanindane-1-carboxaldehyde, 2-methyloctanal, alpha-methyl-4- (1-methylethyl) benzeneacetaldehyde, 6,6-dimethyl 2-norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propylbicyclo [2.2.1] hept-5-ene-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl-1-pentanal, methylnonylacetaldehyde, hexanal, trans-2-hexenal, 1-p-menthene-q- carboxaldehyde or mixtures thereof, so is a preferred embodiment of the invention.

Furthermore, it is advantageous in the context of the invention to use fragrance ketones in addition to the fragrance aldehyde. A preferred embodiment of the invention is therefore present if in addition at least one fragrance ketone is used, in particular selected from buccoxime; iso-jasmone; Methyl-beta-naphthyl ketone; musk indanone; Tonalid / Musk plus; alpha damascone, beta Damascone, delta-damascon, iso-damascon, damascenon, damarose, methyldihydrojasmonate, menthone, carvone, camphor, fenchone, alpha-ionone, beta-ionone, gamma-methyl called lonon, fleuramon, dihydrojasmon, cis-jasmone, iso- E-Super®, methyl cedryl ketone or methyl citrate ion, acetophenone, methyl acetophenone, para-methoxy acetophenone, methyl beta-naphthyl ketone, benzyl acetone, benzophenone, para-hydroxyphenyl butanone, celery ketone or live scone, 6-isopropyl decahydro-2-naphthone, dimethyloctenone, Frescomenthe , 4- (1-Ethoxy-vinyl) -3,3,5,5-tetramethylcyclohexanone, methylheptenone, 2- (2- (4-methyl-3-cyclohexen-1-yl) -propyl) -cyclopentanone, 1- (p-menthene) 6 (2) yl) -1-propanone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 2-acetyl-3,3-dimethylnorbornane, 6,7-dihydro-1, 1, 2 , 3,3-pentamethyl-4 (5H) in-danone, 4-damascol, dulcinyl or cassion, gelson, hexalon, isocyclone E, methylcyclocitron, methyllavedelketone, orivone, para-tertiary butylcyclohexanone, verdone, delphone, muscone, neobutenone, plicaton , Velou-ton, 2,4,4,7 Tetramethyl-oct-6-en-3-one, tetrameran or mixtures thereof. Preferably, the ketones may be selected from Alpha Damascon, Delta Damascone, Iso Damascone, Carvon, gamma-methyl ionone, Iso-E-Super, 2,4,4,7-tetramethyl-oct-6-en-3-one, Benzylacetone, Beta Damascone, Damascenone, methyl dihydrojasmonate, methyl cedrylon, hedione and mixtures thereof.

For other suitable fragrances selected from aldehydes and ketones, see Steffen Arctander Published 1960 and 1969, respectively, Reprinted 2000 ISBN: Aroma Chemicals Vol. 1: 0-931710-37-5, Aroma Chemicals Vol. 2: 0-931710-38 -3, referenced.

In a further preferred embodiment of the invention, the component (b) in amounts of 0.001 wt .-% to 3 wt .-%, preferably 0.01 to 2 wt .-%, in particular 0.1 to 1 wt .-% in the mean, based on the total In this way, particularly good scent results within the meaning of the invention can be realized. If an agent according to the invention contains 0.001% by weight to 3% by weight, preferably 0.01% to 2% by weight, in particular 0.1% to 1% by weight, of fragrance aldehydes,% by weight, based on the total agent, so is also a preferred embodiment of the invention. Thus, also very good scent results within the meaning of the invention can be represented. In particular, it is advantageous for achieving particularly good scent results if the ratio of component (a) to component (b) is 25: 1 to 1: 5. Then again there is a preferred embodiment of the invention.

Furthermore, it is preferred that the total amount of fragrance of the agent, including all fragrance aldehydes contained, 0.01 to 10 wt .-%, preferably 0.1 to 5 wt .-%, in particular 0.3 to 3 wt .-% is. This corresponds to a preferred embodiment of the invention.

According to a further preferred embodiment of the invention, the agent according to the invention is in solid form, preferably in powder form or else in granular form or in the form of molded articles, for example tablets. But it is also possible that the inventive agent in in liquid form, preferably in gel form. This, too, corresponds to a preferred embodiment of the invention.

In addition to the fragrance aldehydes and the (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine, the composition according to the invention may comprise further suitable ingredients, but in particular surfactants. If the agent according to the invention contains at least 5% by weight, preferably at least 8% by weight, in particular at least 10% by weight of surfactant, in particular anionic surfactant and / or nonionic surfactant, then a preferred embodiment of the invention is present. A reasonable upper limit for surfactant may e.g. at 40 wt .-% or 30 wt .-% or 20 wt .-%, wt .-% in each case based on the total mean. Surfactants will be described in more detail below.

Another object of the invention is a textile cleaning or conditioning process in which the textile to be cleaned is subjected to textile washing using a washing, cleaning or care agent according to the invention, in particular in an automatic washing machine, preferably at temperatures above 6O ⁰ C, in particular not 4O ⁰ C.

Another object of the invention is the use of a washing, cleaning or care agent according to the invention for cleaning and / or conditioning of textile fabrics, in particular in an automatic washing machine, preferably at temperatures not above 6O ⁰ C, in particular not above 40 ⁰ C. ,

Another object of the invention is the use of (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine as a separately added component in perfume-containing detergents, cleaning or care products containing fragrance aldehyde, to extend the fragrance effect of the wash , Cleaning or care products. "Separately added component" here refers to the fragrance aldehydes likewise contained and is intended to mean that ethylenediamine and / or (optionally substituted) propylenediamine and fragrance aldehydes enter the washing, cleaning or care agent as separate entities to introduce the components (a) and (b) into the product in a single step, eg together with the rest of the perfuming, provided that the components (a) and (b) are present separately during the addition, for example as separate components of a perfume oil.

