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WO2009028210A1 - Aqueous acryl-urethane block copolymer emulsion, process for production thereof, and aqueous coating material - Google Patents

Aqueous acryl-urethane block copolymer emulsion, process for production thereof, and aqueous coating material Download PDF

Info

Publication number
WO2009028210A1
WO2009028210A1 PCT/JP2008/002375 JP2008002375W WO2009028210A1 WO 2009028210 A1 WO2009028210 A1 WO 2009028210A1 JP 2008002375 W JP2008002375 W JP 2008002375W WO 2009028210 A1 WO2009028210 A1 WO 2009028210A1
Authority
WO
WIPO (PCT)
Prior art keywords
aqueous
acryl
urethane block
block copolymer
copolymer emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/002375
Other languages
French (fr)
Japanese (ja)
Inventor
Koji Izumichi
Naotaka Izumi
Takaki Jono
Ryusuke Kishimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Polyurethane Industry Co Ltd
Original Assignee
Nippon Polyurethane Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Polyurethane Industry Co Ltd filed Critical Nippon Polyurethane Industry Co Ltd
Publication of WO2009028210A1 publication Critical patent/WO2009028210A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D155/00—Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

[PROBLEMS] To provide: an aqueous acryl-urethane block copolymer emulsion, which has a good film-forming property and good water dispersibility; a process for producing the emulsion; and an aqueous coating material. [MEANS FOR SOLVING PROBLEMS] Disclosed is an aqueous acryl-urethane block copolymer emulsion, which has an acryl block having no hydrophilic group and an urethane block through which the acryl block is crosslinked, wherein the urethane block has a nonionic hydrophilic pendant group and an anionic hydrophilic pendant group in its side chains, and wherein the nonionic hydrophilic group and the anionic hydrophilic group are contained in the resin in amounts of 2 to 8 mass% and 0.1 to 0.5 mmol/g, respectively.
PCT/JP2008/002375 2007-08-31 2008-08-29 Aqueous acryl-urethane block copolymer emulsion, process for production thereof, and aqueous coating material Ceased WO2009028210A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007225463A JP2009057451A (en) 2007-08-31 2007-08-31 Acrylic / urethane block copolymer aqueous emulsion, method for producing the same, and aqueous coating material
JP2007-225463 2007-08-31

Publications (1)

Publication Number Publication Date
WO2009028210A1 true WO2009028210A1 (en) 2009-03-05

Family

ID=40386943

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/002375 Ceased WO2009028210A1 (en) 2007-08-31 2008-08-29 Aqueous acryl-urethane block copolymer emulsion, process for production thereof, and aqueous coating material

Country Status (2)

Country Link
JP (1) JP2009057451A (en)
WO (1) WO2009028210A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2338922A1 (en) * 2009-12-28 2011-06-29 Rohm and Haas Company Low voc aqueous compositions of acrylic-urethane block copolymers

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5534606B2 (en) * 2010-11-17 2014-07-02 旭化成ケミカルズ株式会社 Active energy ray-curable resin composition
TWI496794B (en) * 2014-05-30 2015-08-21 Champward Chemical Ind Co Ltd Preparing method for aqueous emulsion via water dispersible polyurethane grafted acrylate copolymerization

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03166212A (en) * 1989-10-06 1991-07-18 Basf Corp Water-dispersing polyurethane-acryl graft copolymer stabilized nonionically and partly anionically
JP2001192428A (en) * 1999-11-30 2001-07-17 Bayer Ag Aqueous polyurethane emulsion
JP2003326662A (en) * 2002-05-17 2003-11-19 Toray Ind Inc Packaging laminated film
JP2004244435A (en) * 2003-02-10 2004-09-02 Mitsubishi Chemicals Corp Aqueous resin composition emulsion and surface coating agent using the same
WO2006104094A1 (en) * 2005-03-28 2006-10-05 Nippon Polyurethane Industry Co., Ltd. Aqueous polyurethane resin composition and process for production thereof
WO2008020492A1 (en) * 2006-08-18 2008-02-21 Nippon Polyurethane Industry Co., Ltd. Emulsion composition containing blocked isocyanate, process for production of the same, and compositions for baking paints or adhesives
JP2008115385A (en) * 2006-10-17 2008-05-22 Bayer Materialscience Ag Aqueous coating composition containing a binder mixture as a primer
WO2008078754A1 (en) * 2006-12-25 2008-07-03 Nippon Polyurethane Industry Co., Ltd. Aqueous polyurethane resin emulsion coating composition and method for producing the same

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03166212A (en) * 1989-10-06 1991-07-18 Basf Corp Water-dispersing polyurethane-acryl graft copolymer stabilized nonionically and partly anionically
JP2001192428A (en) * 1999-11-30 2001-07-17 Bayer Ag Aqueous polyurethane emulsion
JP2003326662A (en) * 2002-05-17 2003-11-19 Toray Ind Inc Packaging laminated film
JP2004244435A (en) * 2003-02-10 2004-09-02 Mitsubishi Chemicals Corp Aqueous resin composition emulsion and surface coating agent using the same
WO2006104094A1 (en) * 2005-03-28 2006-10-05 Nippon Polyurethane Industry Co., Ltd. Aqueous polyurethane resin composition and process for production thereof
WO2008020492A1 (en) * 2006-08-18 2008-02-21 Nippon Polyurethane Industry Co., Ltd. Emulsion composition containing blocked isocyanate, process for production of the same, and compositions for baking paints or adhesives
JP2008115385A (en) * 2006-10-17 2008-05-22 Bayer Materialscience Ag Aqueous coating composition containing a binder mixture as a primer
WO2008078754A1 (en) * 2006-12-25 2008-07-03 Nippon Polyurethane Industry Co., Ltd. Aqueous polyurethane resin emulsion coating composition and method for producing the same
JP2008156488A (en) * 2006-12-25 2008-07-10 Nippon Polyurethane Ind Co Ltd Aqueous polyurethane resin emulsion coating composition and method for producing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2338922A1 (en) * 2009-12-28 2011-06-29 Rohm and Haas Company Low voc aqueous compositions of acrylic-urethane block copolymers
US8461256B2 (en) 2009-12-28 2013-06-11 Rohm And Haas Company Low VOC aqueous compositions of acrylic-urethane block copolymers

Also Published As

Publication number Publication date
JP2009057451A (en) 2009-03-19

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