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WO2008120782A1 - Water-and-oil-repellent antifouling antireflection film, process for producing the same, and lens, glass plate, glass, optical device, apparatus for utilizing solar energy, and display - Google Patents

Water-and-oil-repellent antifouling antireflection film, process for producing the same, and lens, glass plate, glass, optical device, apparatus for utilizing solar energy, and display Download PDF

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Publication number
WO2008120782A1
WO2008120782A1 PCT/JP2008/056372 JP2008056372W WO2008120782A1 WO 2008120782 A1 WO2008120782 A1 WO 2008120782A1 JP 2008056372 W JP2008056372 W JP 2008056372W WO 2008120782 A1 WO2008120782 A1 WO 2008120782A1
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WO
WIPO (PCT)
Prior art keywords
water
oil
repellent antifouling
glass
antireflection film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/056372
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French (fr)
Japanese (ja)
Inventor
Kazufumi Ogawa
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2008120782A1 publication Critical patent/WO2008120782A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/111Anti-reflection coatings using layers comprising organic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00Methods preventing fouling
    • B08B17/02Preventing deposition of fouling or of dust
    • B08B17/06Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00Methods preventing fouling
    • B08B17/02Preventing deposition of fouling or of dust
    • B08B17/06Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • B08B17/065Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1606Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/68Particle size between 100-1000 nm
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/0006Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/73Anti-reflective coatings with specific characteristics
    • C03C2217/732Anti-reflective coatings with specific characteristics made of a single layer
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/75Hydrophilic and oleophilic coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/76Hydrophobic and oleophobic coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Surface Treatment Of Glass (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Laminated Bodies (AREA)

Abstract

A water-and-oil-repellent antifouling antireflection film which has water-and-oil repellency, unsusceptibility to fouling, waterdrop repellency, and durability; a process for producing the film; a lens, glass plate, and glass each having a water-and-oil-repellent antifouling antireflection film formed on a surface thereof; and an optical device, apparatus for utilizing solar energy; and display each employing the film. The water-and-oil-repellent antifouling antireflection film (12) comprises: a platy substrate (1); fine transparent particles (5) with water-and-oil repellency and unsusceptibility to fouling which have been fusion-bonded to asurface of the substrate (1); and a coating film (11) which is made of a water-and-oil-repellent antifouling substance and with which those areas in the surface of the substrate (1) which do not have fine transparent particles (5) fusion-bonded thereto are covered. The surface of each fine transparent particle (5) has been partly fusion-bonded to the surface of the substrate (1), and the exposed part of the particle (5) has been covered with the coating film (11) made of a water-and-oil-repellent antifouling substance.
PCT/JP2008/056372 2007-03-30 2008-03-31 Water-and-oil-repellent antifouling antireflection film, process for producing the same, and lens, glass plate, glass, optical device, apparatus for utilizing solar energy, and display Ceased WO2008120782A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-093676 2007-03-30
JP2007093676A JP5347125B2 (en) 2007-03-30 2007-03-30 Water / oil repellent / antifouling antireflection film and method for producing the same, lens, glass plate, glass, optical device, solar energy utilization device and display

Publications (1)

Publication Number Publication Date
WO2008120782A1 true WO2008120782A1 (en) 2008-10-09

Family

ID=39808362

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/056372 Ceased WO2008120782A1 (en) 2007-03-30 2008-03-31 Water-and-oil-repellent antifouling antireflection film, process for producing the same, and lens, glass plate, glass, optical device, apparatus for utilizing solar energy, and display

Country Status (2)

Country Link
JP (1) JP5347125B2 (en)
WO (1) WO2008120782A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2293121A1 (en) * 2009-09-02 2011-03-09 Sony Corporation Optical element and method for manufacturing optical element
WO2017216592A3 (en) * 2016-06-15 2018-03-15 Hungaro Lux Light Kft Antireflection film and its use on a substrate

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5572803B2 (en) * 2009-03-25 2014-08-20 国立大学法人 香川大学 Water repellent and oil repellent antifouling glass, method for producing the same, glass window using them, solar energy utilization apparatus and optical instrument
JP6360660B2 (en) * 2013-05-23 2018-07-18 日揮触媒化成株式会社 Base material with antireflection film and method for producing the same
KR101546084B1 (en) 2013-08-06 2015-08-20 경기대학교 산학협력단 Surface Structure Layer having Antifouling Property
CN106458683A (en) 2014-05-15 2017-02-22 旭硝子株式会社 Glass article and glass article manufacturing method
KR101916503B1 (en) * 2015-06-24 2018-11-07 경기대학교 산학협력단 Composition For Hydrophobic Thin Film, Hydrophobic Thin Film And Manufacturing Method Thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04239633A (en) * 1991-01-23 1992-08-27 Matsushita Electric Ind Co Ltd Water and repelling film and manufacture thereof
JP2001180981A (en) * 1999-12-24 2001-07-03 Asahi Glass Co Ltd Exterior glass member having antiglare coating film and method of installing the same
WO2004052640A1 (en) * 2002-12-10 2004-06-24 Nippon Sheet Glass Co., Ltd. Article having functional coating film thereon, method for manufacture thereof, and applying material for forming functional coating film
JP2007333291A (en) * 2006-06-14 2007-12-27 Kagawa Univ Solar energy utilization apparatus and manufacturing method thereof
JP2008007365A (en) * 2006-06-28 2008-01-17 Kagawa Univ Solar energy utilization apparatus and manufacturing method thereof
JP2008007363A (en) * 2006-06-28 2008-01-17 Kagawa Univ Water and oil repellent antifouling glass plate, method for producing the same, transport equipment using the same, building and optical equipment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04239633A (en) * 1991-01-23 1992-08-27 Matsushita Electric Ind Co Ltd Water and repelling film and manufacture thereof
JP2001180981A (en) * 1999-12-24 2001-07-03 Asahi Glass Co Ltd Exterior glass member having antiglare coating film and method of installing the same
WO2004052640A1 (en) * 2002-12-10 2004-06-24 Nippon Sheet Glass Co., Ltd. Article having functional coating film thereon, method for manufacture thereof, and applying material for forming functional coating film
JP2007333291A (en) * 2006-06-14 2007-12-27 Kagawa Univ Solar energy utilization apparatus and manufacturing method thereof
JP2008007365A (en) * 2006-06-28 2008-01-17 Kagawa Univ Solar energy utilization apparatus and manufacturing method thereof
JP2008007363A (en) * 2006-06-28 2008-01-17 Kagawa Univ Water and oil repellent antifouling glass plate, method for producing the same, transport equipment using the same, building and optical equipment

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2293121A1 (en) * 2009-09-02 2011-03-09 Sony Corporation Optical element and method for manufacturing optical element
US9759840B2 (en) 2009-09-02 2017-09-12 Dexerials Corporation Optical element and method for manufacturing optical element
WO2017216592A3 (en) * 2016-06-15 2018-03-15 Hungaro Lux Light Kft Antireflection film and its use on a substrate
US11029514B2 (en) 2016-06-15 2021-06-08 Hungaro Lux Light Kft. Antireflection film and its use on a substrate

Also Published As

Publication number Publication date
JP5347125B2 (en) 2013-11-20
JP2008247700A (en) 2008-10-16

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