Another object of the invention is the use of (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine as a separately added component in perfume-containing detergents, cleaning or care products containing fragrance aldehyde, to achieve a long-lasting fresh smell at the application of the washing, Cleaning or care products. "Separately added component" is to be understood as previously described.

The washing, cleaning or care agent may in particular be a textile treatment agent in the form of a textile detergent, fabric conditioner, softening detergent or washing aid. It may also be e.g. to be a hard surface cleaning agent, such as preferably a dishwashing detergent, especially a machine dishwashing detergent. It may also be detergents, e.g. Household cleaners, all-purpose cleaners, window cleaners, floor cleaners, etc. act. Preferably, it may be a

Product for cleaning toilet bowls and Urinalen act, advantageously a flushing cleaner for hanging in the toilet bowl or the cistern, especially around a so-called toilet block. The care agent is preferably cosmetics, e.g. Hair shampoos, deodorants, etc., which can be used for personal care and / or cleaning. The care product may also be air care products and room air improvers.

According to a preferred embodiment, the agent according to the invention is therefore a textile treatment agent, an ironing aid, a cleaning cloth, a laundry detergent, a softener, a cleaning agent, in particular for hard and / or soft surfaces, a household cleaner, a care agent, a laundry care product Room fragrancing agent, an air freshener, a conditioning agent, a coloring agent, a fabric softener, a conditioning substrate, a cleaning agent, a cosmetic, a bleach, a descaling agent, a car care product, floor care products, stoves, leather care products, furniture care products, a scouring agent, a disinfectant Scenting agent, a mold remover and / or a precursor of the aforementioned means. It is an advantage of the invention that the agents according to the invention are very stable on storage.

According to a further preferred embodiment of the invention, the composition according to the invention contains additional fragrance (s), in particular selected from the group consisting of fragrances of natural or synthetic origin, preferably more volatile fragrances, higher-boiling fragrances, solid fragrances and / or strong fragrances.

Adherent fragrances which are advantageously used in the present invention are, for example, essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, bergamot oil, Champacablütenöl, Edeltannöl, Edeltannenzapfen oil, Elemiöl, eucalyptus oil, fennel oil, spruce oil, galbanum oil, geranium oil, gingergrass oil , Guaiac wood oil, gurdy balm oil, helichrysum oil, ho oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, Camphor oil, kanga oil, cardamom oil, cassia oil, pine oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemon grass oil, lime oil, tangerine oil, lemon balm oil, musk kernel oil, myrrh oil, clove oil, neroli oil, niaouli oil, olibanum oil, orange oil, origanum oil, palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sandalwood oil, Celery oil, Spik oil, Star aniseed oil, Turpentine oil, Thuja oil, Thyme oil, Verbena oil, Vetiver oil, Juniper berry oil, Vermouth oil, Wintergreen oil, Ylang-ylang oil, Hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil and cypress oil.

But also higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention as adherent fragrances or fragrance mixtures, ie fragrances. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol , Bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, Eugenof, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole , Iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmone, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl anthraniloic acid methyl ester, p-methylacetophenone, methylchavikole, p-methylquinoline , Methyl β-naphthyl ketone, methyl n-nonyl acetaldehyde, methyl n-nonyl ketone, Mu β-naphthol ethyl ether, β-naphthol methyl ether, nerol, nitrobenzene, n-nonyl aldehyde, nonyl alcohol, n-octyl aldehyde, p-oxyacetophenone, pentadecanolide, β-phenylethyl alcohol, phenyl acetaldehyde dimethyl acetal, phenylacetic acid, pulegone, safrole, salicylic acid isoamyl ester, methyl salicylate, Salicylic acid hexyl ester, cyclohexyl salicylate, santalol, skatole, terpineol, thymes, thymol, γ-undelactone, vaniline, veratrum aldehyde, cinnamaldehyde, cimat alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester. The more volatile fragrances include, in particular, the lower-boiling fragrances of natural or synthetic origin, which can be used alone or in mixtures. Examples of more volatile fragrances are alkyl isothiocyanates (alkylmustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

For the accelerated or delayed release of perfumes, it is possible to use all processes known in the prior art, insofar as they appear to be suitable for the person skilled in the art. According to a preferred embodiment of the invention, the agent according to the invention comprises supported and / or encapsulated perfume. According to a further preferred embodiment, the washing, care or cleaning agent according to the invention comprises at least one, preferably several, active components, in particular washing, care, cleaning and / or cosmetic components, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifying agents, alkalizing agents, anti-wrinkling compounds, antibacterial agents, antioxidants, anti redeposition agents, antistatic agents, builders, bleaches, bleach activators, bleach stabilizers, bleach catalysts, ironing aids, cobuilders, fragrances, anti-shrinkage agents, electrolyte, enzymes, colorants, Colorants, dyes, color transfer inhibitors, fluorescers, fungicides, germicides, odor-complexing agents, adjuvants, hydrotropes, rinse aids, chelating agents, preservatives, corrosion inhibitors, water-miscible organic Solvents, optical brighteners, perfumes, perfume carriers, pearlescers, pH adjusters, repellents and impregnating agents, polymers, swelling and anti-slip agents, foam inhibitors, phyllosilicates, stain-proofing agents, silver protectants, silicone oils, soil release agents, UV protectants, viscosity regulators, Thickeners, discoloration inhibitors, grayness inhibitors, vitamins and / or fabric softeners. For the purposes of this invention, data for the agent according to the invention in% by weight, unless otherwise stated, relate to the total weight of the composition according to the invention.

The amounts of the individual ingredients in the compositions according to the invention are in each case based on the intended use of the agent in question, and the person skilled in the art is familiar with the orders of magnitude of the ingredients to be used or can refer to these from the associated specialist literature. Depending on the intended use of the compositions according to the invention, for example, the surfactant content will be higher or lower. Usually z. For example, the surfactant content of, for example, detergents is between 10 and 50% by weight, preferably between 12.5 and 30% by weight, and more preferably between 15 and 25% by weight, while automatic dishwashing detergents e.g. between 0.1 and 10 wt .-%, preferably between 0.5 and 7.5 wt .-% and in particular between 1 and 5 wt .-% surfactants may contain.

