[go: up one dir, main page]

WO2009090710A1 - Composition de résine chlorovinylique non expansible - Google Patents

Composition de résine chlorovinylique non expansible Download PDF

Info

Publication number
WO2009090710A1
WO2009090710A1 PCT/JP2008/003740 JP2008003740W WO2009090710A1 WO 2009090710 A1 WO2009090710 A1 WO 2009090710A1 JP 2008003740 W JP2008003740 W JP 2008003740W WO 2009090710 A1 WO2009090710 A1 WO 2009090710A1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
vinyl chloride
chloride resin
resin composition
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/003740
Other languages
English (en)
Japanese (ja)
Inventor
Kiyotatsu Iwanami
Ken Nishihara
Kazumasa Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adeka Corp
Original Assignee
Adeka Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adeka Corp filed Critical Adeka Corp
Publication of WO2009090710A1 publication Critical patent/WO2009090710A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59

Definitions

  • the present invention relates to a non-foaming vinyl chloride resin composition, and particularly to a non-foaming vinyl chloride resin composition having excellent heat resistance and color resistance.
  • Chlorine-containing resins such as vinyl chloride resin are used in various fields because they are excellent in flame retardancy and chemical resistance. However, since chlorine-containing resins are thermally decomposed to generate hydrogen chloride, they have the disadvantage that the mechanical strength is reduced and coloring occurs and the commercial value is impaired.
  • ultraviolet absorbers such as organic phosphite compounds, epoxy compounds, phenolic antioxidants, benzophenone or benzotriazoles, Various additives such as hindered amine light stabilizers are combined and used as a stabilizing aid for improving resistance to light, heat, oxidation and the like.
  • Various additives such as hindered amine light stabilizers are combined and used as a stabilizing aid for improving resistance to light, heat, oxidation and the like.
  • Patent Document 1 describes that a Ca-Zn stabilizer and a higher fatty acid potassium salt are used in combination.
  • Patent Document 1 describes that a Ca-Zn stabilizer and a higher fatty acid potassium salt are used in combination.
  • the system using the foaming agent as described above has a drawback that it is not possible to sufficiently obtain an improvement effect on heat resistance and color resistance.
  • an object of the present invention is to provide a non-foamable vinyl chloride resin composition capable of providing a product excellent in heat resistance and color resistance without using a heavy metal stabilizer such as lead. There is.
  • the present inventors have found that in the case of a non-foamable vinyl chloride resin composition that does not use a foaming agent, an organic acid calcium salt, an organic acid zinc salt, and It has been found that the heat resistance and coloration resistance of the vinyl chloride resin composition can be remarkably improved by using the organic acid potassium salt in combination, and the present invention has been achieved.
  • the present invention provides a non-foamable vinyl chloride resin composition containing no foaming agent, comprising at least (a) an organic acid calcium salt, (b) an organic acid zinc salt, and (c) an organic acid potassium salt.
  • a non-foamable vinyl chloride resin composition comprising 5 parts by mass, (b) 0.01 to 5 parts by mass, and (c) 0.001 to 1 part by mass.
  • the component (a) and the component (b) are preferably used so that the molar ratio of calcium to zinc is 1/1 to 10/1.
  • the component (c) includes the component (a) and It is preferable that potassium is used in an amount of 0.01 to 0.3 mol with respect to 1 mol of the total amount of component (b) calcium and zinc.
  • non-foamable vinyl chloride resin composition of the present invention is excellent in thermal stability and color resistance, it is possible to provide a vinyl chloride resin molded product of higher quality than conventional products.
  • the vinyl chloride resin used in the present invention can be obtained by bulk polymerization, solution polymerization, suspension polymerization, emulsion polymerization or the like, and the polymerization method is not particularly limited.
  • Specific resins include, for example, polyvinyl chloride, chlorinated polyvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, vinyl chloride-vinyl acetate copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-propylene copolymer.
