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WO2009028192A1 - Agent adsorbant - Google Patents

Agent adsorbant Download PDF

Info

Publication number
WO2009028192A1
WO2009028192A1 PCT/JP2008/002342 JP2008002342W WO2009028192A1 WO 2009028192 A1 WO2009028192 A1 WO 2009028192A1 JP 2008002342 W JP2008002342 W JP 2008002342W WO 2009028192 A1 WO2009028192 A1 WO 2009028192A1
Authority
WO
WIPO (PCT)
Prior art keywords
ion
water
adsorbent agent
iron oxide
organic polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/002342
Other languages
English (en)
Japanese (ja)
Inventor
Toshiki Matsui
Shin Bito
Toshiyuki Hakata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toda Kogyo Corp
Original Assignee
Toda Kogyo Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toda Kogyo Corp filed Critical Toda Kogyo Corp
Publication of WO2009028192A1 publication Critical patent/WO2009028192A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46—Materials comprising a mixture of inorganic and organic materials
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/103—Arsenic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/105—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/12—Halogens or halogen-containing compounds
    • C02F2101/14—Fluorine or fluorine-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C02F2101/22—Chromium or chromium compounds, e.g. chromates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Dispersion Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne un agent adsorbant qui peut adsorber et retirer des ions, comme un ion de fluor, un ion de phosphore, un ion d'arsenic, un ion de sélénium et un ion de chrome, d'une solution, qui peut conserver sa forme dans l'eau à un niveau élevé et qui peut donc être utilisé pour remplir une colonne ou équivalent lors de son utilisation, et qui peut être utilisé à plusieurs reprises après sa désorption/régénération. L'invention concerne plus particulièrement un agent adsorbant capable d'adsorber un ion toxique contenu dans de l'eau, lequel contient un granulé composite comprenant une particule d'oxyde de fer contenant de l'eau et au moins un élément choisi parmi Zr, Ce, Hf, La et Y et une résine polymère organique choisie parmi au moins une résine copolymère d'éthylène et d'alcool vinylique ou une résine de type polyvinyle acétal, et qui possède une granulométrie moyenne de 0,3 mm à 3,0 mm, un volume de pore de 0,1 cm3/g à 0,5 cm3/g et une résistance à la compression de 3 N à 20 N. La particule d'oxyde de fer contenant de l'eau possède un diamètre moyen de particule primaire de 0,01 µm à 0,5 µm et contient Zr, Ce, Hf, La et Y en une quantité totale de 3,0 % en poids à 30 % en poids, et la résine polymère organique est contenue en une quantité de 3,0 % à 10 % en poids.
PCT/JP2008/002342 2007-08-29 2008-08-28 Agent adsorbant Ceased WO2009028192A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007223181 2007-08-29
JP2007-223181 2007-08-29

Publications (1)

Publication Number Publication Date
WO2009028192A1 true WO2009028192A1 (fr) 2009-03-05

Family

ID=40386931

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/002342 Ceased WO2009028192A1 (fr) 2007-08-29 2008-08-28 Agent adsorbant

Country Status (2)

Country Link
JP (1) JP5482979B2 (fr)
WO (1) WO2009028192A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102745764A (zh) * 2012-07-20 2012-10-24 陕西科技大学 一种利用铝钛复合鞣制废弃物去除铬鞣废水中三价铬的方法
CN104084177A (zh) * 2014-07-15 2014-10-08 京东方科技集团股份有限公司 一种磁性壳聚糖纳米纤维铜离子吸附剂及其制备方法、用途
CN106492753A (zh) * 2016-02-16 2017-03-15 朱小平 一种砷吸附材料的制备方法
WO2018129772A1 (fr) * 2017-01-10 2018-07-19 苏州大学张家港工业技术研究院 Procédé de traitement d'eaux usées contenant du sélénate
CN111909502A (zh) * 2020-06-30 2020-11-10 会通新材料股份有限公司 一种PPO-sPS组合物及其制备方法
CN113149356A (zh) * 2021-04-25 2021-07-23 华设设计集团环境科技有限公司 一种高效除磷复合填料及其制备方法
CN113694899A (zh) * 2021-09-02 2021-11-26 南京大学 一种镧锆双金属树脂基纳米复合材料及其制备方法与应用
CN114906956A (zh) * 2022-04-27 2022-08-16 江苏启创环境科技股份有限公司 微电解耦合纳米复合材料吸附的有机磷废水深度除磷方法
CN117380148A (zh) * 2023-11-15 2024-01-12 西南交通大学 一种镧、锆双金属吸附剂的制备方法及富集水体磷的方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5637708B2 (ja) * 2010-03-19 2014-12-10 戸田工業株式会社 フッ素吸着剤によるフッ素イオン含有排水の処理方法
JP5502678B2 (ja) * 2010-09-27 2014-05-28 株式会社クラレ 組成物、金属イオン吸着材、及び金属回収方法
JP5250140B1 (ja) * 2011-07-12 2013-07-31 三菱製紙株式会社 磁性吸着剤粒子
JP5864284B2 (ja) * 2012-01-26 2016-02-17 太平洋セメント株式会社 塩素バイパスダスト水洗排水からのセレン除去方法
JP5957276B2 (ja) * 2012-04-26 2016-07-27 大日精化工業株式会社 ポリビニルブチラール樹脂及びフェロシアン化金属化合物を含有するセシウム除去材及びセシウム除去材用ペレットの製造方法
EP2927197A4 (fr) * 2012-11-30 2016-04-13 Organo Corp Système pour traiter l'eau résiduelle de la gazéification du charbon, et procédé pour traiter l'eau résiduelle de la gazéification du charbon
JP6377130B2 (ja) * 2014-03-03 2018-08-22 株式会社マエダマテリアル 水処理用吸着剤、その製造方法、水処理装置、水処理装置用カートリッジ及び水処理方法
EP4183761A1 (fr) * 2021-11-18 2023-05-24 Kuraray Europe GmbH Utilisation de polyvinylacétals compactés comme liant dans des feuilles vertes céramiques