The compositions of the invention may contain surfactants, with preference being given to anionic surfactants, nonionic surfactants and mixtures thereof, as well as cationic surfactants. Suitable nonionic surfactants are, in particular, ethoxylation and / or propoxylation products of alkyl glycosides and / or linear or branched alcohols having in each case 12 to 18 C atoms in the alkyl moiety and 3 to 20, preferably 4 to 10, alkyl ether groups. In addition, suitable ethoxylation and / or propoxylation products of N-alkylamines, vicinal diols, fatty acid esters and fatty acid amides which correspond to said long-chain alcohol derivatives with respect to the alkyl moiety and of alkylphenols having 5 to 12 carbon atoms in the alkyl radical are useful. Suitable anionic surfactants are in particular soaps and those which contain sulfate or sulfonate groups with preferably alkali ions as cations. Usable soaps are preferably the alkali salts of the saturated or unsaturated fatty acids having 12 to 18 carbon atoms. Such fatty acids can also be used in incompletely neutralized form. Useful surfactants of the sulfate type include the salts of the sulfuric acid half-esters of fatty alcohols having 12 to 18 carbon atoms and the sulfation products of said nonionic surfactants having a low degree of ethoxylation. Suitable surfactants of the sulfonate type include linear alkylbenzenesulfonates having 9 to 14 carbon atoms in the alkyl moiety, alkanesulfonates having 12 to 18 carbon atoms, and olefin sulfonates having 12 to 18 carbon atoms, which are formed in the reaction of corresponding monoolefins with sulfur trioxide, and alpha-sulfofatty acid esters resulting from the sulfonation of fatty acid methyl or ethyl esters.

Cationic surfactants are preferably selected from esterquats and / or quaternary ammonium compounds (QAV) according to the general formula (R ') (R ") (R"') (R ^IV ) N ⁺ X ^- , in which R ¹ to R ^iv for the same or different C |. _22- alkyl radicals, C ₇ . ₂₈ -Arylalkylreste or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, such as a pyridinium or Imidazoliniumverbindung, form, and X ^" for halide ions, sulfate ions, hydroxide ions or similar anions QACs can be prepared by reaction of tertiary amines with alkylating agents, such as, for example, methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide.The alkylation of tertiary amines with a long alkyl radical and two methyl groups is particularly easy, also the quaternization of tertiary amines having two long radicals and one methyl group can be carried out under mild conditions with the aid of methyl chloride. Amines having three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are quaternized, for example, with dimethyl sulfate. Eligible QACs include benzalkone ium chloride (N alkyl-N, N dimethylbenzylammonium chloride), benzalkone B (m, p-dichlorobenzyldimethyl-C ₁₂ -alkylammonium chloride, benzoxonium chloride (benzyldodecyl-bis- (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N- Hexadecyl-N, N-trimethyl-ammonium bromide), benzetonium chloride (N, N-dimethyl-N [2- [2- [p- (1,1,3,3-tetramethyl-butyl) -phenoxy] -ethoxy] -ethyl] -benzylammonium chloride) , Dialkyldimethylammoniumchloride such as di-n-decyl-dimethyl-ammonium chloride, Didecyldimethylammonium bromide, dioctyl-dimethyl-ammonium chloride, 1-Cetylpyridiniumchlorid and Thiazolinjodid and mixtures thereof. Preferred QUATS are the benzalkonium chlorides containing C ₈ -C ₂₂ alkyl, in particular Ci _Σ -C _{M-alkyl-benzyl-dimethylammonium} chloride.

Esterquats are here preferably compounds of the general formula IV, RS (CO) -C (CH ₂ ) s X ^" _{(| γ)}

in which R ^{5 is} an alkyl or alkenyl radical having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, R ⁶ and R ^{7 are} independently H, OH or O (CO) R ⁵ , s, t and u are each independently of the other the value 1, 2 or 3 and X ^"is an anion, in particular halide, methosulphate, methophosphate or phosphate and mixtures thereof, Preference is given to compounds which for R ^{6 are} the group O (CO) R ⁵ and for R ⁵ contain an alkyl radical having 16 to 18 carbon atoms, particular preference is given to compounds in which R ⁷ additionally represents OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N di (tallow acyl oxyethyl) ammonium methosulfate, bis (palmitoyl) ethyl hydroxyethyl methyl ammonium methosulfate or methyl N, N-bis (acyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate If quaternized compounds of the formula (IV) which have unsaturated groups are used, the acyl groups whose k corresponding fatty acids have an iodine value between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and / or which has a cis / trans isomer ratio (in mol%) of greater than 30:70, preferably greater than 50:50 and in particular greater than 70:30. Commercial examples are the alkylammoniummethosulfate marketed by Stepan under the trade name Stepantex® ^® methyl hydroxyalkyl or known under the trade name Dehyquart® ^® products from Cognis Germany GmbH or the known under the name Rewoquat ^® products by manufacturer Goldschmidt-Witco.

Surfactants are present in the inventive compositions in proportions of preferably 5 wt .-% to 50 wt .-%, in particular from 8 wt .-% to 30 wt .-%. Particularly in laundering agents, preferably up to 30% by weight, in particular from 5% by weight to 15% by weight, of surfactants, among these preferably at least partially cationic surfactants, are used.

