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WO2009122845A1 - Composition cosmétique capillaire - Google Patents

Composition cosmétique capillaire Download PDF

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Publication number
WO2009122845A1
WO2009122845A1 PCT/JP2009/054014 JP2009054014W WO2009122845A1 WO 2009122845 A1 WO2009122845 A1 WO 2009122845A1 JP 2009054014 W JP2009054014 W JP 2009054014W WO 2009122845 A1 WO2009122845 A1 WO 2009122845A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
polymer
hydrogen atom
hair cosmetic
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2009/054014
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English (en)
Japanese (ja)
Inventor
律子 宮川
恭生 永原
明宏 寺口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to KR1020107023906A priority Critical patent/KR101659634B1/ko
Priority to CN2009801211685A priority patent/CN102046145B/zh
Priority to HK11108419.3A priority patent/HK1153952B/xx
Publication of WO2009122845A1 publication Critical patent/WO2009122845A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair cosmetic that imparts volume and gloss to the top of the head.
  • JP 2000-204024 A JP-A-10-95714 JP 2006-199648 A JP 2007-137830 A JP 2007-161986
  • the present invention has been made in view of the above circumstances, and an object of the present invention is to provide a hair cosmetic material that imparts a sense of volume to the top of the head and gloss to the hair.
  • the present inventors have used a specific (A) acrylic acid polymer and (B) nonionic polymer in combination, and a mass ratio represented by (A) / (B)
  • a specific (A) acrylic acid polymer and (B) nonionic polymer in combination, and a mass ratio represented by (A) / (B)
  • the ratio to 0.1 to 10
  • the (A) component and the (B) component interact with each other to form a soft and glossy film on the hair, giving a firmness and elasticity that is not stiff.
  • the volume at the top of the head can be increased and gloss can be imparted to the hair.
  • blending the cationic surfactant of component (C) with this hair cosmetic can give smoothness to the hair, and the present invention has been made.
  • a hair cosmetic comprising the following (A) acrylic acid polymer and (B) nonionic polymer, wherein the mass ratio represented by (A) / (B) is 0.1 to 10.0 .
  • (A) As a constituent unit 70 to 95 mol% of a monomer unit represented by the following general formula (1) and 5 to 30 mol% of a monomer unit represented by the following general formula (2) are included.
  • Acrylic acid polymer (Wherein R 1 represents a hydrogen atom or a methyl group, R 2 represents a hydrogen atom or a —CH 2 OH group, and A represents an oxygen atom or —NH—).
  • R 3 represents a hydrogen atom or a methyl group
  • M represents a hydrogen atom, an alkali metal atom, ammonium or an amine.
  • the subject of said [3] is providing the hair cosmetics which improve the smoothness to hair.
  • a hair cosmetic that imparts a sense of volume at the top of the head and improves the smoothness and gloss of the hair.
  • the hair cosmetics which give smoothness to hair can be provided by mix
  • R 1 represents a hydrogen atom or a methyl group
  • R 2 represents a hydrogen atom or a —CH 2 OH group
  • A represents an oxygen atom or —NH—
  • R 3 represents a hydrogen atom or a methyl group
  • M represents a hydrogen atom, an alkali metal atom, ammonium or an amine.
  • alkali metal atom examples include sodium atom, potassium atom, and amine include monoethanolamine, diethanolamine, triethanolamine and the like.
  • M is an alkali metal atom, ammonium or amine, -COOM forms a salt. To do.
  • R 1 is a hydrogen atom
  • R 2 is a hydrogen atom
  • A is —NH—
  • R 3 is preferably a hydrogen atom
  • M is preferably a hydrogen atom or a sodium atom.
  • the ratio of the monomer unit represented by the general formula (1) is 70 to 95 mol% in the acrylic acid polymer (100 mol% of all monomer units), preferably 75 to 90 mol%.
