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WO2009013106A2 - Appareil réfrigérant doté d'une isolation à vide - Google Patents

Appareil réfrigérant doté d'une isolation à vide Download PDF

Info

Publication number
WO2009013106A2
WO2009013106A2 PCT/EP2008/058626 EP2008058626W WO2009013106A2 WO 2009013106 A2 WO2009013106 A2 WO 2009013106A2 EP 2008058626 W EP2008058626 W EP 2008058626W WO 2009013106 A2 WO2009013106 A2 WO 2009013106A2
Authority
WO
WIPO (PCT)
Prior art keywords
refrigerating appliance
hollow body
appliance according
glass
housing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/058626
Other languages
German (de)
English (en)
Other versions
WO2009013106A3 (fr
Inventor
Juan Antonio Calvillo
Adolf Feinauer
Sandro Kohn
Dasaradh Kumar Patchala
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BSH Hausgeraete GmbH
Original Assignee
BSH Bosch und Siemens Hausgeraete GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BSH Bosch und Siemens Hausgeraete GmbH filed Critical BSH Bosch und Siemens Hausgeraete GmbH
Priority to CN200880100004A priority Critical patent/CN101796358A/zh
Priority to EP08774738A priority patent/EP2185876A2/fr
Publication of WO2009013106A2 publication Critical patent/WO2009013106A2/fr
Publication of WO2009013106A3 publication Critical patent/WO2009013106A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2201/00Insulation
    • F25D2201/10Insulation with respect to heat
    • F25D2201/14Insulation with respect to heat using subatmospheric pressure