An agent according to the invention preferably contains at least one water-soluble and / or water-insoluble, organic and / or inorganic builder. The water-soluble organic builder substances include polycarboxylic acids, in particular citric acid and sugar acids, monomeric and polymeric aminopolycarboxylic acids, in particular methylglycine diacetic acid, nitrilotriacetic acid and ethylenediaminetetraacetic acid and polyaspartic acid, polyphosphonic acids, in particular aminotris (methylenephosphonic acid), ethylenediaminetetrakis (methylenephosphonic acid) and 1-hydroxyethane-1, 1-diphosphonic acid, polymeric hydroxy compounds such as dextrin and also polymeric (poly) carboxylic acids, polymeric acrylic acids, methacrylic acids, maleic acids and mixed polymers thereof, which also polymerize small amounts May contain copolymerized substances without carboxylic acid functionality. The molecular weight of the homopolymers of unsaturated carboxylic acids is generally between 5,000 and 200,000, that of the copolymers between 2,000 and 200,000, preferably 50,000 to 120,000, in each case based on the free acid. A particularly preferred acrylic acid-maleic acid copolymer has a molecular weight of 50,000 to 100,000. Suitable, albeit less preferred, compounds of this class are copolymers of acrylic acid or methacrylic acid with vinyl ethers, such as vinylmethyl ethers, vinyl esters, ethylene, propylene and styrene, in which the proportion of the acid is at least 50% by weight. As water-soluble organic builders, it is also possible to use terpolymers which contain two unsaturated acids and / or salts thereof as monomers and vinyl alcohol and / or a vinyl alcohol derivative or a carbohydrate as the third monomer. The first acidic monomer or its salt is derived from a monoethylenically unsaturated C ₃ -C ₈ -carboxylic acid and preferably from a C ₃ - C ₄ -monocarboxylic acid, in particular from (meth) -acrylic acid. The second acidic monomer or its salt can be a derivative of a C ₄ -C ₈ -dicarboxylic acid, with maleic acid being particularly preferred. The third monomeric unit is formed in this case of vinyl alcohol and / or preferably an esterified vinyl alcohol. In particular, vinyl alcohol derivatives are preferred which represent an ester of short-chain carboxylic acids, for example of C 1 -C ₄ -carboxylic acids, with vinyl alcohol. Preferred polymers contain from 60% by weight to 95% by weight, in particular from 70% by weight to 90% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, and maleic acid or Maleinate and 5 wt .-% to 40% by weight, preferably 10 wt .-% to 30 wt .-% of vinyl alcohol and / or vinyl acetate. Very particular preference is given to polymers in which the weight ratio of (meth) acrylic acid or (meth) acrylate to maleic acid or maleate is between 1: 1 and 4: 1, preferably between 2: 1 and 3: 1 and in particular 2: 1 and 2 , 5: 1 lies. Both the amounts and the weight ratios are based on the acids. The second acidic monomer or its salt can also be a derivative of an allylsulfonic acid which is substituted in the 2-position by an alkyl radical, preferably by a C 1 -C ₄ -alkyl radical, or by an aromatic radical which is preferably derived from benzene or benzene derivatives , Preferred terpolymers contain from 40% by weight to 60% by weight, in particular from 45 to 55% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, from 10% by weight to 30% by weight. %, preferably 15 wt .-% to 25 wt .-% methallylsulfonic acid or Methallylsulfonat and as the third monomer 15 wt .-% to 40 wt .-%, preferably 20 wt .-% to 40 wt .-% of a carbohydrate. This carbohydrate may be, for example, a mono-, di-, oligo- or polysaccharide, mono-, di- or oligosaccharides being preferred. Particularly preferred is sucrose. The use of the third monomer presumably incorporates predetermined breaking points into the polymer which are responsible for the good biodegradability of the polymer. These terpolymers generally have a molecular weight between 1,000 and 200,000, preferably between 200 and 50,000 and especially between 3 000 and 10 000 on. Further preferred copolymers are those which contain acrolein and acrylic acid / acrylic acid salts or vinyl acetate as monomers. The organic builder substances can be used, in particular for the preparation of liquid agents, in the form of aqueous solutions, preferably in the form of 30 to 50 percent by weight aqueous solutions. All of the acids mentioned are generally used in the form of their water-soluble salts, in particular their alkali metal salts.

If desired, organic builder substances may be present in amounts of up to 40% by weight, in particular up to 25% by weight and preferably from 1% by weight to 8% by weight. Quantities close to the stated upper limit are preferably used in paste-form or liquid, in particular water-containing, agents according to the invention. Aftertreatment agents according to the invention, such as e.g. Softener, may optionally also be free of organic builder.

Suitable water-soluble inorganic builder materials are, in particular, alkali metal silicates and polyphosphates, preferably sodium triphosphate. Crystalline or amorphous alkali metal nanosilicates, if desired in amounts of up to 50% by weight, preferably not more than 40% by weight and in liquid media, in particular from 1% by weight to 5% by weight, can be used as water-insoluble, water-dispersible inorganic builder materials. -%, are used. Among these, preferred are the detergent grade crystalline sodium aluminosilicates, especially zeolite A, P and optionally X. Amounts near the above upper limit are preferably used in solid, particulate agents. In particular, suitable aluminosilicates have no particles with a particle size greater than 30 .mu.m and preferably consist of at least 80% by weight of particles having a size of less than 10 .mu.m.

