WO2009103316A2 - Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit - Google Patents
Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit Download PDFInfo
- Publication number
- WO2009103316A2 WO2009103316A2 PCT/EP2008/001367 EP2008001367W WO2009103316A2 WO 2009103316 A2 WO2009103316 A2 WO 2009103316A2 EP 2008001367 W EP2008001367 W EP 2008001367W WO 2009103316 A2 WO2009103316 A2 WO 2009103316A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- evaporator
- refrigerant
- pipe
- pipes
- refrigerating circuit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B47/00—Arrangements for preventing or removing deposits or corrosion, not provided for in another subclass
- F25B47/02—Defrosting cycles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B39/00—Evaporators; Condensers
- F25B39/02—Evaporators
Definitions
- the invention relates to a refrigerating circuit and to a method of selectively cooling or defrosting an evaporator of a refrigerating circuit.
- Refrigerating system evaporators having a plurality of refrigerant pipes are well-known in the art. Refrigerant is flown through these pipes for effecting a heat exchange with an ambient air flow. Refrigerant flow direction and air flow direction often constitute a counter-flow relationship. It is also known to use the same pipes in a defrosting operation by flowing a hot gas therethrough. During a defrosting operation, however, the problem arises that one side of the evaporator (hot gas outlet) is not fully defrosted and the ice build up at this side remains unmelted.
- Refrigerating systems often comprise a Cu pipe serpentine, which is for example located in the floor of the refrigerating system, to which the evaporator is mounted, and helps in the defrosting operation by carrying hot fluid.
- Exemplary embodiments of the invention include a refrigerating circuit comprising a compressor, a condenser/gas cooler, an expansion device, an evaporator, and refrigerant conduits circulating a refrigerant therethrough.
- the evaporator comprises refrigerant piping comprising a plurality of substantially horizontal layers, each layer comprising a plurality of pipes, the pipes being sub- stantially perpendicular to an air flow direction from an air inlet region to an air outlet region of the evaporator.
- a pipe selected from the group of the second pipe to the last but one pipe in the air flow direction in the bottom layer forms the entry pipe of the evaporator.
- the entry pipe is connectable with the expansion device to provide a refrigerating mode, and the entry pipe is connectable with a hot gas conduit to provide a defrosting mode for the evaporator.
- Exemplary embodiments of the invention further include a method of selectively cooling or defrosting an evaporator of a refrigerating circuit, the method comprising the steps of compressing a refrigerant; flowing the refrigerant through a gas cooler/condenser and an expansion device, when cooling is selected, or flowing the refrigerant through a hot gas by-pass conduit, when defrosting is selected; flowing the refrigerant through refrigerant piping of the evaporator, the refrigerant piping comprising a plurality of substantially horizontal layers, each layer comprising a plurality of pipes; and flowing air through the evaporator with the air flow direction being substantially perpendicular to the orientation of the pipes.
- the refrigerant enters the refrigerant piping of the evaporator at a pipe of the group from the second pipe to the last but one pipe in the bottom layer.
- FIG. 1 shows a schematic of an exemplary evaporator and its integration in a refrigerating circuit in accordance with the present invention.
- FIG. 1 shows a portion of a refrigerating circuit in accordance with an embodiment of the present invention in a schematic manner.
- the compressor and the condenser/gas cooler are well-known elements in the art, they have been omitted from FIG. 1 for easy readability.
- the evaporator 4 is shown in detail. It comprises two layers (8, 10) of refrigerant pipes (8a-8h, 1 Oa-IOh). As such evaporators are often disposed in the floor region of a refrigerating sales furniture, for example an island freezer, layer 8 is hereinafter also referred to as the bottom layer, whereas layer 10 is hereinafter also referred to as the top layer.
- Each layer comprises eight refrigerant pipes, which are shown as circles giving their representation a cross-sectional appearance, which indicates that the pipes run perpendicular to the drawing plane.
- the pipes are numbered with regard to the air flow direction 12, which is from left to right in the schematic of FIG. 1.
- 8a is the first pipe with regard to the air flow direction
- 8b the second pipe
- ..., and 8h is the eighth and last pipe with regard to the air flow direction.
- An analogous numbering is adhered to for the top layer 10.
- connection elements which are schematically depicted by solid lines and dashed lines.
- the solid lines represent connection elements that are disposed towards the user from the drawing plane, whereas the dashed lines represent connection elements behind the drawing plane.
- the pipes 8a to 8h and 10a to 10h combine with the connection elements to form a refrigerant serpentine whose long legs run back and forth through the drawing plane.
- This piping is used to flow a refrigerant through the evaporator, with the detailed description of the connection setup and the resulting refrigerant flow given below.