  • the proportion of the monomer unit represented by the formula (2) is 5 to 30 mol% in the acrylic acid polymer (in 100 mol% of all monomer units), and preferably 10 to 25 mol%.
  • the acrylic acid-based polymer can contain a monomer unit other than the monomer unit represented by the general formula (1) or (2) as long as the effects of the present invention are not impaired.
  • Examples of other monomer units include nonionic monomers, amphoteric monomers, semipolar monomers, and cationic monomers other than the monomer units represented by the general formula (1) or (2).
  • monomer units corresponding to monomers and polysiloxane group-containing monomers are preferably 0 to 25 mol% in the acrylic acid polymer.
  • the acrylic acid polymer of the present invention may be a random copolymer or a block copolymer, and the acrylic acid polymer of the present invention comprises monomer units represented by the general formulas (1) and (2).
  • An acrylic acid polymer composed of a copolymer as a unit is preferred.
  • nonionic monomers include esters of alcohols having 1 to 22 carbon atoms and (meth) acrylic acid, amides of alkylamines having 1 to 22 carbon atoms and (meth) acrylic acid, ethylene glycol, 1 1,3-propylene glycol and the like (meth) acrylic acid monoesters, esters obtained by etherifying the hydroxyl groups of these monoesters with methanol, ethanol, etc., (meth) acryloylmorpholine, etc.
  • Examples of the body include betaine group-containing (meth) acrylic esters, betaine group-containing (meth) acrylamides, etc.
  • examples of semipolar monomers include amine oxide group-containing (meth) acrylic esters and amine oxide groups (Meth) acrylamide and the like.
  • examples of the cationic monomer include a quaternary amine. Sulfonium group-containing (meth) acrylic esters, quaternary ammonium group-containing (meth) acrylamide and the like.
  • the polysiloxane group-containing monomer is a compound having a polysiloxane structure and a structure capable of being covalently linked to an acrylic acid polymer.
  • a structural unit has a high affinity with the silicone oil usually used together in the cosmetic composition, and serves to bind the silicone oil with other structural units in the acrylic acid-based polymer. In particular, it is considered that there is a function to increase the adsorption power of silicone oil to damaged hair and the like.
  • the ratio of each monomer unit in the acrylic acid polymer is the carbonyl group, amide bond, IR absorption of polysiloxane structure and various functional groups, and the methyl group or amide bond site of polydimethylsiloxane and adjacent to them. It can be measured by 1 H-NMR of a methyl group, methylene group or the like, or 13 C-NMR thereof.
  • the weight average molecular weight of the acrylic acid polymer is usually 3,000 to 100,000. If it is less than 3,000, the volume at the top of the head may be inferior, and if it exceeds 100,000, the hair and skin may be irritated.
  • the weight average molecular weight is preferably 10,000 to 30,000, more preferably 10,000 to 20,000, and further preferably 12,000 to 17,000 from the viewpoint of further increasing the volume feeling and gloss at the top of the head. preferable.
  • the molecular weight of the acrylic acid polymer can be adjusted, for example, by controlling the degree of polymerization of the polymer.
  • the molecular weight and viscosity can also be controlled by increasing or decreasing the addition amount of a crosslinking agent such as a polyfunctional acrylate.
  • a crosslinking agent such as a polyfunctional acrylate.
  • the acrylic acid-based polymer can be obtained in accordance with the method described in JP-A-2007-137830. For example, it can be obtained by mixing monomers that give respective structural units or precursors thereof and copolymerizing them by a method such as solution polymerization, suspension polymerization, emulsion polymerization or the like.
  • the counter ion in the general formula (2) can be subjected to polymerization by substituting a part or all of it for other than hydrogen ion by a neutralization reaction before polymerization, and neutralized after polymerization or other reaction. A part or all of the reaction can be replaced with other than hydrogen ions. These can be appropriately selected depending on the ease of synthesis.
  • the polymerization reaction is preferably performed in a hydrophilic solvent such as ethanol.
