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WO2008139980A1 - リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法 - Google Patents

リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法 Download PDF

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Publication number
WO2008139980A1
WO2008139980A1 PCT/JP2008/058438 JP2008058438W WO2008139980A1 WO 2008139980 A1 WO2008139980 A1 WO 2008139980A1 JP 2008058438 W JP2008058438 W JP 2008058438W WO 2008139980 A1 WO2008139980 A1 WO 2008139980A1
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WO
WIPO (PCT)
Prior art keywords
radical polymerization
catalyst
living radical
polymerization method
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/058438
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English (en)
French (fr)
Inventor
Atsushi Goto
Takeshi Fukuda
Yoshinobu Tsujii
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyoto University NUC
Original Assignee
Kyoto University NUC
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Filing date
Publication date
Application filed by Kyoto University NUC filed Critical Kyoto University NUC
Priority to US12/599,270 priority Critical patent/US9175099B2/en
Priority to CN2008800241867A priority patent/CN101687939B/zh
Priority to JP2009514123A priority patent/JP5850599B2/ja
Priority to EP08752343.7A priority patent/EP2147936B1/en
Publication of WO2008139980A1 publication Critical patent/WO2008139980A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

安価で、活性が高く、環境に優しいリビングラジカル重合触媒を提供すること リビングラジカル重合方法のための触媒であって、窒素またはリンから選択される中心元素と、該中心元素に結合した少なくとも１つのハロゲン原子とを含む触媒が提供される。この触媒の存在下で、ラジカル反応性不飽和結合を有するモノマーをラジカル重合反応させることにより、分子量分布の狭いポリマーを得ることができ、リビングラジカル重合のコストを劇的に低減することができる。本発明は、触媒の低毒性、低使用量、高溶解性、温和な反応条件、無着色・無臭（成形品の後処理が不要）などの利点を有し、従来のリビングラジカル重合方法に比べて格段に環境に優しく経済性に優れる。
PCT/JP2008/058438 2007-05-09 2008-05-02 リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法 Ceased WO2008139980A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/599,270 US9175099B2 (en) 2007-05-09 2008-05-02 Living radical polymerization method using a phosphorus compound or nitrogen compound as a catalyst
CN2008800241867A CN101687939B (zh) 2007-05-09 2008-05-02 使用磷化合物或氮化合物作为催化剂的新型活性自由基聚合法
JP2009514123A JP5850599B2 (ja) 2007-05-09 2008-05-02 リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法
EP08752343.7A EP2147936B1 (en) 2007-05-09 2008-05-02 Novel living radical polymerization method using phosphorus compound or nitrogen compound as catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-125099 2007-05-09
JP2007125099 2007-05-09

Publications (1)

Publication Number Publication Date
WO2008139980A1 true WO2008139980A1 (ja) 2008-11-20

Family

ID=40002184

Family Applications (1)

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PCT/JP2008/058438 Ceased WO2008139980A1 (ja) 2007-05-09 2008-05-02 リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法

Country Status (5)

Country Link
US (1) US9175099B2 (ja)
EP (1) EP2147936B1 (ja)
JP (1) JP5850599B2 (ja)
CN (1) CN101687939B (ja)
WO (1) WO2008139980A1 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009136510A1 (ja) * 2008-05-09 2009-11-12 国立大学法人京都大学 アルコールを触媒として用いた新規リビングラジカル重合法
WO2010140372A1 (ja) 2009-06-03 2010-12-09 国立大学法人京都大学 リビングラジカル重合の重合開始剤
WO2011016166A1 (ja) 2009-08-06 2011-02-10 国立大学法人京都大学 リビングラジカル重合触媒および重合方法
JP2011068865A (ja) * 2009-08-31 2011-04-07 Dainichiseika Color & Chem Mfg Co Ltd アクリル樹脂処理顔料組成物、顔料分散液、それらの製造方法および使用
JP2011074267A (ja) * 2009-09-30 2011-04-14 Toagosei Co Ltd 塗料用熱硬化性組成物
JP2011074326A (ja) * 2009-10-01 2011-04-14 Toagosei Co Ltd 硬化性組成物
WO2013027419A1 (ja) 2011-08-25 2013-02-28 国立大学法人京都大学 リビングラジカル重合触媒および重合方法
JP2016160370A (ja) * 2015-03-03 2016-09-05 三菱レイヨン株式会社 重合体の製造方法
JP2017155210A (ja) * 2016-02-29 2017-09-07 大日精化工業株式会社 ポリマーの製造方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2330154B1 (en) * 2008-07-28 2017-01-11 Dainichiseika Color & Chemicals Mfg. Co., Ltd. Aqueous pigment dispersion and applications thereof
US10173925B2 (en) * 2014-03-31 2019-01-08 Dow Global Technologies Llc Synthetic polymer rheology modifier and water retention agent replacement for cellulose ether in cement compositions
CN106046221B (zh) * 2016-05-23 2018-06-26 北京化工大学 一类可逆-休眠自由基聚合的催化剂及聚合方法
CN109280115A (zh) * 2018-09-12 2019-01-29 福州大学 一种基于Finkelstein反应实现可控自由基聚合的方法
WO2023005567A1 (en) 2021-07-30 2023-02-02 Basf Se A composition and its application in controlled living water-based emulsion polymerization
JPWO2023190392A1 (ja) * 2022-03-30 2023-10-05
WO2025067315A1 (en) 2023-09-27 2025-04-03 Basf Se Process of reversible complexation mediated polymerization and product obtained therefrom