- the third pipe with regard to the air flow direction 12 in the bottom layer 8, i.e. pipe 8c, hereinafter also referred to as entry pipe, is in connection to an evaporator inlet section 14 of the refrigerant conduits.
- Said evaporator inlet section is selectively connected to a hot gas conduit 6 or the expansion device 2 of the refrigerating circuit.
- According means (not shown) for enabling a flow connection between the evaporator inlet section 14 and either the expansion device 2 or the hot gas conduit 6 and blocking the respective other of the expansion device 2 and the hot gas conduit 6 are well-known in the art and therefore not described in detail.
- the connection with the expansion device 2 is selected for a refrigerating mode, whereas the connection with the hot gas conduit 6 is selected for a defrosting mode.
- the hot gas conduit 6 originates between the compressor and the condenser/gas cooler. Thus, it establishes a by-pass conduit, diverting the refrigerant after its compression and before its cooling in the condenser/gas cooler from the conventional refrigerating circuit. It is appar- ent that the junction between the compressor and the condenser/gas cooler may comprise appropriate means for guiding the refrigerant either into the hot gas conduit 6 or towards the condenser/gas cooler.
- the hot gas conduit 6 may also comprise an expansion device for controlling the temperature/pressure of the refrigerant upon entering the evaporator 4 in the defrosting mode.
- the refrigerant enters the evaporator 4 at the entry pipe 8c. From there it is flown through a first section 18 of the refrigerant piping of the evaporator 4.
- the first section comprises the pipes 8c, 8d, ..., 8g, and 8h, which are the entry pipe 8c and all pipes on the bottom layer that are down- stream thereof. These pipes are interconnected by first connection elements 20.
- the refrigerant is flown substantially perpendicular to the air flow direction in the pipes and substantially in a co-flow relationship with the air flow direction 12 in the first connection elements 20 towards the end of the evaporator 4.
- the second section 22 of refrigerant piping comprises the pipes on the top layer from the end of the evaporator 4 to the pipe that is on the same level as the entry pipe with regards to the air flow direction 12, in this embodiment the pipe 10c.
- the pipes of the second section 22 of the refrigerant piping are interconnected by second connection elements 24.
- the refrigerant flow in the pipes 10c to 10h of the second section 22 of refrigerant piping is substantially perpendicular to the air flow direction 12.
- the refrigerant flow in the second connection elements 24 exhibits a substantially counter-flow relationship with the air flow direction 12.
- pipe 8a is the exit pipe of the evaporator. It is connected to the evaporator outlet section 16 of the refrigerant con- duits, which leads the refrigerant back to the compressor.
- the above-described structure of the evaporator 4 has a number of implications for the defrosting and the refrigerating modes.
- the refrigerating mode it is the primary object- ive to generate a heat transfer between the refrigerant and the air flow that is as efficient as possible.
- the counter-flow relationship between the refrigerant and the air flow direction 12 in the second section 22 of the refrigerant piping provides for very good heat transfer conditions.
- the third section 26 of the refrigerant piping provides for an extended region, where the refrigerant is at its warmest in the evaporator and the air flow is also at its warmest right after entering the evaporator 4.
- This set-up provides for a maximum heating of the refrigerant and thus for a maximum heat transfer from the air flow before the refrigerant leaves the evaporator 4 through the exit pipe 8a.
- the third section 26 allows for a maximum amount of superheating of the gaseous refrigerant.
- the above-described structure of the evaporator 4 is particularly efficient for a number of reasons.
- the hot refrigerant after by-passing the condenser/gas cooler and the expansion device 2, enters the evaporator 4 at entry pipe 8c.
- the refrigerant is the warmest and has the biggest effect in melting the ice build-up in the evaporator 4.
- the region around the entry pipe 8c and the downstream portion thereof in the bottom layer receive the most heat, espe- cially in the beginning stages of the defrosting operation.
- an advantageous effect thereof is that the support structure to which the evaporator 4 is attached, for example the floor portion of an island freezer, is warmed up starting in the middle region and expanding to the sides.
- a warming of the support structure at an early stage of the defrosting operation prevents a scenario wherein ice is melted somewhere in the evaporator 4 and the water is re-frozen at the support structure, when supposed to drain out of the evaporator 4.
- the set-up provides for the support structure, which may be slightly inclined, to be an idea! gutter for water generated by melting the ice in all parts of the evaporator 4 at later stages of the defrosting operation.
- Another advantage is that water vapour which may be generated around the entry pipe 8c, where continuous heating is effected by flowing hot fluid through the refrigerant piping, cannot easily leave the evaporator 4 and re-freeze in other parts of the refrigerating system, where the temperature is still below 0 0 C.
