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WO2009004239A3 - Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co - Google Patents

Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co Download PDF

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Publication number
WO2009004239A3
WO2009004239A3 PCT/FR2008/051072 FR2008051072W WO2009004239A3 WO 2009004239 A3 WO2009004239 A3 WO 2009004239A3 FR 2008051072 W FR2008051072 W FR 2008051072W WO 2009004239 A3 WO2009004239 A3 WO 2009004239A3
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WO
WIPO (PCT)
Prior art keywords
gaseous
gaseous effluents
essentially containing
oxidation
dihydrogen
Prior art date
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Ceased
Application number
PCT/FR2008/051072
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English (en)
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WO2009004239A2 (fr
Inventor
H Raymond Guyomarc
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Bio3D Applications
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Bio3D Applications
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Publication date
Application filed by Bio3D Applications filed Critical Bio3D Applications
Priority to JP2010511712A priority Critical patent/JP2010531214A/ja
Priority to US12/664,211 priority patent/US20110165056A1/en
Priority to EP08806007A priority patent/EP2212241A2/fr
Priority to CA2690743A priority patent/CA2690743A1/fr
Publication of WO2009004239A2 publication Critical patent/WO2009004239A2/fr
Publication of WO2009004239A3 publication Critical patent/WO2009004239A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/042—Decomposition of water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/40—Carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/34—Grates; Mechanical ash-removing devices
    • C10J3/36—Fixed grates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1853—Steam reforming, i.e. injection of steam only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'invention concerne un procédé de traitement d'un premier effluent gazeux (11) comprenant essentiellement du dioxyde de carbone (CO2) et d'un deuxième effluent gazeux (21) comprenant essentiellement de la vapeur d'eau (H2O), ledit procédé comprenant les étapes suivantes : génération d'un premier flux gazeux (12) comprenant du monoxyde de carbone (CO) par passage dudit premier effluent gazeux (11) au travers d'une première couche de matière réactive oxydoréductrice (101) comprenant des éléments de carbone à haute température; génération d'un deuxième flux gazeux (22) comprenant essentiellement du dihydrogène (H2) par passage dudit deuxième effluent gazeux (21) au travers d'une deuxième couche oxydoréductrice de matière réactive (201) comprenant des éléments de carbone à haute température; et valorisation d'au moins l'un des premier et deuxième flux gazeux (12, 22). Le procédé peut en outre comprendre une synthèse de molécules hydrocarbonées (HC) à partir du dihydrogène (H2) et du monoxyde de carbone (CO). L'invention concerne en outre un système mettant en œuvre le procédé selon l'invention.
PCT/FR2008/051072 2007-06-15 2008-06-16 Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co Ceased WO2009004239A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2010511712A JP2010531214A (ja) 2007-06-15 2008-06-16 Ｈ２及びｃｏを別々に生成するためのガス廃棄物の処理方法並びにシステム
US12/664,211 US20110165056A1 (en) 2007-06-15 2008-06-16 Method and system for processing gaseous effluents for independently producing h2 and co
EP08806007A EP2212241A2 (fr) 2007-06-15 2008-06-16 Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co
CA2690743A CA2690743A1 (fr) 2007-06-15 2008-06-16 Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0704304A FR2917399A1 (fr) 2007-06-15 2007-06-15 Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co
FR0704304 2007-06-15

Publications (2)

Publication Number Publication Date
WO2009004239A2 WO2009004239A2 (fr) 2009-01-08
WO2009004239A3 true WO2009004239A3 (fr) 2009-02-26

Family

ID=39004780

Family Applications (1)

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PCT/FR2008/051072 Ceased WO2009004239A2 (fr) 2007-06-15 2008-06-16 Procede et systeme de traitement d'effluents gazeux pour produire independamment h2 et co

Country Status (7)