  • Examples of the organic acid calcium salt as the component (a) used in the present invention include calcium salts of organic carboxylic acids, phenols and organic phosphoric acids.
  • organic carboxylic acid examples include acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, 2-ethylhexylic acid, neodecanoic acid, capric acid, undecanoic acid, lauric acid, and tridecanoic acid.
  • phenols for example, tert-butylphenol, nonylphenol, di-nonylphenol, cyclohexyl phenol, phenylphenol, octylphenol, phenol, cresol, xylenol, n- butylphenol, isoamyl phenol, ethyl phenol, isopropyl phenol, isooctylphenol, Examples include 2-ethylhexylphenol, tertiary nonylphenol, decylphenol, tertiary octylphenol, isohexylphenol, octadecylphenol, diisobutylphenol, methylpropylphenol, diamylphenol, methylisohexylphenol, and methyltertiaryoctylphenol.
  • organic phosphoric acids examples include mono- or dioctyl phosphoric acid, mono- or didodecyl phosphoric acid, mono- or dioctadecyl phosphoric acid, mono- or di- (nonylphenyl) phosphoric acid, phosphonic acid nonylphenyl ester, Examples include phosphonic acid stearyl ester.
  • the amount of the organic acid calcium salt added in the present invention is 0.01 to 5 parts by mass, preferably 0.05 to 3 parts by mass with respect to 100 parts by mass of the vinyl chloride resin.
  • organic acid zinc salt (b) used in the present invention examples include zinc salts of organic carboxylic acids, phenols and organic phosphoric acids. What was mentioned above is mentioned as an example of organic carboxylic acid, phenols, and organic phosphoric acids.
  • the zinc salts of the organic carboxylic acids, phenols and organic phosphoric acids described above may be any of acidic salts, neutral salts and basic salts, and some or all of the bases of the basic salts.
  • An overbased complex neutralized with carbonic acid may be used.
  • the amount of the organic acid zinc salt which is the component (b) is 0.01 to 5 parts by mass, preferably 0.05 to 3 parts by mass with respect to 100 parts by mass of the vinyl chloride resin.
  • Examples of the organic acid potassium salt as component (c) used in the present invention include zinc salts of organic carboxylic acids, phenols and organic phosphoric acids.
  • Examples of organic carboxylic acids, phenols and organic phosphoric acids include those already exemplified.
  • the zinc salts of the organic carboxylic acids, phenols and organic phosphoric acids may be any of acidic salts, neutral salts and basic salts, and these may be a part or all of the bases in the basic salts.
  • An overbased complex obtained by neutralizing with carbonic acid may be used.
  • the amount of the organic acid potassium salt added is 0.001 to 1 part by mass, preferably 0.01 to 0.5 part by mass with respect to 100 parts by mass of the vinyl chloride resin.
  • the ratio of the component (a) and the component (b) is 1 / molar ratio of calcium and zinc. It is preferably 1 to 10/1, and more preferably 2/1 to 8/1. Furthermore, the ratio of the component (c) is preferably 0.01 to 0.3 mol, more preferably 0.05 to 0.25 mol of potassium with respect to 1 mol of the total amount of calcium and zinc of the components (a) and (b). More preferred.
  • composition of the present invention includes other additives usually used in vinyl chloride resin compositions, such as plasticizers, hydrotalcite compounds, zeolite compounds, ⁇ -diketone compounds, perchlorates, epoxy compounds.
  • plasticizers such as plasticizers, hydrotalcite compounds, zeolite compounds, ⁇ -diketone compounds, perchlorates, epoxy compounds.
  • Polyhydric alcohol, phosphorus-based, phenol-based and sulfur-based antioxidants, ultraviolet absorbers, hindered amine-based light stabilizers, fillers, lubricants, and the like can be added.
  • plasticizer examples include dibutyl phthalate, butyl hexyl phthalate, diheptyl phthalate, dioctyl phthalate, diisononyl phthalate, diisodecyl phthalate, dilauryl phthalate, dicyclohexyl phthalate, dioctyl terephthalate and the like; dioctyl adipate, diisononyl adipate , Diisodecyl adipate, di (butyl diglycol) adipate and the like adipate plasticizers; triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, tri (isopropylphenyl) phosphate, triethyl phosphate, tributyl phosphate, trioctyl phosphate, tri Phosphate such as (butoxyethyl) phosphate, oct
  • polyester plasticizer using acid, terephthalic acid, etc., and monohydric alcohol or monocarboxylic acid as a stopper if necessary; tetrahydrophthalic acid plasticizer, azelaic acid plasticizer, sebacic acid plasticizer, stearin Acid plasticizer, citric acid plasticizer, trimellitic acid plasticizer, pyromellitic acid Plasticizers, biphenyltetracarboxylic acid ester plasticizer, and chlorinated plasticizers and the like.