Definitions

  • the present invention relates to a refrigerator, in particular its thermal insulation.
  • Refrigerators currently on the market generally have a heat-insulating housing with a solid outer and inner skin that together define a cavity.
  • an insulating layer of foamed synthetic resin is produced by injecting the resin in liquid form into the cavity and allowing it to expand and set.
  • a propellant gas must be available which, for example, may have been dissolved under high pressure in the liquid synthetic resin prior to injection or is released from it after injection by a chemical reaction.
  • the bubbles formed in the synthetic resin inevitably contain the propellant, so that the insulating effect of the foam layer can not be better than that of the propellant gas itself.
  • Object of the present invention is to provide a refrigeration device that allows to maintain an excellent insulation effect for a long time.
  • the object is achieved in that in a refrigeration device with a housing surrounding a space containing a heat insulating layer containing the heat insulating layer evacuated glass hollow body.
  • Methods for producing such hollow bodies are known from US Pat. No. 4,303,431 A1 or WO 1980 000438A1.
  • Glass hollow bodies produced by these known methods can form a bed in the housing.
  • the glass hollow bodies can also be embedded in a matrix.
  • this matrix can be foamed like a conventional insulating layer of the type described above; this allows the use of the hollow glass body as an insulation-improving additive, without the need for further elaborate adjustments according to the invention to the refrigeration appliances or their production processes.
  • the hollow bodies may be arranged in a regular grid.
  • the thermal insulation layer comprises a monolayer or a small whole number of monolayers of the hollow bodies.
  • the hollow bodies may be spherical or cylindrical. In the case of cylindrical hollow body whose longitudinal axis is preferably aligned in the thickness direction of the heat insulating layer.
  • a reflective coating of the hollow body additionally reduces its heat permeability.
  • Fig. 1 is a schematic view of a refrigerator according to a first
  • FIGS. 2 to 4 show steps in the production of a housing element according to a second embodiment of the invention
  • FIG. 5 shows a section through a housing wall according to a third embodiment of the invention.
  • Fig. 1 shows in a perspective view of a refrigerator to which the present invention is applicable.
  • the refrigerator has in a conventional manner a body 1 and an attached door 2, which define an interior space 3.
  • Carcass 1 and door 2 are each hollow body with a one-piece plastic deep-drawn inner wall and a one-piece or assembled from a plurality of plate-shaped elements outer wall.
  • a circumferential groove 4 is formed, which is provided to anchor therein in a conventional manner a magnetic seal (not shown). Two openings at the bottom of the groove 4, which are covered by the attachment of the magnetic seal of this, can be used to fill the inner cavity of the door 2 with a heat-insulating filling of evacuated glass beads.
  • the glass spheres which have different diameters in the millimeter - A -
  • An alternative way to isolate a refrigerator with the design shown in Fig. 1 using evacuated glass beads is to mix them with a in a conventional manner injected into the cavities of the body 1 and door 2 resin and mixed with the glass beads To inject resin, in particular polyurethane resin, in the cavities of the body 1 and door 2 and to let expand it. Thus, a foam filling is obtained in the cavities, the insulating effect is improved by the proportion of evacuated glass beads contained therein.
  • the housing of the refrigerating appliance can also be composed of a plurality of plate-shaped panels, one of which forms the door, a side wall, ceiling, floor or rear wall of the body 1.
  • Fig. 2 shows a plurality of such glass balls 7 distributed in a flat shell 8, whose dimensions correspond to those of the door 2 or a wall of the body 1.
  • the number of glass beads 7 is dimensioned so that they lie close to each other in a closed position covering the bottom of the shell 8 and thus form an arrangement in the form of a regular grid with square cells in the case shown here.
  • a thin plate or foil 9 made of synthetic resin is placed, as can be seen in Fig. 3, which shows a partial section through the shell 8, and on the resin plate 9 is another layer 10 'of glass beads. 7 applied close to each other. This process can be repeated as many times as necessary to obtain a desired layer thickness.
  • the resulting stack of glass spheres 7 and resin plates 9 is heated to expand the synthetic resin plates 9 to soften and adhere to the glass beads 7, and possibly expand depending on the material used for the plates 9.
  • Fig. 4 shows the state of the composite after expanding the plate 9; Gaps 11 between the glass balls 7 are essentially filled by the synthetic resin material of the plate 9, so that the glass balls 7 are firmly bound in the synthetic resin material and heat transfer by air flow in the spaces 1 1 between the glass balls 7 is largely excluded.
  • the composite of Fig. 4 can be removed from the shell 8 and provided with a protective sheath, or it can be the shell 8 used as a shell of the panel.
  • the glass spheres In order to provide an ideally efficient insulation, it is desirable to minimize the volume of the spaces 11 between the evacuated glass spheres 7. For this purpose, the glass spheres must be replaced by hollow bodies of another, a given hollow volume efficient filling shape.
  • FIG. 12 A section through an insulation panel with such cylindrical glass hollow bodies 12 is shown in FIG.
  • the hollow bodies 12 of uniform dimensions are each aligned with their longitudinal axis perpendicular to the outer and inner walls 13 and 14 of the panel and extend substantially over the entire width of the space between the walls 13, 14.
  • a regular grid can be obtained, for example, by the hollow body 12 first on one or two sides, as shown in Fig. 6, attached to a synthetic resin tape 15, from the strips thus obtained are cut in a dimension of the desired panel of corresponding length and these strips are stacked as shown in the section of Fig. 7 so as to successively construct the panel.
  • the hollow body 12 can be generated as the hollow balls 7 by first by blowing metal vapor into a molten glass filled with the metal vapor
  • Tube is formed and the tube in the still molten state with a
  • Cross-flow is blown to make him locally to contract and constricting into individual hollow body. During cooling, the beats
  • Metal vapor is then deposited as a reflective layer 16 on the inner walls of the hollow body and leaves in the interior of a vacuum.
  • the mirror layer 16 is an additional obstacle to the propagation of thermal radiation and thus improves the insulation capacity of the hollow body in addition.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Refrigerator Housings (AREA)
  • Thermal Insulation (AREA)
  • Building Environments (AREA)

Abstract

L'invention concerne un appareil réfrigérant comprenant une enceinte entourant un espace interne et présentant une couche d'isolation thermique, ladite couche d'isolation thermique contenant des corps creux en verre (12) sous vide.
PCT/EP2008/058626 2007-07-24 2008-07-03 Appareil réfrigérant doté d'une isolation à vide Ceased WO2009013106A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN200880100004A CN101796358A (zh) 2007-07-24 2008-07-03 具有真空绝热的制冷单元
EP08774738A EP2185876A2 (fr) 2007-07-24 2008-07-03 Appareil refrigerant dote d'une isolation a vide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007034298.7 2007-07-24
DE200710034298 DE102007034298A1 (de) 2007-07-24 2007-07-24 Kältegerät mit Vakuumisolation

Publications (2)

Publication Number Publication Date
WO2009013106A2 true WO2009013106A2 (fr) 2009-01-29
WO2009013106A3 WO2009013106A3 (fr) 2009-06-18

Family

ID=40157103

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/058626 Ceased WO2009013106A2 (fr) 2007-07-24 2008-07-03 Appareil réfrigérant doté d'une isolation à vide

Country Status (5)

Country Link
EP (1) EP2185876A2 (fr)
CN (1) CN101796358A (fr)
DE (1) DE102007034298A1 (fr)
RU (1) RU2010103937A (fr)
WO (1) WO2009013106A2 (fr)