- the water vapour helps in defrosting the evaporator 4 from the middle region towards the sides.
- the refrigerant piping of the evaporator 4 of the exemplary embodiment is not designed in a way to sustain CO 2 in a liquid phase. That means that, when CO 2 is used as refrigerant, the condensation energy is not at the disposal of the defrosting process, which is compensated for by the energy-efficient lay- out of the evaporator 4.
- the hot gas conduit 6 may be a by-pass conduit to the refrigerating circuit. It may also be part of an independent defrosting circuit. It is apparent that in addition to the flow switching means between the expansion device 2 and the hot gas conduit 6, second guiding means would be necessary to direct the fluid coming out of the evaporator 4 into the defrosting circuit or the refrigerant circuit.
- the defrosting circuit would in that case need additional means for generating fluid circulation, for example a compressor.
- the hot gas conduit 6 may carry a fluid in a liquid or gaseous state to the evaporator, depending on the specific embodiment of the invention.
- the evaporator 4 may comprise three or more layers as well. This would lead to some changes as to how the pipes are con- nected with connection elements. Assume an evaporator having the two layers 8 and 10, as depicted, as well as an additional third layer.Assume that the eight pipes of the third layer are denoted 30a, 30b, ..., 3Og, and 3Oh, in analogy with the first layer 8 and the second layer 10.
- the first section 18 of the refrigerant piping would have the same structure as in the exemplary embodiment of FIG. 1. However, the second section 22 of the refrigerant piping would have a fairly different layout. It would comprise the pipes 10c to 1Oh of the intermediate layer and the pipes 30c to 3Oh of the third layer.
- a plurality of options can be thought of as to how to connect these pipes with each other.
- a first option would be connecting - in refrigerant flow direction - pipes 10a, 3Oh, 10b, 3Og, 10f, etc., forming a kind of sawtooth wave shape of the connection elements.
- Another option would be connecting - in refrigerant flow direction - pipes 1Oh, 3Oh, 3Og, 10g, 10f, 3Of, etc., forming a kind of square wave shape of the connection elements.
- Both options have in common that the refrigerant flows in a generally counter-flow relationship with respect to the air flow direction 12 in the second section 22 of the refrigerant piping.
- connection options increase with the number of layers of refrigerant pipes.
- the third section 26 of the refrigerant piping is concerned, a lot of options for connections starting at the last pipe of the second section 22, i.e. either 10c or 30c, to the exit pipe 8a exist.
- 10c or 30c the last pipe of the second section 22
- Exemplary embodiments of the invention allow for energy-efficient cooling of the air flow through an evaporator in a refrigerating mode as well as for energy-efficient defrosting of said evaporator in a defrost- ing mode.
- Introducing the hot gas into a pipe in the middle portion of the bottom layer of the evaporator in the defrosting mode provides for a number of advantages.
- the region around the point of entry of the hot gas will be heated most and will be defrosted quickest. Therefore, the support structure, to which the evaporator is mounted, will be defrosted in the beginning stages of a de- frosting operation and thus will provide for an ice-free surface, which is ideal for receiving and draining the water that is generated throughout the defrosting process.
- the water vapour which is generated in the most heated portion of the evaporator during the defrosting process, will not be able to leave the evaporator, as it will not stay a vapour on its way to the end portions of the evaporator.
- energy losses due to the heated vapour leaving the evaporator to be defrosted are minimized and ice built-up in other parts of the refrigerating system, caused by said water vapour, is prevented.
- the defrosting operation in a refrigerant circuit in accordance with an embodiment of the invention is so energy-efficient that shorter de- frosting times can be achieved than with electric defrosting. This time duration advantage is paired with the overall simplification of not having an additional electric defrosting system integrated into a refrigerating system.
- the hot gas conduit is a by-pass con- duit originating between the compressor and the expansion device and ending between the expansion device and the evaporator.
- the refrigerant entry pipe may be a pipe in the first half of the evaporator in the air flow direction.
- a first section of the refrigerant piping of the evaporator comprises the entry pipe and the pipes on the bottom layer that are downstream of the entry pipe with regard to the air flow direction. This allows for an early and thorough heating of the bottom region of the evaporator in the defrosting process, which is beneficial to the draining of the melted water during the later stages of the defrosting.
- This first section leaves the beginning of the evaporator in the air flow direction out, which leaves the option of flowing the refrigerant therethrough shortly before leaving the evaporator, which in turn is beneficial in the refrigerating mode. Therefore, this layout is a good basis for achieving an excellent trade-off between the refrigerating and the defrosting modes.