  • the hydrotalcite compound is a carbonate double salt compound of magnesium and / or zinc and aluminum, and is preferably a compound represented by the following general formula (I).
  • x1 and x2 in the formula (I) each represent a number satisfying the condition represented by the following formula, and m represents a real number. 0 ⁇ x2 / x1 ⁇ 10 and 2 ⁇ x1 + x2 ⁇ 20.
  • the hydrotalcite compound may be a natural product or a synthetic product.
  • a method for synthesizing the above synthetic product known methods such as those described in Japanese Patent Publication No. 46-2280, Japanese Patent Publication No. 50-30039, Japanese Patent Publication No. 51-29129, Japanese Patent Publication No. 61-174270, etc. Things can be used.
  • the hydrotalcite compound can be used without being limited by the crystal structure, the crystal particle size, the presence or absence of crystal water, and the amount thereof.
  • hydrotalcite treated with perchloric acid can also be used, and the surface thereof has higher fatty acid such as stearic acid, higher fatty acid metal salt such as alkali metal oleate, alkali dodecylbenzenesulfonate.
  • An organic sulfonic acid metal salt such as a metal salt, a higher fatty acid amide, a higher fatty acid ester, or a wax coated with a wax can also be used.
  • the zeolite compound is an aluminosilicate of an alkali or alkaline earth metal having a unique three-dimensional zeolite crystal structure, and representative examples thereof include A-type, X-type, Y-type and P-type zeolite, monodenite, anal Site, sodalite group aluminosilicate, clinobutyrolite, erionite, chabazite and the like.
  • These zeolitic compounds may be water-containing substances having crystal water (so-called zeolite water) or anhydrides from which crystal water has been removed.
  • the particle diameter of these compounds is preferably from 0.1 to 50 ⁇ m, particularly preferably from 0.5 to 10 ⁇ m.
  • ⁇ -diketone compound examples include dehydroacetic acid, dibenzoylmethane, palmitoylbenzoylmethane, stearoylbenzoylmethane, and the like. In the present invention, these metal salts are also useful as described above.
  • perchlorates include perchloric acid metal salts, ammonium perchlorate, perchloric acid-treated hydrotalcite, and perchloric acid-treated silicates.
  • metal constituting the metal salt include lithium, sodium, potassium, calcium, magnesium, strontium, barium, zinc, cadmium, lead, and aluminum.
  • the perchloric acid metal salt may be an anhydride or a hydrated salt.
  • butyl diglycol even those dissolved in an alcohol-based solvent and ester type such as butyl diglycol adipate, may be the dehydrated product.
  • epoxy compound examples include bisphenol type and novolak type epoxy resins, epoxidized soybean oil, epoxidized linseed oil, epoxidized tung oil, epoxidized fish oil, epoxidized beef tallow oil, epoxidized castor oil, and epoxidized safflower oil.
  • polyhydric alcohol examples include pentaerythritol, dipentaerythritol, sorbitol, mannitol, trimethylolpropane, ditrimethylolpropane, pentaerythritol or stearic acid partial ester of dipentaerythritol, bis (dipentaerythritol) adipate,
  • examples include glycerin, diglycerin, and tris (2-hydroxyethyl) isocyanurate.
  • Examples of the phosphorus antioxidant include triphenyl phosphite, tris (2,4-ditert-butylphenyl) phosphite, tris (nonylphenyl) phosphite, tris (dinonylphenyl) phosphite, tris ( Mono, di-mixed nonylphenyl) phosphite, bis (2-tert-butyl-4,6-dimethylphenyl) -ethyl phosphite, diphenyl acid phosphite, 2,2'-methylenebis (4,6-di-tert-butyl) Phenyl) octyl phosphite, diphenyl decyl phosphite, phenyl diisodecyl phosphite, tributyl phosphite, tris (2-ethylhexyl) phosphite, tride
  • phenolic antioxidant examples include 2,6-ditert-butyl-p-cresol, 2,6-diphenyl-4-octadecyloxyphenol, stearyl (3,5-ditert-butyl-4- Hydroxyphenyl) -propionate, distearyl (3,5-ditert-butyl-4-hydroxybenzyl) phosphonate, thiodiethylene glycol bis [(3,5-ditert-butyl-4-hydroxyphenyl) propionate], 1,6 -Hexamethylenebis [(3,5-ditert-butyl-4-hydroxyphenyl) propionate], 1,6-hexamethylenebis [(3,5-ditert-butyl-4-hydroxyphenyl) propionic acid amide] 4,4'-thiobis (6-tert-butyl-m-cresol), 2,2'-methylenebis (4-methyl-6-tert-butylphenol), 2,2'-methylenebis (4-ethyl-6- Ter
  • sulfur-based antioxidant examples include dialkylthiodipropionates such as dilauryl thiodipropionate, dimyristyl and distearyl, and ⁇ -alkyl mercapto of polyols such as pentaerythritol tetra ( ⁇ -dodecyl mercaptopropionate).