  • a known polymerization initiator such as dimethyl 2,2'-azobis (2-methylpropionate) can be used.
  • each monomer is mix
  • the proportion of the structural unit composed of each monomer in the copolymer of the present invention is the same as the blending amount of each monomer at the time of copolymerization.
  • the polymerization reaction is preferably performed in a hydrophilic solvent.
  • hydrophilic solvents include ketone solvents such as acetone, methyl ethyl ketone, and methyl isobutyl ketone, alcohol solvents such as methanol, ethanol, n-propanol, i-propanol, n-butanol, i-butanol, and sec-butanol, water, and the like Is mentioned. These may be used alone or in combination of two or more. Among these, it is preferable to use an alcohol solvent.
  • peroxides such as benzoyl
  • the polymerization reaction can be performed, for example, in an inert gas atmosphere such as nitrogen or argon, preferably at 30 to 120 ° C., more preferably at 40 to 100 ° C., usually for 1 to 30 hours.
  • the produced copolymer may be isolated from the reaction solution by an appropriate means such as solvent distillation or addition of a poor solvent.
  • This copolymer can be used as it is or after further purification, for example, in the production of cosmetics. Purification can be carried out by combining appropriate means such as reprecipitation, solvent washing, membrane separation and the like as necessary.
  • the blending amount of the acrylic acid polymer is preferably 0.05 to 2.0% by mass, more preferably 0.1 to 1.0% by mass in the hair cosmetic. If the blending amount is less than 0.05% by mass, the effect of the present invention may be insufficient. If it exceeds 2.0% by mass, stickiness may occur and the volume may decrease.
  • Nonionic polymers include homopolymers obtained by homopolymerization of the following nonionic monomers, copolymers (copolymers) obtained by copolymerizing a plurality of types, water-soluble polysaccharides (cellulose-based, gum-based). And non-ionic polymers such as starch-based polymers, and the like, can be used singly or in appropriate combination of two or more.
  • Nonionic monomers include vinyl pyrrolidone, vinyl acetate, (meth) acrylic acid and alcohols having 1 to 22 carbon atoms, polyhydric alcohols, or hydroxy group-containing alkyl groups, (meth) acrylamides and amines thereof. Amide, dialkyl (1 to 22 carbon atoms) aminoethyl (meth) acrylate, vinylimidazole, vinylcaprolactam, polyalkylene (carbon number) in which the hydrogen atom is substituted with an alkyl group having 1 to 22 carbon atoms or a hydroxy group-containing alkyl. 2-3) glycol and the like.
  • (meth) acrylic acid refers to acrylic acid and / or methacrylic acid.
  • the nonionic polymer a vinylpyrrolidone polymer and a cellulose polymer are preferable.
  • the vinyl pyrrolidone-based polymer refers to polyvinyl pyrrolidone which is a homopolymer of vinyl pyrrolidone, or a copolymer (copolymer) of vinyl pyrrolidone and another nonionic monomer.
  • polyvinylpyrrolidone those having a K value of 10 to 100 are preferable. Specific examples thereof include Rubiscol K17, 30, 90 / BASF, polyvinylpyrrolidone K-30, 85, 90, 30W, 85W / manufactured by Nippon Shokubai. It is done. If the K value is less than 10, the effect may be insufficient, and if it exceeds 100, the handling property may be deteriorated.
  • the K value is a viscosity characteristic value that correlates with the molecular weight, and is calculated by applying a relative viscosity value (25 ° C.) measured by a capillary viscometer to the following Fikentscher equation.
