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WO2008111653A1 - ブラシ状カーボンナノ構造物製造用触媒体、触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法 - Google Patents

ブラシ状カーボンナノ構造物製造用触媒体、触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法 Download PDF

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Publication number
WO2008111653A1
WO2008111653A1 PCT/JP2008/054672 JP2008054672W WO2008111653A1 WO 2008111653 A1 WO2008111653 A1 WO 2008111653A1 JP 2008054672 W JP2008054672 W JP 2008054672W WO 2008111653 A1 WO2008111653 A1 WO 2008111653A1
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WO
WIPO (PCT)
Prior art keywords
brush
carbon nanostructure
shaped carbon
producing
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/054672
Other languages
English (en)
French (fr)
Inventor
Yoshikazu Nakayama
Toru Sakai
Takeshi Nagasaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Sanso Holdings Corp
Osaka Metropolitan University
Original Assignee
Osaka Prefecture University PUC
Nippon Sanso Holdings Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osaka Prefecture University PUC, Nippon Sanso Holdings Corp filed Critical Osaka Prefecture University PUC
Priority to JP2009504088A priority Critical patent/JP5409345B2/ja
Priority to US12/450,171 priority patent/US8034738B2/en
Priority to PCT/JP2008/066576 priority patent/WO2009113195A1/ja
Priority to JP2010502690A priority patent/JPWO2009113195A1/ja
Publication of WO2008111653A1 publication Critical patent/WO2008111653A1/ja
Anticipated expiration legal-status Critical
Priority to US13/224,115 priority patent/US8530374B2/en
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/34—Length
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/524—Spinel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

　本発明は、ロープ状ＣＮＴ等のＣＮＴ集合体の作製に利用することができる高密度なブラシ状カーボンナノ構造物を高効率に製造すること及びその製造を可能にするブラシ状カーボンナノ構造物製造用触媒体を提供することを目的とする。本発明は、基体３２と前記基体表面に形成された反応防止層３４と前記反応防止層３４上の触媒層から構成され、前記触媒層が触媒金属を主成分とする金属系触媒粒子４２からなる触媒粒子層４４であり、前記金属系触媒粒子４２の平均粒径Ｄが０．５ｎｍ≦Ｄ≦８０ｎｍの範囲にあり、前記金属系触媒粒子４２の個々の粒径ｄが前記平均粒径Ｄの範囲内にあるブラシ状カーボンナノ構造物製造用触媒体並びに触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法である。
PCT/JP2008/054672 2007-03-14 2008-03-13 ブラシ状カーボンナノ構造物製造用触媒体、触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法 Ceased WO2008111653A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2009504088A JP5409345B2 (ja) 2007-03-14 2008-03-13 ブラシ状カーボンナノ構造物製造用触媒体、その製造方法及びブラシ状カーボンナノ構造物製造方法
US12/450,171 US8034738B2 (en) 2007-03-14 2008-03-13 Process for producing catalyst body for production of brush-shaped carbon nanostructure
PCT/JP2008/066576 WO2009113195A1 (ja) 2008-03-13 2008-09-12 ブラシ状カーボンナノ構造物製造用触媒体、触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法
JP2010502690A JPWO2009113195A1 (ja) 2007-03-14 2008-09-12 ブラシ状カーボンナノ構造物製造用触媒体、触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法
US13/224,115 US8530374B2 (en) 2007-03-14 2011-09-01 Catalyst body for production of brush-shaped carbon nanostructure

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-064929 2007-03-14
JP2007064929 2007-03-14

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/450,171 A-371-Of-International US8034738B2 (en) 2007-03-14 2008-03-13 Process for producing catalyst body for production of brush-shaped carbon nanostructure
US13/224,115 Division US8530374B2 (en) 2007-03-14 2011-09-01 Catalyst body for production of brush-shaped carbon nanostructure

Publications (1)

Publication Number Publication Date
WO2008111653A1 true WO2008111653A1 (ja) 2008-09-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/054672 Ceased WO2008111653A1 (ja) 2007-03-14 2008-03-13 ブラシ状カーボンナノ構造物製造用触媒体、触媒体製造方法、ブラシ状カーボンナノ構造物及びその製法

Country Status (3)