  • dialkylthiodipropionates such as dilauryl thiodipropionate, dimyristyl and distearyl
  • ⁇ -alkyl mercapto of polyols such as pentaerythritol tetra ( ⁇ -dodecyl mercaptopropionate).
  • propionic acid esters examples include propionic acid esters.
  • Examples of the ultraviolet absorber include 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 5,5′-methylenebis (2-hydroxy-4-methoxybenzophenone).
  • 2-hydroxybenzophenones such as 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 2- (2′-hydroxy-3 ′, 5′-ditert-butylphenyl) benzotriazole, 2 -(2'-hydroxy-3 ', 5'-ditert-butylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3'-tert-butyl-5'-methylphenyl) -5- Chlorobenzotriazole, 2- (2'-hydroxy-5'-tert-octylphenyl) benzotriazole, 2- (2'-hydroxy-3 ', 5'-dicumylphenyl) benzotriazole, 2,2'-methylenebis 2-
  • hindered amine light stabilizer examples include 2,2,6,6-tetramethyl-4-piperidyl stearate, 1,2,2,6,6-pentamethyl-4-piperidyl stearate, 2,2, 6,6-tetramethyl-4-piperidylbenzoate, N- (2,2,6,6-tetramethyl-4-piperidyl) dodecylsuccinimide, 1-[(3,5-ditert-butyl-4- Hydroxyphenyl) propionyloxyethyl] -2,2,6,6-tetramethyl-4-piperidyl- (3,5-ditert-butyl-4-hydroxyphenyl) propionate, bis (2,2,6,6- Tetramethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) -2- Butyl-2- (3,5-ditert-butyl
  • filler examples include calcium carbonate, silica, clay, glass beads, mica, sericite, glass flake, asbestos, wollastonite, potassium titanate, PMF, gypsum fiber, zonotlite, MOS, phosphate fiber, and glass fiber. , Carbonate fiber, aramid fiber and the like.
  • the lubricant examples include hydrocarbons such as natural paraffin and low molecular weight polyethylene, fatty acids such as stearic acid, lauric acid and erucic acid, aliphatic alcohols such as cetyl alcohol and stearyl alcohol, stearic acid amide, and melenbis.
  • fatty acid amides such as stearamide, lower alcohol esters of fatty acids such as butyl stearate, higher alcohol esters of higher fatty acids such as glycerol monostearate, and the like.
  • additives that are usually used in vinyl chloride resins as necessary, for example, crosslinking agents, antistatic agents, antifogging agents, plate-out preventing agents, surface treatment agents, flame retardants , Fluorescent agents, antifungal agents, bactericides, metal deactivators, mold release agents, processing aids, antioxidants, light stabilizers, and the like.
  • composition of the present invention can be used regardless of the processing method of the vinyl chloride resin.
  • it can be suitably used for calendar processing, roll processing, extrusion molding processing, melt rolling, injection molding processing, pressure molding processing, paste processing, powder molding processing, foam molding processing, and the like.
  • composition of the present invention comprises: wall materials, floor materials, window frames, wall materials, corrugated sheets, gutters, etc .; automotive interior and exterior materials; fish food packaging materials such as trays; packings, gaskets, hoses, pipes, It can be used for joints, sheets, toys, etc.
  • non-foamable vinyl chloride resin composition of the present invention can provide a vinyl chloride resin molded product having better thermal stability and color resistance than conventional products, it can be used in various industrial fields. worth it.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention concerne une composition de résine chlorovinylique non expansible qui contient au moins (a) un sel de calcium d'acide organique, (b) un sel de zinc d'acide organique et (c) un sel de potassium d'acide organique et qui ne contient aucun agent moussant. Les teneurs en sel de calcium d'acide organique (a), sel de zinc d'acide organique (b) et sel de potassium d'acide organique (c) représentent de 0,01 à 5 parties en poids, de 0,01 à 5 parties en poids et de 0,001 à 1 partie en poids, respectivement, par rapport aux 100 parties en poids d'une résine chlorovinylique. Il devient possible de fournir une composition de résine chlorovinylique non expansible ayant d'excellentes caractéristiques de résistance à la chaleur et de résistance de coloration sans qu'aucun stabilisant métallique lourd tel que le plomb ne soit nécessaire.
PCT/JP2008/003740 2008-01-16 2008-12-12 Composition de résine chlorovinylique non expansible Ceased WO2009090710A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008006558A JP5424440B2 (ja) 2008-01-16 2008-01-16 非発泡性塩化ビニル系樹脂組成物
JP2008-006558 2008-01-16