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017099997A1 (fr) * 2015-12-08 2017-06-15 Whirlpool Corporation Structure isolante dotée d'élément isolant et procédé pour leur fabrication
WO2017100034A1 (fr) * 2015-12-08 2017-06-15 Whirlpool Corporation Structures d'isolation sous vide avec une charge isolante
US9835369B2 (en) 2012-04-02 2017-12-05 Whirlpool Corporation Vacuum insulated structure tubular cabinet construction
US9833942B2 (en) 2012-04-11 2017-12-05 Whirlpool Corporation Method to create vacuum insulated cabinets for refrigerators
US9840042B2 (en) 2015-12-22 2017-12-12 Whirlpool Corporation Adhesively secured vacuum insulated panels for refrigerators
US10018406B2 (en) 2015-12-28 2018-07-10 Whirlpool Corporation Multi-layer gas barrier materials for vacuum insulated structure
US10030905B2 (en) 2015-12-29 2018-07-24 Whirlpool Corporation Method of fabricating a vacuum insulated appliance structure
US10041724B2 (en) 2015-12-08 2018-08-07 Whirlpool Corporation Methods for dispensing and compacting insulation materials into a vacuum sealed structure
US10052819B2 (en) 2014-02-24 2018-08-21 Whirlpool Corporation Vacuum packaged 3D vacuum insulated door structure and method therefor using a tooling fixture
WO2018164668A1 (fr) * 2017-03-07 2018-09-13 Whirlpool Corporation Procédés de fabrication d'un matériau noyau super isolant pour une structure d'isolation sous vide
US10105931B2 (en) 2014-02-24 2018-10-23 Whirlpool Corporation Multi-section core vacuum insulation panels with hybrid barrier film envelope
US10161669B2 (en) 2015-03-05 2018-12-25 Whirlpool Corporation Attachment arrangement for vacuum insulated door
US10222116B2 (en) 2015-12-08 2019-03-05 Whirlpool Corporation Method and apparatus for forming a vacuum insulated structure for an appliance having a pressing mechanism incorporated within an insulation delivery system
US10345031B2 (en) 2015-07-01 2019-07-09 Whirlpool Corporation Split hybrid insulation structure for an appliance
US10365030B2 (en) 2015-03-02 2019-07-30 Whirlpool Corporation 3D vacuum panel and a folding approach to create the 3D vacuum panel from a 2D vacuum panel of non-uniform thickness
US10422569B2 (en) 2015-12-21 2019-09-24 Whirlpool Corporation Vacuum insulated door construction
US10429125B2 (en) 2015-12-08 2019-10-01 Whirlpool Corporation Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein
US10598424B2 (en) 2016-12-02 2020-03-24 Whirlpool Corporation Hinge support assembly
US10610985B2 (en) 2015-12-28 2020-04-07 Whirlpool Corporation Multilayer barrier materials with PVD or plasma coating for vacuum insulated structure
US10712080B2 (en) 2016-04-15 2020-07-14 Whirlpool Corporation Vacuum insulated refrigerator cabinet
US10731915B2 (en) 2015-03-11 2020-08-04 Whirlpool Corporation Self-contained pantry box system for insertion into an appliance
US10807298B2 (en) 2015-12-29 2020-10-20 Whirlpool Corporation Molded gas barrier parts for vacuum insulated structure
US10808987B2 (en) 2015-12-09 2020-10-20 Whirlpool Corporation Vacuum insulation structures with multiple insulators
US10907891B2 (en) 2019-02-18 2021-02-02 Whirlpool Corporation Trim breaker for a structural cabinet that incorporates a structural glass contact surface
US10907888B2 (en) 2018-06-25 2021-02-02 Whirlpool Corporation Hybrid pigmented hot stitched color liner system
US11009284B2 (en) 2016-04-15 2021-05-18 Whirlpool Corporation Vacuum insulated refrigerator structure with three dimensional characteristics
US11052579B2 (en) 2015-12-08 2021-07-06 Whirlpool Corporation Method for preparing a densified insulation material for use in appliance insulated structure
US11175090B2 (en) 2016-12-05 2021-11-16 Whirlpool Corporation Pigmented monolayer liner for appliances and methods of making the same
US11247369B2 (en) 2015-12-30 2022-02-15 Whirlpool Corporation Method of fabricating 3D vacuum insulated refrigerator structure having core material
US11320193B2 (en) 2016-07-26 2022-05-03 Whirlpool Corporation Vacuum insulated structure trim breaker
US11320194B2 (en) 2019-04-30 2022-05-03 Whirlpool Corporation Barrier layer for insulated structures
US11391506B2 (en) 2016-08-18 2022-07-19 Whirlpool Corporation Machine compartment for a vacuum insulated structure
CN117646498A (zh) * 2023-12-28 2024-03-05 山东广泰声学新材料技术有限公司 一种节能隔音建筑材料及其制备方法
US11994336B2 (en) 2015-12-09 2024-05-28 Whirlpool Corporation Vacuum insulated structure with thermal bridge breaker with heat loop
US12070924B2 (en) 2020-07-27 2024-08-27 Whirlpool Corporation Appliance liner having natural fibers

