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WO2009047100A2 - Utilisation de polydiméthylsiloxanes cycliques pour donner un effet mat - Google Patents

Utilisation de polydiméthylsiloxanes cycliques pour donner un effet mat Download PDF

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Publication number
WO2009047100A2
WO2009047100A2 PCT/EP2008/062454 EP2008062454W WO2009047100A2 WO 2009047100 A2 WO2009047100 A2 WO 2009047100A2 EP 2008062454 W EP2008062454 W EP 2008062454W WO 2009047100 A2 WO2009047100 A2 WO 2009047100A2
Authority
WO
WIPO (PCT)
Prior art keywords
use according
hydrophobically modified
hectorite
hair
hectorites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/062454
Other languages
German (de)
English (en)
Other versions
WO2009047100A3 (fr
Inventor
Uwe Bergemann
Rolf Bayersdörfer
Burkhard Müller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO2009047100A2 publication Critical patent/WO2009047100A2/fr
Publication of WO2009047100A3 publication Critical patent/WO2009047100A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the invention relates to the use of at least one specific cyclic polydimethylsiloxane in a temporary deformation agent for keratinic fibers to provide a matte effect on the keratinic fibers treated with this composition.
  • keratinic fibers in principle, all animal hair, e.g. Wool, horsehair, angora hair, furs, feathers and products or textiles made from them. Preferably, however, it is human hair.
  • Means for the deformation of keratinous fibers have long been known and find use in various embodiments for the construction, for refreshing and for fixing hairstyles, which can be obtained in many types of hair only using firming agents.
  • Such agents are also referred to as styling agents, with both hair treatment agents, which serve a permanent, as well as those which serve a temporary shaping of the hair play an important role.
  • Temporary shapes which should give a good grip, without affecting the healthy appearance of the hair, can be achieved for example by hair sprays, hair waxes, hair gels, hair drier, etc.
  • classic hair sprays cause a strong gloss, which is not always desirable.
  • Hairsprays usually contain synthetic polymers as a shaping component.
  • Preparations containing a dissolved or dispersed polymer can be applied to the hair by means of propellant gases or by a pumping mechanism. As a rule, a satisfactory uniform distribution of the polymer on the hair is achieved.
  • the application of spray or pump containers is easy and clean possible.
  • silicones are used in particular in care products, but also, for example, in means for the temporary deformation of the hair, so-called styling agents.
  • Volatile silicones such as short chain linear polydimethylsiloxanes containing about 3 to 9 silicon atoms, and their cyclic analogs are also used as solvents for nonvolatile silicone components.
  • EP 0 431 218 A2 discloses silicone-containing hairsprays containing certain silicone gums. These should be characterized by an improved conditioning effect and a special hold of the hairstyle created. Volatile silicones are used as solvents for the silicone rubbers.
  • hydrophobically modified clays are used which serve as suspending agents for the silicone rubbers and prevent the latter from irreversibly agglomerating during the course of storage of the hair sprays.
  • Other effects associated with the use of the volatile silicones or the hydrophobically modified clays are not described.
  • the object of the present invention was to provide new fields of application for volatile silicones in agents for temporary deformation of keratinous fibers.
  • the invention therefore relates to the use of at least one cyclic polydimethylsiloxane selected from cyclotrisiloxane, cyclotetrasiloxane, cyclopentasiloxane, cyclohexasiloxane and cycloheptasiloxane in a means for temporarily deforming keratinic fibers to produce a matt effect on the keratinic fibers treated with this agent.
  • the cyclic polydimethylsiloxane is used in an amount of 0.05 to 5.0 wt .-%, based on the total weight of the agent for the temporary deformation of keratinous fibers, more preferably in an amount of 0.5 to 4.5 wt %, more preferably in an amount of 0.7 to 4.0% by weight, based in each case on the total weight of the agent for the temporary deformation of keratinic fibers.
  • the cyclic polydimethylsiloxane is therefore used in combination with at least one hydrophobically modified clay mineral.
  • hydrophobically modified clay mineral all clay minerals that can be hydrophobically modified are suitable. However, particularly good effects are achieved with hydrophobically modified bentonites or hydrophobically modified hectorites.
  • the bentonites and hectorites are naturally occurring clay minerals, which have a substantially three-layer structure and approximately the chemical formulas AI 2 [(OH) 2 / Si 4 Oio] xn H 2 O or Mo 13 (Mg 217 LiO 13 ) [Si 4 OiO (OH) 2 ], where M is usually Na.
  • These minerals have a high ion exchange capacity, so that in particular Al may be exchanged for various other metals.
  • the resulting negative charges of individual layers are compensated by the incorporation of cations, in particular Na + and Ca 2+ in interlayer positions.
  • hydrophobic modification of these clay minerals is carried out by reaction with cationic surface-active compounds which have hydrophobic properties and are incorporated into the structure of the clay minerals instead of the absorbed cations.
  • the suitable surface-active compounds are quaternary ammonium compounds which carry at least one long-chain alkyl substituent.
  • hydrophobically modified clay minerals are commercially available.
  • hydrophobically modified bentonites or hectorites selected from quaternium-18 bentonites, quaternium-18 hectorites, stearalkonium bentonites, stearalkonium hectorites and disteardimonium hectorites are used, the use of disteardimonium hectorite being particularly preferred.
  • a mixture of cyclopentasiloxane and disteardimonium hectorite is used. Suitable mixtures are commercially available. For example, a mixture of cyclopentasiloxane, disteardimonium hectorite and propylene carbonate in the approximate weight ratio of 77: 18: 5 under the name Bentone Gel VS5-PCV from Rheox Inc. is offered. The use of this mixture is particularly preferred.
  • hydrophobically modified clay minerals are used, they are preferably used in an amount of from 0.05 to 5.0% by weight, based on the total weight of the agent for the temporary deformation of keratinic fibers, more preferably in an amount of 0.1 to 4.0 wt .-%, most preferably in an amount of 0.15 to 3.0 wt .-%, each based on the total weight of the agent for the temporary deformation of keratinous fibers.
  • the cyclic polydimethylsiloxanes having 3 to 7 silicon atoms, optionally in admixture with hydrophobically modified clay minerals, according to the invention can be added to any means for the temporary deformation of keratinic fibers to produce a matte effect. However, particularly pronounced matt effects can be achieved when used in hair sprays that are based on classic film-forming and / or setting polymers. These give the treated hair without the addition of cyclic polydimethylsiloxanes usually a strong gloss.
  • the cyclic polydimethylsiloxanes having 3 to 7 silicon atoms are therefore used in aerosol and non-aerosol hair sprays to create a matte effect on the keratinic fibers treated with these agents.
  • the use in aerosol hair sprays is particularly preferred.
  • hair sprays containing as a film-forming and / or setting polymer at least one homo- or copolymer of vinylpyrrolidone or an amphoteric copolymer of octylacrylamide, acrylates and / or methacrylates and butylamino ethyl methacrylate.
  • hairsprays containing as film-forming and / or setting polymer at least one amphoteric copolymer of octylacrylamide, acrylates and / or methacrylates and butylaminoethyl methacrylate.
  • film-forming and / or firming polymers are exemplary of vinylpyrrolidone, copolymers of vinylpyrrolidone and vinyl acetate, for example, Luviskol ® VA 37, or PVP / VA Copolymer 60/40 W NP, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, and sold under the name Amphomer ® available amphoteric octylacrylamide-acrylate-butylaminoethyl methacrylate copolymer called.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne l'utilisation d'au moins un polydiméthylsiloxane cyclique, sélectionné parmi le cyclotrisiloxane, le cyclotétrasiloxane, le cyclopentasiloxane, le cyclohexasiloxane et le cycloheptasiloxane, de préférence en mélange avec un minéral argileux modifié hydrophobiquement, dans un produit destiné à la déformation temporaire de fibres kératiniques pour donner un effet mat aux fibres kératiniques traitées avec ce produit.
PCT/EP2008/062454 2007-10-08 2008-09-18 Utilisation de polydiméthylsiloxanes cycliques pour donner un effet mat Ceased WO2009047100A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007048290.8 2007-10-08
DE200710048290 DE102007048290A1 (de) 2007-10-08 2007-10-08 Verwendung cyclischer Polydimethylsiloxane zur Erzeugung eines Matteffekts