Suitable substitutes or partial substitutes for the said aluminosilicate are crystalline alkali silicates which may be present alone or in a mixture with amorphous silicates. The alkali metal silicates useful as builders in the compositions according to the invention preferably have a molar ratio of alkali metal oxide to SiO _{2 of} less than 0.95, in particular of 1: 1, 1 to 1: 12, and may be amorphous or crystalline. Preferred alkali metal silicates are the sodium silicates, in particular the amorphous sodium silicates, with a molar ratio of Na ₂ O: SiO ₂ of 1: 2 to 1: 2.8. The crystalline silicates which may be present alone or in admixture with amorphous silicates, are crystalline layer silicates with the general formula Na ₂ Si _x O y are used _{2x + 1} H ₂ O, in which x, known as the modulus, an integer of 1, 9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. Preferred crystalline phyllosilicates are those in which x in the abovementioned general formula assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates (Na ₂ Si ₂ O ₅ y H ₂ O) are preferred. Also prepared from amorphous alkali silicates, practically anhydrous crystalline alkali silicates of the above general Formula in which x is a number from 1, 9 to 2.1, can be used in inventive compositions. In a further preferred embodiment of the composition according to the invention, a crystalline sodium layer silicate with a modulus of 2 to 3 is used, as can be prepared from sand and soda. Crystalline sodium silicates with a modulus in the range of 1.9 to 3.5 are used in a further preferred embodiment of compositions according to the invention. If alkali metal aluminosilicate, in particular zeolite, is also present as an additional builder substance, the weight ratio of aluminosilicate to silicate, in each case based on anhydrous active substances, is preferably 1:10 to 10: 1. In agents containing both amorphous and crystalline alkali metal silicates, the weight ratio of amorphous alkali metal silicate to crystalline alkali metal silicate is preferably 1: 2 to 2: 1 and especially 1: 1 to 2: 1.

If desired, builder substances are preferably present in the compositions according to the invention in amounts of up to 60% by weight, in particular from 5% by weight to 40% by weight. Aftertreatment agents according to the invention, such as e.g. Softener, are preferably free of inorganic builder.

Suitable peroxygen compounds are, in particular, organic peracids or pers acid salts of organic acids, such as phthalimidopercaproic acid, perbenzoic acid or salts of diperdodecanedioic acid, hydrogen peroxide and inorganic salts which release hydrogen peroxide under the conditions of use, such as perborate, percarbonate and / or persilicate. If solid peroxygen compounds are to be used, they can be used in the form of powders or granules, which can also be enveloped in a manner known in principle. Particular preference is given to using alkali percarbonate, alkali perborate monohydrate or, in particular, in liquid media, hydrogen peroxide in the form of aqueous solutions containing from 3% by weight to 10% by weight of hydrogen peroxide. If an agent according to the invention contains bleaches, such as preferably peroxygen compounds, they are present in amounts of preferably up to 50% by weight, in particular from 5% by weight to 30% by weight. The addition of small amounts of known bleach stabilizers such as phosphonates, borates or metaborates and metasilicates and magnesium salts such as magnesium sulfate may be useful.

As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylenediamines. acetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate , 2,5-diacetoxy-2,5-dihydrofuran and enol esters, as well as acetylated sorbitol and mannitol or mixtures thereof (SORMAN), acylated sugar derivatives, in particular pentaacetylglucose (PAG), pentaacetyl fructose, tetraacetylxylose and octaacetyl lactose as well as acetylated, optionally N-alkylated glucamine and gluconolactone , and / or N-acylated lactams, for example N-benzoyl-caprolactam. Hydrophilic substituted acyl acetals and acyl lactams are also preferably used. Combinations of conventional bleach activators can also be used. Such bleach activators may be present in the customary amount range, preferably in amounts of from 1% by weight to 10% by weight, in particular from 2% by weight to 8% by weight, based on the total agent.

In addition to the conventional bleach activators listed above or in their place, sulfone imines and / or bleach-enhancing transition metal salts or transition metal complexes can also be present as so-called bleach catalysts. Suitable transition metal compounds include, in particular, manganese, iron, cobalt, ruthenium or molybdenum-salene complexes and their N-analogues, manganese, iron, cobalt, ruthenium or molybdenum carbonyl complexes, manganese, iron, , Cobalt, ruthenium, molybdenum, titanium, vanadium, and copper complexes with nitrogen-containing tripod ligands, cobalt, iron, copper, and ruthenium-ammine complexes. Combinations of bleach activators and transition metal bleach catalysts can also be used. Bleach-enhancing transition metal complexes, in particular having the central atoms Mn, Fe, Co, Cu, Mo, V, Ti and / or Ru, can be used in customary amounts, preferably in an amount of up to 1% by weight, in particular 0.0025% by weight. % to 0.25 wt .-% and particularly preferably from 0.01 wt .-% to 0.1 wt .-%, each based on the total agent used.

Suitable enzymes which can be used in the compositions are those from the class of proteases, cutinases, amylases, pullulanases, hemicellulases, cellulases, lipases, oxidases and peroxidases and mixtures thereof. Particularly suitable are from fungi or bacteria, such as Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus, Humicola lanuginosa, Humicola insolens, Pseudomonas pseudoalcaligenes or Pseudomonas cepacia derived enzymatic agents. The optionally used enzymes may be adsorbed to carriers and / or embedded in encapsulants to protect against premature inactivation. If desired, they are preferably present in the compositions according to the invention in amounts of not more than 5% by weight, in particular from 0.2% by weight to 2% by weight. The agents may contain, for example, derivatives of diaminostilbenedisulfonic acid or their alkali metal salts as optical brighteners. For example, salts of 4,4'-bis (2-anilino-4-morpholino-1, 3,5-triazinyl-6-annino) stilbene-2,2'-disulphonic acid or similarly constructed compounds which replace the morpholino Group carry a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group. Furthermore, brighteners of the substituted diphenylstyrene type may be present, for example the alkali metal salts of 4,4'-bis (2-sulfostyryl) -diphenyl, 4,4'-bis (4-chloro-3-sulfostyryl) -diphenyl or 4- (4-chlorostyryl) -4 '- (2-sulfostyryl) -diphenyls. Mixtures of the aforementioned brightener can be used.

Suitable foam inhibitors include, for example, organopolysiloxanes and mixtures thereof with microfine, optionally signed silica and also Pa raffinwachse and mixtures thereof with silanated silica or bis-fatty acid alkylenediamides. It is also advantageous to use mixtures of various foam inhibitors, for example those of silicones, paraffins or waxes. Preferably, the foam inhibitors, in particular silicone and / or paraffin-containing foam inhibitors, are bound to a granular, water-soluble or dispersible carrier substance. In particular, mixtures of paraffin waxes and bistearylethylenediamides are preferred.

