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WO2009037251A3 - Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe - Google Patents

Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe Download PDF

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Publication number
WO2009037251A3
WO2009037251A3 PCT/EP2008/062298 EP2008062298W WO2009037251A3 WO 2009037251 A3 WO2009037251 A3 WO 2009037251A3 EP 2008062298 W EP2008062298 W EP 2008062298W WO 2009037251 A3 WO2009037251 A3 WO 2009037251A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal
complex
polymer
coordination
phosphorus atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/062298
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English (en)
Other versions
WO2009037251A2 (fr
Inventor
Steven Van Zutphen
Nicolas Mezailles
Pascal Le Floch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecole Polytechnique
Original Assignee
Ecole Polytechnique
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Filing date
Publication date
Application filed by Ecole Polytechnique filed Critical Ecole Polytechnique
Priority to US12/405,853 priority Critical patent/US8268068B2/en
Publication of WO2009037251A2 publication Critical patent/WO2009037251A2/fr
Publication of WO2009037251A3 publication Critical patent/WO2009037251A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/14—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing two or more elements other than carbon, oxygen, nitrogen, sulfur and silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F275/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers containing phosphorus, selenium, tellurium or a metal as defined in group C08F30/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/001—Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0091—Complexes with metal-heteroatom-bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2996—Glass particles or spheres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

L'invention a pour objet un complexe de coordination à base de métaux caractérisé en ce qu'il comprend des atomes de métal et un polymère comportant des goupements de type trialkyjphosphine, triaikyl oxyde, sulfure, selenure ou tellure de phosphine, ou encore d'iminophosphorane, lesdits atomes étant greffés sur le polymère par des liaisons de type coordination. Ce type de complexe polymère-métal rencontre de nombreuses applications faisant appel à la chimie de coordination des métaux, telles que la catalyse, la purification ou l'extraction des métaux ou bien encore le domaine de l'imagerie médicale utilisant des nanoparticules luminescentes métalliques.
PCT/EP2008/062298 2007-09-17 2008-09-16 Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe Ceased WO2009037251A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/405,853 US8268068B2 (en) 2007-09-17 2009-03-17 Metal-polymer coordination complex incorporating phosphorus atoms and applications using such a complex

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0757637A FR2921067B1 (fr) 2007-09-17 2007-09-17 Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe
FR0757637 2007-09-17

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/405,853 Continuation-In-Part US8268068B2 (en) 2007-09-17 2009-03-17 Metal-polymer coordination complex incorporating phosphorus atoms and applications using such a complex

Publications (2)

Publication Number Publication Date
WO2009037251A2 WO2009037251A2 (fr) 2009-03-26
WO2009037251A3 true WO2009037251A3 (fr) 2010-02-18

Family

ID=39537967

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/062298 Ceased WO2009037251A2 (fr) 2007-09-17 2008-09-16 Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe

Country Status (3)

Country Link
US (1) US8268068B2 (fr)
FR (1) FR2921067B1 (fr)
WO (1) WO2009037251A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2921067B1 (fr) 2007-09-17 2010-08-27 Ecole Polytech Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe
EP2230244B1 (fr) * 2009-03-17 2014-05-07 Ecole Polytechnique DGAR Polymères de phosphore et leurs utilisations
TW201219470A (en) * 2010-11-12 2012-05-16 Univ Nat Taiwan Oil dispersible composite of metallic nanoparticle and method for synthesizing the same
EP2851370B1 (fr) 2013-09-19 2016-03-09 Magpie Polymers Procédé de préparation de tris(hydroxyméthyl) phosphine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1583037A (fr) * 1967-10-02 1969-10-10
FR2277103A1 (fr) * 1974-07-05 1976-01-30 Aquitaine Petrole Nouveaux coordinats diphosphines polymeres et leurs derives metalles
US4157313A (en) * 1975-02-26 1979-06-05 Agence Nationale De Valorisation De La Recherche Composite support notably for supporting catalysts containing a metal