Publications (2)

Publication Number Publication Date
WO2009047100A2 true WO2009047100A2 (fr) 2009-04-16
WO2009047100A3 WO2009047100A3 (fr) 2009-05-28

Family

ID=40418221

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/062454 Ceased WO2009047100A2 (fr) 2007-10-08 2008-09-18 Utilisation de polydiméthylsiloxanes cycliques pour donner un effet mat

Country Status (2)

Country Link
DE (1) DE102007048290A1 (fr)
WO (1) WO2009047100A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016071044A1 (fr) * 2014-11-07 2016-05-12 Henkel Ag & Co. Kgaa Produits de mise en forme temporaire de fibres kératiniques, contenant une poudre d'oxyde métallique modifiée de façon hydrophobe, un polymère filmogène et de l'éthanol
CN116283169A (zh) * 2023-04-14 2023-06-23 湖北浩川水利水电工程有限公司 一种防渗防漏材料及制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1102563A (fr) * 1954-04-07 1955-10-24 Fixateur cosmétique élastique
GB2132653B (en) * 1982-12-07 1985-12-18 Dow Corning Hair treatment compositions
EP0116207A3 (fr) * 1982-12-15 1986-03-12 Beecham Group Plc Préparation cosmétique
US4983377A (en) 1989-10-31 1991-01-08 The Procter & Gamble Company Silicone hairspray compositions
JPH06199640A (ja) * 1992-12-28 1994-07-19 Kao Corp 毛髪化粧料
GB9827222D0 (en) * 1998-12-10 1999-02-03 Unilever Plc Aqueous hair styling aids
EP1355617A1 (fr) * 2001-01-30 2003-10-29 Unilever Plc Produit de modelage a deux phases qui fournit les avantages du modelage et du traitement
DE102005060435A1 (de) * 2005-12-15 2007-06-21 Henkel Kgaa Haarwachsspray

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016071044A1 (fr) * 2014-11-07 2016-05-12 Henkel Ag & Co. Kgaa Produits de mise en forme temporaire de fibres kératiniques, contenant une poudre d'oxyde métallique modifiée de façon hydrophobe, un polymère filmogène et de l'éthanol
CN116283169A (zh) * 2023-04-14 2023-06-23 湖北浩川水利水电工程有限公司 一种防渗防漏材料及制备方法和应用

Also Published As

Publication number Publication date
DE102007048290A1 (de) 2009-04-09
WO2009047100A3 (fr) 2009-05-28

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