In addition, the compositions may also contain components which positively influence the oil and Fettauswaschbarkeit from textiles, so-called soil release agents. This effect becomes particularly evident when a textile is soiled which has previously been washed several times with an agent according to the invention containing this oil and fat-dissolving component. The preferred oil and fat dissolving components include, for example, nonionic cellulose ethers such as methylcellulose and methylhydroxypropylcellulose with a proportion of methoxyl groups of 15 to 30 wt .-% and hydroxypropoxyl groups of 1 to 15 wt .-%, each based on the nonionic Cellulose ethers, and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof with monomeric and / or polymeric diols, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof.

The compositions may also color transfer inhibitors, preferably in amounts of from 0.1 wt .-% to 2 wt .-%, in particular 0.1 wt .-% to 1 wt .-%, containing in a preferred embodiment of the invention polymers Vinylpyrrolidone, vinylimidazole, vinylpyridine N-oxide or copolymers of these are. Useful are both polyvinylpyrrolidones having molecular weights of from 15,000 to 50,000 and polyvinylpyrrolidones having molecular weights of more than 1,000,000, in particular from 1,500,000 to 4,000,000, N-vinylimidazole / N-vinylpyrrolidone copolymers, polyvinyloxazolidones, Copolymers based on vinyl monomers and carboxamides, pyrrolidone group-containing polyesters and polyamides, grafted polyamidoamines and polyethyleneimines, polymers with amide groups of secondary amines, polyamine-N-oxide polymers, polyvinyl alcohols and copolymers based on acrylamidoalkenylsulfonic acids. However, it is also possible to use enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which gives off hydrogen peroxide in water. The addition of a mediator compound for the peroxidase, for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, whereby also above-mentioned polymeric Farbübertragungsinhibitorwirkstoffe can be used. Polyvinylpyrrolidone preferably has an average molecular weight in the range from 10 000 to 60 000, in particular in the range from 25 000 to 50 000, for use in compositions according to the invention. Among the copolymers, those of vinylpyrrolidone and vinylimidazole in a molar ratio of 5: 1 to 1: 1 having an average molecular weight in the range of 5,000 to 50,000, especially 10,000 to 20,000 are preferred.

Graying inhibitors have the task of keeping suspended from the textile fiber dirt suspended in the fleet. Water-soluble colloids of mostly organic nature are suitable for this purpose, for example starch, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or of cellulose or salts of acidic sulfuric acid esters of cellulose or starch. Also, water-soluble polyamides containing acidic groups are suitable for this purpose. Furthermore, other than the above-mentioned starch derivatives can be used, for example aldehyde starches. Preference is given to using cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, for example in amounts of from 0.1 to 5% by weight, based on the compositions become.

Among the organic solvents which can be used in the compositions according to the invention, especially if they are in liquid or pasty form, are alcohols having 1 to 4 C atoms, in particular methanol, ethanol, isopropanol and tert-butanol, diols having 2 to 4 C atoms , in particular ethylene glycol and propylene glycol, and mixtures thereof and the derivable from said classes of compound ethers. Such water-miscible solvents are preferably present in the compositions according to the invention in amounts of not more than 30% by weight, in particular from 6% by weight to 20% by weight.

In order to establish a desired pH, which does not naturally result from the mixture of the other components, the compositions according to the invention may contain system and environmentally acceptable acids, in particular citric acid, acetic acid, tartaric acid, malic acid, lactic acid, glycolic acid, succinic acid, glutaric acid and / or adipic acid, but also mineral acids, especially particular sulfuric acid, or bases, in particular ammonium or alkali hydroxides. Such pH regulators are preferably not more than 20 wt .-%, in particular from 1, 2 wt .-% to 17 wt .-%, contained in the inventive compositions.

The preparation of solid compositions according to the invention presents no difficulties and can be carried out in a manner known in the art, for example by spray-drying or granulation, with optional peroxygen compound and optional bleach catalyst optionally being added later. For the preparation of compositions according to the invention having an increased bulk density, in particular in the range from 650 g / l to 950 g / l, a process comprising an extrusion step is preferred. The preparation of liquid inventive means also presents no difficulties and can also be done in a known manner.

According to a preferred embodiment, the teaching according to the invention can be used to significantly reduce the perfume fraction in washing, cleaning and personal care products. This makes it possible to offer perfumed products even for those particularly sensitive consumers who can not use normally perfumed products due to special intolerances and irritations, or only to a limited extent. In this context, especially skin care products and deodorants, but also detergents, such. To call hand detergent.

A preferred solid, in particular powdered, detergent according to the invention can contain, in addition to the constituents according to the invention (ie, (a) fragrant aldehydes and (b) (optionally substituted) ethylenediamines and / or (optionally substituted) propylenediamines), in particular also components which are e.g. are selected from the following:

Anionic surfactants, preferably alkylbenzenesulfonate, alkylsulfate, e.g. in amounts of preferably 5-30% by weight

Nonionic surfactants, such as preferably fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide, e.g. in amounts of preferably 0.5-15% by weight

Builders, e.g. Zeolite, polycarboxylate, sodium citrate, in amounts of e.g. 0-70% by weight, advantageously 5-60% by weight, preferably 10-55% by weight, in particular 15-40% by weight,

Alkalis, e.g. Sodium carbonate, in amounts of e.g. 0-35 wt .-% advantageously 1-30 wt .-%, preferably 2-25 wt .-%, in particular 5-20 wt .-%,

Bleaching agents, e.g. Sodium perborate, sodium percarbonate, in amounts of e.g. 0-30% by weight, advantageously 5-25% by weight, preferably 10-20% by weight,

- corrosion inhibitors, e.g. Sodium silicate, in amounts of e.g. 0-10% by weight, advantageously 1-6% by weight, preferably 2-5% by weight, in particular 3-4% by weight,