Country Link
US (2) US8034738B2 (ja)
JP (2) JP5409345B2 (ja)
WO (1) WO2008111653A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010106983A1 (ja) * 2009-03-14 2010-09-23 大陽日酸株式会社 配向カーボンナノチューブ連続合成方法及び同連続合成装置
JP2011207724A (ja) * 2010-03-30 2011-10-20 Taiyo Nippon Sanso Corp ロープ状炭素構造物製造用配向カーボンナノチューブ、ロープ状炭素構造物及びその製法
JP2012166988A (ja) * 2011-02-15 2012-09-06 Taiyo Nippon Sanso Corp Ｃｎｔ製造用の四層型触媒基体、基板炭化層付きｃｎｔ、炭化層付きｃｎｔ、ｃｎｔ製法、ｃｎｔ回収方法及びｃｎｔ連続製造装置
JP2012224507A (ja) * 2011-04-20 2012-11-15 Fujitsu Ltd カーボンナノチューブの形成方法及び熱拡散装置
JP2021529716A (ja) * 2019-09-23 2021-11-04 大連理工大学 複数の小サイズ触媒からなる複合触媒に基づいて高純度カーボンナノコイルを合成する方法
WO2023074167A1 (ja) * 2021-10-29 2023-05-04 三菱重工業株式会社 微細金属粒子の製造方法
WO2023189197A1 (ja) * 2022-03-30 2023-10-05 三菱重工業株式会社 微細金属粒子の製造方法

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JP5924725B2 (ja) * 2011-11-14 2016-05-25 ヤマハ株式会社 歪みセンサ及び歪みセンサの製造方法
JP6014906B2 (ja) 2013-05-10 2016-10-26 ヤマハ株式会社 歪みセンサ
WO2016129774A1 (ko) * 2015-02-12 2016-08-18 에스케이이노베이션 주식회사 수직배향 탄소 나노 튜브 집합체의 제조방법
US10285218B1 (en) * 2018-05-14 2019-05-07 The Florida International University Board Of Trustees Direct and selective area synthesis of graphene using microheater elements
WO2022035142A1 (ko) * 2020-08-12 2022-02-17 주식회사 엘지화학 저밀도 탄소나노튜브 및 이를 포함하는 복합재

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010106983A1 (ja) * 2009-03-14 2010-09-23 大陽日酸株式会社 配向カーボンナノチューブ連続合成方法及び同連続合成装置
JP2010215437A (ja) * 2009-03-14 2010-09-30 Taiyo Nippon Sanso Corp 配向カーボンナノチューブ連続合成方法及び同連続合成装置
JP2011207724A (ja) * 2010-03-30 2011-10-20 Taiyo Nippon Sanso Corp ロープ状炭素構造物製造用配向カーボンナノチューブ、ロープ状炭素構造物及びその製法
JP2012166988A (ja) * 2011-02-15 2012-09-06 Taiyo Nippon Sanso Corp Ｃｎｔ製造用の四層型触媒基体、基板炭化層付きｃｎｔ、炭化層付きｃｎｔ、ｃｎｔ製法、ｃｎｔ回収方法及びｃｎｔ連続製造装置
JP2012224507A (ja) * 2011-04-20 2012-11-15 Fujitsu Ltd カーボンナノチューブの形成方法及び熱拡散装置
JP2021529716A (ja) * 2019-09-23 2021-11-04 大連理工大学 複数の小サイズ触媒からなる複合触媒に基づいて高純度カーボンナノコイルを合成する方法
JP7008373B2 (ja) 2019-09-23 2022-01-25 大連理工大学 複数の小サイズ触媒からなる複合触媒に基づいて高純度カーボンナノコイルを合成する方法
WO2023074167A1 (ja) * 2021-10-29 2023-05-04 三菱重工業株式会社 微細金属粒子の製造方法
JP2023066934A (ja) * 2021-10-29 2023-05-16 三菱重工業株式会社 微細金属粒子の製造方法
JP7291191B2 (ja) 2021-10-29 2023-06-14 三菱重工業株式会社 微細金属粒子の製造方法
WO2023189197A1 (ja) * 2022-03-30 2023-10-05 三菱重工業株式会社 微細金属粒子の製造方法
JP2023147875A (ja) * 2022-03-30 2023-10-13 三菱重工業株式会社 微細金属粒子の製造方法
JP7469354B2 (ja) 2022-03-30 2024-04-16 三菱重工業株式会社 微細金属粒子の製造方法

Also Published As

Publication number Publication date
JP5409345B2 (ja) 2014-02-05
US8530374B2 (en) 2013-09-10
US20100074833A1 (en) 2010-03-25
US20110319260A1 (en) 2011-12-29
JPWO2008111653A1 (ja) 2010-06-24
US8034738B2 (en) 2011-10-11
JPWO2009113195A1 (ja) 2011-07-21

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