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WO2009001783A1 - ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法 - Google Patents

ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法 Download PDF

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Publication number
WO2009001783A1
WO2009001783A1 PCT/JP2008/061354 JP2008061354W WO2009001783A1 WO 2009001783 A1 WO2009001783 A1 WO 2009001783A1 JP 2008061354 W JP2008061354 W JP 2008061354W WO 2009001783 A1 WO2009001783 A1 WO 2009001783A1
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WO
WIPO (PCT)
Prior art keywords
polyol
production
fat
polyurethane foam
natural oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/061354
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English (en)
French (fr)
Inventor
Takayuki Sasaki
Yasuyuki Sasao
Naohiro Kumagai
Chitoshi Suzuki
Shigeru Ikai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to CN200880021120A priority Critical patent/CN101679538A/zh
Priority to EP08765774A priority patent/EP2161289A4/en
Priority to JP2009520562A priority patent/JP5201141B2/ja
Publication of WO2009001783A1 publication Critical patent/WO2009001783A1/ja
Priority to US12/644,043 priority patent/US8642668B2/en
Anticipated expiration legal-status Critical
Priority to US14/136,002 priority patent/US20140113985A1/en
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/638—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the use of compounds having carbon-to-carbon double bonds other than styrene and/or olefinic nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/06—Flexible foams

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyethers (AREA)

Abstract

　従来の軟質ポリウレタンフォームよりもバイオマス度が高く、かつフォーム物性および外観が良好な軟質ポリウレタンフォームの製造方法を提供する。 　下記天然油脂由来ポリオール（ａ１）および／または下記ポリオキシアルキレンポリオール（ａ２）の存在下に、ビニル系モノマーを重合して得られたポリマー分散ポリオールを用いる。天然油脂由来ポリオール（ａ１）：天然油脂に化学反応を用いて水酸基を付与してなり、水酸基価が２０～２５０ｍｇＫＯＨ／ｇであり、かつ分子量分布が１．２以上である天然油脂由来ポリオール。ポリオキシアルキレンポリオール（ａ２）：配位アニオン重合触媒およびカチオン重合触媒からなる群から選ばれる１種以上の重合触媒（ｂ）の存在下に、前記天然油脂由来ポリオール（ａ１）にアルキレンオキシド（ｃ）を開環重合させたポリオキシアルキレンポリオール。
PCT/JP2008/061354 2007-06-22 2008-06-20 ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法 Ceased WO2009001783A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN200880021120A CN101679538A (zh) 2007-06-22 2008-06-20 分散有聚合物的多元醇及软质聚氨酯泡沫的制造方法
EP08765774A EP2161289A4 (en) 2007-06-22 2008-06-20 PROCESS FOR PREPARING POLYMER-DISPERSED POLYOL AND METHOD FOR PRODUCING FLEXIBLE POLYURETHANEUM FOAM
JP2009520562A JP5201141B2 (ja) 2007-06-22 2008-06-20 ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法
US12/644,043 US8642668B2 (en) 2007-06-22 2009-12-22 Polymer-dispersed polyol and process for producing flexible polyurethane foam
US14/136,002 US20140113985A1 (en) 2007-06-22 2013-12-20 Polymer-dispersed polyol and process for producing flexible polyurethane foam

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007165014 2007-06-22
JP2007-165014 2007-06-22

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/644,043 Continuation US8642668B2 (en) 2007-06-22 2009-12-22 Polymer-dispersed polyol and process for producing flexible polyurethane foam

Publications (1)

Publication Number Publication Date
WO2009001783A1 true WO2009001783A1 (ja) 2008-12-31

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PCT/JP2008/061354 Ceased WO2009001783A1 (ja) 2007-06-22 2008-06-20 ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法

Country Status (7)

Country Link
US (2) US8642668B2 (ja)
EP (1) EP2161289A4 (ja)
JP (1) JP5201141B2 (ja)
KR (1) KR20100033971A (ja)
CN (1) CN101679538A (ja)
TW (1) TW200911860A (ja)
WO (1) WO2009001783A1 (ja)

Cited By (10)