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10296077A (ja) * 1996-08-14 1998-11-10 Takeda Chem Ind Ltd イオン吸着剤
JP2006305551A (ja) * 2005-03-29 2006-11-09 Toda Kogyo Corp 吸着剤
JP2007014826A (ja) * 2005-06-10 2007-01-25 Asahi Kasei Chemicals Corp 多孔性成形体およびその製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4810792B2 (ja) * 2004-01-26 2011-11-09 栗田工業株式会社 吸着材及び水処理方法
JP5062976B2 (ja) * 2005-06-15 2012-10-31 旭化成ケミカルズ株式会社 排水処理装置および排水処理方法
JP4854999B2 (ja) * 2005-07-20 2012-01-18 株式会社日本海水 フッ素吸着剤及びその製法
JP4609660B2 (ja) * 2006-01-27 2011-01-12 戸田工業株式会社 吸着剤

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10296077A (ja) * 1996-08-14 1998-11-10 Takeda Chem Ind Ltd イオン吸着剤
JP2006305551A (ja) * 2005-03-29 2006-11-09 Toda Kogyo Corp 吸着剤
JP2007014826A (ja) * 2005-06-10 2007-01-25 Asahi Kasei Chemicals Corp 多孔性成形体およびその製造方法

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102745764A (zh) * 2012-07-20 2012-10-24 陕西科技大学 一种利用铝钛复合鞣制废弃物去除铬鞣废水中三价铬的方法
CN104084177A (zh) * 2014-07-15 2014-10-08 京东方科技集团股份有限公司 一种磁性壳聚糖纳米纤维铜离子吸附剂及其制备方法、用途
CN104084177B (zh) * 2014-07-15 2017-02-01 京东方科技集团股份有限公司 一种磁性壳聚糖纳米纤维铜离子吸附剂及其制备方法、用途
CN106492753A (zh) * 2016-02-16 2017-03-15 朱小平 一种砷吸附材料的制备方法
WO2018129772A1 (fr) * 2017-01-10 2018-07-19 苏州大学张家港工业技术研究院 Procédé de traitement d'eaux usées contenant du sélénate
CN111909502B (zh) * 2020-06-30 2022-05-17 会通新材料股份有限公司 一种PPO-sPS组合物及其制备方法
CN111909502A (zh) * 2020-06-30 2020-11-10 会通新材料股份有限公司 一种PPO-sPS组合物及其制备方法
CN113149356A (zh) * 2021-04-25 2021-07-23 华设设计集团环境科技有限公司 一种高效除磷复合填料及其制备方法
CN113694899A (zh) * 2021-09-02 2021-11-26 南京大学 一种镧锆双金属树脂基纳米复合材料及其制备方法与应用
CN113694899B (zh) * 2021-09-02 2022-07-12 南京大学 一种镧锆双金属树脂基纳米复合材料及其制备方法与应用
CN114906956A (zh) * 2022-04-27 2022-08-16 江苏启创环境科技股份有限公司 微电解耦合纳米复合材料吸附的有机磷废水深度除磷方法
CN114906956B (zh) * 2022-04-27 2023-06-20 江苏启创环境科技股份有限公司 微电解耦合纳米复合材料吸附的有机磷废水深度除磷方法
CN117380148A (zh) * 2023-11-15 2024-01-12 西南交通大学 一种镧、锆双金属吸附剂的制备方法及富集水体磷的方法

Also Published As

Publication number Publication date
JP5482979B2 (ja) 2014-05-07
JP2009072773A (ja) 2009-04-09

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