  • K (1.5log ⁇ rel ⁇ 1) / (0.15 + 0.003c) + (300 clog ⁇ rel + (c + 1.5 clog ⁇ rel ) 2 ) 1/2 /(0.15c+0.003c 2 )
  • ⁇ rel relative viscosity of polyvinyl pyrrolidone aqueous solution with respect to water
  • c concentration of polyvinyl pyrrolidone in aqueous polyvinyl pyrrolidone solution
  • vinyl pyrrolidone / vinyl acetate copolymer As a copolymer (copolymer) of vinyl pyrrolidone and other nonionic monomer, vinyl pyrrolidone / vinyl acetate copolymer (specifically, PVP / VA W-735, S-630, E-535 / ISP, Rubiscol VA55I, VA73E / BASF), vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (copolymers 845, 937, 958 / ISP), N-vinylpyrrolidone / methacrylamide / N-vinylimidazole copolymer (Rubiset Clear BASF) and the like, and particularly preferred among these is a vinylpyrrolidone / vinyl acetate copolymer, and the molar ratio represented by vinylpyrrolidone VP (mol) / vinyl acetate VA (mol) is VP (mol) / VA (mol
  • This ratio is within the range where the copolymer is completely water-soluble (1 g of this product is added to 1000 mL of water and completely dissolved when left for 30 minutes after infiltration (measurement temperature 25 ° C.). According to the above). Further, 60/40 to 80/20 is preferable from the viewpoint of the effect of giving firmness and firmness. Specific examples that fall within this range include PVP / VA W-735, manufactured by S-630 / ISP, manufactured by Rubiscor VA73E / BASF, and the like.
  • the molar ratio of vinylpyrrolidone (VP) and vinyl acetate (VA) can be determined, for example, by dissolving the copolymer in deuterium and measuring 1 H-NMR.
  • cellulose polymer examples include hydroxyethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose and the like.
  • a 1% by weight aqueous solution is obtained.
  • Those of ⁇ 6,000 mPa ⁇ s are preferred.
  • hydroxyethylcellulose Suditomo Seika HEC SY-25F, SW-25F, SZ-25Y / manufactured by Sumitomo Seika
  • hydroxypropyl methylcellulose (Metroise 60SH-4000, 65SH-15000, 90SH-30000 / Shin-Etsu Chemical Co., Ltd.), hydroxyethyl methylcellulose (Metroses SEB-15000, SNB-30000 / Shin-Etsu Chemical Co., Ltd.), etc. It is done. If the viscosity of the 2% by weight aqueous solution is less than 1,000 mPa ⁇ s or the viscosity of the 1% by weight aqueous solution is less than 100 mPa ⁇ s, the effect of the present invention may be insufficient, and the viscosity of the 2% by weight aqueous solution may be 50,000 mPa ⁇ s.
  • the said viscosity is BM type
  • the weight average molecular weight of the nonionic polymer is not particularly limited, but is preferably 10,000 to 1,000,000, more preferably 10,000 to 500,000.
  • the weight average molecular weight can be determined by a light scattering method.
  • the compounding amount of the nonionic polymer is preferably 0.05 to 2.0% by mass, more preferably 0.1 to 1.0% by mass in the hair cosmetic. If the blending amount is less than 0.05% by mass, the effect of increasing the volume may be insufficient.
  • the mass ratio of the component (A) and the component (B) represented by (A) / (B) is 0.1 to 10.0, preferably 0.5 to 7.0, 0.8 to 4.0 is more preferable.
  • the mass ratio of the component (A) and the component (B) is 0.1 to 10.0, it is possible to impart a volume feeling at the top of the head and a gloss of the hair. If it is less than 0.1, the effect is insufficient, and if it exceeds 10.0, the volume feeling and gloss may be deteriorated.
  • Cationic surfactants include aliphatic amines and their quaternary ammonium salts, fatty acid amide amine salts, alkyltrialkylene glycol ammonium salts, acylguanidine derivatives, mono-N-long chain acyl basics.
  • Amino acid-based cationic surfactants such as amino acid lower alkyl ester salts, alkylbenzalkonium salts, alkylpyridinium salts, imidazolinium salts and the like can be mentioned, and these can be used singly or in appropriate combination of two or more. .
