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WO2008102729A1 - α－オレフィン重合体及びその製造方法 - Google Patents

α－オレフィン重合体及びその製造方法 Download PDF

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Publication number
WO2008102729A1
WO2008102729A1 PCT/JP2008/052662 JP2008052662W WO2008102729A1 WO 2008102729 A1 WO2008102729 A1 WO 2008102729A1 JP 2008052662 W JP2008052662 W JP 2008052662W WO 2008102729 A1 WO2008102729 A1 WO 2008102729A1
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WO
WIPO (PCT)
Prior art keywords
molecular weight
olefin
melting
melting peak
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/052662
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English (en)
French (fr)
Inventor
Takenori Fujimura
Masami Kanamaru
Yutaka Minami
Takuji Okamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Priority to US12/526,978 priority Critical patent/US8178635B2/en
Priority to CN200880005405.7A priority patent/CN101616938B/zh
Priority to JP2009500172A priority patent/JP5379677B2/ja
Priority to EP08711486.4A priority patent/EP2113521B1/en
Publication of WO2008102729A1 publication Critical patent/WO2008102729A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

炭素数２０～４０のα－オレフィン一種以上の重合体であって、（１）ＧＰＣ法により測定したポリスチレン換算の重量平均分子量（Ｍｗ）と数平均分子量（Ｍｎ）から求めた分子量分布（Ｍｗ／Ｍｎ）が２以下、かつＭｗが５０００以下であり、（２）ＤＳＣによる融点（Ｔｍ）測定において得られる融解ピークが一つであり、該融解ピークの面積から計算される融解吸熱量（ΔＨ）が２０Ｊ／ｇ以上、かつ半値幅が１０°C以下であり、（３）Ｍｗ　１０００～５０００、平均炭素数（Ｃｎ）２０～４０において、ＭｗとＣｎと、ＤＳＣで測定したＴｍとが、０．００２５×Ｍｗ＋（Ｃｎ×３．３８１２－２９．５）≦Ｔｍ≦０．００２５×Ｍｗ＋（（Ｃｎ＋１）×３．３８１２－２９．５）を満たし、（４）炭素数２０～４０のα－オレフィン連鎖部に由来する立体規則性指標値［Ｍ2］が２０モル％以上である、分子量と融点のバランスに優れたα－オレフィン重合体を提供する。
PCT/JP2008/052662 2007-02-19 2008-02-18 α－オレフィン重合体及びその製造方法 Ceased WO2008102729A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/526,978 US8178635B2 (en) 2007-02-19 2008-02-18 α-Olefin polymer and process for production thereof
CN200880005405.7A CN101616938B (zh) 2007-02-19 2008-02-18 α-链烯烃聚合物及其制备方法
JP2009500172A JP5379677B2 (ja) 2007-02-19 2008-02-18 α−オレフィン重合体及びその製造方法
EP08711486.4A EP2113521B1 (en) 2007-02-19 2008-02-18 Alpha-olefin polymer and process for production thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007038044 2007-02-19
JP2007-038044 2007-02-19

Publications (1)

Publication Number Publication Date
WO2008102729A1 true WO2008102729A1 (ja) 2008-08-28

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ID=39710006

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PCT/JP2008/052662 Ceased WO2008102729A1 (ja) 2007-02-19 2008-02-18 α－オレフィン重合体及びその製造方法

Country Status (6)

Country Link
US (1) US8178635B2 (ja)
EP (1) EP2113521B1 (ja)
JP (1) JP5379677B2 (ja)
CN (1) CN101616938B (ja)
TW (1) TW200848434A (ja)
WO (1) WO2008102729A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010117028A1 (ja) * 2009-04-10 2010-10-14 出光興産株式会社 αオレフィンオリゴマーおよびその製造方法
WO2011004676A1 (ja) * 2009-07-08 2011-01-13 出光興産株式会社 重合触媒及びその保存方法
JP2011236410A (ja) * 2010-04-12 2011-11-24 Sankyo Kasei Kk 植物系樹脂ペレット及びその製造方法並びに植物系樹脂材料による射出成形装置
WO2012035710A1 (ja) * 2010-09-16 2012-03-22 出光興産株式会社 高粘度高級アルファオレフィン重合体及びその製造方法
JP2012112536A (ja) * 2010-11-19 2012-06-14 Panasonic Corp 蓄熱装置およびこれを備える空気調和装置
WO2013031779A1 (ja) * 2011-09-01 2013-03-07 出光興産株式会社 α－オレフィン重合体の製造方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012214662A1 (de) * 2012-08-17 2014-02-20 Henkel Ag & Co. Kgaa Kosmetische Zusammensetzungen mit zeitverzögerter Wirkstofffreisetzung
EP3191497B1 (en) 2014-09-10 2023-05-03 SABIC Global Technologies B.V. Boron-bridged 2-indenyl metallocene complexes for olefin polymerization
US11732071B2 (en) 2018-05-04 2023-08-22 Lg Chem, Ltd. Olefin-based copolymer and method for preparing the same
CN116655676B (zh) * 2022-02-18 2025-08-29 中国石油天然气股份有限公司 一种非茂金属催化剂、聚丁烯-1弹性体及其制备方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03100004A (ja) 1989-09-07 1991-04-25 Hoechst Ag ポリオレフィンワックスの製法
JPH05222120A (ja) 1992-02-10 1993-08-31 Mitsui Petrochem Ind Ltd カチオン重合触媒およびオレフィンのカチオン重合法
JPH06293805A (ja) 1992-12-15 1994-10-21 Hoechst Ag ポリオレフィン−ワックスの製造方法
JPH06345809A (ja) 1993-06-07 1994-12-20 Mitsui Petrochem Ind Ltd 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
JPH07507352A (ja) 1992-05-26 1995-08-10 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド 反応性で低分子量の粘性ポリ（１−オレフィン）及びコポリ（１−オレフィン）、及びそれらの製造方法
JP2000159832A (ja) 1998-11-30 2000-06-13 Bp Amoco Corp オリゴマ―化方法
JP2001335607A (ja) * 2000-05-30 2001-12-04 Idemitsu Petrochem Co Ltd α−オレフィン重合体の製造方法及び潤滑油
WO2003070790A1 (en) * 2002-02-21 2003-08-28 Idemitsu Petrochemical Co., Ltd. CRYSTALLINE POLYMER OF HIGHER α-OLEFIN AND PROCESS FOR PRODUCING THE SAME
JP2005075908A (ja) 2003-08-29 2005-03-24 Idemitsu Kosan Co Ltd 高級α−オレフィン共重合体及びその製造方法
WO2005073242A1 (ja) 2004-01-28 2005-08-11 Idemitsu Kosan Co., Ltd. 遷移金属化合物及びオレフィン重合用触媒

