[go: up one dir, main page]

WO2009106474A3 - Catalyseur à phase enrichie à base de mélange d'oxydes de mo-v-te-nb, et procédé d'élaboration - Google Patents

Catalyseur à phase enrichie à base de mélange d'oxydes de mo-v-te-nb, et procédé d'élaboration Download PDF

Info

Publication number
WO2009106474A3
WO2009106474A3 PCT/EP2009/051961 EP2009051961W WO2009106474A3 WO 2009106474 A3 WO2009106474 A3 WO 2009106474A3 EP 2009051961 W EP2009051961 W EP 2009051961W WO 2009106474 A3 WO2009106474 A3 WO 2009106474A3
Authority
WO
WIPO (PCT)
Prior art keywords
phase
catalyst material
tellurium
niobium
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2009/051961
Other languages
English (en)
Other versions
WO2009106474A2 (fr
Inventor
Olaf Timpe
Ayyamperumal Sakthivel
Annette Trunschke
Robert SCHLÖGL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE112009000404T priority Critical patent/DE112009000404T5/de
Publication of WO2009106474A2 publication Critical patent/WO2009106474A2/fr
Publication of WO2009106474A3 publication Critical patent/WO2009106474A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/084—Decomposition of carbon-containing compounds into carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un procédé d'élaboration d'un matériau catalyseur à base d'oxydes de métaux comprenant des oxydes de molybdène (Mo), de vanadium (V), de tellure (Te) et de niobium (Nb). Ce procédé consiste d'abord (i) à prendre un mélange précurseur du catalyseur comprenant du molybdène (Mo), du vanadium (V), du tellure (Te) et du niobium (Nb), et à le calciner sous atmosphère oxygénée à une température de 150 à 400°C de façon à obtenir un matériau catalyseur calciné. Le procédé consiste ensuite (ii) à prendre ce matériau catalyseur calciné et à le soumettre à un traitement à une pression d'au moins 10 MPa à une température d'au moins 400°C en présence d'une phase fluide inerte de façon élaborer un matériau catalyseur comprenant des oxydes de molybdène (Mo), de vanadium (V), de tellure (Te) et de niobium (Nb). Ce procédé donne des matériaux catalyseurs présentant des teneurs très élevées de phase cristallographique MI, offrant une excellente conversion en propane, ainsi que, lors de la conversion du propane, des taux et des coefficients de sélectivité élevés pour l'acide acrylique.
PCT/EP2009/051961 2008-02-25 2009-02-19 Catalyseur à phase enrichie à base de mélange d'oxydes de mo-v-te-nb, et procédé d'élaboration Ceased WO2009106474A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE112009000404T DE112009000404T5 (de) 2008-02-25 2009-02-19 Phasen-angereicherter MoVTeNb-Mischoxidkatalysator und Verfahren zu seiner Herstellung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3124708P 2008-02-25 2008-02-25
US61/031,247 2008-02-25

Publications (2)

Publication Number Publication Date
WO2009106474A2 WO2009106474A2 (fr) 2009-09-03
WO2009106474A3 true WO2009106474A3 (fr) 2010-05-06

Family

ID=40912122

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/051961 Ceased WO2009106474A2 (fr) 2008-02-25 2009-02-19 Catalyseur à phase enrichie à base de mélange d'oxydes de mo-v-te-nb, et procédé d'élaboration

Country Status (2)

