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WO2009019919A1 - プロピレン系重合体、その製造方法、それを使用する組成物およびその用途 - Google Patents

プロピレン系重合体、その製造方法、それを使用する組成物およびその用途 Download PDF

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Publication number
WO2009019919A1
WO2009019919A1 PCT/JP2008/059058 JP2008059058W WO2009019919A1 WO 2009019919 A1 WO2009019919 A1 WO 2009019919A1 JP 2008059058 W JP2008059058 W JP 2008059058W WO 2009019919 A1 WO2009019919 A1 WO 2009019919A1
Authority
WO
WIPO (PCT)
Prior art keywords
requirement
same
propylene polymer
gpc
proportion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/059058
Other languages
English (en)
French (fr)
Inventor
Masaaki Ito
Hideshi Uchino
Yoshiyuki Ishihama
Masaru Aoki
Masato Nakano
Fusaaki Katou
Kazuo Asuka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Polypropylene Corp
Original Assignee
Japan Polypropylene Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Polypropylene Corp filed Critical Japan Polypropylene Corp
Priority to CN2008801019385A priority Critical patent/CN101772519B/zh
Priority to EP08752891A priority patent/EP2177544B1/en
Priority to US12/672,089 priority patent/US8080624B2/en
Priority to AT08752891T priority patent/ATE556095T1/de
Publication of WO2009019919A1 publication Critical patent/WO2009019919A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

　流動特性がよく、高い溶融張力、高いスウェル比を持つことにより、成形加工性に優れ、発泡成形、シート成形、ブロー成形等に好適に用いることができるプロピレン系重合体を提供する。 　下記の要件（ｉ）～（ｖｉ）を満たすことを特徴とするプロピレン系重合体等による。 　要件（ｉ）：ＭＦＲが０．１ｇ／１０分以上、１００ｇ／１０分以下である。 　要件（ｉｉ）：ＧＰＣによるＱ値が３．５以上、１０．５以下である。 　要件（ｉｉｉ）：ＧＰＣによって得られる分子量分布曲線において、分子量が２００万以上の成分の比率が０．４重量％以上、１０重量％未満である。 　要件（ｉｖ）：ＯＤＣＢによる昇温溶出分別において、４０°C以下の温度で溶出する成分が３．０重量％以下である。 　要件（ｖ）：１３Ｃ－ＮＭＲでのアイソタクチックトライアッド分率（ｍｍ）が９５％以上である。 　要件（ｖｉ）：伸長粘度の測定における歪硬化度（λｍａｘ）が６．０以上である。
PCT/JP2008/059058 2007-08-06 2008-05-16 プロピレン系重合体、その製造方法、それを使用する組成物およびその用途 Ceased WO2009019919A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2008801019385A CN101772519B (zh) 2007-08-06 2008-05-16 丙烯类聚合物、其制造方法、使用该丙烯类聚合物的组合物及其用途
EP08752891A EP2177544B1 (en) 2007-08-06 2008-05-16 Propylene polymer, process for producing the same, composition containing the same, and use thereof
US12/672,089 US8080624B2 (en) 2007-08-06 2008-05-16 Propylene-based polymer, production method therefor, composition using the same, and application thereof
AT08752891T ATE556095T1 (de) 2007-08-06 2008-05-16 Propylenpolymer, herstellungsverfahren dafür, zusammensetzung damit und verwendung davon

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007204136 2007-08-06
JP2007-204136 2007-08-06

Publications (1)

Publication Number Publication Date
WO2009019919A1 true WO2009019919A1 (ja) 2009-02-12

Family

ID=40341155

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/059058 Ceased WO2009019919A1 (ja) 2007-08-06 2008-05-16 プロピレン系重合体、その製造方法、それを使用する組成物およびその用途

Country Status (6)

Country Link
US (1) US8080624B2 (ja)
EP (1) EP2177544B1 (ja)
JP (1) JP4558066B2 (ja)
CN (1) CN101772519B (ja)
AT (1) ATE556095T1 (ja)
WO (1) WO2009019919A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009293020A (ja) * 2008-05-09 2009-12-17 Japan Polypropylene Corp 押出発泡成形用樹脂組成物およびそれを用いた発泡体
JP2009299046A (ja) * 2008-05-13 2009-12-24 Japan Polypropylene Corp メタロセン化合物を用いたプロピレン系重合体の製造方法
WO2011040555A1 (ja) 2009-09-30 2011-04-07 住友化学株式会社 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１－ヘキセンの製造方法、エチレン系重合体の製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法
JP2022024535A (ja) * 2020-07-28 2022-02-09 日本ポリプロ株式会社 分岐状プロピレン系重合体