Publications (1)

Publication Number Publication Date
WO2009090710A1 true WO2009090710A1 (fr) 2009-07-23

Family

ID=40885121

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/003740 Ceased WO2009090710A1 (fr) 2008-01-16 2008-12-12 Composition de résine chlorovinylique non expansible

Country Status (2)

Country Link
JP (1) JP5424440B2 (fr)
WO (1) WO2009090710A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010087093A1 (fr) * 2009-01-29 2010-08-05 株式会社Adeka Composition de résine de chlorure de vinyle
CN114174407A (zh) * 2019-08-15 2022-03-11 Sika技术股份公司 包含吸热发泡剂的可热膨胀组合物
JP2023092239A (ja) * 2021-12-21 2023-07-03 株式会社クボタケミックス リブ継手用樹脂組成物およびリブ継手
JP2023092238A (ja) * 2021-12-21 2023-07-03 株式会社クボタケミックス 水道管継手用樹脂組成物および水道管継手

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110358214B (zh) * 2019-07-10 2021-12-28 深圳市邻友通科技发展有限公司 一种充气床垫外围带材料、内拉带材料、其制备方法和充气床垫

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5313659A (en) * 1976-07-23 1978-02-07 Adeka Argus Chem Co Ltd Stabilized halogen-containing resin compositions
JPS54114556A (en) * 1978-02-28 1979-09-06 Sakai Chem Ind Co Ltd Chlorine-containing resin composition
JPS60130629A (ja) * 1983-12-16 1985-07-12 Dainippon Ink & Chem Inc 発泡体用塩化ビニル樹脂組成物
JPS63268755A (ja) * 1987-04-27 1988-11-07 Mitsubishi Kasei Vinyl Co 塩化ビニル系重合体組成物
JPH01292053A (ja) * 1988-05-18 1989-11-24 Kiyoueishiya Yushi Kagaku Kogyo Kk 低温硬化性プラスチゾル組成物
JPH02232239A (ja) * 1989-03-03 1990-09-14 Sakai Chem Ind Co Ltd 発泡用塩化ビニル系樹脂組成物
JPH0468044A (ja) * 1990-07-09 1992-03-03 Sumitomo Chem Co Ltd 表面艶消し製品
JPH10219004A (ja) * 1997-02-12 1998-08-18 Asahi Denka Kogyo Kk 農業用熱可塑性樹脂フィルム
JP2004189777A (ja) * 2002-12-06 2004-07-08 Asahi Denka Kogyo Kk 電線被覆用塩素含有樹脂組成物
JP2004189776A (ja) * 2002-12-06 2004-07-08 Asahi Denka Kogyo Kk ホース用塩素含有樹脂組成物
JP2008214480A (ja) * 2007-03-02 2008-09-18 Adeka Corp 塩化ビニル系樹脂組成物

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04202452A (ja) * 1990-11-30 1992-07-23 Katsuta Kako Kk ポリ塩化ビニル系樹脂組成物