Country Link
DE (1) DE112009000404T5 (fr)
WO (1) WO2009106474A2 (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079169B2 (en) 2010-05-12 2015-07-14 Shell Oil Company Methane aromatization catalyst, method of making and method of using the catalyst
CN103459014A (zh) * 2011-03-25 2013-12-18 罗门哈斯公司 混合金属氧化物催化剂的蒸汽再煅烧
US9486788B2 (en) 2012-09-28 2016-11-08 Rohm And Haas Company Preparation of propane oxidation catalysts
BR112015006658A2 (pt) * 2012-09-28 2017-07-04 Rohm & Haas processo para preparar um catalisador de oxidação de propano
CN103285890A (zh) * 2013-05-26 2013-09-11 浙江大学 一种Cr掺杂的催化氧化丙烷制备丙烯酸催化剂及其制备方法
EP3041605A1 (fr) * 2013-08-27 2016-07-13 Linde Aktiengesellschaft Procédé de fabrication d'un catalyseur, catalyseur ainsi que procédé de déshydrogénation oxydative d'hydrocarbures
DE102013014241A1 (de) 2013-08-27 2015-03-05 Linde Aktiengesellschaft Verfahren zur Herstellung eines Katalysators, Katalysator sowie Verfahren für die oxidative Dehydrierung von Kohlenwasserstoffen
EP3246092A1 (fr) * 2016-05-19 2017-11-22 Shell Internationale Research Maatschappij B.V. Traitement d'un catalyseur d'oxyde metallique mixte contenant du molybdene, du vanadium, du niobium et eventuellement du tellure
EP3246090A1 (fr) * 2016-05-19 2017-11-22 Shell Internationale Research Maatschappij B.V. Traitement d'un catalyseur d'oxyde metallique mixte contenant du molybdene, du vanadium, du niobium et eventuellement du tellure
CA2936448C (fr) * 2016-07-19 2024-02-20 Nova Chemicals Corporation Traitement hydrothermal a pression controlee de catalyseur odh
CA2945435C (fr) * 2016-10-18 2025-09-02 Nova Chemicals Corp Traitement de catalyseur oxydant deshydrogenant au peroxyde et a liberation de gaz basse pression hydrothermique
DE102017000861A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVTeNb-Katalysators aus preisgünstigen Metalloxiden
DE102017000848A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung molybdänhaltiger Mischoxidmaterialien
DE102017000865A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit erhöhter spezifischer Oberfläche und höherer Aktivität für die oxidative Dehyxdrierung von Ethan zu Ethylen
DE102017000862A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit reduziertem Gehalt an Niob und Tellur und höherer Aktivität für die oxidative Dehydrierung von Ethan
DE102017121709A1 (de) 2017-09-19 2019-03-21 Clariant International Ltd Synthese eines MoVNbTe-Schalenkatalysators für die oxidative Dehydrierung von Ethan zu Ehtylen
CA2993683A1 (fr) 2018-02-02 2019-08-02 Nova Chemicals Corporation Methode destinee a un catalyseur odh a forte active in situ
US11583845B2 (en) * 2018-07-17 2023-02-21 University Of Science And Technology Of China Method for preparing pure M1 phase MoVTeNb-oxide catalyst with high specific surface area
CA3050720A1 (fr) 2018-08-03 2020-02-03 Nova Chemicals Corporation Compositions de catalyseurs de deshydrogenation oxydatifs
CN113492017A (zh) * 2020-04-08 2021-10-12 中国石油天然气股份有限公司 一种负载型丙烷催化氧化制丙烯酸催化剂及其制备方法与应用
CN116510742B (zh) * 2023-04-06 2024-08-23 济南大学 一种钼钒氧簇修饰的碳基锰酸铁复合催化剂的制备方法及其应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008068332A1 (fr) * 2006-12-08 2008-06-12 Schloegl Robert Nouveau catalyseur métal/oxyde mésoporeux mixte et son procédé de préparation

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69318684T2 (de) 1992-12-24 1999-01-14 Mitsubishi Chemical Corp., Tokio/Tokyo Herstellungsverfahren eines Katalysators zur Herstellung von Nitrilen
EP0608838B1 (fr) 1993-01-28 1997-04-16 Mitsubishi Chemical Corporation Procédé pour la préparation d'un acide carboxylique insaturé
EP1025073B1 (fr) 1997-10-21 2002-02-13 Basf Aktiengesellschaft Procede d'oxydation en phase gazeuse catalysee heterogene du propane en acroleine et/ou en acide acrylique
US6060419A (en) 1998-01-05 2000-05-09 Sunoco, Inc. (R&M) Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts
DE19837517A1 (de) 1998-08-19 2000-02-24 Basf Ag Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan
US6432870B1 (en) 1999-05-25 2002-08-13 Toagosei Co., Ltd. Process for preparing metal oxide catalyst for acrylic acid production
US6734136B2 (en) 2000-09-28 2004-05-11 Rohm And Haas Company IR and/or SM promoted multi-metal oxide catalyst
KR100814702B1 (ko) 2000-09-28 2008-03-18 롬 앤드 하스 캄파니 불포화 니트릴 제조방법
DE60137644D1 (de) 2000-12-22 2009-03-26 Nippon Kayaku Kk Verfahren zur herstellung sauerstoffhaltiger ungesättigter verbindungen
US6610639B1 (en) 2002-05-13 2003-08-26 Colgate-Palmolive Company High foaming, grease cutting light duty liquid composition containing zinc chloride
US20070203022A1 (en) 2004-07-22 2007-08-30 Fritz Haber Institut Der Max Planck Gesellschaft Metal Oxide Catalyst And Method For The Preparation Thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008068332A1 (fr) * 2006-12-08 2008-06-12 Schloegl Robert Nouveau catalyseur métal/oxyde mésoporeux mixte et son procédé de préparation