Stabilizers, eg phosphonates, advantageously 0-1% by weight, Foam inhibitor, for example soap, silicone oils, paraffins, advantageously 0-4% by weight, preferably 0.1-3% by weight, in particular 0.2-1% by weight,

Enzymes, e.g. Proteases, amylases, cellulases, lipases, advantageously 0-2% by weight, preferably 0.2-1% by weight, in particular 0.3-0.8% by weight,

- grayness inhibitor, e.g. Carboxymethylcellulose, advantageously 0-1% by weight,

Discoloration inhibitor, e.g. Polyvinylpyrrolidone derivatives, preferably 0-2% by weight,

- Adjustment means, e.g. Sodium sulfate, advantageously 0-20% by weight,

Optical brighteners, e.g. Stilbene derivative, biphenyl derivative, advantageously 0-0.4% by weight, in particular 0.1-0.3% by weight,

- If necessary, other fragrances

- If necessary water

- if necessary, soap

- optionally bleach activators

- optionally cellulose derivatives

- if necessary, dirt repellent,

% By weight, based in each case on the total agent.

In another preferred embodiment of the invention, the washing, cleaning or care agent is in liquid form, preferably in gel form. Preferred liquid washing, cleaning or care agents have water contents of e.g. 10-95 wt .-%, preferably 20-80 wt .-% and in particular 30-70 wt .-%, based on the total agent. In the case of liquid concentrates, the water content may also be particularly low, e.g. <30 wt .-%, preferably <20 wt .-%, in particular <15 wt .-%, wt .-% in each case based on the total agent. The liquid agents may also contain non-aqueous solvents.

In addition to the constituents according to the invention, a preferred liquid, in particular gel detergent according to the invention may contain, in particular, components which are e.g. are selected from the following:

Anionic surfactants, preferably alkylbenzenesulfonate, alkylsulfate, e.g. in amounts of preferably 5-40% by weight

Nonionic surfactants, such as preferably fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide, e.g. in amounts of preferably 0.5-25% by weight

Builders, e.g. Zeolite, polycarboxylate, sodium citrate, advantageously 0-15% by weight, preferably 0.01-10% by weight, in particular 0.1-5% by weight,

Foam inhibitor, e.g. Soap, silicone oils, paraffins, in amounts of e.g. 0-10 wt .-%, advantageously 0.1-4 wt .-%, preferably 0.2-2 wt .-%, in particular 1-3 wt .-%,

- Enzymes, for example proteases, amylases, cellulases, lipases, in amounts of, for example, 0-3 wt .-%, advantageously 0.1-2 wt .-%, preferably 0.2-1 wt .-%, in particular 0.3 -0.8% by weight, Optical brightener, eg stilbene derivative, biphenyl derivative, in amounts of eg 0-1% by weight, advantageously 0.1-0.3% by weight, in particular 0.1-0.4% by weight .

- If necessary, other fragrances

- stabilizers if necessary,

- Water

optionally soap, in quantities of e.g. 0-25% by weight, advantageously 1-20% by weight, preferably 2-15% by weight, in particular 5-10% by weight,

- If necessary, solvents (preferably alcohols), advantageously 0-25 wt .-%, preferably 1-20 wt .-%, in particular 2-15 wt .-%, wt .-% in each case based on the total agent.

In addition to the constituents according to the invention, a preferred liquid softener according to the invention may in particular also contain components which are selected from the following:

Cationic surfactants, such as in particular esterquats, e.g. in amounts of 5-30% by weight,

Cosurfactants, e.g. Glycerol monostearate, stearic acid, fatty alcohols, fatty alcohol ethoxylates, e.g. in amounts of 0-5% by weight, preferably 0.1-4% by weight,

Emulsifiers, e.g. Fatty amine ethoxylates, e.g. in amounts of 0-4 wt .-%, preferably

0.1-3 wt .-%, optionally other perfumes

Dyes, preferably in the ppm range

Stabilizers, preferably in the ppm range

Solvents, in particular water, in amounts of preferably 60-90% by weight,

-% by weight, based in each case on the total agent.

Example:

The odor effect of a commercially available particulate detergent containing 0.9% by weight of octanal was investigated. This corresponds to the detergent A.

The scent effect of an otherwise comparable commercial particulate detergent composition was also examined, which wt .-% octanal also contained 0.9, and still further 1, 4 wt .-% N, N ^{'dimethylethylenediamine.} This corresponds to the detergent B.

To investigate the fragrance effect of the detergent A and B washing experiments were conducted in a commercial washing machine (Miele washing machine type W 1734 WPS; washload: cotton textiles and Halbleinen in amount of 3.0 Kg; Hau ptwaschprog ramm at 4O ⁰ C.).

The washed laundry was then submitted to a panel of 7 people trained by the smell, who assessed the intensity of the laundry smell in the wet state as well as in the dry state (7 days after the laundry). To check the laundry smell after 7 days, the wet laundry was previously dried on a leash and, after drying, folded and stored in an open rack until 7 days had elapsed since the laundry.

The intensity was rated by each evaluator on a scale of 1 to 6, where the value 1 stands for a fragrance that is only slightly perceptible, while the value 6 stands for a very intense fragrance. The evaluation was repeated twice. From the total ratings, the average value was finally calculated. The following average values were obtained:

Fragrance intensity of the fragrance intensity of the wet laundry dry laundry after 7 days

Detergent A 5.3 1, 5 detergent B 4, 1 4.1

The laundry detergent B which was in accordance with the invention consequently resulted in a significantly improved fragrance intensity in the dry laundry after 7 days, compared with laundry detergent A.

Likewise, the fragrance effect of a commercial liquid softener was investigated, which contained 0.9 wt .-% octanal. This corresponds to the softener A. Also, the fragrance effect of an otherwise comparable commercial liquid softener was examined, which also contained 0.9 wt .-% octanal. This fabric softener also containing 1, 4 wt .-% N, N ^'- Dimethylethylendiannin. This corresponds to the fabric softener B.