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US2857365A (en) * 1956-05-11 1958-10-21 Monsanto Chemicals Manufacture of low molecular weight olefin/maleic anhydride copolymers
JPS4713366B1 (ja) * 1966-03-30 1972-04-22
JPH11322822A (ja) 1998-05-08 1999-11-26 Hitachi Chem Co Ltd ラジカルリビング重合用触媒及びこれを用いたメタクリル酸エステル重合体又は共重合体の製造方法
JP2002249505A (ja) 2000-12-22 2002-09-06 Mitsubishi Chemicals Corp メタクリレート系重合体の製造方法
JP2007092014A (ja) 2005-09-01 2007-04-12 Kyoto Univ 新規リビングラジカル重合法

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JPH0713366B2 (ja) 1992-05-18 1995-02-15 建設省土木研究所長 砂質地盤の補強杭
US5530079A (en) * 1995-01-03 1996-06-25 Xerox Corporation Polymerization processes
US6133389A (en) 1995-02-06 2000-10-17 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene-hexafluoropropylene copolymers
DE69633024T2 (de) * 1995-02-06 2005-08-04 E.I. Du Pont De Nemours And Co., Wilmington Amorphe HFP/TFE Copolymere
CN1098864C (zh) * 1998-08-12 2003-01-15 华东理工大学 含有路易斯酸的活性自由基聚合反应催化剂及其应用
US6911515B2 (en) * 2001-03-23 2005-06-28 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
US7345127B2 (en) * 2001-03-23 2008-03-18 University Of Pennsylvania Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
AU2003253045A1 (en) * 2002-07-23 2004-02-09 Akzo Nobel N.V. Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2857365A (en) * 1956-05-11 1958-10-21 Monsanto Chemicals Manufacture of low molecular weight olefin/maleic anhydride copolymers
JPS4713366B1 (ja) * 1966-03-30 1972-04-22
JPH11322822A (ja) 1998-05-08 1999-11-26 Hitachi Chem Co Ltd ラジカルリビング重合用触媒及びこれを用いたメタクリル酸エステル重合体又は共重合体の製造方法
JP2002249505A (ja) 2000-12-22 2002-09-06 Mitsubishi Chemicals Corp メタクリレート系重合体の製造方法
JP2007092014A (ja) 2005-09-01 2007-04-12 Kyoto Univ 新規リビングラジカル重合法

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CHEMICAL COMMUNICATION, 2001, pages 797 - 798
J.D. LEE: "Inorganic Chemistry", 15 April 1982, pages: 311
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PRASAD D.V.P.R.V AND MAHADEVAN V.: "Effects of phosphorus oxychloride, phosphorous trichloride and dichlorophenylphosphine on the radical polymerisation of acrylonitrile under heterogeneous conditions", POLYMER BULLETIN, vol. 2, no. 2, 1980, pages 117 - 123, XP008125188 *
See also references of EP2147936A4 *
SYNTHETIC COMMUNICATION, vol. 33, 2003, pages 3851 - 3859

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8378044B2 (en) 2008-05-09 2013-02-19 Kyoto University Living radical polymerization method using alcohol as catalyst
WO2009136510A1 (ja) * 2008-05-09 2009-11-12 国立大学法人京都大学 アルコールを触媒として用いた新規リビングラジカル重合法
WO2010140372A1 (ja) 2009-06-03 2010-12-09 国立大学法人京都大学 リビングラジカル重合の重合開始剤
JP5645165B2 (ja) * 2009-06-03 2014-12-24 国立大学法人京都大学 リビングラジカル重合の重合開始剤
US8742045B2 (en) 2009-06-03 2014-06-03 Kyoto University Polymerization initiator for living radical polymerization
CN102459356B (zh) * 2009-06-03 2013-06-12 国立大学法人京都大学 活性自由基聚合的聚合引发剂
CN102459356A (zh) * 2009-06-03 2012-05-16 国立大学法人京都大学 活性自由基聚合的聚合引发剂
JP5610402B2 (ja) * 2009-08-06 2014-10-22 国立大学法人京都大学 リビングラジカル重合触媒および重合方法
CN102574938A (zh) * 2009-08-06 2012-07-11 国立大学法人京都大学 用于活性自由基聚合的催化剂及聚合方法
WO2011016166A1 (ja) 2009-08-06 2011-02-10 国立大学法人京都大学 リビングラジカル重合触媒および重合方法
CN102574938B (zh) * 2009-08-06 2015-03-11 国立大学法人京都大学 用于活性自由基聚合的催化剂及聚合方法
US9546226B2 (en) 2009-08-06 2017-01-17 Kyoto University Catalyst for living radical polymerization and polymerization method
JP2011068865A (ja) * 2009-08-31 2011-04-07 Dainichiseika Color & Chem Mfg Co Ltd アクリル樹脂処理顔料組成物、顔料分散液、それらの製造方法および使用
JP2011074267A (ja) * 2009-09-30 2011-04-14 Toagosei Co Ltd 塗料用熱硬化性組成物
JP2011074326A (ja) * 2009-10-01 2011-04-14 Toagosei Co Ltd 硬化性組成物
WO2013027419A1 (ja) 2011-08-25 2013-02-28 国立大学法人京都大学 リビングラジカル重合触媒および重合方法
JP2016160370A (ja) * 2015-03-03 2016-09-05 三菱レイヨン株式会社 重合体の製造方法
JP2017155210A (ja) * 2016-02-29 2017-09-07 大日精化工業株式会社 ポリマーの製造方法

Also Published As

Publication number Publication date
US9175099B2 (en) 2015-11-03
JP5850599B2 (ja) 2016-02-03
EP2147936B1 (en) 2017-09-27
CN101687939B (zh) 2012-12-26
US20100298499A1 (en) 2010-11-25
JPWO2008139980A1 (ja) 2010-08-05
EP2147936A4 (en) 2011-04-20
CN101687939A (zh) 2010-03-31
EP2147936A1 (en) 2010-01-27

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