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WO2009027007A3 - Method and apparatus for the production of syngas from heavy oil - Google Patents

Method and apparatus for the production of syngas from heavy oil Download PDF

Info

Publication number
WO2009027007A3
WO2009027007A3 PCT/EP2008/006439 EP2008006439W WO2009027007A3 WO 2009027007 A3 WO2009027007 A3 WO 2009027007A3 EP 2008006439 W EP2008006439 W EP 2008006439W WO 2009027007 A3 WO2009027007 A3 WO 2009027007A3
Authority
WO
WIPO (PCT)
Prior art keywords
heavy oil
soot
naphtha
syngas
pox reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/006439
Other languages
German (de)
French (fr)
Other versions
WO2009027007A2 (en
Inventor
Juergen Glaser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Publication of WO2009027007A2 publication Critical patent/WO2009027007A2/en
Publication of WO2009027007A3 publication Critical patent/WO2009027007A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/049—Composition of the impurity the impurity being carbon
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0877—Methods of cooling by direct injection of fluid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1252—Cyclic or aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Physical Water Treatments (AREA)

Abstract

The invention relates to a method and an apparatus for producing a gas (syngas) (6) containing carbon monoxide and hydrogen by partially oxidizing a charge (1) containing higher-boiling hydrocarbons (heavy oil) (11) in a gasification device (POX reactor) (R) and cooling and washing (W) the gasification product (4) obtained in the POX reactor (R). Accumulated soot-laden waste water (5) is mixed with naphtha (7) and is then introduced into a separating device (D) from which a largely soot-free water fraction (10) and a water-free naphtha/soot mixture (9) are separately withdrawn. The naphtha/soot mixture is fed to the POX reactor (R) along with the heavy oil (11) as a charge.
PCT/EP2008/006439 2007-08-24 2008-08-05 Method and apparatus for the production of syngas from heavy oil Ceased WO2009027007A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007040092.8 2007-08-24
DE200710040092 DE102007040092A1 (en) 2007-08-24 2007-08-24 Process and apparatus for producing synthesis gas from heavy oil

Publications (2)

Publication Number Publication Date
WO2009027007A2 WO2009027007A2 (en) 2009-03-05
WO2009027007A3 true WO2009027007A3 (en) 2009-04-30

Family

ID=40280222

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/006439 Ceased WO2009027007A2 (en) 2007-08-24 2008-08-05 Method and apparatus for the production of syngas from heavy oil

Country Status (3)

Country Link
DE (1) DE102007040092A1 (en)
TW (1) TW200927645A (en)
WO (1) WO2009027007A2 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992906A (en) * 1958-05-29 1961-07-18 Texaco Inc Carbon recovery method
US4205962A (en) * 1978-04-28 1980-06-03 Texaco Inc. Process for gas cleaning with reclaimed water
US4315834A (en) * 1977-11-02 1982-02-16 A.S.E.D. Process for recovering the soot formed during the production of synthesis gas by partial oxidation of hydrocarbonaceous materials
WO2000029514A1 (en) * 1998-11-16 2000-05-25 Texaco Development Corporation Removal of soot in a gasification system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992906A (en) * 1958-05-29 1961-07-18 Texaco Inc Carbon recovery method
US4315834A (en) * 1977-11-02 1982-02-16 A.S.E.D. Process for recovering the soot formed during the production of synthesis gas by partial oxidation of hydrocarbonaceous materials
US4205962A (en) * 1978-04-28 1980-06-03 Texaco Inc. Process for gas cleaning with reclaimed water
WO2000029514A1 (en) * 1998-11-16 2000-05-25 Texaco Development Corporation Removal of soot in a gasification system

Also Published As

Publication number Publication date
WO2009027007A2 (en) 2009-03-05
TW200927645A (en) 2009-07-01
DE102007040092A1 (en) 2009-02-26

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