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US948541A (en) 1908-03-23 1910-02-08 Clyde J Coleman Heat-insulating wall.
WO1980000438A1 (fr) 1978-08-28 1980-03-20 Leonard B Torobin Methode et appareil de production de microspheres creuses
US4303431A (en) 1979-07-20 1981-12-01 Torobin Leonard B Method and apparatus for producing hollow microspheres
US5171346A (en) 1991-01-22 1992-12-15 Aktiebolaget Electrolux Method of forming a composite thermal insulating material
WO2008047334A1 (fr) 2006-10-17 2008-04-24 Kingspan Research And Developments Limited Matériau isolant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US948541A (en) 1908-03-23 1910-02-08 Clyde J Coleman Heat-insulating wall.
WO1980000438A1 (fr) 1978-08-28 1980-03-20 Leonard B Torobin Methode et appareil de production de microspheres creuses
US4303431A (en) 1979-07-20 1981-12-01 Torobin Leonard B Method and apparatus for producing hollow microspheres
US5171346A (en) 1991-01-22 1992-12-15 Aktiebolaget Electrolux Method of forming a composite thermal insulating material
WO2008047334A1 (fr) 2006-10-17 2008-04-24 Kingspan Research And Developments Limited Matériau isolant

Cited By (67)

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US10746458B2 (en) 2012-04-02 2020-08-18 Whirlpool Corporation Method of making a folded vacuum insulated structure
US9835369B2 (en) 2012-04-02 2017-12-05 Whirlpool Corporation Vacuum insulated structure tubular cabinet construction
US10663217B2 (en) 2012-04-02 2020-05-26 Whirlpool Corporation Vacuum insulated structure tubular cabinet construction
US9874394B2 (en) 2012-04-02 2018-01-23 Whirlpool Corporation Method of making a folded vacuum insulated structure
US9885516B2 (en) 2012-04-02 2018-02-06 Whirlpool Corporation Vacuum insulated door structure and method for the creation thereof
US10697697B2 (en) 2012-04-02 2020-06-30 Whirlpool Corporation Vacuum insulated door structure and method for the creation thereof
US10350817B2 (en) 2012-04-11 2019-07-16 Whirlpool Corporation Method to create vacuum insulated cabinets for refrigerators
US9833942B2 (en) 2012-04-11 2017-12-05 Whirlpool Corporation Method to create vacuum insulated cabinets for refrigerators
US10105931B2 (en) 2014-02-24 2018-10-23 Whirlpool Corporation Multi-section core vacuum insulation panels with hybrid barrier film envelope
US10052819B2 (en) 2014-02-24 2018-08-21 Whirlpool Corporation Vacuum packaged 3D vacuum insulated door structure and method therefor using a tooling fixture
US10828844B2 (en) 2014-02-24 2020-11-10 Whirlpool Corporation Vacuum packaged 3D vacuum insulated door structure and method therefor using a tooling fixture
US10365030B2 (en) 2015-03-02 2019-07-30 Whirlpool Corporation 3D vacuum panel and a folding approach to create the 3D vacuum panel from a 2D vacuum panel of non-uniform thickness
US10161669B2 (en) 2015-03-05 2018-12-25 Whirlpool Corporation Attachment arrangement for vacuum insulated door
US11243021B2 (en) 2015-03-05 2022-02-08 Whirlpool Corporation Attachment arrangement for vacuum insulated door
US11713916B2 (en) 2015-03-05 2023-08-01 Whirlpool Corporation Attachment arrangement for vacuum insulated door
US10731915B2 (en) 2015-03-11 2020-08-04 Whirlpool Corporation Self-contained pantry box system for insertion into an appliance
US10345031B2 (en) 2015-07-01 2019-07-09 Whirlpool Corporation Split hybrid insulation structure for an appliance
US10907886B2 (en) 2015-12-08 2021-02-02 Whirlpool Corporation Methods for dispensing and compacting insulation materials into a vacuum sealed structure
US10041724B2 (en) 2015-12-08 2018-08-07 Whirlpool Corporation Methods for dispensing and compacting insulation materials into a vacuum sealed structure
US10422573B2 (en) 2015-12-08 2019-09-24 Whirlpool Corporation Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein
US10429125B2 (en) 2015-12-08 2019-10-01 Whirlpool Corporation Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein
