WO2010055160A3 - Saure wässrige thiodiglykolethoxlat zusammensetzung und ihre verwendung in einem beizverfahren von metallischen oberflächen - Google Patents
Saure wässrige thiodiglykolethoxlat zusammensetzung und ihre verwendung in einem beizverfahren von metallischen oberflächen Download PDFInfo
- Publication number
- WO2010055160A3 WO2010055160A3 PCT/EP2009/065232 EP2009065232W WO2010055160A3 WO 2010055160 A3 WO2010055160 A3 WO 2010055160A3 EP 2009065232 W EP2009065232 W EP 2009065232W WO 2010055160 A3 WO2010055160 A3 WO 2010055160A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid aqueous
- metallic surfaces
- etching metallic
- thiodiglycol
- ethoxylate composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/04—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in markedly acid liquids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/173—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/065—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/081—Iron or steel solutions containing H2SO4
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/50—Treatment of iron or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/56—Treatment of aluminium or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Die vorliegende Erfindung betrifft eine saure, wässrige Zusammensetzung die ein Thiodiglykolalkoxylat enthält, zum Behandeln metallischer Oberflächen. Die Erfindung betrifft ferner die Verwendung einer oder mehrerer Verbindung(en) der allgemeinen Formel (I) als Korrosionsinhibitor.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/129,594 US8901060B2 (en) | 2008-11-17 | 2009-11-16 | Use of thioglycol ethoxylate as a corrosion inhibitor |
| EP09751935A EP2358924A2 (de) | 2008-11-17 | 2009-11-16 | Saure wässrige thiodiglykolethoxlat zusammensetzung und ihre verwendung in einem beizverfahren von metallischen oberflächen |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08169230.3 | 2008-11-17 | ||
| EP08169230 | 2008-11-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2010055160A2 WO2010055160A2 (de) | 2010-05-20 |
| WO2010055160A3 true WO2010055160A3 (de) | 2010-08-19 |
Family
ID=41796122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2009/065232 Ceased WO2010055160A2 (de) | 2008-11-17 | 2009-11-16 | Verwendung von thioglykolethoxylat als korrosionsinhibitor |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US8901060B2 (de) |
| EP (1) | EP2358924A2 (de) |
| WO (1) | WO2010055160A2 (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2939146B1 (fr) | 2008-11-28 | 2012-11-16 | Arkema France | Utilisation d'acide alcane sulfonique pour elimination de la rouille |
| EP2492372A1 (de) * | 2011-02-23 | 2012-08-29 | Enthone, Inc. | Wässrige Lösung und Verfahren zur Bildung einer Passivierungsschicht |
| PT2886683T (pt) | 2011-05-03 | 2020-03-26 | Atotech Deutschland Gmbh | Banho de galvanoplastia e método para produzir camadas de crómio escuro |
| US20140119984A1 (en) * | 2012-10-29 | 2014-05-01 | Halliburton Energy Services, Inc. | Withanolide corrosion inhibitor for carbon steel |
| US10633607B2 (en) | 2015-08-20 | 2020-04-28 | Dow Global Technologies Llc | Lubricant with sulfur-containing polyalkylene glycol |
| US11124884B2 (en) | 2016-04-29 | 2021-09-21 | Chemetall Gmbh | Composition for reducing the removal of material by pickling in the pickling of metal surfaces that contain galvanized and/or ungalvanized steel |
| RU2754070C2 (ru) * | 2016-04-29 | 2021-08-25 | Хеметалл Гмбх | Способ антикоррозионной обработки металлической поверхности с уменьшенным травлением материала |
| US10844312B2 (en) | 2016-06-24 | 2020-11-24 | Dow Global Technologies Llc | Lubricant composition |
| CN109312249B (zh) | 2016-06-24 | 2021-12-31 | 陶氏环球技术有限责任公司 | 润滑剂组合物 |
| FR3070694B1 (fr) | 2017-09-01 | 2020-07-03 | Arkema France | Inhibiteurs de corrosion metallique |
| JP2025500265A (ja) | 2021-12-17 | 2025-01-09 | シーシーアイ・ノース・アメリカ・コーポレーション | 燃料電池作動におけるフラックス曝露に適合性のある有機非イオン性抑制剤を用いた熱伝導系 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1780594A (en) * | 1929-10-09 | 1930-11-04 | Grasselli Chemical Co | Acid treatment of metal articles |
| US2858274A (en) * | 1954-03-16 | 1958-10-28 | Exxon Research Engineering Co | Thio formal synthetic lubricants |