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
FLOREA M ET AL: "High surface area Mo-V-Te-Nb-O catalysts: Preparation, characterization and catalytic behaviour in ammoxidation of propane", CATALYSIS TODAY, ELSEVIER, vol. 112, no. 1-4, 15 March 2006 (2006-03-15), pages 139 - 142, XP025116707, ISSN: 0920-5861, [retrieved on 20060315] *
SALIL BHATT: "Synthesis, characterization and kinetic studies of mixed metal Mo-V-Nb-Te oxide catalysts for propane ammoxidation to acrolynitrile", 21 February 2006, UNIVERSITY OF CINCINNATI, XP002540906 *

Also Published As

Publication number Publication date
WO2009106474A2 (fr) 2009-09-03
DE112009000404T5 (de) 2010-12-30

Similar Documents

Publication Publication Date Title
WO2009106474A3 (fr) Catalyseur à phase enrichie à base de mélange d'oxydes de mo-v-te-nb, et procédé d'élaboration
KR100932373B1 (ko) ｐＨ 변화에 따른 다성분계 비스무스 몰리브데이트 촉매제조방법 및 상기촉매를 이용하여 1,3-부타디엔을 제조하는방법
EP1262235A3 (fr) Catalyseur d'oxydes mixtes contenant du molybdène et du vanadium et son procédé de préparation
EP0962253A3 (fr) Procédé de préparation d'un catalyseur d'oxydes multimétalliques
KR20190121391A (ko) 메탄 산화 커플링 촉매제 및 그 제조 방법과 적용
MY159015A (en) Oxide catalyst, process for production of oxide catalyst, process for production of unsaturated acid, and process for production of unsaturated nitrile
WO2010022830A3 (fr) Catalyseur destiné à l'oxydation en phase gazeuse d'hydrocarbures aromatiques les transformant en aldéhydes, acides carboxyliques et/ou anhydrides d'acides carboxyliques, notamment en anhydride d'acide phtalique, et procédé de production d'un catalyseur de ce type
WO2011146426A3 (fr) Procédé de préparation d'un catalyseur d'époxydation
AU2013255828A1 (en) Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation
RU2015109709A (ru) Оксидный катализатор и способ его получения, а также способы получения ненасыщенного альдегида, диолефина и ненасыщенного нитрила
KR101706851B1 (ko) 다성분계 복합금속산화물 촉매의 제조방법
KR100963079B1 (ko) 다성분계 비스무스 몰리브데이트 촉매, 그 제조방법 및 상기 촉매를 이용한 1,3-부타디엔 제조방법
CA2933484C (fr) Catalyseur ameliore destine a la deshydrogenation oxydative
TW201004704A (en) Method for regenerating catalyst for the production of methacrylic acid and process for preparing methacrylic acid
JP4900449B2 (ja) メタクリル酸製造用触媒の製造方法及びメタクリル酸の製造方法
CN111629825A (zh) 钼-碲-钒-铌基odh催化剂的制备方法
CN107010648A (zh) 一种有序氧化铝介孔材料及其制备方法
JP2011178719A (ja) ブタジエンの製造方法
KR20210102893A (ko) 알칸의 산화적 탈수소화 및/또는 알켄의 산화
TWI495626B (zh) Preparation of conjugated diolefins
SG170046A1 (en) Mixed oxide catalysts made of hollow shapes
WO2011146421A3 (fr) Procédé de fabrication d'un catalyseur très sélectif pour la production d'oxyde d'éthylène
WO2009151255A3 (fr) Catalyseur d’oxydation de contact en phase gazeuse d’un hydrocarbure, son procédé de préparation et procédé d’oxydation en phase gazeuse d’un hydrocarbure utilisant ce catalyseur
Popova et al. Effect of oxalic acid content and medium of thermal treatment on physicochemical and catalytic properties of MoVTeNb oxide catalysts in propane ammoxidation
CN113083283A (zh) Mo-V-Te-Nb-O催化剂及其制备方法与应用

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09715226

Country of ref document: EP

Kind code of ref document: A2

RET De translation (de og part 6b)

Ref document number: 112009000404

Country of ref document: DE

Date of ref document: 20101230

Kind code of ref document: P

122 Ep: pct application non-entry in european phase

Ref document number: 09715226

Country of ref document: EP

Kind code of ref document: A2