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WO2009035234A3 - Process for the chlorine by oxidation of hydrogen chloride - Google Patents

Process for the chlorine by oxidation of hydrogen chloride Download PDF

Info

Publication number
WO2009035234A3
WO2009035234A3 PCT/KR2008/005241 KR2008005241W WO2009035234A3 WO 2009035234 A3 WO2009035234 A3 WO 2009035234A3 KR 2008005241 W KR2008005241 W KR 2008005241W WO 2009035234 A3 WO2009035234 A3 WO 2009035234A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen chloride
chlorine
based catalyst
oxidation
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2008/005241
Other languages
French (fr)
Other versions
WO2009035234A2 (en
Inventor
Gwanghyun Lee
Sang Wook Lee
Inwan Sohn
Young Chul Kwon
Junhye Song
Chang-Sub Son
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanwha Chemical Corp
Original Assignee
Hanwha Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hanwha Chemical Corp filed Critical Hanwha Chemical Corp
Publication of WO2009035234A2 publication Critical patent/WO2009035234A2/en
Publication of WO2009035234A3 publication Critical patent/WO2009035234A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/03—Preparation from chlorides
    • C01B7/04—Preparation of chlorine from hydrogen chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)

Abstract

The present invention relates to a method for preparing chlorine by decomposing hydrogen chloride, in which hydrogen chloride is reacted with oxygen containing gas in the presence of a cerium based catalyst at comparatively low temperature of up to 400°C to produce chlorine. The cerium based catalyst of the present invention maintains its catalytic activity for a long time, compared with other catalysts prepared by the conventional processes, has excellent stability at high temperature, and has high economical efficiency, so that it paves the way to the development of an economically excellent oxidative decomposition process to produce chlorine from hydrogen chloride.
PCT/KR2008/005241 2007-09-10 2008-09-04 Process for the chlorine by oxidation of hydrogen chloride Ceased WO2009035234A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020070091300A KR20090026381A (en) 2007-09-10 2007-09-10 Method for producing chlorine by low temperature catalytic oxidation of hydrogen chloride
KR10-2007-0091300 2007-09-10

Publications (2)

Publication Number Publication Date
WO2009035234A2 WO2009035234A2 (en) 2009-03-19
WO2009035234A3 true WO2009035234A3 (en) 2009-05-07

Family

ID=40452673

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/005241 Ceased WO2009035234A2 (en) 2007-09-10 2008-09-04 Process for the chlorine by oxidation of hydrogen chloride

Country Status (2)

Country Link
KR (1) KR20090026381A (en)
WO (1) WO2009035234A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009021675A1 (en) * 2009-05-16 2010-11-18 Bayer Technology Services Gmbh Process for producing chlorine by gas phase oxidation of hydrogen chloride in the presence of a ceria catalyst
US20140241976A1 (en) 2011-07-05 2014-08-28 Bayer Intellectual Property Gmbh Process for the production of chlorine using a cerium oxide catalyst in an isothermic reactor
JP2014520742A (en) * 2011-07-05 2014-08-25 バイエル インテレクチュアル プロパティー ゲゼルシャフト ミット ベシュレンクテル ハフツング Method for producing chlorine using cerium oxide catalyst in adiabatic reaction cascade
WO2013060628A1 (en) 2011-10-24 2013-05-02 Bayer Intellectual Property Gmbh Catalyst and method for producing chlorine by means of a gas-phase oxidation
EP3421416A1 (en) 2017-06-29 2019-01-02 Covestro Deutschland AG Photocatalytic oxidation of hydrogen chloride with carbon monoxide
EP3670444A1 (en) 2018-12-18 2020-06-24 Covestro Deutschland AG Photocatalytic oxidation of hydrogen chloride with oxygen

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950016873A (en) * 1993-12-01 1995-07-20 김은영 Cerium chloride-dichromium trioxide catalyst for the production of chlorine by oxidation of hydrogen chloride and preparation method thereof
KR970015456A (en) * 1995-09-12 1997-04-28 랑핑거, 스타인호프 How to prepare chlorine from hydrogen chloride
KR20020056939A (en) * 1999-11-22 2002-07-10 그래햄 이. 테일러 Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950016873A (en) * 1993-12-01 1995-07-20 김은영 Cerium chloride-dichromium trioxide catalyst for the production of chlorine by oxidation of hydrogen chloride and preparation method thereof
KR970015456A (en) * 1995-09-12 1997-04-28 랑핑거, 스타인호프 How to prepare chlorine from hydrogen chloride
KR20020056939A (en) * 1999-11-22 2002-07-10 그래햄 이. 테일러 Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
GRUY F. ET AL., J. AM. CERAM. SOC., vol. 77, 1994, pages 1537 - 1544 *

Also Published As

Publication number Publication date
KR20090026381A (en) 2009-03-13
WO2009035234A2 (en) 2009-03-19

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