- first connection elements connect respective adjacent pipes of the first section of the refrigerant piping of the evaporator, such that in operation the refrigerant flows in a co-flow relationship with the air flow direction in the first connection elements. This allows for an advantageous heating of the bottom layer, and therefore of the underlying support structure, from a middle region towards an end region of the evaporator.
- a second section of the refrigerant pip- ing of the evaporator comprises the pipes on the level of and downstream from the entry pipe with regard to the air flow direction above the bottom layer.
- second connection elements connect the pipes of the second section of the refrigerant piping of the evaporator, such that in operation the refrigerant flows in an overall counter-flow relationship with the air flow direction in the second connection elements. This allows for using an advantageous counter-flow relationship between the refrigerant and the air flow in the refrigerating mode.
- This layout furthermore allows for implementing the beneficial counter-flow for one or a plurality of layers above the bottom layer, i. e. in the second section of the refrigerant piping.
- the first pipe in the air flow direction in the bottom layer is an exit pipe.
- This exit pipe may be connected to an evaporator outlet section of the refrigerant conduits. Having the refrigerant leave the evaporator in the first pipe in the air flow direction in the bottom layer ensures that the re- frigerant flows last through the inlet region of the evaporator with regard to the air flow. In the refrigerating mode, this leads to a region of heat exchange between the air flow and the refrigerant, when they are both in their warmest state throughout the evaporator. This allows for the maximum amount of superheating of the refrigerant, when in gaseous form already, which provides for maximum use of the energetic capacity of the refrigerant in the refrigerating process.
- a third section of the refrigerant piping of the evaporator comprises the pipes upstream of the refrigerant entry pipe with regard to the air flow direction. This allows for an extended region of heat transfer between the air flow and the refrigerant, where they are both at their substantially warmest in the refrigerating mode. It allows for that region to include all layers, forming a heat exchange region with above described properties across the hole cross-section of the air flow.
- the refrigerant piping of the evaporator may comprise two or three layers. An evaporator having four, five or more layers can also be thought of. Each layer of the refrigerant piping of the evaporator may comprise five to ten pipes, particularly six to eight pipes. These numbers of pipes have been found to be be- neficial for an efficient heat exchange both in the refrigerating and the defrosting mode. Depending on the application, less than five pipes or more than ten pipes may also constitute a good layer size.
- the refrigerant entry pipe is the second or third pipe in the air flow direction in the bottom layer of the refrigerant piping of the evaporator. This allows for the hot gas entering the evaporator towards the middle in the refrigerating mode, advantageously heating the middle portion of the bottom region of the evaporator first in a defrosting mode. It also leaves room for having a heat exchange area of relatively warm refrigerant and relatively warm air flow in the beginning of the evaporator with regard to the air flow direction, when the system is operated in the refrigerating mode.
- the refrigerant may be CO 2 . It can also be R22 or R404A or any other refrigerant suitable to the refrigerating circuit.
- the air flow in the evaporator is in the refrigerating mode cooled down to a temperature below 0 0 C.
- the invention is suitable for freezers and below 0 0 C refrigerating systems, where defrosting is a big issue.
- the refrigerating circuit comprises two expansion devices and two evaporators, a first expansion device and a first evaporator forming a below 0 0 C refrigerating portion of the refrigerating circuit, the second expansion device and the second evaporator forming an above 0 0 C refrigerating por- tion of the refrigerating circuit.
- the invention can be applied to a dual system including a freezer and a refrigerator. In this case, the defrosting may be carried out on the freezing portion or on the refrigerating portion or on both portions. It is apparent that according piping and according compressing means will be necessary.
- Second connection elements 26 Third section of refrigerant piping of evaporator
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Defrosting Systems (AREA)
Abstract
L’invention concerne un circuit de réfrigération qui comprend un compresseur, un condenseur/refroidisseur de gaz, un dispositif de détente (2), un évaporateur (4), et des conduits de frigorigène dans lesquels circule un frigorigène. L'évaporateur (4) comprend une tuyauterie de frigorigène présentant plusieurs couches sensiblement horizontales (8, 10) comprenant chacune plusieurs tuyaux (8a-8h, 10a-10h) sensiblement perpendiculaires à un sens d'écoulement de l'air (12) et s'étendant d'une zone d'admission d'air à une zone de sortie d'air de l'évaporateur (4). Un tuyau choisi dans le groupe formé du second (8b) à l'avant dernier tuyau (8g) et installé dans la couche de fond (8) constitue le tuyau d'admission (8c) de l'évaporateur (4). Le tuyau d'admission (8c) se raccorde au dispositif de détente (2) pour assurer un mode de réfrigération, et à un conduit de gaz chaud (6) pour assurer un mode de dégivrage de l'évaporateur (4).