  • quaternary ammonium salts of aliphatic amines are preferable, and quaternary ammonium salts having 18 to 22 carbon atoms are more preferable.
  • Specific examples include behenyltrimethylammonium chloride and stearyltrimethylammonium chloride.
  • the blending amount of the component (C) is preferably 0.1 to 5.0% by mass in the hair cosmetic, and more preferably 0.2 to 2.0% by mass in terms of improving the smoothness of the hair. If the blending amount is less than 0.1% by mass, the conditioning effect may be insufficient, and if it exceeds 5.0% by mass, the stability of the preparation may be adversely affected.
  • the hair cosmetic composition of the present invention can be blended with various additive components commonly used in general hair cosmetic compositions as long as the effects of the present invention are not impaired. These can be used individually by 1 type or in combination of 2 or more types.
  • the additive component include silicones such as dimethylpolysiloxane and amino-modified silicone, anionic surfactants such as alkyl sulfate ester salts and sodium polyoxyethylene alkyl ether sulfate, coconut oil fatty acid amidopropyl betaine, lauryldimethylaminoacetic acid Amphoteric surfactants such as betaine, hydrogenated soybean phospholipid, alkyldiaminoethylglycine hydrochloride, sodium laurylaminopropionate, sucrose fatty acid ester, sorbitan fatty acid ester, sorbitol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxy Nonionic surfactants such as ethylene hydrogenated
  • Polyhydric alcohol, hydrocarbons, ester oils, higher alcohols such as stearyl alcohol, herbal medicines, various protein hydrolysates, vitamins, bactericides, ultraviolet absorbers, antioxidants, colorants, pH buffering agents, fragrances, A solvent (water, ethanol, etc.), fine particle powder, etc. are mentioned.
  • These additive components can be used singly or in appropriate combination of two or more, and can be blended at an appropriate stage when preparing a hair cosmetic.
  • the pH of the hair cosmetic composition of the present invention is preferably 3-6. This pH is close to the pH of the hair and is difficult to damage the hair.
  • the pH adjuster include inorganic acid salts such as sodium pyrophosphate, and organic acids such as glycolic acid and citric acid.
  • pH is measured with a HM-30G pH meter manufactured by Toa DKK Corporation at a measurement temperature of 25 ° C.
  • the viscosity (25 ° C.) of the hair cosmetic composition of the present invention is preferably 1,000 to 20,000 mPa ⁇ s, more preferably 3,000 to 10,000 mPa ⁇ s. By setting it as this range, it is difficult to use and easy to extend. In the present invention, the viscosity is measured (25 ° C.) using a BM type viscometer manufactured by TOKIMEC. 4 rotors, 30 rpm, 20 seconds later.
  • the hair cosmetic composition of the present invention can be widely used in many dosage forms such as liquid, cream, foam, spray, gel, etc., and is a conditioner, treatment, hair color, non-washing type treatment, hair serum. Suitable for hair packs and the like.
  • the hair cosmetic composition of the present invention can be prepared based on a conventional method of dosage form, and can be appropriately filled in a container.
  • Preparation Example 4 A-4 Polymer A-4 was obtained in the same manner as in Preparation Example 1 except that the blending amount was adjusted so as to be the structural unit shown in Table 1 below.
  • Preparation Example 5 A-5 Polymer A-5 was obtained in the same manner as in Preparation Example 1 except that the blending amount was adjusted so as to be the structural unit shown in Table 1 below.
  • Preparation Example 6 A'-6 Polymer A′-6 was obtained in the same manner as in Preparation Example 1 except that the blending amount was adjusted so as to be the structural unit shown in Table 1 below.
  • Table 1 shows the functional groups of the general formula (1) or (2) of the polymers A-1 to A′-6, the ratio (molar ratio) of the monomer units of the general formula (1) or (2), and the weight average molecular weight. Show.