| US3997614A (en) * | 1972-10-25 | 1976-12-14 | Reichhold Chemicals, Inc. | Polythiaformals |
| DE2856587A1 (de) * | 1978-02-02 | 1979-08-09 | Ciba Geigy Ag | Perfluoralkylthioaethylaetherderivate |
| US4832802A (en) * | 1988-06-10 | 1989-05-23 | Mcgean-Rohco, Inc. | Acid zinc-nickel plating baths and methods for electrodepositing bright and ductile zinc-nickel alloys and additive composition therefor |
| US5417841A (en) * | 1990-08-03 | 1995-05-23 | Mcgean-Rohco, Inc. | Copper plating of gravure rolls |
| JPH10130873A (ja) * | 1996-10-25 | 1998-05-19 | Nippon Shokubai Co Ltd | 金属腐食抑制剤およびそれを含む金属腐食抑制液並びにそれを用いた金属腐食抑制方法 |
| EP0878605A2 (de) * | 1997-05-13 | 1998-11-18 | Halliburton Energy Services, Inc. | Einsatz von korrosionsverhindernden organischen Säurezusammensetzungen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2518245A (en) * | 1946-08-24 | 1950-08-08 | Shell Dev | Process for preparing copolymers from alkylene glycols and di(hydroxyalkyl) sulfides |
| US3470146A (en) * | 1967-05-26 | 1969-09-30 | Sinclair Koppers Co | Suspension polymerization of vinyl aromatic monomers |
| GB2039299B (en) | 1978-12-26 | 1983-05-25 | Rohco Inc | Brightening and levelling agent for acid zinc plating baths |
| DE4021694A1 (de) * | 1990-07-07 | 1992-01-09 | Henkel Kgaa | Neue thiodiglykolalkxylat-derivate, verfahren zu ihrer herstellung und ihre verwendung als weichmacher fuer textilien |
| DE4204885A1 (de) * | 1992-02-19 | 1993-08-26 | Henkel Kgaa | Thiodiglykol-derivate, verfahren zu ihrer herstellung und deren verwendung zum weichmachen von textilien |
| JP2007507607A (ja) | 2003-09-30 | 2007-03-29 | ビーエーエスエフ アクチェンゲゼルシャフト | アルコキシレート化したアルカノールの使用により金属表面を酸洗いする方法 |
-
2009
- 2009-11-16 US US13/129,594 patent/US8901060B2/en not_active Expired - Fee Related
- 2009-11-16 EP EP09751935A patent/EP2358924A2/de not_active Withdrawn
- 2009-11-16 WO PCT/EP2009/065232 patent/WO2010055160A2/de not_active Ceased
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1780594A (en) * | 1929-10-09 | 1930-11-04 | Grasselli Chemical Co | Acid treatment of metal articles |
| US2858274A (en) * | 1954-03-16 | 1958-10-28 | Exxon Research Engineering Co | Thio formal synthetic lubricants |
| US3997614A (en) * | 1972-10-25 | 1976-12-14 | Reichhold Chemicals, Inc. | Polythiaformals |
| DE2856587A1 (de) * | 1978-02-02 | 1979-08-09 | Ciba Geigy Ag | Perfluoralkylthioaethylaetherderivate |
| US4832802A (en) * | 1988-06-10 | 1989-05-23 | Mcgean-Rohco, Inc. | Acid zinc-nickel plating baths and methods for electrodepositing bright and ductile zinc-nickel alloys and additive composition therefor |
| US5417841A (en) * | 1990-08-03 | 1995-05-23 | Mcgean-Rohco, Inc. | Copper plating of gravure rolls |
| JPH10130873A (ja) * | 1996-10-25 | 1998-05-19 | Nippon Shokubai Co Ltd | 金属腐食抑制剤およびそれを含む金属腐食抑制液並びにそれを用いた金属腐食抑制方法 |
| EP0878605A2 (de) * | 1997-05-13 | 1998-11-18 | Halliburton Energy Services, Inc. | Einsatz von korrosionsverhindernden organischen Säurezusammensetzungen |
Non-Patent Citations (4)
| Title |
|---|
| BASF SE: "Chemicals for the detergent and formulator industries", 1 June 2009 (2009-06-01), XP002587459, Retrieved from the Internet <URL:www.veredlungschemikalien.basf.de/ev.../FK_EVD_ES524_e.pdf> [retrieved on 20100616] * |
| BASF: "Lugalvan HS-1000", 1 December 2006 (2006-12-01), XP002587601, Retrieved from the Internet <URL:www.basf.co.kr/.../TI_Lugalvan%20HS1000_EVD1459e_Dec2006.pdf> [retrieved on 20100616] * |
| BASF: "Performance chemicals for metal surface treatment", 1 October 2005 (2005-10-01), XP002587600, Retrieved from the Internet <URL:http://www.performancechemicals.basf.com/ev-wcms-in/internet/en_GB/function/conversions:/publish/upload/EV/EV5/products/metal_surface_treatment_products/Chemicals_for_Metal_Surface_Treatment_EVD0111_e.pdf> [retrieved on 20100616] * |
| FRANK DIETSCHE ET AL: "Organic Corrosion Inibitors for interim corrosion protection", NACE ; INTERNATIONAL CORROSION CONFERENCE SERIES (CORROSION 2007 - 20070311 TO 20070315 - NASHVILLE, TN),, no. 7358, 11 March 2007 (2007-03-11), pages 1 - 12, XP009134939 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110232679A1 (en) | 2011-09-29 |
| EP2358924A2 (de) | 2011-08-24 |
| US8901060B2 (en) | 2014-12-02 |
| WO2010055160A2 (de) | 2010-05-20 |
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