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WO2009028177A1 - カラートナー用バインダー樹脂およびこれを用いるカラートナー - Google Patents

カラートナー用バインダー樹脂およびこれを用いるカラートナー Download PDF

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Publication number
WO2009028177A1
WO2009028177A1 PCT/JP2008/002318 JP2008002318W WO2009028177A1 WO 2009028177 A1 WO2009028177 A1 WO 2009028177A1 JP 2008002318 W JP2008002318 W JP 2008002318W WO 2009028177 A1 WO2009028177 A1 WO 2009028177A1
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WIPO (PCT)
Prior art keywords
color toners
binder resin
molecular weight
reaction product
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/002318
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English (en)
French (fr)
Inventor
Hiroshi Matsuoka
Kazuya Sakata
Hiroyuki Takei
Kenji Uchiyama
Ichirou Sasaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
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Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Priority to JP2009529990A priority Critical patent/JP5118704B2/ja
Priority to CN2008801018626A priority patent/CN101772736B/zh
Priority to US12/675,362 priority patent/US8450039B2/en
Priority to KR1020107006863A priority patent/KR101156764B1/ko
Priority to EP08828725.5A priority patent/EP2199863B1/en
Publication of WO2009028177A1 publication Critical patent/WO2009028177A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08706—Polymers of alkenyl-aromatic compounds
    • G03G9/08708—Copolymers of styrene
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08722—Polyvinylalcohols; Polyallylalcohols; Polyvinylethers; Polyvinylaldehydes; Polyvinylketones; Polyvinylketals
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08724—Polyvinylesters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08788—Block polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08791—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by the presence of specified groups or side chains
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08795—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

　本発明によれば、少なくともカルボキシル基含有ビニル樹脂（Ｃ）、グリシジル基含有ビニル樹脂（Ｅ）、およびこれらの反応物を含み、１６０°Cにおける貯蔵弾性率Ｇ'が、測定周波数６．２８ラジアン／秒において、２０Ｐａ以上８００Ｐａ未満であり、バインダー樹脂中のテトラヒドロフラン（ＴＨＦ）可溶分が、ゲルパーミエーションクロマトグラフィー（ＧＰＣ）により測定される分子量分布において、分子量２０，０００以上４０，０００未満の領域にメインピークを有し、融点６０°C以上１２０°C以下の少なくとも１種の離型剤を、前記カルボキシル基含有ビニル樹脂（Ｃ）、前記グリシジル基含有ビニル樹脂（Ｅ）、およびこれらの反応物の合計１００質量％に対して、３．５質量％以上１２質量％以下で含む、カラートナー用バインダー樹脂が提供される。
PCT/JP2008/002318 2007-08-30 2008-08-27 カラートナー用バインダー樹脂およびこれを用いるカラートナー Ceased WO2009028177A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2009529990A JP5118704B2 (ja) 2007-08-30 2008-08-27 カラートナー用バインダー樹脂およびこれを用いるカラートナー
CN2008801018626A CN101772736B (zh) 2007-08-30 2008-08-27 彩色调色剂用粘合剂树脂及使用其的彩色调色剂
US12/675,362 US8450039B2 (en) 2007-08-30 2008-08-27 Binder resin for color toners and color toner using the same
KR1020107006863A KR101156764B1 (ko) 2007-08-30 2008-08-27 컬러 토너용 바인더 수지 및 이를 이용하는 컬러 토너
EP08828725.5A EP2199863B1 (en) 2007-08-30 2008-08-27 Binder resin for color toners and color toners made by using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007224178 2007-08-30
JP2007-224178 2007-08-30

Publications (1)

Publication Number Publication Date
WO2009028177A1 true WO2009028177A1 (ja) 2009-03-05

Family

ID=40386917

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/002318 Ceased WO2009028177A1 (ja) 2007-08-30 2008-08-27 カラートナー用バインダー樹脂およびこれを用いるカラートナー

Country Status (7)