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2008/001367 WO2009103316A2 (fr) | 2008-02-21 | 2008-02-21 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
| EP09711818.6A EP2242965B1 (fr) | 2008-02-21 | 2009-02-16 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
| CA2708641A CA2708641A1 (fr) | 2008-02-21 | 2009-02-16 | Circuit de refrigeration et procede selectif de refroidissement ou de degivrage d'un evaporateur du circuit |
| ES09711818.6T ES2646115T3 (es) | 2008-02-21 | 2009-02-16 | Circuito de refrigeración y método para enfriar o descongelar selectivamente un evaporador del mismo |
| PCT/EP2009/001062 WO2009103471A2 (fr) | 2008-02-21 | 2009-02-16 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
| US12/809,639 US20100300122A1 (en) | 2008-02-21 | 2009-02-16 | Refrigerating Circuit And Method Of Selectively Cooling Or Defrosting An Evaporator Thereof |
| NO09711818A NO2242965T3 (fr) | 2008-02-21 | 2009-02-16 | |
| PL09711818T PL2242965T3 (pl) | 2008-02-21 | 2009-02-16 | Obieg chłodzenia i sposób selektywnego schładzania lub odmrażania jego parownika |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2008/001367 WO2009103316A2 (fr) | 2008-02-21 | 2008-02-21 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2009103316A2 true WO2009103316A2 (fr) | 2009-08-27 |
Family
ID=40935739
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2008/001367 Ceased WO2009103316A2 (fr) | 2008-02-21 | 2008-02-21 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
| PCT/EP2009/001062 Ceased WO2009103471A2 (fr) | 2008-02-21 | 2009-02-16 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2009/001062 Ceased WO2009103471A2 (fr) | 2008-02-21 | 2009-02-16 | Circuit de réfrigération et procédé sélectif de refroidissement ou de dégivrage d'un évaporateur du circuit |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20100300122A1 (fr) |
| CA (1) | CA2708641A1 (fr) |
| ES (1) | ES2646115T3 (fr) |
| WO (2) | WO2009103316A2 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8011192B2 (en) * | 2005-06-23 | 2011-09-06 | Hill Phoenix, Inc. | Method for defrosting an evaporator in a refrigeration circuit |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5663970U (fr) * | 1979-10-19 | 1981-05-29 | ||
| JPS5721761A (en) * | 1980-07-14 | 1982-02-04 | Mitsubishi Electric Corp | Cooler |
| JPS6096550U (ja) * | 1983-12-05 | 1985-07-01 | 三菱電機株式会社 | 冷凍装置 |
| JPH0648125B2 (ja) * | 1985-05-29 | 1994-06-22 | 株式会社日立製作所 | ヒ−トポンプ式空気調和機 |
| US4995453A (en) * | 1989-07-05 | 1991-02-26 | Signet Systems, Inc. | Multiple tube diameter heat exchanger circuit |
| US6923013B2 (en) * | 2001-05-04 | 2005-08-02 | Carrier Corporation | Evaporator for medium temperature refrigerated merchandiser |
| US6460372B1 (en) * | 2001-05-04 | 2002-10-08 | Carrier Corporation | Evaporator for medium temperature refrigerated merchandiser |
| US8011192B2 (en) * | 2005-06-23 | 2011-09-06 | Hill Phoenix, Inc. | Method for defrosting an evaporator in a refrigeration circuit |
| JP4506609B2 (ja) * | 2005-08-08 | 2010-07-21 | 三菱電機株式会社 | 空気調和機及び空気調和機の製造方法 |
-
2008
- 2008-02-21 WO PCT/EP2008/001367 patent/WO2009103316A2/fr not_active Ceased
-
2009
- 2009-02-16 US US12/809,639 patent/US20100300122A1/en not_active Abandoned
- 2009-02-16 CA CA2708641A patent/CA2708641A1/fr not_active Abandoned
- 2009-02-16 WO PCT/EP2009/001062 patent/WO2009103471A2/fr not_active Ceased
- 2009-02-16 ES ES09711818.6T patent/ES2646115T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20100300122A1 (en) | 2010-12-02 |
| CA2708641A1 (fr) | 2009-08-27 |
| WO2009103471A3 (fr) | 2009-10-29 |
| WO2009103471A2 (fr) | 2009-08-27 |
| ES2646115T3 (es) | 2017-12-12 |
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Legal Events
| Date | Code | Title | Description |
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| NENP | Non-entry into the national phase |
Ref country code: DE |
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| WA | Withdrawal of international application |