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WO2008114500A1 - 無黄変低硬度ポリウレタンエラストマー形成性組成物、及びそれを用いた無黄変低硬度ポリウレタンエラストマーの製造方法 - Google Patents

無黄変低硬度ポリウレタンエラストマー形成性組成物、及びそれを用いた無黄変低硬度ポリウレタンエラストマーの製造方法 Download PDF

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Publication number
WO2008114500A1
WO2008114500A1 PCT/JP2008/000583 JP2008000583W WO2008114500A1 WO 2008114500 A1 WO2008114500 A1 WO 2008114500A1 JP 2008000583 W JP2008000583 W JP 2008000583W WO 2008114500 A1 WO2008114500 A1 WO 2008114500A1
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WO
WIPO (PCT)
Prior art keywords
free
low
polyurethane elastomer
yellowing
hardness polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/000583
Other languages
English (en)
French (fr)
Inventor
Teppei Oyanagi
Takahiro Aizawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Polyurethane Industry Co Ltd
Original Assignee
Nippon Polyurethane Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Polyurethane Industry Co Ltd filed Critical Nippon Polyurethane Industry Co Ltd
Priority to KR1020097019007A priority Critical patent/KR101118979B1/ko
Priority to US12/531,511 priority patent/US20100087617A1/en
Publication of WO2008114500A1 publication Critical patent/WO2008114500A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C08G18/4241—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

【課題】　無黄変であり、可塑剤を用いることなく低硬度や非ブリード性が達成され、タックが少なく、硬度の温度変化が小さい熱硬化性ポリウレタンエラストマーの提供する。 【解決手段】　可塑剤を含まず、かつ下記に示す（Ａ）イソシアネート基末端プレポリマー及び（Ｂ）ポリエステルポリオールからなることを特徴とする、無黄変低硬度ポリウレタンエラストマー形成性組成物により解決する。 （Ａ）イソシアネート基末端プレポリマー： 　ヘキサメチレンジイソシアネートと分子量５００以下の側鎖アルキル基含有グリコールとを反応させる工程を経て得られるイソシアネート基末端プレポリマー。 （Ｂ）ポリエステルポリオール： 　トリメチロールプロパン、３－メチル－１，５－ペンタンジオール、アジピン酸から得られる、平均官能基数＝２．５～３．５、数平均分子量８００～５，０００ポリエステルポリオール。
PCT/JP2008/000583 2007-03-16 2008-03-14 無黄変低硬度ポリウレタンエラストマー形成性組成物、及びそれを用いた無黄変低硬度ポリウレタンエラストマーの製造方法 Ceased WO2008114500A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1020097019007A KR101118979B1 (ko) 2007-03-16 2008-03-14 무황변 저경도 폴리우레탄 엘라스토머 형성성 조성물, 및 이를 사용한 무황변 저경도 폴리우레탄 엘라스토머의 제조 방법
US12/531,511 US20100087617A1 (en) 2007-03-16 2008-03-14 Composition capable of forming yellowing-free, low-hardness polyurethane elastomer, and method for producing yellowing-free, low-hardness polyurethane elastomer using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-067698 2007-03-16
JP2007067698A JP5517093B2 (ja) 2007-03-16 2007-03-16 無黄変低硬度ポリウレタンエラストマー形成性組成物、及びそれを用いた無黄変低硬度ポリウレタンエラストマーの製造方法

Publications (1)

Publication Number Publication Date
WO2008114500A1 true WO2008114500A1 (ja) 2008-09-25

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ID=39765619

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PCT/JP2008/000583 Ceased WO2008114500A1 (ja) 2007-03-16 2008-03-14 無黄変低硬度ポリウレタンエラストマー形成性組成物、及びそれを用いた無黄変低硬度ポリウレタンエラストマーの製造方法

Country Status (4)

Country Link
US (1) US20100087617A1 (ja)
JP (1) JP5517093B2 (ja)
KR (1) KR101118979B1 (ja)
WO (1) WO2008114500A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012090385A1 (ja) * 2010-12-28 2012-07-05 キヤノン株式会社 現像ローラ、プロセスカートリッジ及び電子写真装置