  • Non-washing type hair conditioners having the compositions shown in Tables 3 to 6 were prepared by the following method. The following evaluation was performed about the obtained hair conditioner. The results are also shown in the table.
  • Examples 22 to 43, Comparative Examples 6 to 10 Wash-out type hair conditioners having the compositions shown in Tables 7 to 10 were prepared by the following method. The following evaluation was performed about the obtained hair conditioner. The results are also shown in the table.
  • the raw materials used in preparing the examples and comparative examples are shown below.
  • the fragrance compositions A, B, and C used in the above examples conform to the fragrance compositions A to C described in JP-A-2003-95895.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique capillaire caractérisée en ce qu'elle contient (A) un polymère acrylique décrit ci-dessous et (B) un polymère non ionique. Ladite composition cosmétique capillaire se caractérise également en ce que le rapport de masse (A)/(B) se situe dans la plage allant de 0,1 à 10,0. (A) Ledit polymère acrylique contient, en tant qu'unités constitutionnelles, 70 à 95 % par mole d'une unité monomère représentée par la formule générale (1) et 5 à 30 % par mole d'une unité monomère représentée par la formule générale (2) (Dans ces formules, R1 représente un atome d'hydrogène ou un groupe méthyle ; R2 représente un atome d'hydrogène ou un groupe -CH2OH ; A représente un atome d'oxygène ou un groupe -NH- ; R3 représente un atome d'hydrogène ou un groupe méthyle ; et M représente un atome d'hydrogène, un atome de métal alcalin, un ammonium ou une amine.)
PCT/JP2009/054014 2008-04-04 2009-03-04 Composition cosmétique capillaire Ceased WO2009122845A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020107023906A KR101659634B1 (ko) 2008-04-04 2009-03-04 모발 화장료
CN2009801211685A CN102046145B (zh) 2008-04-04 2009-03-04 毛发类化妆品
HK11108419.3A HK1153952B (en) 2008-04-04 2009-03-04 Hair cosmetic composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008-098229 2008-04-04
JP2008098229A JP5804665B2 (ja) 2008-04-04 2008-04-04 毛髪化粧料

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WO2009122845A1 true WO2009122845A1 (fr) 2009-10-08

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KR (1) KR101659634B1 (fr)
CN (1) CN102046145B (fr)
MY (1) MY159866A (fr)
WO (1) WO2009122845A1 (fr)

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JP5509533B2 (ja) * 2008-04-04 2014-06-04 ライオン株式会社 毛髪洗浄剤及び洗浄剤製品
JP5575453B2 (ja) * 2009-10-28 2014-08-20 株式会社ミルボン 毛髪処理剤
WO2011125713A1 (fr) * 2010-04-06 2011-10-13 ライオン株式会社 Produit cosmétique capillaire
KR101947360B1 (ko) * 2010-10-05 2019-02-12 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 아크릴레이트 공중합체 증점제
JP2012102065A (ja) * 2010-11-12 2012-05-31 Kao Corp 毛髪化粧料の使用方法、その毛髪化粧料
JP2012102064A (ja) * 2010-11-12 2012-05-31 Kao Corp 毛髪化粧料、及び、その使用方法
EP2659880B1 (fr) * 2010-12-28 2019-11-06 Kao Corporation Produit cosmétique pour les cheveux
BR112020009895A2 (pt) 2017-11-20 2020-10-13 Kao Corporation cosméticos para o cabelo
CN112999137B (zh) * 2021-03-11 2022-09-16 福州东艺善秀商业有限公司 一种含有矿物温泉水的保湿舒缓修复膏霜及其制备方法

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KR20100133452A (ko) 2010-12-21
JP5804665B2 (ja) 2015-11-04
HK1153952A1 (en) 2012-04-20
CN102046145A (zh) 2011-05-04
KR101659634B1 (ko) 2016-09-26
CN102046145B (zh) 2013-03-27
JP2009249329A (ja) 2009-10-29

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