To investigate the fragrance effect of the softener A and B washing experiments were (Miele washing machine type W 1734 WPS; washload:; Hau ptwaschprog ramm at 4O ⁰ C cotton textiles and Halbleinen in amount of 3.0 Kg) in a commercial washing machine performed.

The washed laundry was then in turn submitted to a panel of 7 people with an olfactory education, who assessed the intensity of the laundry odor in the wet state and in the dry state (7 days after washing), analogous to the investigation of the detergent, as already described.

The following average values were obtained:

Fragrance intensity of the fragrance intensity of the wet laundry dry laundry after 7 days

Fabric softener A 5,7 1, 7 detergent B 4,3 3,9

The softener B consistent with the invention consequently resulted in a significantly improved fragrance intensity in the dry laundry after 7 days compared to fabric softener A.

Claims

claims: 1. washing, cleaning or care products containing (a) fragrance aldehydes as well (b) (optionally substituted) ethylenediamines and / or (optionally substituted) propylenediamines. 2. Composition according to claim 1, characterized in that the component (a) and the component (b) are added separately in the washing, cleaning or care agent matrix. 3. The composition according to any one of claims 1 or 2, characterized in that as component (b) 1, 2-diaminoethane, propane-1, 3-diamine, 1, 2-dianilinoethane, N, N ^{'-dimethylethylenediamine,} N, N '- diethyl ethyl-1, 3-diamine, N, N'-Diisopropylethyl-1, 3-diamine, N, ^N' -Dimethylpropan-1, 3-diamine, N, N'-diethylpropane-1, 3-diamine and / or N, N'-diisopropylpropane-1,3-diamine is used. 4. Composition according to one of claims 1 to 3, characterized in that as component (a) a fragrance aldehyde is used, selected from Adoxal, Anisaldehyd, Cymal, Ethylvanillin, Florhydral, Helional, Heliotropin, Hydroxycitronellal, Koavon, Lauraldehyd, Lyral, Methylnonylacetaldehyd , PT Bucinal, phenylacetaldehyde, undecylenealdehyde, vanillin, 2,6,10-trimethyl-9-undecenal, 3-dodecene-1-al, alpha-n-amylcinnamaldehyde, 4-methoxybenzaldehyde, benzaldehyde, 3- (4-tert-butylphenyl ) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal, 3-phenyl-2 -propenal, cis- / trans-3,7-dimethyl-2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-dimethyl-6-octenyl) oxy] acetaldehyde, 4-isopropylbenzylaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1 carboxaldehyde, 2-methyl-3- (isopropylphenyl) propanal, 1-decanal, decyl aldehyde, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2, 6)] decylidene-8) -butanal , Oc tahydro-4,7-methane-1H-indenecarboxaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alphadimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxy benzaldehyde, alpha-n-hexylcinnamaldehyde, m-cymene-7-carboxaldehyde, alpha-methylphenylacetaldehyde, 7-hydroxy-3,7-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde , 4- (3) (4-Methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cylohexene 1-carboxaldehyde, 7-methoxy-3,7-dimethyloctan-1-al 2-methylundecanal, 2-methyldecanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl - 3- (4-tert-butyl) propanal, dihydrocinnamaldehyde, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6-methoxyhexahydro-4,7-methanindane 1- or 2-carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecene-1-al, A-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3-cyclohexencarboxalde hyd, 7-hydroxy-3,7-dimethyl-octanal, trans-4-decenal, 2,6-nonadienal, para-tolylacetaldehyde, A-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1 cyclohexen-1-yl) -2-butenal, ortho Methoxycinnamaldehyde, 3,5,6-trimethyl-3-cyclohexenecarboxaldehyde, 3,7-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6,10-dimethyl) 3-oxa-5,9-undecadiene-1-al), hexahydro-4,7-methanindane-1-carboxaldehyde, 2-methyl-octanal, alpha-methyl-4- (1-methylethyl) -benzylacetaldehyde, 6,6-dimethyl 2-norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propylbicyclo [2.2.1] hept-5-en-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl-1-pentanal, methylnonylacetaldehyde, hexanal, trans-2-hexenal, 1-p-menthene-q- carboxaldehyde or mixtures thereof. 5. Composition according to one of claims 1 to 4, characterized in that the component (b) in amounts of 0.001 wt .-% to 3 wt .-% is contained in the agent, based on the total agent. 6. Composition according to one of claims 1 to 5, characterized in that it contains 0.001 wt .-% to 3 wt .-% fragrance aldehydes, wt .-% based on the total agent. 7. Composition according to one of claims 1 to 6, characterized in that the ratio of component (a) to component (b) is 25: 1 to 1: 5. 8. Composition according to one of claims 1 to 7, characterized in that the total amount of fragrance of the agent is 0.01 to 10 wt .-%. 9. Composition according to one of claims 1-8, characterized in that it is in solid form, preferably in powder form. 10. Composition according to one of claims 1-8, characterized in that it is in liquid form, preferably in gel form. 11. Composition according to one of claims 1-10, characterized in that it contains at least 5 wt .-%, preferably at least 8 wt .-%, in particular at least 10 wt .-% surfactant, in particular anionic surfactant and / or nonionic surfactant. 12. textile cleaning or conditioning method in which the textile to be cleaned is subjected to a textile washing using a washing, cleaning or care agent according to any one of claims 1-11, in particular in an automatic washing machine. 13. Use of a washing, cleaning or care agent according to any one of claims 1-12 for cleaning and / or conditioning of textile fabrics, in particular in an automatic washing machine. 14. Use of (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine as a separately added component in perfume-containing washing, cleaning or care products containing fragrance aldehyde, to extend the fragrance effect of the washing, cleaning or care agent. 15. Use of (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine as a separately added component in perfume-containing detergents, cleaners or conditioners which contain fragrance aldehyde to obtain a long-lasting refreshing odor when using the washing, cleaning or care products.