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3100004B2 (ja) 1992-08-04 2000-10-16 株式会社日立製作所 脱水機の脱水槽
JP4902099B2 (ja) * 2003-10-09 2012-03-21 出光興産株式会社 極性基含有高級オレフィン重合体及びその製造方法
EP1681333B1 (en) * 2003-10-29 2010-04-21 Idemitsu Kosan Co., Ltd. Heat-storage material composition
JP5064662B2 (ja) * 2005-06-15 2012-10-31 出光興産株式会社 α−オレフィン重合体変性物及びその架橋体の製造方法
CN101312993A (zh) * 2005-11-30 2008-11-26 出光兴产株式会社 高结晶性高级α-烯烃类聚合物及其制造方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03100004A (ja) 1989-09-07 1991-04-25 Hoechst Ag ポリオレフィンワックスの製法
JPH05222120A (ja) 1992-02-10 1993-08-31 Mitsui Petrochem Ind Ltd カチオン重合触媒およびオレフィンのカチオン重合法
JPH07507352A (ja) 1992-05-26 1995-08-10 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド 反応性で低分子量の粘性ポリ（１−オレフィン）及びコポリ（１−オレフィン）、及びそれらの製造方法
JPH06293805A (ja) 1992-12-15 1994-10-21 Hoechst Ag ポリオレフィン−ワックスの製造方法
JPH06345809A (ja) 1993-06-07 1994-12-20 Mitsui Petrochem Ind Ltd 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
JP2000159832A (ja) 1998-11-30 2000-06-13 Bp Amoco Corp オリゴマ―化方法
JP2001335607A (ja) * 2000-05-30 2001-12-04 Idemitsu Petrochem Co Ltd α−オレフィン重合体の製造方法及び潤滑油
WO2003070790A1 (en) * 2002-02-21 2003-08-28 Idemitsu Petrochemical Co., Ltd. CRYSTALLINE POLYMER OF HIGHER α-OLEFIN AND PROCESS FOR PRODUCING THE SAME
JP2005075908A (ja) 2003-08-29 2005-03-24 Idemitsu Kosan Co Ltd 高級α−オレフィン共重合体及びその製造方法
WO2005073242A1 (ja) 2004-01-28 2005-08-11 Idemitsu Kosan Co., Ltd. 遷移金属化合物及びオレフィン重合用触媒

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* Cited by examiner, † Cited by third party
Title
"The Japan Society for Analytical Chemistry", THE SOCIAL GATHERING FOR POLYMER ANALYSIS AND RESEARCH, article "New Polymer Analysis Handbook"
J. ORGANOMET. CHEM, vol. 369, 1989, pages 359
See also references of EP2113521A4

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010117028A1 (ja) * 2009-04-10 2010-10-14 出光興産株式会社 αオレフィンオリゴマーおよびその製造方法
CN102388072A (zh) * 2009-04-10 2012-03-21 出光兴产株式会社 α烯烃低聚物及其制造方法
WO2011004676A1 (ja) * 2009-07-08 2011-01-13 出光興産株式会社 重合触媒及びその保存方法
US8975202B2 (en) 2009-07-08 2015-03-10 Idemitsu Kosan Co., Ltd. Polymerization catalysts and method for preservation of same
JP2011236410A (ja) * 2010-04-12 2011-11-24 Sankyo Kasei Kk 植物系樹脂ペレット及びその製造方法並びに植物系樹脂材料による射出成形装置
WO2012035710A1 (ja) * 2010-09-16 2012-03-22 出光興産株式会社 高粘度高級アルファオレフィン重合体及びその製造方法
JP2012112536A (ja) * 2010-11-19 2012-06-14 Panasonic Corp 蓄熱装置およびこれを備える空気調和装置
WO2013031779A1 (ja) * 2011-09-01 2013-03-07 出光興産株式会社 α－オレフィン重合体の製造方法

Also Published As

Publication number Publication date
EP2113521A1 (en) 2009-11-04
CN101616938A (zh) 2009-12-30
US8178635B2 (en) 2012-05-15
EP2113521B1 (en) 2013-04-10
EP2113521A4 (en) 2010-08-04
CN101616938B (zh) 2012-08-15
JP5379677B2 (ja) 2013-12-25
JPWO2008102729A1 (ja) 2010-05-27
TW200848434A (en) 2008-12-16
US20100036066A1 (en) 2010-02-11

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