US11009288B2 (en) 2015-12-08 2021-05-18 Whirlpool Corporation Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein
US12202175B2 (en) 2015-12-08 2025-01-21 Whirlpool Corporation Method for preparing a densified insulation material for use in appliance insulated structure
US10605519B2 (en) 2015-12-08 2020-03-31 Whirlpool Corporation Methods for dispensing and compacting insulation materials into a vacuum sealed structure
US11691318B2 (en) 2015-12-08 2023-07-04 Whirlpool Corporation Method for preparing a densified insulation material for use in appliance insulated structure
US10222116B2 (en) 2015-12-08 2019-03-05 Whirlpool Corporation Method and apparatus for forming a vacuum insulated structure for an appliance having a pressing mechanism incorporated within an insulation delivery system
WO2017099997A1 (fr) * 2015-12-08 2017-06-15 Whirlpool Corporation Structure isolante dotée d'élément isolant et procédé pour leur fabrication
WO2017100034A1 (fr) * 2015-12-08 2017-06-15 Whirlpool Corporation Structures d'isolation sous vide avec une charge isolante
US11052579B2 (en) 2015-12-08 2021-07-06 Whirlpool Corporation Method for preparing a densified insulation material for use in appliance insulated structure
US11994337B2 (en) 2015-12-09 2024-05-28 Whirlpool Corporation Vacuum insulation structures with multiple insulators
US10808987B2 (en) 2015-12-09 2020-10-20 Whirlpool Corporation Vacuum insulation structures with multiple insulators
US11994336B2 (en) 2015-12-09 2024-05-28 Whirlpool Corporation Vacuum insulated structure with thermal bridge breaker with heat loop
US11555643B2 (en) 2015-12-09 2023-01-17 Whirlpool Corporation Vacuum insulation structures with multiple insulators
US10422569B2 (en) 2015-12-21 2019-09-24 Whirlpool Corporation Vacuum insulated door construction
US10914505B2 (en) 2015-12-21 2021-02-09 Whirlpool Corporation Vacuum insulated door construction
US9840042B2 (en) 2015-12-22 2017-12-12 Whirlpool Corporation Adhesively secured vacuum insulated panels for refrigerators
US10018406B2 (en) 2015-12-28 2018-07-10 Whirlpool Corporation Multi-layer gas barrier materials for vacuum insulated structure
US10610985B2 (en) 2015-12-28 2020-04-07 Whirlpool Corporation Multilayer barrier materials with PVD or plasma coating for vacuum insulated structure
US10514198B2 (en) 2015-12-28 2019-12-24 Whirlpool Corporation Multi-layer gas barrier materials for vacuum insulated structure
US10807298B2 (en) 2015-12-29 2020-10-20 Whirlpool Corporation Molded gas barrier parts for vacuum insulated structure
US10030905B2 (en) 2015-12-29 2018-07-24 Whirlpool Corporation Method of fabricating a vacuum insulated appliance structure
US11577446B2 (en) 2015-12-29 2023-02-14 Whirlpool Corporation Molded gas barrier parts for vacuum insulated structure
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WO2018164668A1 (fr) * 2017-03-07 2018-09-13 Whirlpool Corporation Procédés de fabrication d'un matériau noyau super isolant pour une structure d'isolation sous vide
US10907888B2 (en) 2018-06-25 2021-02-02 Whirlpool Corporation Hybrid pigmented hot stitched color liner system
US11543172B2 (en) 2019-02-18 2023-01-03 Whirlpool Corporation Trim breaker for a structural cabinet that incorporates a structural glass contact surface
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US11686525B2 (en) 2019-04-30 2023-06-27 Whirlpool Corporation Barrier layer for insulated structures
US12070924B2 (en) 2020-07-27 2024-08-27 Whirlpool Corporation Appliance liner having natural fibers
CN117646498A (zh) * 2023-12-28 2024-03-05 山东广泰声学新材料技术有限公司 一种节能隔音建筑材料及其制备方法

Also Published As

Publication number Publication date
RU2010103937A (ru) 2011-08-27
CN101796358A (zh) 2010-08-04
WO2009013106A3 (fr) 2009-06-18
DE102007034298A1 (de) 2009-01-29
EP2185876A2 (fr) 2010-05-19

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