Country Link
US (1) US8450039B2 (ja)
EP (1) EP2199863B1 (ja)
JP (1) JP5118704B2 (ja)
KR (1) KR101156764B1 (ja)
CN (1) CN101772736B (ja)
TW (1) TWI424292B (ja)
WO (1) WO2009028177A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102648439A (zh) * 2009-11-20 2012-08-22 三井化学株式会社 调色剂用粘合剂树脂、调色剂及其制造方法
WO2013176016A1 (ja) 2012-05-22 2013-11-28 三井化学株式会社 トナー用バインダー樹脂及びトナー
JP6250218B1 (ja) * 2017-06-29 2017-12-20 長瀬産業株式会社 トナー、トナーの製造方法、及び、捺染布帛の製造方法
JP2018185363A (ja) * 2017-04-24 2018-11-22 三井化学株式会社 トナー用バインダー樹脂、トナー、トナー用バインダー樹脂の製造方法およびトナーの製造方法
JP7590890B2 (ja) 2021-02-25 2024-11-27 三井化学株式会社 トナー用バインダー樹脂

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8445170B2 (en) * 2007-08-30 2013-05-21 Mitsui Chemicals, Inc. Binder resin for color toners and color toner using the same
MY170479A (en) * 2010-10-04 2019-08-06 Canon Kk Toner
JP5709065B2 (ja) 2011-10-17 2015-04-30 株式会社リコー トナー、該トナーを用いた現像剤、画像形成装置
JP2013130834A (ja) * 2011-12-22 2013-07-04 Fuji Xerox Co Ltd 電子写真用マゼンタトナー、現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置、及び、画像形成方法
JP6067981B2 (ja) * 2012-03-15 2017-01-25 シャープ株式会社 粉砕トナーの製造方法
CN111474258B (zh) * 2020-04-17 2022-09-06 湖北航天化学技术研究所 叠氮缩水甘油聚醚支化程度的测定方法

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JPS6490943A (en) 1987-09-30 1989-04-10 Matsushita Seiko Kk Indicator for calory integrating value
JPH03118552A (ja) * 1989-09-30 1991-05-21 Sekisui Chem Co Ltd トナー用樹脂組成物及びトナー
JPH06175455A (ja) * 1992-12-09 1994-06-24 Fujitsu Ltd カラー電子写真装置
JPH1069119A (ja) * 1996-08-28 1998-03-10 Konica Corp 静電荷像現像用トナー及び熱定着方法
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JPH10171162A (ja) 1996-12-12 1998-06-26 Mitsubishi Chem Corp カラートナー
JP2001188383A (ja) * 1999-12-28 2001-07-10 Canon Inc 乾式トナー
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JP2004177969A (ja) 2003-12-17 2004-06-24 Mitsubishi Chemicals Corp 画像形成方法
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JP2005266788A (ja) * 2004-02-20 2005-09-29 Canon Inc トナーの製造方法及びトナー
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Title
See also references of EP2199863A4

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102648439A (zh) * 2009-11-20 2012-08-22 三井化学株式会社 调色剂用粘合剂树脂、调色剂及其制造方法
CN102648439B (zh) * 2009-11-20 2013-11-06 三井化学株式会社 调色剂用粘合剂树脂、调色剂及其制造方法
US8586273B2 (en) 2009-11-20 2013-11-19 Mitsui Chemicals, Inc. Binder resin for toner, toner and method for producing same
WO2013176016A1 (ja) 2012-05-22 2013-11-28 三井化学株式会社 トナー用バインダー樹脂及びトナー
KR20140139592A (ko) 2012-05-22 2014-12-05 미쓰이 가가쿠 가부시키가이샤 토너용 바인더 수지 및 토너
US20150079516A1 (en) * 2012-05-22 2015-03-19 Mitsui Chemicals, Inc. Binder resin for toner and toner
JPWO2013176016A1 (ja) * 2012-05-22 2016-01-12 三井化学株式会社 トナー用バインダー樹脂及びトナー
US9594321B2 (en) 2012-05-22 2017-03-14 Mitsui Chemicals, Inc. Binder resin for toner and toner
JP2018185363A (ja) * 2017-04-24 2018-11-22 三井化学株式会社 トナー用バインダー樹脂、トナー、トナー用バインダー樹脂の製造方法およびトナーの製造方法
JP6250218B1 (ja) * 2017-06-29 2017-12-20 長瀬産業株式会社 トナー、トナーの製造方法、及び、捺染布帛の製造方法
JP7590890B2 (ja) 2021-02-25 2024-11-27 三井化学株式会社 トナー用バインダー樹脂

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EP2199863A4 (en) 2011-01-12
KR101156764B1 (ko) 2012-06-18
JPWO2009028177A1 (ja) 2010-11-25
TW200912569A (en) 2009-03-16
US8450039B2 (en) 2013-05-28
CN101772736A (zh) 2010-07-07
JP5118704B2 (ja) 2013-01-16
EP2199863A1 (en) 2010-06-23
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