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JP4637157B2 (ja) * 2006-11-17 2011-02-23 日本ポリプロ株式会社 プロピレン系重合体及びその製造方法
JP5342915B2 (ja) * 2008-05-13 2013-11-13 日本ポリプロ株式会社 ポリプロピレン系熱成形用シートおよびその深絞り成形体
JP4990218B2 (ja) * 2008-05-15 2012-08-01 日本ポリプロ株式会社 プロピレン系樹脂組成物およびその成形体
JP4990217B2 (ja) * 2008-05-15 2012-08-01 日本ポリプロ株式会社 プロピレン系樹脂組成物およびその成形体
JP5124517B2 (ja) * 2008-05-16 2013-01-23 日本ポリプロ株式会社 ポリプロピレン系ブロー成形体
JP5393421B2 (ja) * 2009-02-02 2014-01-22 日本ポリプロ株式会社 オレフィン重合用触媒およびその製造方法
EP2818511B1 (en) 2012-02-23 2015-10-21 Japan Polypropylene Corporation Polypropylene-based resin composition and foam sheet
JP6089765B2 (ja) 2012-02-23 2017-03-08 日本ポリプロ株式会社 ポリプロピレン系樹脂発泡シートおよび熱成形体
US8609778B1 (en) 2012-08-09 2013-12-17 Americas Styrenics, LLC Styrenic resin incorporating recycled polystyrene
US9115228B2 (en) 2012-08-09 2015-08-25 Americas Styrenics, LLC Styrenic resin having improved extensional viscosity
US9096698B2 (en) 2012-08-09 2015-08-04 Americas Styrenics, LLC Styrenic resin incorporating recycled polystyrene
CN104768980B (zh) 2012-10-31 2018-04-13 埃克森美孚化学专利公司 宽分子量分布的聚丙烯树脂
WO2014070384A1 (en) 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Articles comprising broad molecular weight distribution polypropylene resins
JP6375655B2 (ja) * 2013-03-19 2018-08-22 日本ポリプロ株式会社 繊維強化ポリプロピレン系難燃樹脂組成物及びそれを用いた成形体
JP5979047B2 (ja) * 2013-03-21 2016-08-24 日本ポリプロ株式会社 プロピレン重合用触媒およびプロピレン系重合体の製造方法
JP6398814B2 (ja) * 2014-03-20 2018-10-03 日本ポリプロ株式会社 メタロセン錯体およびオレフィン重合体の製造方法
JP6332093B2 (ja) * 2014-03-20 2018-05-30 日本ポリプロ株式会社 プロピレン系重合体
JP6561655B2 (ja) * 2014-08-08 2019-08-21 日本ポリプロ株式会社 オレフィン重合体の製造方法
CN114591523B (zh) 2016-08-09 2024-12-24 日本聚丙烯株式会社 装饰膜和使用其生产装饰成形体的方法
US10947373B2 (en) * 2016-08-18 2021-03-16 Japan Polypropylene Corporation Polypropylene resin composition for microporous film and use of polypropylene resin composition
KR102095523B1 (ko) * 2016-11-24 2020-03-31 주식회사 엘지화학 고분자의 물성을 예측하는 방법
US11390731B2 (en) 2017-07-13 2022-07-19 Exxonmobil Chemical Patents Inc. Process to produce strain hardened polypropylene
MY184007A (en) * 2017-09-21 2021-03-17 Tbm Co Ltd Thermoplastic resin composition and formed article formed by using thermoplastic resin composition
CN115556441B (zh) 2017-11-20 2025-04-11 日本聚丙烯株式会社 装饰薄膜及使用其的装饰成形体的制造方法
JP6988599B2 (ja) * 2018-03-14 2022-01-05 トヨタ自動車株式会社 解析装置
JP7322134B2 (ja) 2019-03-07 2023-08-07 株式会社クラレ エラストマー樹脂組成物、粘接着フィルム及びその製造方法、フィルム、並びに成形体
JP7211296B2 (ja) * 2019-07-19 2023-01-24 日本ポリプロ株式会社 分岐状ポリプロピレン系重合体
EP4129656A4 (en) * 2020-03-27 2024-04-03 Yupo Corporation ADHESIVE SHEET LAMINATE AND METHOD FOR MANUFACTURING THE SAME
EP4159439A4 (en) 2020-06-02 2023-12-06 Japan Polypropylene Corporation POLYPROPYLENE-BASED RESIN COMPOSITION, LAMINATE, AND METHODS OF MAKING THE SAME
WO2023026838A1 (ja) 2021-08-23 2023-03-02 日本ポリプロ株式会社 分岐状プロピレン系重合体
EP4501975A4 (en) 2022-03-24 2025-08-06 Japan Polypropylene Corp PROPYLENE-BASED BRANCHED POLYMER

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009293020A (ja) * 2008-05-09 2009-12-17 Japan Polypropylene Corp 押出発泡成形用樹脂組成物およびそれを用いた発泡体
JP2009299046A (ja) * 2008-05-13 2009-12-24 Japan Polypropylene Corp メタロセン化合物を用いたプロピレン系重合体の製造方法
WO2011040555A1 (ja) 2009-09-30 2011-04-07 住友化学株式会社 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１－ヘキセンの製造方法、エチレン系重合体の製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法
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JP7532981B2 (ja) 2020-07-28 2024-08-14 日本ポリプロ株式会社 分岐状プロピレン系重合体

Also Published As

Publication number Publication date
US8080624B2 (en) 2011-12-20
CN101772519A (zh) 2010-07-07
ATE556095T1 (de) 2012-05-15
CN101772519B (zh) 2012-07-04
EP2177544A1 (en) 2010-04-21
US20100227987A1 (en) 2010-09-09
JP4558066B2 (ja) 2010-10-06
EP2177544A4 (en) 2011-01-26
EP2177544B1 (en) 2012-05-02
JP2009057542A (ja) 2009-03-19

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