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WO2008108398A1 - 炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒 - Google Patents

炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒 Download PDF

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Publication number
WO2008108398A1
WO2008108398A1 PCT/JP2008/053934 JP2008053934W WO2008108398A1 WO 2008108398 A1 WO2008108398 A1 WO 2008108398A1 JP 2008053934 W JP2008053934 W JP 2008053934W WO 2008108398 A1 WO2008108398 A1 WO 2008108398A1
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WO
WIPO (PCT)
Prior art keywords
organic compound
oxidation
hydrocarbon
producing
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/053934
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English (en)
French (fr)
Inventor
Shigeo Ooyama
Xiaoming Zhang
Jiqing Lu
Juan Jose Bravo Suarez
Kyoko Bando
Zhaoxia Song
Susumu Tsubota
Tadahiro Fujitani
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National Institute of Advanced Industrial Science and Technology AIST
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National Institute of Advanced Industrial Science and Technology AIST
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Priority to JP2009502604A priority Critical patent/JP5017619B2/ja
Publication of WO2008108398A1 publication Critical patent/WO2008108398A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/618—Surface area more than 1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　　高い触媒安定性に加えて、高い原料転化率を可能とした、含酸素有機化合物を製造する方法を提供する。 　酸素源と還元剤を含む反応流体により炭化水素を酸化して、含酸素有機化合物を製造する方法において、メソ細孔構造を有する壁材がミクロ細孔構造を有するチタノシリケートの種結晶を含有する担体、いわゆるミクロ－メソハイブリッド担体を用い、これに微細な金粒子を担持させたものを触媒とすることにより、原料転化率の向上と、触媒寿命の向上の両方を達成する。
PCT/JP2008/053934 2007-03-05 2008-03-05 炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒 Ceased WO2008108398A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009502604A JP5017619B2 (ja) 2007-03-05 2008-03-05 炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-054711 2007-03-05
JP2007054711 2007-03-05

Publications (1)

Publication Number Publication Date
WO2008108398A1 true WO2008108398A1 (ja) 2008-09-12

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ID=39738271

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PCT/JP2008/053934 Ceased WO2008108398A1 (ja) 2007-03-05 2008-03-05 炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒

Country Status (2)

Country Link
JP (1) JP5017619B2 (ja)
WO (1) WO2008108398A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008230876A (ja) * 2007-03-19 2008-10-02 Toyota Central R&D Labs Inc メソ孔及びマイクロ孔を有する金属酸化物多孔体の製造方法、メソ孔及びマイクロ孔を有する金属酸化物多孔体及びそれを用いたガス浄化材料
JP2010536819A (ja) * 2007-08-20 2010-12-02 チュールム ベタイリグングスゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー パテンテ ツヴァイ コマンディートゲゼルシャフト 均質な気相中でオレフィンの酸化によりエポキシドを効率的に製造する方法
WO2011051643A1 (en) * 2009-10-29 2011-05-05 Dow Global Technologies Inc. Selective catalytic oxidation of c1-c3 alkanes

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1176820A (ja) * 1997-09-05 1999-03-23 Agency Of Ind Science & Technol 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
JP2002541127A (ja) * 1999-04-08 2002-12-03 ザ ダウ ケミカル カンパニー 酸化された金触媒を使用してオレフィンをオレフィンオキシドにハイドロ酸化するための方法
JP2005053808A (ja) * 2003-08-01 2005-03-03 Kansai Tlo Kk メタロシリケート光触媒を用いた有機化合物の製造方法
JP2006081988A (ja) * 2004-09-15 2006-03-30 Ne Chemcat Corp 排ガス浄化用チタニア系酸化触媒、排ガス浄化用触媒構造体および排ガス浄化方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1176820A (ja) * 1997-09-05 1999-03-23 Agency Of Ind Science & Technol 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
JP2002541127A (ja) * 1999-04-08 2002-12-03 ザ ダウ ケミカル カンパニー 酸化された金触媒を使用してオレフィンをオレフィンオキシドにハイドロ酸化するための方法
JP2005053808A (ja) * 2003-08-01 2005-03-03 Kansai Tlo Kk メタロシリケート光触媒を用いた有機化合物の製造方法
JP2006081988A (ja) * 2004-09-15 2006-03-30 Ne Chemcat Corp 排ガス浄化用チタニア系酸化触媒、排ガス浄化用触媒構造体および排ガス浄化方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008230876A (ja) * 2007-03-19 2008-10-02 Toyota Central R&D Labs Inc メソ孔及びマイクロ孔を有する金属酸化物多孔体の製造方法、メソ孔及びマイクロ孔を有する金属酸化物多孔体及びそれを用いたガス浄化材料
JP2010536819A (ja) * 2007-08-20 2010-12-02 チュールム ベタイリグングスゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー パテンテ ツヴァイ コマンディートゲゼルシャフト 均質な気相中でオレフィンの酸化によりエポキシドを効率的に製造する方法
WO2011051643A1 (en) * 2009-10-29 2011-05-05 Dow Global Technologies Inc. Selective catalytic oxidation of c1-c3 alkanes

Also Published As

Publication number Publication date
JP5017619B2 (ja) 2012-09-05
JPWO2008108398A1 (ja) 2010-06-17

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