Country Link
US (1) US20110165056A1 (fr)
EP (1) EP2212241A2 (fr)
JP (1) JP2010531214A (fr)
CA (1) CA2690743A1 (fr)
FR (1) FR2917399A1 (fr)
RU (1) RU2010101050A (fr)
WO (1) WO2009004239A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2955865B1 (fr) * 2010-02-01 2012-03-16 Cotaver Procede de recyclage du dioxyde de carbone (co2)
ITMI20120857A1 (it) * 2012-05-17 2013-11-18 Greengate Srl Generatore di gas di sintesi
KR102251314B1 (ko) * 2018-03-30 2021-05-12 한국화학연구원 가역적 산화-환원 변환제를 사용하여 이산화탄소 및 물로부터 일산화탄소와 수소를 생산하는 시스템 및 그 방법
CN115899751B (zh) * 2022-11-10 2025-09-12 中国石油化工股份有限公司 一种联产合成气的富氧燃烧加热炉系统及运行方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1980002150A1 (fr) * 1979-04-04 1980-10-16 Oliveira E De Procede de preparation de gaz de synthese
BE902904A (fr) * 1985-07-15 1985-11-04 Godrie Paul G Procedes de fabrication de combustibles ou de reactifs h2-co-co2 pour l'industrie chimique
WO2002048292A1 (fr) * 2000-12-11 2002-06-20 Hyun Yong Kim Procede de gazeification de matieres carbonees et appareil correspondant
US6565824B1 (en) * 2000-10-16 2003-05-20 Gene E. Lightner Production of carbon monoxide from carbon dioxide and carbon
DE10317084A1 (de) * 2002-04-13 2004-10-21 Jeschar, Rudolf, Prof. Dr.-Ing. Dr.-Ing. E.h. Verfahren zur energetischen und stofflichen Verwertung von Reststoffen unter Einsatz von Kaskadenreaktoren
FR2854887A1 (fr) * 2003-05-14 2004-11-19 Bio 3D Applic Systeme et procede pour recycler thermiquement des dechets, et application de ce systeme au traitement de dechets a forte teneur en eau
US20070012229A1 (en) * 2005-07-15 2007-01-18 Jc Enviro Enterprises Corp. Method and apparatus for generating combustible synthesis gas
CN1900241A (zh) * 2006-06-21 2007-01-24 广西大学 外源高温co2与生物质还原反应制取可燃气体的工艺

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1980002150A1 (fr) * 1979-04-04 1980-10-16 Oliveira E De Procede de preparation de gaz de synthese
BE902904A (fr) * 1985-07-15 1985-11-04 Godrie Paul G Procedes de fabrication de combustibles ou de reactifs h2-co-co2 pour l'industrie chimique
US6565824B1 (en) * 2000-10-16 2003-05-20 Gene E. Lightner Production of carbon monoxide from carbon dioxide and carbon
WO2002048292A1 (fr) * 2000-12-11 2002-06-20 Hyun Yong Kim Procede de gazeification de matieres carbonees et appareil correspondant
DE10317084A1 (de) * 2002-04-13 2004-10-21 Jeschar, Rudolf, Prof. Dr.-Ing. Dr.-Ing. E.h. Verfahren zur energetischen und stofflichen Verwertung von Reststoffen unter Einsatz von Kaskadenreaktoren
FR2854887A1 (fr) * 2003-05-14 2004-11-19 Bio 3D Applic Systeme et procede pour recycler thermiquement des dechets, et application de ce systeme au traitement de dechets a forte teneur en eau
US20070012229A1 (en) * 2005-07-15 2007-01-18 Jc Enviro Enterprises Corp. Method and apparatus for generating combustible synthesis gas
CN1900241A (zh) * 2006-06-21 2007-01-24 广西大学 外源高温co2与生物质还原反应制取可燃气体的工艺

Also Published As

Publication number Publication date
FR2917399A1 (fr) 2008-12-19
RU2010101050A (ru) 2011-07-20
EP2212241A2 (fr) 2010-08-04
WO2009004239A2 (fr) 2009-01-08
JP2010531214A (ja) 2010-09-24
US20110165056A1 (en) 2011-07-07
CA2690743A1 (fr) 2009-01-08

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