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US2237045A (en) * 1936-06-18 1941-04-01 Monsanto Chemicals Copper fungicide
GB761985A (en) * 1953-08-13 1956-11-21 Bradford Dyers Ass Ltd Polymeric materials
US2772188A (en) * 1953-11-18 1956-11-27 Wilson A Reeves Ammonia insolubilized methylol-phosphorus polymers and cellulosic materials impregnated therewith
US2810701A (en) * 1954-11-09 1957-10-22 Wilson A Reeves Aqueous emulsion-suspension textile treating compositions and processes of treating textiles with same
US3035053A (en) * 1955-07-19 1962-05-15 Albright & Wilson Mfg Ltd Tris-aminomethylphosphines
US3142663A (en) * 1957-05-14 1964-07-28 Shell Oil Co Polymers with chains containing phosphorus, carbon, and silicon
US3221057A (en) * 1960-11-21 1965-11-30 Hooker Chemical Corp Phosphorus polymers
US3248429A (en) * 1962-12-03 1966-04-26 Hooker Chemical Corp Phosphorus polymers
US3404022A (en) * 1965-03-26 1968-10-01 Agriculture Usa Process for flameproofing cellulosic material
US3477953A (en) * 1966-11-29 1969-11-11 Hooker Chemical Corp Sequestration of metal ions with hydroxyalkyl phosphine oxides
US3625738A (en) * 1969-07-28 1971-12-07 Us Agriculture Process for stabilizing organophosphorus solutions and imparting rot and flame resistance to organic textile materials
US3655573A (en) * 1970-07-13 1972-04-11 Hooker Chemical Corp Synergistic metal sequestrant
US4048324A (en) * 1973-12-28 1977-09-13 Armand Kohn Fungicidal composition and method
US3953165A (en) 1974-08-22 1976-04-27 The United States Of America As Represented By The Secretary Of Agriculture Flameproofing resins for organic textiles from adduct polymers
US3953166A (en) 1974-08-22 1976-04-27 The United States Of America As Represented By The Secretary Of Agriculture Flame resistant organic textiles through treatment with phenols and adduct polymers
JPS5218800A (en) 1975-08-05 1977-02-12 Toyobo Co Ltd Process for preparing condensation products containing phosphorus
GB9120652D0 (en) * 1991-09-27 1991-11-06 Albright & Wilson Use of phosphonium compounds in the preparation of leather
CA2215833A1 (fr) 1995-03-29 1996-10-03 Alan R. Ketring Composes de phosphine hydroxyalkylee utilises en tant que produits pharmaceutiques, diagnostiques et therapeutiques et leur procede de fabrication
US5691436A (en) * 1996-07-16 1997-11-25 Blount; David H. Production of silicon-phosphorus containing compositions
US5948386A (en) 1997-03-14 1999-09-07 The Curators Of The University Of Missouri Conjugate and method for forming aminomethyl phosphorus conjugates
EP1027460B1 (fr) * 1997-10-30 2004-11-24 Rhodia Consumer Specialties Limited Tannage du cuir
US6827745B1 (en) * 1999-06-18 2004-12-07 Rhodia Consumer Specialties Limted Mixture of THP and a moderator to tan leather
FR2921067B1 (fr) 2007-09-17 2010-08-27 Ecole Polytech Complexe de coordination metal-polymere incorporant des atomes de phosphore et applications utilisant un tel complexe

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1583037A (fr) * 1967-10-02 1969-10-10
FR2277103A1 (fr) * 1974-07-05 1976-01-30 Aquitaine Petrole Nouveaux coordinats diphosphines polymeres et leurs derives metalles
US4157313A (en) * 1975-02-26 1979-06-05 Agence Nationale De Valorisation De La Recherche Composite support notably for supporting catalysts containing a metal

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BERNING D E ET AL: "In Vitro and In Vivo Characterization of a <99m>Tc Complex with Tris(hydroxymethyl)phosphine (THP)", NUCLEAR MEDICINE AND BIOLOGY, ELSEVIER, NY, US, vol. 23, no. 5, 1 July 1996 (1996-07-01), pages 617 - 622, XP004051837, ISSN: 0969-8051 *

Also Published As

Publication number Publication date
FR2921067A1 (fr) 2009-03-20
FR2921067B1 (fr) 2010-08-27
WO2009037251A2 (fr) 2009-03-26
US20100068143A1 (en) 2010-03-18
US8268068B2 (en) 2012-09-18

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