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5313659A (en) * 1976-07-23 1978-02-07 Adeka Argus Chem Co Ltd Stabilized halogen-containing resin compositions
JPS54114556A (en) * 1978-02-28 1979-09-06 Sakai Chem Ind Co Ltd Chlorine-containing resin composition
JPS60130629A (ja) * 1983-12-16 1985-07-12 Dainippon Ink & Chem Inc 発泡体用塩化ビニル樹脂組成物
JPS63268755A (ja) * 1987-04-27 1988-11-07 Mitsubishi Kasei Vinyl Co 塩化ビニル系重合体組成物
JPH01292053A (ja) * 1988-05-18 1989-11-24 Kiyoueishiya Yushi Kagaku Kogyo Kk 低温硬化性プラスチゾル組成物
JPH02232239A (ja) * 1989-03-03 1990-09-14 Sakai Chem Ind Co Ltd 発泡用塩化ビニル系樹脂組成物
JPH0468044A (ja) * 1990-07-09 1992-03-03 Sumitomo Chem Co Ltd 表面艶消し製品
JPH10219004A (ja) * 1997-02-12 1998-08-18 Asahi Denka Kogyo Kk 農業用熱可塑性樹脂フィルム
JP2004189777A (ja) * 2002-12-06 2004-07-08 Asahi Denka Kogyo Kk 電線被覆用塩素含有樹脂組成物
JP2004189776A (ja) * 2002-12-06 2004-07-08 Asahi Denka Kogyo Kk ホース用塩素含有樹脂組成物
JP2008214480A (ja) * 2007-03-02 2008-09-18 Adeka Corp 塩化ビニル系樹脂組成物

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010087093A1 (fr) * 2009-01-29 2010-08-05 株式会社Adeka Composition de résine de chlorure de vinyle
US8841371B2 (en) 2009-01-29 2014-09-23 Adeka Corporation Vinyl chloride resin composition
CN114174407A (zh) * 2019-08-15 2022-03-11 Sika技术股份公司 包含吸热发泡剂的可热膨胀组合物
JP2023092239A (ja) * 2021-12-21 2023-07-03 株式会社クボタケミックス リブ継手用樹脂組成物およびリブ継手
JP2023092238A (ja) * 2021-12-21 2023-07-03 株式会社クボタケミックス 水道管継手用樹脂組成物および水道管継手
JP7680948B2 (ja) 2021-12-21 2025-05-21 株式会社クボタケミックス リブ継手用樹脂組成物およびリブ継手

Also Published As

Publication number Publication date
JP2009167289A (ja) 2009-07-30
JP5424440B2 (ja) 2014-02-26

Similar Documents

Publication Publication Date Title
WO2012111240A1 (fr) Composition de résine chlorure de vinyle
JP4942513B2 (ja) 塩化ビニル系樹脂組成物
JPWO2010041378A1 (ja) 透明製品用塩化ビニル系樹脂組成物及び該組成物を成形してなる透明成形品
EP2975086A1 (fr) Composition de résine de chlorure de vinyle pour article transparent
JP5709246B2 (ja) 塩化ビニル系樹脂組成物
JP5782031B2 (ja) 透明製品用塩化ビニル系樹脂組成物
JP5530104B2 (ja) 塩化ビニル系樹脂組成物
WO2009090710A1 (fr) Composition de résine chlorovinylique non expansible
JP2011190320A (ja) 電線被覆用塩化ビニル系樹脂組成物
JP2012021122A (ja) 塩化ビニル系樹脂組成物
WO2010103933A1 (fr) Composition de résine de chlorure de vinyle
EP2045291B1 (fr) Composition de résine chlorure de vinyle
JP5264080B2 (ja) 粉体成型用塩化ビニル系樹脂組成物
JP5258058B2 (ja) 塩化ビニル系樹脂組成物の成形加工方法
JP5036289B2 (ja) 塩化ビニル系樹脂組成物
WO2014057563A1 (fr) Composition de résine pour film d'impression et film d'impression
JP5600080B2 (ja) 印刷フィルム用樹脂組成物および印刷フィルム
JP2008274032A (ja) ハイドロタルサイト及び該ハイドロタルサイトを含有してなる合成樹脂組成物
JP2006001963A (ja) 防水シート用塩化ビニル系樹脂組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08870997

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 08870997

Country of ref document: EP

Kind code of ref document: A1