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JP2009035617A (ja) * 2007-08-01 2009-02-19 Inoac Corp 軟質ポリウレタン発泡体
WO2010055631A1 (ja) * 2008-11-11 2010-05-20 三洋化成工業株式会社 膜モジュールのウレタン樹脂シール材用ポリマーポリオール
JP2010150547A (ja) * 2008-12-23 2010-07-08 Bayer Material Science Llc 天然油ベースポリオールを含むポリマーポリオール、該ポリマーポリオールを含むポリウレタンフォーム、およびその製造方法
JP2010162447A (ja) * 2009-01-14 2010-07-29 Sanyo Chem Ind Ltd 膜モジュールのシール材用ポリウレタン樹脂形成性組成物
JP2011038013A (ja) * 2009-08-12 2011-02-24 Musashi Toryo Kk ビニル変性ポリエステルポリオール、二液硬化型塗料組成物および硬化物
JP2011511131A (ja) * 2008-02-01 2011-04-07 ダウ グローバル テクノロジーズ インコーポレイティド 天然油系コポリマーポリオール及び天然油系コポリマーポリオールから作製されるポリウレタン製造物
WO2011043343A1 (ja) 2009-10-05 2011-04-14 旭硝子株式会社 ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法
JP2011098310A (ja) * 2009-11-09 2011-05-19 Sanyo Chem Ind Ltd 膜モジュールのウレタン樹脂シール材用ポリマーポリオール
KR20120024654A (ko) * 2009-05-11 2012-03-14 드리테 파텐트포트폴리오 베타일리궁스게젤샤프트 엠베하 운트 코. 카게 반응성 희석제에서 중합체 입자의 비-수성 분산액
JP2024002575A (ja) * 2022-06-24 2024-01-11 株式会社イノアックコーポレーション ポリウレタンフォーム

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CN101809053B (zh) * 2007-09-28 2012-09-26 旭硝子株式会社 软质聚氨酯泡沫及热压成形品的制造方法以及热压成形品
GB0903717D0 (en) * 2009-03-04 2009-04-15 Innochem Ltd Flexible polyurethane foam
WO2012027114A1 (en) * 2010-08-24 2012-03-01 Dow Global Technologies Llc Method for making resilient low density polyurethane foam having low compression sets
WO2016064698A1 (en) 2014-10-22 2016-04-28 Dow Global Technologies Llc Dual catalyst system for high primary hydroxyl polyols
KR101896769B1 (ko) * 2016-08-31 2018-09-07 현대자동차주식회사 폴리우레탄 필터 폼
WO2018089967A1 (en) 2016-11-14 2018-05-17 Virginia Commonwealth University Inhibitors of cancer invasion, attachment, and/or metastasis
US10793692B2 (en) * 2018-10-24 2020-10-06 Covestro Llc Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers
US11572433B2 (en) 2021-03-12 2023-02-07 Covestro Llc In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
US11718705B2 (en) 2021-07-28 2023-08-08 Covestro Llc In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams
KR102876422B1 (ko) 2024-10-28 2025-10-27 금강침대 주식회사 대두기반 폴리올을 이용한 친환경 침대용 매트리스 폼의 제조방법

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009035617A (ja) * 2007-08-01 2009-02-19 Inoac Corp 軟質ポリウレタン発泡体
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KR101681794B1 (ko) * 2009-05-11 2016-12-01 드리테 파텐트포트폴리오 베타일리궁스게젤샤프트 엠베하 운트 코. 카게 반응성 희석제에서 중합체 입자의 비-수성 분산액
JP2011038013A (ja) * 2009-08-12 2011-02-24 Musashi Toryo Kk ビニル変性ポリエステルポリオール、二液硬化型塗料組成物および硬化物
WO2011043343A1 (ja) 2009-10-05 2011-04-14 旭硝子株式会社 ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法
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CN102549022A (zh) * 2009-10-05 2012-07-04 旭硝子株式会社 聚合物分散多元醇及软质聚氨酯泡沫塑料的制造方法
JP2011098310A (ja) * 2009-11-09 2011-05-19 Sanyo Chem Ind Ltd 膜モジュールのウレタン樹脂シール材用ポリマーポリオール
JP2024002575A (ja) * 2022-06-24 2024-01-11 株式会社イノアックコーポレーション ポリウレタンフォーム
JP7766559B2 (ja) 2022-06-24 2025-11-10 株式会社イノアックコーポレーション ポリウレタンフォーム及び寝具

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EP2161289A4 (en) 2010-07-07
US20100096768A1 (en) 2010-04-22
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KR20100033971A (ko) 2010-03-31
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