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WO2010056463A3 - Procédé de valorisation énergétique des déchets utilisant une réaction biologique de conversion à la vapeur d'eau à l'aide de monoxyde de carbone produit par gazéification pour produire de l'hydrogène - Google Patents

Procédé de valorisation énergétique des déchets utilisant une réaction biologique de conversion à la vapeur d'eau à l'aide de monoxyde de carbone produit par gazéification pour produire de l'hydrogène Download PDF

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Publication number
WO2010056463A3
WO2010056463A3 PCT/US2009/060813 US2009060813W WO2010056463A3 WO 2010056463 A3 WO2010056463 A3 WO 2010056463A3 US 2009060813 W US2009060813 W US 2009060813W WO 2010056463 A3 WO2010056463 A3 WO 2010056463A3
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WIPO (PCT)
Prior art keywords
waste
carbon monoxide
gas
shift reaction
fermentation
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/060813
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English (en)
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WO2010056463A2 (fr
Inventor
Jens Wiik Jensen
Eric Dickman
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UNI-CONTROL LLC
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UNI-CONTROL LLC
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Publication of WO2010056463A3 publication Critical patent/WO2010056463A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P3/00Preparation of elements or inorganic compounds except carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/02Photobioreactors
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/18External loop; Means for reintroduction of fermented biomass or liquid percolate
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M33/00Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus
    • C12M33/10Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus by centrifugation ; Cyclones
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M33/00Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus
    • C12M33/14Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus with filters, sieves or membranes
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M39/00Means for cleaning the apparatus or avoiding unwanted deposits of microorganisms
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/06Photobioreactors combined with devices or plants for gas production different from a bioreactor of fermenter
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/08Bioreactors or fermenters combined with devices or plants for production of electricity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903Feed preparation
    • C10J2300/0909Drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1665Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1681Integration of gasification processes with another plant or parts within the plant with biological plants, e.g. involving bacteria, algae, fungi
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Sustainable Development (AREA)
  • Molecular Biology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

La présente invention concerne un procédé de valorisation énergétique des déchets consistant à : gazéifier une charge comprenant des déchets, pour obtenir un produit gazeux de gazéificateur contenant un gaz de synthèse et un produit non gazeux de gazéificateur; convertir par voie biologique le monoxyde de carbone contenu dans un gaz d'alimentation de fermentation pour obtenir un produit gazeux de fermentation contenant de l'hydrogène, au moins une partie du monoxyde de carbone étant obtenu à partir du produit gazeux du gazéificateur; et utiliser au moins une partie du produit gazeux de fermentation contenant de l'hydrogène en tant que combustible. La conversion biologique peut consister à introduire un gaz d'alimentation de fermentation dans un réacteur à puits profond, où ledit réacteur contient une suspension comprenant un milieu nutritif liquide déficient en source de carbone et des micro-organismes photoactivés capables d'effectuer la réaction de conversion à la vapeur d'eau; présente une profondeur verticale et une largeur de puits; comprend un tuyau de descente et une colonne de montée séparés par une cloison; et comprend un espace de tête au-dessus d'une conduite de remplissage de suspension à fonctionnement normal.
PCT/US2009/060813 2008-11-12 2009-10-15 Procédé de valorisation énergétique des déchets utilisant une réaction biologique de conversion à la vapeur d'eau à l'aide de monoxyde de carbone produit par gazéification pour produire de l'hydrogène Ceased WO2010056463A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11384808P 2008-11-12 2008-11-12
US61/113,848 2008-11-12

Publications (2)

Publication Number Publication Date
WO2010056463A2 WO2010056463A2 (fr) 2010-05-20
WO2010056463A3 true WO2010056463A3 (fr) 2010-07-15

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PCT/US2009/060813 Ceased WO2010056463A2 (fr) 2008-11-12 2009-10-15 Procédé de valorisation énergétique des déchets utilisant une réaction biologique de conversion à la vapeur d'eau à l'aide de monoxyde de carbone produit par gazéification pour produire de l'hydrogène

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102154034B (zh) * 2011-03-20 2013-08-14 中国烟草总公司郑州烟草研究院 烟草秸秆废弃物与煤共转化催化气化的方法
US8895274B2 (en) * 2011-11-28 2014-11-25 Coskata, Inc. Processes for the conversion of biomass to oxygenated organic compound, apparatus therefor and compositions produced thereby
FR3012446B1 (fr) * 2013-10-24 2017-05-26 Commissariat Energie Atomique Procede de production d'un produit organique a partir d'une charge de matiere carbonee mettant en oeuvre une gazeification suivie d'une fermentation du gaz de synthese.
CN104990306A (zh) * 2015-07-13 2015-10-21 中国能源建设集团广东省电力设计研究院有限公司 利用生物质发电的联供系统
CN105603002A (zh) * 2016-02-18 2016-05-25 武汉锦星科技有限公司 一种污泥与餐厨垃圾的放电等离子共处置方法
CN108751294B (zh) * 2018-09-07 2021-08-03 滨州学院 污水处理剂
CN109250883B (zh) * 2018-11-27 2021-09-14 内蒙古济世源环保生物科技有限公司 污泥处理方法
CN116216640A (zh) * 2022-12-09 2023-06-06 中国矿业大学 一种生物质-污泥等离子共转化制氢装置及方法
US12281344B2 (en) 2023-06-05 2025-04-22 Lanzatech, Inc. Integrated gas fermentation

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US6084139A (en) * 1997-12-05 2000-07-04 Gibros Pec B.V. Method for processing waste or biomass material
US20010020044A1 (en) * 1999-06-07 2001-09-06 Whitney John P. Process for recycling heterogeneous waste
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US20080182298A1 (en) * 2007-01-26 2008-07-31 Andrew Eric Day Method And System For The Transformation Of Molecules,To Transform Waste Into Useful Substances And Energy

Patent Citations (5)

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US6084139A (en) * 1997-12-05 2000-07-04 Gibros Pec B.V. Method for processing waste or biomass material
US20010020044A1 (en) * 1999-06-07 2001-09-06 Whitney John P. Process for recycling heterogeneous waste
US6410283B1 (en) * 2001-06-07 2002-06-25 Endesco Clean Harbors, L.L.C. Conversion of sewage sludge into electric power
US20080014126A1 (en) * 2006-07-11 2008-01-17 Linde Aktiengesellschaft Process and apparatus for generating hydrogen and hydrogen-containing gas mixtures
US20080182298A1 (en) * 2007-01-26 2008-07-31 Andrew Eric Day Method And System For The Transformation Of Molecules,To Transform Waste Into Useful Substances And Energy

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