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5317019B2 (ja) * 2009-10-02 2013-10-16 日本ポリウレタン工業株式会社 低硬度ポリウレタンエラストマー形成性組成物及び粘着シート
JP5381595B2 (ja) * 2009-10-08 2014-01-08 Ｄｉｃ株式会社 超低硬度熱硬化性ポリウレタンエラストマー形成組成物、及びそれを用いたゲル状物
JP6439237B2 (ja) * 2013-06-19 2018-12-19 Dic株式会社 新規ポリエステルポリウレタンポリオール、２液型ラミネート接着剤用ポリオール剤、樹脂組成物、硬化性樹脂組成物、２液型ラミネート用接着剤、及び太陽電池用バックシート
WO2015112528A1 (en) * 2014-01-22 2015-07-30 Sun Chemical Corporation Urethane-compatible polyester adhesion promoters
JP6902918B2 (ja) * 2017-04-28 2021-07-14 第一工業製薬株式会社 ポリウレタン樹脂用ポリオール組成物、ポリウレタン樹脂形成性組成物、複合材料

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09151230A (ja) * 1995-11-29 1997-06-10 Nippon Polyurethane Ind Co Ltd ２液注型用ポリウレタンエラストマー組成物、及び該組成物を用いたポリウレタンエラストマーの製造法
JP2004091768A (ja) * 2002-07-12 2004-03-25 Nippon Polyurethane Ind Co Ltd エラストマー形成性組成物、エラストマーシートの製造方法、複合シートの製造方法、建築工事用シートの製造方法
JP2004256779A (ja) * 2003-02-28 2004-09-16 Nippon Polyurethane Ind Co Ltd ウレタンエラストマー形成性組成物、印刷ロールおよびその製造方法
JP2004263108A (ja) * 2003-03-03 2004-09-24 Nippon Polyurethane Ind Co Ltd ウレタンエラストマー形成性組成物およびシール材
JP2004323707A (ja) * 2003-04-25 2004-11-18 Toyo Ink Mfg Co Ltd 成型加工用シート、成型加工用粘着シート、およびそれらを用いて製造される着色成型体
JP2005068286A (ja) * 2003-08-25 2005-03-17 Nippon Polyurethane Ind Co Ltd エラストマー形成性組成物、エラストマーシートの製造方法、複合シートの製造方法、建築工事用シートの製造方法
JP2005132934A (ja) * 2003-10-30 2005-05-26 Nippon Polyurethane Ind Co Ltd 硬化性ポリウレタン樹脂組成物及び該組成物から成る成型品

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09151230A (ja) * 1995-11-29 1997-06-10 Nippon Polyurethane Ind Co Ltd ２液注型用ポリウレタンエラストマー組成物、及び該組成物を用いたポリウレタンエラストマーの製造法
JP2004091768A (ja) * 2002-07-12 2004-03-25 Nippon Polyurethane Ind Co Ltd エラストマー形成性組成物、エラストマーシートの製造方法、複合シートの製造方法、建築工事用シートの製造方法
JP2004256779A (ja) * 2003-02-28 2004-09-16 Nippon Polyurethane Ind Co Ltd ウレタンエラストマー形成性組成物、印刷ロールおよびその製造方法
JP2004263108A (ja) * 2003-03-03 2004-09-24 Nippon Polyurethane Ind Co Ltd ウレタンエラストマー形成性組成物およびシール材
JP2004323707A (ja) * 2003-04-25 2004-11-18 Toyo Ink Mfg Co Ltd 成型加工用シート、成型加工用粘着シート、およびそれらを用いて製造される着色成型体
JP2005068286A (ja) * 2003-08-25 2005-03-17 Nippon Polyurethane Ind Co Ltd エラストマー形成性組成物、エラストマーシートの製造方法、複合シートの製造方法、建築工事用シートの製造方法
JP2005132934A (ja) * 2003-10-30 2005-05-26 Nippon Polyurethane Ind Co Ltd 硬化性ポリウレタン樹脂組成物及び該組成物から成る成型品

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012090385A1 (ja) * 2010-12-28 2012-07-05 キヤノン株式会社 現像ローラ、プロセスカートリッジ及び電子写真装置
US8660472B2 (en) 2010-12-28 2014-02-25 Canon Kabushiki Kaisha Developing roller, process cartridge, and electrophotographic apparatus

Also Published As

Publication number Publication date
US20100087617A1 (en) 2010-04-08
KR101118979B1 (ko) 2012-03-13
KR20090118973A (ko) 2009-11-18
JP2008222984A (ja) 2008-09-25
JP5517093B2 (ja) 2014-06-11

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